Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides?
Abstract
Starting generally with a 4:6:3 molar ratio of Pt, Sn, and R (where R = La–Sm), with or without the application of a NaCl flux, seven ternary compounds were obtained as single crystals. The platinides Pt4Sn6R3 (R = La–Nd) crystallize with the Pt4Ge6Pr3 type of structure (oP52, Pnma, a = 27.6–27.8 Å, b = 4.59–4.64 Å, c = 9.33–9.40 Å). With R = Pr, Pt4Sn6Pr3–x (oP52, Pnma, a = 7.2863(3) Å, b = 4.4909(2) Å, c = 35.114(1) Å) is also obtained, which might be considered a high-temperature polymorph with disorder on the Sn- and Pr-sites. For R = Nd and Sm, a structurally related isostructural series with a slightly different composition Pt3Sn5R2–x (oP52, Cmc21, a = 4.50–4.51 Å, b = 26.14–26.30 Å, c ≈ 7.29 Å) has been observed, together with Pt7Sn9Sm5 (oS42, Amm2, a = 4.3289(5) Å, b = 28.798(4) Å, c = 7.2534(9) Å) under the same conditions. The latter exhibits the rare Zr5Pd9P7-type structure, linking polar intermetallics to metal phosphides, in accord with P7Pd9Zr5≡Pt7Sn9Sm5. Finally, all structures may be described in terms of either negative Pt/Sn networks encapsulating positive R atoms, or {PtSnx} clusters (x = 5, 6, or rarely 7) sharing vertices and edges withmore »
- Authors:
-
[2];
[2];
[3];
[1]
- Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States, Ames Laboratory, USDOE, Iowa State University, Ames, Iowa 50011, United States
- Ames Laboratory, USDOE, Iowa State University, Ames, Iowa 50011, United States, Department of Materials and Environmental Chemistry, Stockholm University, Svante Arrhenius väg 16 C, 10691 Stockholm, Sweden
- Ames Laboratory, USDOE, Iowa State University, Ames, Iowa 50011, United States, Department of Materials and Environmental Chemistry, Stockholm University, Svante Arrhenius väg 16 C, 10691 Stockholm, Sweden, Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011, United States
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1617547
- Alternate Identifier(s):
- OSTI ID: 1630910
- Report Number(s):
- IS-J-10,218
Journal ID: ISSN 0020-1669
- Grant/Contract Number:
- AC02-07CH11358; 46595
- Resource Type:
- Published Article
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Name: Inorganic Chemistry Journal Volume: 59 Journal Issue: 10; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chemical structure; platinum; cluster chemistry; crystal structure; intermetallics
Citation Formats
Rhodehouse, Melissa L., Smetana, Volodymyr, Celania, Chris, Mudring, Anja-Verena, and Meyer, Gerd H. Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides?. United States: N. p., 2020.
Web. doi:10.1021/acs.inorgchem.0c00884.
Rhodehouse, Melissa L., Smetana, Volodymyr, Celania, Chris, Mudring, Anja-Verena, & Meyer, Gerd H. Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides?. United States. https://doi.org/10.1021/acs.inorgchem.0c00884
Rhodehouse, Melissa L., Smetana, Volodymyr, Celania, Chris, Mudring, Anja-Verena, and Meyer, Gerd H. Thu .
"Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides?". United States. https://doi.org/10.1021/acs.inorgchem.0c00884.
@article{osti_1617547,
title = {Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides?},
author = {Rhodehouse, Melissa L. and Smetana, Volodymyr and Celania, Chris and Mudring, Anja-Verena and Meyer, Gerd H.},
abstractNote = {Starting generally with a 4:6:3 molar ratio of Pt, Sn, and R (where R = La–Sm), with or without the application of a NaCl flux, seven ternary compounds were obtained as single crystals. The platinides Pt4Sn6R3 (R = La–Nd) crystallize with the Pt4Ge6Pr3 type of structure (oP52, Pnma, a = 27.6–27.8 Å, b = 4.59–4.64 Å, c = 9.33–9.40 Å). With R = Pr, Pt4Sn6Pr3–x (oP52, Pnma, a = 7.2863(3) Å, b = 4.4909(2) Å, c = 35.114(1) Å) is also obtained, which might be considered a high-temperature polymorph with disorder on the Sn- and Pr-sites. For R = Nd and Sm, a structurally related isostructural series with a slightly different composition Pt3Sn5R2–x (oP52, Cmc21, a = 4.50–4.51 Å, b = 26.14–26.30 Å, c ≈ 7.29 Å) has been observed, together with Pt7Sn9Sm5 (oS42, Amm2, a = 4.3289(5) Å, b = 28.798(4) Å, c = 7.2534(9) Å) under the same conditions. The latter exhibits the rare Zr5Pd9P7-type structure, linking polar intermetallics to metal phosphides, in accord with P7Pd9Zr5≡Pt7Sn9Sm5. Finally, all structures may be described in terms of either negative Pt/Sn networks encapsulating positive R atoms, or {PtSnx} clusters (x = 5, 6, or rarely 7) sharing vertices and edges with R in the second coordination sphere and with considerable heterometallic Pt–R bonding contributions.},
doi = {10.1021/acs.inorgchem.0c00884},
journal = {Inorganic Chemistry},
number = 10,
volume = 59,
place = {United States},
year = {2020},
month = {5}
}
Free Publicly Available Full Text
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https://doi.org/10.1021/acs.inorgchem.0c00884
https://doi.org/10.1021/acs.inorgchem.0c00884
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Table 1: Crystallographic details and refinement parameters for RxPtySnz (R = La, Ce, Nd, Sm).
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Works referenced in this record:
The Stannides EuPdSn and EuPtSn
journal, June 1996
- Pöttgen, Rainer
- Zeitschrift für Naturforschung B, Vol. 51, Issue 6
Cation-Poor Complex Metallic Alloys in Ba(Eu)–Au–Al(Ga) Systems: Identifying the Keys that Control Structural Arrangements and Atom Distributions at the Atomic Level
journal, October 2015
- Smetana, Volodymyr; Steinberg, Simon; Mudryk, Yaroslav
- Inorganic Chemistry, Vol. 54, Issue 21
The High-Temperature Phases HT-YPtSn, HT-GdPtSn, and HT-TbPtSn
journal, May 2007
- Freerks Riecken, Jan; Heymann, Gunter; Huppertz, Hubert
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 633, Issue 5-6
Three Alkali-Metal–Gold–Gallium Systems. Ternary Tunnel Structures and Some Problems with Poorly Ordered Cations
journal, April 2012
- Smetana, Volodymyr; Miller, Gordon J.; Corbett, John D.
- Inorganic Chemistry, Vol. 51, Issue 14
Crystal structure of the novel compound Ce3Pt4Al6
journal, January 2008
- Tursina, A. I.; Gribanov, A. V.; Bukhan’Ko, N. G.
- Chemistry of Metals and Alloys, Vol. 1, Issue 1
Revisiting Ce 3 Pt 4 Ge 6 – crystal structure and physical properties
journal, January 2016
- Janka, Oliver; Hoffmann, Rolf-Dieter; Eilers-Rethwisch, Matthias
- Inorganic Chemistry Frontiers, Vol. 3, Issue 10
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015
- Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
- Journal of Applied Crystallography, Vol. 48, Issue 1
Four Polyanionic Compounds in the K–Au–Ga System: A Case Study in Exploratory Synthesis and of the Art of Structural Analysis
journal, January 2012
- Smetana, Volodymyr; Corbett, John D.; Miller, Gordon J.
- Inorganic Chemistry, Vol. 51, Issue 3
The stannides YbPtSn and Yb 2 Pt 3 Sn 5
journal, March 1999
- ,
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 214, Issue 3
Novel intermetallic Yb∼3Pt∼4Si6−x (x=0.3) – A disordered variant of the Y3Pt4Ge6-type
journal, September 2013
- Gribanov, Alexander; Rogl, Peter; Grytsiv, Andriy
- Journal of Alloys and Compounds, Vol. 571
Atomic Radii in Crystals
journal, November 1964
- Slater, J. C.
- The Journal of Chemical Physics, Vol. 41, Issue 10
Crystal structure refinement with SHELXL
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
Synthesis, Structure and Properties of the High-pressure Modifications of the Ternary Compounds REPtSn (RE = La, Pr, Sm)
journal, December 2006
- Riecken, Jan F.; Rodewald, Ute Ch.; Heymann, Gunter
- Zeitschrift für Naturforschung B, Vol. 61, Issue 12
Electronic structure and lattice geometry of LaPtSn
journal, August 2004
- Diviš, Martin; Janoušová, Blanka; Rusz, Ján
- Journal of Alloys and Compounds, Vol. 376, Issue 1-2
Crystal structure of the compound Ce3Pt4Ge6
journal, February 1992
- Gribanov, A. V.; Sologub, O. L.; Salamakha, P. S.
- Journal of Alloys and Compounds, Vol. 179, Issue 1-2
Atomic Screening Constants from SCF Functions. II. Atoms with 37 to 86 Electrons
journal, August 1967
- Clementi, E.; Raimondi, D. L.; Reinhardt, W. P.
- The Journal of Chemical Physics, Vol. 47, Issue 4
From the Nonexistent Polar Intermetallic Pt 3 Pr 4 via Pt 2– x Pr 3 to Pt/Sn/Pr Ternaries
journal, April 2018
- Rhodehouse, Melissa L.; Bell, Thomas; Smetana, Volodymyr
- Inorganic Chemistry, Vol. 57, Issue 16
Gold Polar Intermetallics: Structural Versatility through Exclusive Bonding Motifs
journal, October 2017
- Smetana, Volodymyr; Rhodehouse, Melissa; Meyer, Gerd
- Accounts of Chemical Research, Vol. 50, Issue 11
The Stannides La 3 Pd 4 Sn 6 , Ce 3 Pd 4 Sn 6 , and Pr 3 Pd 4 Sn 6 : A New Structure Type with a Complex Three-Dimensional [Pd 4 Sn 6 ] Polyanion
journal, February 2000
- Niepmann, Dirk; Pöttgen, Rainer; Künnen, Bernd
- Chemistry of Materials, Vol. 12, Issue 2
The crystal structure of CeTSn (T Ni, Pd and Pt)
journal, March 1993
- Higashi, Iwami; Kobayashi, Kimiko; Takabatake, Toshiro
- Journal of Alloys and Compounds, Vol. 193, Issue 1-2
A ternary alloy with PbCl2-type structure: TiNiSi(E)
journal, May 1965
- Shoemaker, C. B.; Shoemaker, D. P.
- Acta Crystallographica, Vol. 18, Issue 5
EuNi 5 InH 1.5−x (x = 0–1.5): hydrogen induced structural and magnetic transitions
journal, January 2017
- Bigun, Inna; Smetana, Volodymyr; Mudryk, Yaroslav
- Journal of Materials Chemistry C, Vol. 5, Issue 12
The High-Pressure Modification of CePtSn – Synthesis, Structure, and Magnetic Properties
journal, August 2005
- Riecken, Jan F.; Heymann, Gunter; Soltner, Theresa
- Zeitschrift für Naturforschung B, Vol. 60, Issue 8
Magnetocaloric Behavior in Ternary Europium Indides EuT 5 In: Probing the Design Capability of First-Principles-Based Methods on the Multifaceted Magnetic Materials
journal, November 2016
- Bigun, Inna; Steinberg, Simon; Smetana, Volodymyr
- Chemistry of Materials, Vol. 29, Issue 6
SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
HoPtSn and other intermetallic compounds with the Fe2P-type structure
journal, January 1973
- Dwight, A. E.; Harper, W. C.; Kimball, C. W.
- Journal of the Less Common Metals, Vol. 30, Issue 1
Crystal structure of Y3Pt4Ge6: An intergrowth of BaAl4 and YIrGe2 slabs
journal, December 1990
- Venturini, G.; Malaman, B.
- Journal of the Less Common Metals, Vol. 167, Issue 1
Neue Germanide mit geordneter Ce3Pt4Ge6-Struktur – Die VerbindungenLn3Pt4Ge6 (Ln: Pr–Dy)
journal, June 2006
- Imre, Anette; Hellmann, Andrea; Mewis, Albrecht
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 7
Cluster Complexes as anti-Werner Complexes
journal, December 2008
- Meyer, Gerd
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 634, Issue 15
Spin glass anomalies in HP-NdPtSn—structural, magnetic and specific heat studies
journal, October 2006
- Heymann, Gunter; Rayaprol, Sudhindra; Riecken, Jan F.
- Solid State Sciences, Vol. 8, Issue 10
Structure and properties of Eu 2 Pt 3 Sn 5
journal, July 2009
- Harmening, Thomas; Hermes, Wilfried; Eul, Matthias
- Zeitschrift für Kristallographie, Vol. 224, Issue 7
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.