Nanocrystal synthesis, μfluidic sample dilution and direct extraction of single emission linewidths in continuous flow

Lignos, Ioannis; Utzat, Hendrik; Bawendi, Moungi G.; Jensen, Klavs F.

doi:10.1039/D0LC00213E

Title: Nanocrystal synthesis, μfluidic sample dilution and direct extraction of single emission linewidths in continuous flow

Journal Article · 02 June 2020 · Lab on a chip (Print)

DOI: https://doi.org/10.1039/D0LC00213E · OSTI ID:1616630

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Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA, Department of Chemistry
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA

We present a flow-based system coupled with an optical interferometry setup for the extraction of single nanocrystal properties.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-07ER46456

OSTI ID:: 1616630

Journal Information:: Lab on a chip (Print), Journal Name: Lab on a chip (Print) Journal Issue: 11 Vol. 20; ISSN LCAHAM; ISSN 1473-0197

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: France

Language:: English

References (46)

Facile Room‐Temperature Anion Exchange Reactions of Inorganic Perovskite Quantum Dots Enabled by a Modular Microfluidic Platform Abdel‐Latif, Kameel; Epps, Robert W.; Kerr, Corwin B. Advanced Functional Materials, Vol. 29, Issue 23 https://doi.org/10.1002/adfm.201900712	journal	March 2019
In-Situ Microfluidic Study of Biphasic Nanocrystal Ligand-Exchange Reactions Using an Oscillatory Flow Reactor Shen, Yi; Abolhasani, Milad; Chen, Yue Angewandte Chemie International Edition, Vol. 56, Issue 51 https://doi.org/10.1002/anie.201710899	journal	November 2017
Multistage Microfluidic Platform for the Continuous Synthesis of III-V Core/Shell Quantum Dots Baek, Jinyoung; Shen, Yi; Lignos, Ioannis Angewandte Chemie International Edition, Vol. 57, Issue 34 https://doi.org/10.1002/anie.201805264	journal	July 2018
Millisecond-Timescale Monitoring of PbS Nanoparticle Nucleation and Growth Using Droplet-Based Microfluidics Lignos, Ioannis; Stavrakis, Stavros; Kilaj, Ardita Small, Vol. 11, Issue 32 https://doi.org/10.1002/smll.201500119	journal	May 2015
Fluorescence correlation spectroscopy with high count rate and low background: analysis of translational diffusion Rigler, R.; Mets, �.; Widengren, J. European Biophysics Journal, Vol. 22, Issue 3 https://doi.org/10.1007/BF00185777	journal	August 1993
Fluorescence Correlation Spectroscopy: Past, Present, Future Elson, Elliot L. Biophysical Journal, Vol. 101, Issue 12 https://doi.org/10.1016/j.bpj.2011.11.012	journal	December 2011
Hydrodynamic Flow Profiling in Microchannel Structures by Single Molecule Fluorescence Correlation Spectroscopy Gösch, Michael; Blom, Hans; Holm, Johan Analytical Chemistry, Vol. 72, Issue 14 https://doi.org/10.1021/ac991448p	journal	July 2000
Microfluidic Technology: Uncovering the Mechanisms of Nanocrystal Nucleation and Growth Lignos, Ioannis; Maceiczyk, Richard; deMello, Andrew J. Accounts of Chemical Research, Vol. 50, Issue 5 https://doi.org/10.1021/acs.accounts.7b00088	journal	April 2017
Reconceptualizing Fluorescence Correlation Spectroscopy for Monitoring and Analyzing Periodically Passing Objects Zamir, Eli; Frey, Christoph; Weiss, Marian Analytical Chemistry, Vol. 89, Issue 21 https://doi.org/10.1021/acs.analchem.7b03108	journal	October 2017
Oscillatory Microprocessor for Growth and in Situ Characterization of Semiconductor Nanocrystals Abolhasani, Milad; Coley, Connor W.; Xie, Lisi Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02821	journal	August 2015
Mechanistic Insights and Controlled Synthesis of Radioluminescent ZnSe Quantum Dots Using a Microfluidic Reactor Guidelli, Eder Jose; Lignos, Ioannis; Yoo, Jason Jungwan Chemistry of Materials, Vol. 30, Issue 23 https://doi.org/10.1021/acs.chemmater.8b03587	journal	November 2018
Tracking the Fluorescence Lifetimes of Cesium Lead Halide Perovskite Nanocrystals During Their Synthesis Using a Fully Automated Optofluidic Platform Lignos, Ioannis; Maceiczyk, Richard M.; Kovalenko, Maksym V. Chemistry of Materials, Vol. 32, Issue 1 https://doi.org/10.1021/acs.chemmater.9b03438	journal	November 2019
Synthesis of 1 nm Pd Nanoparticles in a Microfluidic Reactor: Insights from in Situ X-ray Absorption Fine Structure Spectroscopy and Small-Angle X-ray Scattering Karim, Ayman M.; Al Hasan, Naila; Ivanov, Sergei The Journal of Physical Chemistry C, Vol. 119, Issue 23 https://doi.org/10.1021/acs.jpcc.5b01681	journal	May 2015
Evolution of the Single-Nanocrystal Photoluminescence Linewidth with Size and Shell: Implications for Exciton–Phonon Coupling and the Optimization of Spectral Linewidths Cui, Jian; Beyler, Andrew P.; Coropceanu, Igor Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b03790	journal	December 2015
Synthesis of Cesium Lead Halide Perovskite Nanocrystals in a Droplet-Based Microfluidic Platform: Fast Parametric Space Mapping Lignos, Ioannis; Stavrakis, Stavros; Nedelcu, Georgian Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b04981	journal	February 2016
PbS Nanocrystal Emission Is Governed by Multiple Emissive States Caram, Justin R.; Bertram, Sophie N.; Utzat, Hendrik Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b02147	journal	September 2016
Probing Linewidths and Biexciton Quantum Yields of Single Cesium Lead Halide Nanocrystals in Solution Utzat, Hendrik; Shulenberger, Katherine E.; Achorn, Odin B. Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b03120	journal	October 2017
Unveiling the Shape Evolution and Halide-Ion-Segregation in Blue-Emitting Formamidinium Lead Halide Perovskite Nanocrystals Using an Automated Microfluidic Platform Lignos, Ioannis; Protesescu, Loredana; Emiroglu, Dilara Börte Nano Letters, Vol. 18, Issue 2 https://doi.org/10.1021/acs.nanolett.7b04838	journal	January 2018
Facile Droplet-based Microfluidic Synthesis of Monodisperse IV–VI Semiconductor Nanocrystals with Coupled In-Line NIR Fluorescence Detection Lignos, Ioannis; Protesescu, Loredana; Stavrakis, Stavros Chemistry of Materials, Vol. 26, Issue 9 https://doi.org/10.1021/cm500774p	journal	April 2014
Flow Synthesis of Biocompatible Fe ₃ O ₄ Nanoparticles: Insight into the Effects of Residence Time, Fluid Velocity, and Tube Reactor Dimension on Particle Size Distribution Jiao, Mingxia; Zeng, Jianfeng; Jing, Lihong Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm504313c	journal	February 2015
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
High-Temperature Microfluidic Synthesis of CdSe Nanocrystals in Nanoliter Droplets Chan, Emory M.; Alivisatos, A. Paul; Mathies, Richard A. Journal of the American Chemical Society, Vol. 127, Issue 40 https://doi.org/10.1021/ja051381p	journal	October 2005
Real-Time Sizing of Nanoparticles in Microfluidic Channels Using Confocal Correlation Spectroscopy Kuyper, Christopher L.; Budzinski, Kristi L.; Lorenz, Robert M. Journal of the American Chemical Society, Vol. 128, Issue 3 https://doi.org/10.1021/ja0569252	journal	January 2006
Single-Nanocrystal Spectroscopy of White-Light-Emitting CdSe Nanocrystals Dukes, Albert D.; Samson, Philip C.; Keene, Joseph D. The Journal of Physical Chemistry A, Vol. 115, Issue 16 https://doi.org/10.1021/jp1109509	journal	April 2011
The “Surface Optical” Phonon in CdSe Nanocrystals Lin, Chen; Kelley, David F.; Rico, Mikaela ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn5008513	journal	March 2014
Nucleation and Growth of Gold Nanoparticles Studied via in situ Small Angle X-ray Scattering at Millisecond Time Resolution Polte, Jörg; Erler, Robert; Thünemann, Andreas F. ACS Nano, Vol. 4, Issue 2 https://doi.org/10.1021/nn901499c	journal	January 2010
Direct probe of spectral inhomogeneity reveals synthetic tunability of single-nanocrystal spectral linewidths Cui, Jian; Beyler, Andrew P.; Marshall, Lisa F. Nature Chemistry, Vol. 5, Issue 7 https://doi.org/10.1038/nchem.1654	journal	June 2013
Opportunities and challenges for quantum dot photovoltaics Kovalenko, Maksym V. Nature Nanotechnology, Vol. 10, Issue 12 https://doi.org/10.1038/nnano.2015.284	journal	December 2015
Fluorescence correlation spectroscopy for flow rate imaging and monitoring—optimization, limitations and artifacts Brister, Paul C.; Kuricheti, Kalyan K.; Buschmann, Volker Lab Chip, Vol. 5, Issue 7 https://doi.org/10.1039/B500129C	journal	January 2005
A stable droplet reactor for high temperature nanocrystal synthesis Nightingale, A. M.; Krishnadasan, S. H.; Berhanu, D. Lab Chip, Vol. 11, Issue 7 https://doi.org/10.1039/C0LC00507J	journal	January 2011
Deconstructing the photon stream from single nanocrystals: from binning to correlation Cui, Jian; Beyler, Andrew P.; Bischof, Thomas S. Chem. Soc. Rev., Vol. 43, Issue 4 https://doi.org/10.1039/C3CS60330J	journal	January 2014
Nanocrystal synthesis in microfluidic reactors: where next? Phillips, Thomas W.; Lignos, Ioannis G.; Maceiczyk, Richard M. Lab on a Chip, Vol. 14, Issue 17 https://doi.org/10.1039/C4LC00429A	journal	January 2014
Toward continuous and scalable production of colloidal nanocrystals by switching from batch to droplet reactors Niu, Guangda; Ruditskiy, Aleksey; Vara, Madeline Chemical Society Reviews, Vol. 44, Issue 16 https://doi.org/10.1039/C5CS00049A	journal	January 2015
Synthesis of silver nanoparticles in a microfluidic coaxial flow reactor Baber, Razwan; Mazzei, Luca; Thanh, Nguyen T. K. RSC Advances, Vol. 5, Issue 116 https://doi.org/10.1039/C5RA17466J	journal	January 2015
Controllable synthesis of nanocrystals in droplet reactors Pan, Liang-Jun; Tu, Jia-Wei; Ma, Hao-Tian Lab on a Chip, Vol. 18, Issue 1 https://doi.org/10.1039/C7LC00800G	journal	January 2018
Automated microfluidic platform for systematic studies of colloidal perovskite nanocrystals: towards continuous nano-manufacturing Epps, Robert W.; Felton, Kobi C.; Coley, Connor W. Lab on a Chip, Vol. 17, Issue 23 https://doi.org/10.1039/C7LC00884H	journal	January 2017
Differential detection photothermal spectroscopy: towards ultra-fast and sensitive label-free detection in picoliter & femtoliter droplets Maceiczyk, Richard M.; Hess, David; Chiu, Flora W. Y. Lab Chip, Vol. 17, Issue 21 https://doi.org/10.1039/C7LC00946A	journal	January 2017
Continuous microfluidic synthesis of colloidal ultrasmall gold nanoparticles: in situ study of the early reaction stages and application for catalysis Tofighi, Ghazal; Lichtenberg, Henning; Pesek, Jan Reaction Chemistry & Engineering, Vol. 2, Issue 6 https://doi.org/10.1039/C7RE00114B	journal	January 2017
On-line analysis of CdSe nanoparticle formation in a continuous flow chip-based microreactor Krishnadasan, S.; Tovilla, J.; Vilar, R. Journal of Materials Chemistry, Vol. 14, Issue 17 https://doi.org/10.1039/b401559b	journal	January 2004
A serial dilution microfluidic device using a ladder network generating logarithmic or linear concentrations Kim, Choong; Lee, Kangsun; Kim, Jong Hyun Lab on a Chip, Vol. 8, Issue 3 https://doi.org/10.1039/b714536e	journal	January 2008
Extracting Spectral Dynamics from Single Chromophores in Solution Marshall, Lisa F.; Cui, Jian; Brokmann, Xavier Physical Review Letters, Vol. 105, Issue 5 https://doi.org/10.1103/PhysRevLett.105.053005	journal	July 2010
Thermodynamic Fluctuations in a Reacting System—Measurement by Fluorescence Correlation Spectroscopy Magde, Douglas; Elson, Elliot; Webb, W. W. Physical Review Letters, Vol. 29, Issue 11 https://doi.org/10.1103/PhysRevLett.29.705	journal	September 1972
Colloidal nanoparticles as advanced biological sensors Howes, Philip D.; Chandrawati, Rona; Stevens, Molly M. Science, Vol. 346, Issue 6205 https://doi.org/10.1126/science.1247390	journal	October 2014
Building devices from colloidal quantum dots Kagan, C. R.; Lifshitz, E.; Sargent, E. H. Science, Vol. 353, Issue 6302 https://doi.org/10.1126/science.aac5523	journal	August 2016
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Annual Review of Materials Science, Vol. 30, Issue 1, p. 545-610 https://doi.org/10.1146/annurev.matsci.30.1.545	journal	August 2000
Photon-correlation Fourier spectroscopy Brokmann, Xavier; Bawendi, Moungi; Coolen, Laurent Optics Express, Vol. 14, Issue 13 https://doi.org/10.1364/OE.14.006333	journal	January 2006

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