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Title: Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces

Abstract

The structure and ultrafast dynamics of the electric double layer (EDL) are central to chemical reactivity and physical properties at solid/aqueous interfaces. While the Gouy–Chapman–Stern model is widely used to describe EDLs, it is solely based on the macroscopic electrostatic attraction of electrolytes for the charged surfaces. Structure and dynamics in the Stern layer are, however, more complex because of competing effects due to the localized surface charge distribution, surface–solvent–ion correlations, and the interfacial hydrogen bonding environment. Here, we report combined time-resolved vibrational sum frequency generation (TR-vSFG) spectroscopy with ab initio DFT-based molecular dynamics simulations (AIMD/DFT-MD) to get direct access to the molecular-level understanding of how ions change the structure and dynamics of the EDL. We show that innersphere adsorbed ions tune the hydrophobicity of the silica–aqueous interface by shifting the structural makeup in the Stern layer from dominant water–surface interactions to water–water interactions. This drives an initially inhomogeneous interfacial water coordination landscape observed at the neat interface toward a homogeneous, highly interconnected in-plane 2D hydrogen bonding (2D-HB) network at the ionic interface, reminiscent of the canonical, hydrophobic air–water interface. This ion-induced transformation results in a characteristic decrease of the vibrational lifetime (T1) of excited interfacial O–H stretching modes frommore » T1 ~ 600 fs to T1 ~ 250 fs. Hence, we propose that the T1 determined by TR-vSFG in combination with DFT-MD simulations can be widely used for a quantitative spectroscopic probe of the ion kosmotropic/chaotropic effect at aqueous interfaces as well as of the ion-induced surface hydrophobicity.« less

Authors:
ORCiD logo [1];  [2];  [3];  [3];  [3]; ORCiD logo [3]; ORCiD logo [2]
+ Show Author Affiliations
  1. Temple Univ., Philadelphia, PA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. Temple Univ., Philadelphia, PA (United States)
  3. Univ. Paris-Saclay, Evry (France)
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1617295
Report Number(s):
PNNL-SA-140244
Journal ID: ISSN 0002-7863
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 142; Journal Issue: 15; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Interfaces; Layers; Silica; Molecules; Ions

Citation Formats

Tuladhar, Aashish, Dewan, Shalaka, Pezzotti, Simone, Brigiano, Flavio Siro, Creazzo, Fabrizio, Gaigeot, Marie-Pierre, and Borguet, Eric. Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces. United States: N. p., 2020. Web. doi:10.1021/jacs.9b13273.
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Tuladhar, Aashish, Dewan, Shalaka, Pezzotti, Simone, Brigiano, Flavio Siro, Creazzo, Fabrizio, Gaigeot, Marie-Pierre, & Borguet, Eric. Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces. United States. https://doi.org/10.1021/jacs.9b13273
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Tuladhar, Aashish, Dewan, Shalaka, Pezzotti, Simone, Brigiano, Flavio Siro, Creazzo, Fabrizio, Gaigeot, Marie-Pierre, and Borguet, Eric. Wed . "Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces". United States. https://doi.org/10.1021/jacs.9b13273. https://www.osti.gov/servlets/purl/1617295.
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@article{osti_1617295,
title = {Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces},
author = {Tuladhar, Aashish and Dewan, Shalaka and Pezzotti, Simone and Brigiano, Flavio Siro and Creazzo, Fabrizio and Gaigeot, Marie-Pierre and Borguet, Eric},
abstractNote = {The structure and ultrafast dynamics of the electric double layer (EDL) are central to chemical reactivity and physical properties at solid/aqueous interfaces. While the Gouy–Chapman–Stern model is widely used to describe EDLs, it is solely based on the macroscopic electrostatic attraction of electrolytes for the charged surfaces. Structure and dynamics in the Stern layer are, however, more complex because of competing effects due to the localized surface charge distribution, surface–solvent–ion correlations, and the interfacial hydrogen bonding environment. Here, we report combined time-resolved vibrational sum frequency generation (TR-vSFG) spectroscopy with ab initio DFT-based molecular dynamics simulations (AIMD/DFT-MD) to get direct access to the molecular-level understanding of how ions change the structure and dynamics of the EDL. We show that innersphere adsorbed ions tune the hydrophobicity of the silica–aqueous interface by shifting the structural makeup in the Stern layer from dominant water–surface interactions to water–water interactions. This drives an initially inhomogeneous interfacial water coordination landscape observed at the neat interface toward a homogeneous, highly interconnected in-plane 2D hydrogen bonding (2D-HB) network at the ionic interface, reminiscent of the canonical, hydrophobic air–water interface. This ion-induced transformation results in a characteristic decrease of the vibrational lifetime (T1) of excited interfacial O–H stretching modes from T1 ~ 600 fs to T1 ~ 250 fs. Hence, we propose that the T1 determined by TR-vSFG in combination with DFT-MD simulations can be widely used for a quantitative spectroscopic probe of the ion kosmotropic/chaotropic effect at aqueous interfaces as well as of the ion-induced surface hydrophobicity.},
doi = {10.1021/jacs.9b13273},
journal = {Journal of the American Chemical Society},
number = 15,
volume = 142,
place = {United States},
year = {Wed Apr 01 00:00:00 EDT 2020},
month = {Wed Apr 01 00:00:00 EDT 2020}
}
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https://doi.org/10.1021/jacs.9b13273
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Works referenced in this record:

ATMOSPHERIC SCIENCE: A Matter of Humidity
journal, February 2009

Compensatory water effects link yearly global land CO2 sink changes to temperature
journal, January 2017

  • Jung, Martin; Reichstein, Markus; Schwalm, Christopher R.
  • Nature, Vol. 541, Issue 7638
  • DOI: 10.1038/nature20780

Water is an active matrix of life for cell and molecular biology
journal, June 2017

Putting molecular biology into water
journal, August 1993

Do we underestimate the importance of water in cell biology?
journal, September 2006

  • Chaplin, Martin
  • Nature Reviews Molecular Cell Biology, Vol. 7, Issue 11
  • DOI: 10.1038/nrm2021

Subnanoscale hydrophobic modulation of salt bridges in aqueous media
journal, April 2015

Spectral evidence for hydrated salts in recurring slope lineae on Mars
journal, September 2015

  • Ojha, Lujendra; Wilhelm, Mary Beth; Murchie, Scott L.
  • Nature Geoscience, Vol. 8, Issue 11
  • DOI: 10.1038/ngeo2546

Seasonal Flows on Warm Martian Slopes
journal, August 2011

Surface geochemistry of the clay minerals
journal, March 1999

  • Sposito, G.; Skipper, N. T.; Sutton, R.
  • Proceedings of the National Academy of Sciences, Vol. 96, Issue 7
  • DOI: 10.1073/pnas.96.7.3358

High-resolution mapping of global surface water and its long-term changes
journal, December 2016

  • Pekel, Jean-François; Cottam, Andrew; Gorelick, Noel
  • Nature, Vol. 540, Issue 7633
  • DOI: 10.1038/nature20584

Enhanced water permeability and tunable ion selectivity in subnanometer carbon nanotube porins
journal, August 2017

  • Tunuguntla, Ramya H.; Henley, Robert Y.; Yao, Yun-Chiao
  • Science, Vol. 357, Issue 6353
  • DOI: 10.1126/science.aan2438

Water at Biological and Inorganic Interfaces
journal, August 2013

Water-water correlations in electrolyte solutions probed by hyper-Rayleigh scattering
journal, December 2017

  • Shelton, David P.
  • The Journal of Chemical Physics, Vol. 147, Issue 21
  • DOI: 10.1063/1.4998589

Comment on “Water-water correlations in electrolyte solutions probed by hyper-Rayleigh scattering” [J. Chem. Phys. 147, 214505 (2017)]
journal, October 2018

  • Chen, Y.; Okur, H. I.; Dupertuis, N.
  • The Journal of Chemical Physics, Vol. 149, Issue 16
  • DOI: 10.1063/1.5023579

Study of the pair correlations between p-nitroaniline molecules in solution by depolarized hyper-Rayleigh scattering
journal, May 2012

  • Chan, Y. C.; Wong, K. Y.
  • The Journal of Chemical Physics, Vol. 136, Issue 17
  • DOI: 10.1063/1.4712031

Effects of Ions on Hydrogen-Bonding Water Networks in Large Aqueous Nanodrops
journal, June 2012

  • O’Brien, Jeremy T.; Williams, Evan R.
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja303191r

The Effects of Dissolved Halide Anions on Hydrogen Bonding in Liquid Water
journal, November 2007

  • Smith, Jared D.; Saykally, Richard J.; Geissler, Phillip L.
  • Journal of the American Chemical Society, Vol. 129, Issue 45
  • DOI: 10.1021/ja071933z

Water structure, dynamics, and vibrational spectroscopy in sodium bromide solutions
journal, October 2009

  • Lin, Y. -S.; Auer, B. M.; Skinner, J. L.
  • The Journal of Chemical Physics, Vol. 131, Issue 14
  • DOI: 10.1063/1.3242083

Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water
journal, July 2003

Effect of Surface Charge on the Vibrational Dynamics of Interfacial Water
journal, September 2009

  • Eftekhari-Bafrooei, Ali; Borguet, Eric
  • Journal of the American Chemical Society, Vol. 131, Issue 34
  • DOI: 10.1021/ja903340e

Effect of Electric Fields on the Ultrafast Vibrational Relaxation of Water at a Charged Solid–Liquid Interface as Probed by Vibrational Sum Frequency Generation
journal, May 2011

  • Eftekhari-Bafrooei, Ali; Borguet, Eric
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 12
  • DOI: 10.1021/jz200194e

Beyond the Gouy–Chapman Model with Heterodyne-Detected Second Harmonic Generation
journal, April 2019

  • Ohno, Paul E.; Chang, HanByul; Spencer, Austin P.
  • The Journal of Physical Chemistry Letters, Vol. 10, Issue 10
  • DOI: 10.1021/acs.jpclett.9b00727

Separating the pH-Dependent Behavior of Water in the Stern and Diffuse Layers with Varying Salt Concentration
journal, September 2017

  • Darlington, Akemi M.; Jarisz, Tasha A.; DeWalt-Kerian, Emma L.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 37
  • DOI: 10.1021/acs.jpcc.7b03522

pH-Dependent Inversion of Hofmeister Trends in the Water Structure of the Electrical Double Layer
journal, June 2017

  • DeWalt-Kerian, Emma L.; Kim, Sun; Azam, Md. Shafiul
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 13
  • DOI: 10.1021/acs.jpclett.7b01005

Optical imaging of surface chemistry and dynamics in confinement
journal, July 2017

LI. A contribution to the theory of electrocapillarity
journal, April 1913

  • Chapman, David Leonard
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 25, Issue 148
  • DOI: 10.1080/14786440408634187

The Electrical Double Layer and the Theory of Electrocapillarity.
journal, December 1947

Molecular hydrophobicity at a macroscopically hydrophilic surface
journal, January 2019

  • Cyran, Jenée D.; Donovan, Michael A.; Vollmer, Doris
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 5
  • DOI: 10.1073/pnas.1819000116

Throwing Salt into the Mix: Altering Interfacial Water Structure by Electrolyte Addition
journal, December 2013

  • Covert, Paul A.; Jena, Kailash C.; Hore, Dennis K.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 1
  • DOI: 10.1021/jz402052s

The Effect of Salt on the Water Structure at a Charged Solid Surface: Differentiating Second- and Third-order Nonlinear Contributions
journal, April 2011

  • Jena, Kailash C.; Covert, Paul A.; Hore, Dennis K.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 9
  • DOI: 10.1021/jz200251h

Probing Charged Aqueous Interfaces Near Critical Angles: Effect of Varying Coherence Length
journal, June 2019

The elusive silica/water interface: isolated silanols under water as revealed by vibrational sum frequency spectroscopy
journal, January 2017

  • Dalstein, Laetitia; Potapova, Elizaveta; Tyrode, Eric
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 16
  • DOI: 10.1039/C7CP01507K

Vibrational spectra of water molecules at quartz/water interfaces
journal, January 1994

Experimental Correlation Between Interfacial Water Structure and Mineral Reactivity
journal, May 2013

  • Dewan, Shalaka; Yeganeh, Mohsen S.; Borguet, Eric
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 11
  • DOI: 10.1021/jz4007417

Structures of Water Molecules at the Interfaces of Aqueous Salt Solutions and Silica: Cation Effects
journal, April 2009

  • Yang, Zheng; Li, Qifeng; Chou, Keng C.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 19
  • DOI: 10.1021/jp811517p

Water Structure at the Buried Silica/Aqueous Interface Studied by Heterodyne-Detected Vibrational Sum-Frequency Generation
journal, April 2016

  • Myalitsin, Anton; Urashima, Shu-hei; Nihonyanagi, Satoshi
  • The Journal of Physical Chemistry C, Vol. 120, Issue 17
  • DOI: 10.1021/acs.jpcc.6b03275

Vibrational spectra of water at water/α-quartz (0001) interface
journal, March 2004

Liquid flow along a solid surface reversibly alters interfacial chemistry
journal, June 2014

The Topmost Water Structure at a Charged Silica/Aqueous Interface Revealed by Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy
journal, June 2018

  • Urashima, Shu-hei; Myalitsin, Anton; Nihonyanagi, Satoshi
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 14
  • DOI: 10.1021/acs.jpclett.8b01650

Ultrafast Vibrational Dynamics at Water Interfaces
journal, September 2006

Effect of Hydrogen-Bond Strength on the Vibrational Relaxation of Interfacial Water
journal, March 2010

  • Eftekhari-Bafrooei, Ali; Borguet, Eric
  • Journal of the American Chemical Society, Vol. 132, Issue 11
  • DOI: 10.1021/ja907745r

Unveiling Microscopic Structures of Charged Water Interfaces by Surface-Specific Vibrational Spectroscopy
journal, January 2016

Structural definition of the BIL and DL: a new universal methodology to rationalize non-linear χ (2) ( ω ) SFG signals at charged interfaces, including χ (3) ( ω ) contributions
journal, January 2018

  • Pezzotti, Simone; Galimberti, Daria Ruth; Shen, Y. Ron
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 7
  • DOI: 10.1039/C7CP06110B

The dissolution kinetics of quartz in sodium chloride solutions at 25 degrees to 300 degrees C
journal, June 1994

What the Diffuse Layer (DL) Reveals in Non-Linear SFG Spectroscopy
journal, July 2018

  • Pezzotti, Simone; Galimberti, Daria; Shen, Y.
  • Minerals, Vol. 8, Issue 7
  • DOI: 10.3390/min8070305

Deconvolution of BIL-SFG and DL-SFG spectroscopic signals reveals order/disorder of water at the elusive aqueous silica interface
journal, January 2019

  • Pezzotti, Simone; Galimberti, Daria Ruth; Gaigeot, Marie-Pierre
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 40
  • DOI: 10.1039/C9CP02766A

Phase-referenced nonlinear spectroscopy of the α-quartz/water interface
journal, December 2016

  • Ohno, Paul E.; Saslow, Sarah A.; Wang, Hong-fei
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms13587

Second Harmonic and Sum-Frequency Generation from Aqueous Interfaces Is Modulated by Interference
journal, April 2016

  • Gonella, Grazia; Lütgebaucks, Cornelis; de Beer, Alex G. F.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 17
  • DOI: 10.1021/acs.jpcc.5b12453

Ultrafast Hydrogen-Bond Dynamics in the Infrared Spectroscopy of Water
journal, September 2003

Temperature dependence of vibrational relaxation in liquid H2O
journal, July 2002

  • Lock, A. J.; Bakker, H. J.
  • The Journal of Chemical Physics, Vol. 117, Issue 4
  • DOI: 10.1063/1.1485966

Ultrafast memory loss and energy redistribution in the hydrogen bond network of liquid H2O
journal, March 2005

Linking Surface Potential and Deprotonation in Nanoporous Silica: Second Harmonic Generation and Acid/Base Titration
journal, October 2010

  • Campen, R. Kramer; Pymer, Allison K.; Nihonyanagi, Satoshi
  • The Journal of Physical Chemistry C, Vol. 114, Issue 43
  • DOI: 10.1021/jp1037574

2D H-Bond Network as the Topmost Skin to the Air–Water Interface
journal, June 2017

  • Pezzotti, Simone; Galimberti, Daria Ruth; Gaigeot, Marie-Pierre
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 13
  • DOI: 10.1021/acs.jpclett.7b01257

2D-HB-Network at the air-water interface: A structural and dynamical characterization by means of ab initio and classical molecular dynamics simulations
journal, May 2018

  • Pezzotti, Simone; Serva, Alessandra; Gaigeot, Marie-Pierre
  • The Journal of Chemical Physics, Vol. 148, Issue 17
  • DOI: 10.1063/1.5018096

Hydrophobicity of Hydroxylated Amorphous Fused Silica Surfaces
journal, June 2013

  • Isaienko, Oleksandr; Borguet, Eric
  • Langmuir, Vol. 29, Issue 25
  • DOI: 10.1021/la401259r

Electrolytes at the Hydroxylated (0001) α-Quartz/Water Interface: Location and Structural Effects on Interfacial Silanols by DFT-Based MD
journal, June 2016

  • Pfeiffer-Laplaud, Morgane; Gaigeot, Marie-Pierre
  • The Journal of Physical Chemistry C, Vol. 120, Issue 26
  • DOI: 10.1021/acs.jpcc.6b01819

Adsorption of Singly Charged Ions at the Hydroxylated (0001) α-Quartz/Water Interface
journal, February 2016

  • Pfeiffer-Laplaud, Morgane; Gaigeot, Marie-Pierre
  • The Journal of Physical Chemistry C, Vol. 120, Issue 9
  • DOI: 10.1021/acs.jpcc.5b10947

Sodium Halide Adsorption and Water Structure at the α-Alumina(0001)/Water Interface
journal, June 2019

  • Wang, Ruiyu; DelloStritto, Mark; Remsing, Richard C.
  • The Journal of Physical Chemistry C, Vol. 123, Issue 25
  • DOI: 10.1021/acs.jpcc.9b03054

Combining ab-initio and classical molecular dynamics simulations to unravel the structure of the 2D-HB-network at the air-water interface
journal, August 2018

A New Hypothesis for the Dissolution Mechanism of Silicates
journal, August 2012

  • Kubicki, James D.; Sofo, Jorge O.; Skelton, Adam A.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 33
  • DOI: 10.1021/jp300623v

Effect of Ions on H-Bond Structure and Dynamics at the Quartz(101)–Water Interface
journal, October 2016

Vibrational relaxation of pure liquid water
journal, April 2006

  • Lindner, Jörg; Vöhringer, Peter; Pshenichnikov, Maxim S.
  • Chemical Physics Letters, Vol. 421, Issue 4-6
  • DOI: 10.1016/j.cplett.2006.01.081

Ultrafast Structural Dynamics of Water Induced by Dissipation of Vibrational Energy
journal, February 2007

  • Ashihara, Satoshi; Huse, Nils; Espagne, Agathe
  • The Journal of Physical Chemistry A, Vol. 111, Issue 5
  • DOI: 10.1021/jp0676538

Vibrational Spectroscopy as a Probe of Structure and Dynamics in Liquid Water
journal, March 2010

  • Bakker, H. J.; Skinner, J. L.
  • Chemical Reviews, Vol. 110, Issue 3
  • DOI: 10.1021/cr9001879

Vibrational spectroscopy of HOD in liquid D2O. VI. Intramolecular and intermolecular vibrational energy flow
journal, July 2003

  • Lawrence, C. P.; Skinner, J. L.
  • The Journal of Chemical Physics, Vol. 119, Issue 3
  • DOI: 10.1063/1.1582173

Vibrational energy relaxation of HOD in liquid D 2 O
journal, February 1996

  • Rey, Rossend; Hynes, James T.
  • The Journal of Chemical Physics, Vol. 104, Issue 6
  • DOI: 10.1063/1.470931

Vibrational deactivation of surface OH chemisorbed on SiO 2 : Solvent effects
journal, June 1985

  • Heilweil, E. J.; Casassa, M. P.; Cavanagh, R. R.
  • The Journal of Chemical Physics, Vol. 82, Issue 11
  • DOI: 10.1063/1.448646

Efficient Spectral Diffusion at the Air/Water Interface Revealed by Femtosecond Time-Resolved Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy
journal, May 2016

  • Inoue, Ken-ichi; Ishiyama, Tatsuya; Nihonyanagi, Satoshi
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 10
  • DOI: 10.1021/acs.jpclett.6b00701

Aqueous Heterogeneity at the Air/Water Interface Revealed by 2D-HD-SFG Spectroscopy
journal, June 2014

  • Hsieh, Cho-Shuen; Okuno, Masanari; Hunger, Johannes
  • Angewandte Chemie International Edition, Vol. 53, Issue 31
  • DOI: 10.1002/anie.201402566

Ultrafast vibrational energy transfer at the water/air interface revealed by two-dimensional surface vibrational spectroscopy
journal, October 2011

  • Zhang, Zhen; Piatkowski, Lukasz; Bakker, Huib J.
  • Nature Chemistry, Vol. 3, Issue 11
  • DOI: 10.1038/nchem.1158

Strong frequency dependence of vibrational relaxation in bulk and surface water reveals sub-picosecond structural heterogeneity
journal, September 2015

  • van der Post, Sietse T.; Hsieh, Cho-Shuen; Okuno, Masanari
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9384

Gate-Controlled Sum-Frequency Vibrational Spectroscopy for Probing Charged Oxide/Water Interfaces
journal, August 2019

Structure of Water at Charged Interfaces: A Molecular Dynamics Study
journal, June 2014

  • Dewan, Shalaka; Carnevale, Vincenzo; Bankura, Arindam
  • Langmuir, Vol. 30, Issue 27
  • DOI: 10.1021/la5011055
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