Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework

Moreau, Liane M.; Herve, Alexandre; Straub, Mark D.; Russo, Dominic R.; Abergel, Rebecca J.; Alayoglu, Selim; Arnold, John; Braun, Augustin; Deblonde, Gauthier P.; Liu, Yangdongling; Lohrey, Trevor D.; Olive, Daniel T.; Qiao, Yusen; Rees, Julian A.; Shuh, David K.; Teat, Simon J.; Booth, Corwin H.; Minasian, Stefan G.

doi:10.1039/c9sc06117g

Title: Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework

Journal Article · 31 December 2019 · Chemical Science

DOI: https://doi.org/10.1039/c9sc06117g · OSTI ID:1616333

^[1]; Herve, Alexandre ^[1];

^[2]; Russo, Dominic R. ^[2];

^[2]; Alayoglu, Selim ^[1];

^[2];

^[1];

^[1]; Liu, Yangdongling ^[1];

^[2]; Olive, Daniel T. ^[3];

^[4]; Rees, Julian A. ^[1];

^[1];

^[1]

Lawrence Berkeley National Laboratory; Berkeley; USA
Lawrence Berkeley National Laboratory; Berkeley; USA; University of California; Berkeley
Lawrence Berkeley National Laboratory; Berkeley; USA; Los Alamos National Laboratory; Los Alamos
Lawrence Berkeley National Laboratory; Berkeley; USA; University of Pennsylvania; Philadelphia

ThO₂ and UO₂ nanoparticles synthesized using a COF-5 template exhibit unpassivated surfaces and provide insight into nanoscale properties of actinides.

View Journal Article

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: 89233218CNA000001; AC02-05CH11231; AC02-76SF00515; AC52-07NA27344

OSTI ID:: 1616333

Report Number(s):: LA-UR-19-30509; LLNL-JRNL-795572

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 18 Vol. 11; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (173)

Covalent Organic Frameworks: Structures, Synthesis, and Applications Lohse, Maria S.; Bein, Thomas Advanced Functional Materials, Vol. 28, Issue 33 https://doi.org/10.1002/adfm.201705553	journal	July 2018
Enhanced Potential of Amorphous Electrode Materials: Case Study of RuO2 Delmer, O.; Balaya, P.; Kienle, L. Advanced Materials, Vol. 20, Issue 3 https://doi.org/10.1002/adma.200701349	journal	February 2008
Emerging Nanotechnology and Advanced Materials for Cancer Radiation Therapy Song, Guosheng; Cheng, Liang; Chao, Yu Advanced Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adma.201700996	journal	June 2017
Actinyl Peroxide Nanospheres Burns, Peter C.; Kubatko, Karrie-Ann; Sigmon, Ginger Angewandte Chemie International Edition, Vol. 44, Issue 14 https://doi.org/10.1002/anie.200462445	journal	March 2005
Synthesis of Monodisperse Spherical Nanocrystals Park, Jongnam; Joo, Jin; Kwon, Soon Gu Angewandte Chemie International Edition, Vol. 46, Issue 25 https://doi.org/10.1002/anie.200603148	journal	June 2007
Self-Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low-Valent Uranium Nocton, Grégory; Burdet, Fabien; Pécaut, Jacques Angewandte Chemie International Edition, Vol. 46, Issue 40 https://doi.org/10.1002/anie.200702374	journal	October 2007
The Structure of the Plutonium Oxide Nanocluster [Pu38O56Cl54(H2O)8]14− Soderholm, L.; Almond, Philip M.; Skanthakumar, S. Angewandte Chemie International Edition, Vol. 47, Issue 2 https://doi.org/10.1002/anie.200704420	journal	January 2008
Polyimido Uranium(IV) Clusters: Imidometalates with an M ₇ (μ ₃ -N) ₆ (μ ₂ -N) ₆ Core Analogous to the Anderson-Type Polyoxometalate Motif Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel Angewandte Chemie International Edition, Vol. 47, Issue 30 https://doi.org/10.1002/anie.200801420	journal	June 2008
Differential Ion Exchange in Elliptical Uranyl Diphosphonate Nanotubules Adelani, Pius O.; Albrecht-Schmitt, Thomas E. Angewandte Chemie International Edition, Vol. 49, Issue 47 https://doi.org/10.1002/anie.201004797	journal	October 2010
Synthesis of Air-Stable, Volatile Uranium(IV) and (VI) Compounds and Their Gas-Phase Conversion To Uranium Oxide Films Appel, Linus; Leduc, Jennifer; Webster, Christopher L. Angewandte Chemie International Edition, Vol. 54, Issue 7 https://doi.org/10.1002/anie.201409606	journal	December 2014
Structural Snapshots of Cluster Growth from {U ₆ } to {U ₃₈ } During the Hydrolysis of UCl ₄ Chatelain, Lucile; Faizova, Radmila; Fadaei-Tirani, Farzaneh Angewandte Chemie International Edition, Vol. 58, Issue 10 https://doi.org/10.1002/anie.201812509	journal	January 2019
Chemical Vapor Deposition of Phase-Pure Uranium Dioxide Thin Films from Uranium(IV) Amidate Precursors Straub, Mark D.; Leduc, Jennifer; Frank, Michael Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201901924	journal	March 2019
Application of AXAFS Spectroscopy to Transition-Metal Oxides: Influence of the Nearest and Next Nearest Neighbour Shells in Vanadium Oxides Keller, Daphne E.; Weckhuysen, Bert M.; Koningsberger, Diek C. Chemistry - A European Journal, Vol. 13, Issue 20 https://doi.org/10.1002/chem.200601128	journal	July 2007
The Structure of Layered Covalent-Organic Frameworks Lukose, Binit; Kuc, Agnieszka; Heine, Thomas Chemistry - A European Journal, Vol. 17, Issue 8 https://doi.org/10.1002/chem.201001290	journal	January 2011
Non-aqueous Synthesis of Isotropic and Anisotropic Actinide Oxide Nanocrystals Hudry, Damien; Apostolidis, Christos; Walter, Olaf Chemistry - A European Journal, Vol. 18, Issue 27 https://doi.org/10.1002/chem.201200513	journal	May 2012
A Journey inside the U28 Nanocapsule Gil, Adrià; Karhánek, David; Miró, Pere Chemistry - A European Journal, Vol. 18, Issue 27 https://doi.org/10.1002/chem.201200801	journal	May 2012
Controlled Synthesis of Thorium and Uranium Oxide Nanocrystals Hudry, Damien; Apostolidis, Christos; Walter, Olaf Chemistry - A European Journal, Vol. 19, Issue 17 https://doi.org/10.1002/chem.201203888	journal	March 2013
Ultra-Small Plutonium Oxide Nanocrystals: An Innovative Material in Plutonium Science Hudry, Damien; Apostolidis, Christos; Walter, Olaf Chemistry - A European Journal, Vol. 20, Issue 33 https://doi.org/10.1002/chem.201402008	journal	July 2014
Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U ₃₈ Falaise, Clément; Volkringer, Christophe; Hennig, Christoph Chemistry - A European Journal, Vol. 21, Issue 46 https://doi.org/10.1002/chem.201502207	journal	September 2015
Coordination of Tetravalent Actinides (An=Th ^IV , U ^IV , Np ^IV , Pu ^IV ) with DOTA: From Dimers to Hexamers Tamain, Christelle; Dumas, Thomas; Hennig, Christoph Chemistry - A European Journal, Vol. 23, Issue 28 https://doi.org/10.1002/chem.201700493	journal	April 2017
Thorium Oxo‐Clusters as Building Blocks for Open Frameworks Falaise, Clément; Kozma, Karoly; Nyman, May Chemistry – A European Journal, Vol. 24, Issue 53 https://doi.org/10.1002/chem.201802671	journal	August 2018
Extension of the Plutonium Oxide Nanocluster Family to Include {Pu ₁₆ } and {Pu ₂₂ } Sigmon, Ginger E.; Hixon, Amy E. Chemistry - A European Journal, Vol. 25, Issue 10 https://doi.org/10.1002/chem.201805605	journal	January 2019
In-situ Scanning Transmission X-Ray Microscopy of Catalytic Solids and Related Nanomaterials de Groot, Frank M. F.; de Smit, Emiel; van Schooneveld, Matti M. ChemPhysChem, Vol. 11, Issue 5 https://doi.org/10.1002/cphc.200901023	journal	March 2010
Metals@MOFs - Loading MOFs with Metal Nanoparticles for Hybrid Functions Meilikhov, Mikhail; Yusenko, Kirill; Esken, Daniel European Journal of Inorganic Chemistry, Vol. 2010, Issue 24, p. 3701-3714 https://doi.org/10.1002/ejic.201000473	journal	July 2010
First Evidence of a Water-Soluble Plutonium(IV) Hexanuclear Cluster: First Evidence of a Water-Soluble Plutonium(IV) Hexanuclear Cluster Tamain, Christelle; Dumas, Thomas; Guillaumont, Dominique European Journal of Inorganic Chemistry, Vol. 2016, Issue 22 https://doi.org/10.1002/ejic.201600656	journal	July 2016
Covalent organic frameworks and their metal nanoparticle composites: Prospects for hydrogen storage Kalidindi, Suresh Babu; Fischer, Roland A. physica status solidi (b), Vol. 250, Issue 6 https://doi.org/10.1002/pssb.201248477	journal	March 2013
Probing actinide electronic structure through pu cluster calculations Ryzhkov, Mickhail V.; Mirmelstein, Alexei; Yu, Sung-Woo International Journal of Quantum Chemistry, Vol. 113, Issue 16 https://doi.org/10.1002/qua.24417	journal	February 2013
Nanoscience, Nanotechnology, and Chemistry Whitesides, George?M. Small, Vol. 1, Issue 2 https://doi.org/10.1002/smll.200400130	journal	February 2005
Nanocrystals of Uranium Oxide: Controlled Synthesis and Enhanced Electrochemical Performance of Hydrogen Evolution by Ce Doping Hu, Shi; Li, Haoyi; Liu, Huiling Small, Vol. 11, Issue 22 https://doi.org/10.1002/smll.201403245	journal	January 2015
Uranium Grenthe, Ingmar; Drożdżynński, Janusz; Fujino, Takeo The Chemistry of the Actinide and Transactinide Elements https://doi.org/10.1007/1-4020-3598-5_5	book	January 2008
Actinide Nanoparticle Research Kalmykov, Stepan N.; Denecke, Melissa A. Springer Berlin, Heidelberg https://doi.org/10.1007/978-3-642-11432-8	book	January 2011
Soft X-ray scanning transmission X-ray microscopy (STXM) of actinide particles Nilsson, Hans J.; Tyliszczak, Tolek; Wilson, Richard E. Analytical and Bioanalytical Chemistry, Vol. 383, Issue 1 https://doi.org/10.1007/s00216-005-3355-5	journal	July 2005
Investigation of reaction conditions on synthesis of UO2.34 and UO2 via hydrothermal route Chen, Ping; Huang, Dongyu; Chen, Chenchen Journal of Radioanalytical and Nuclear Chemistry, Vol. 313, Issue 1 https://doi.org/10.1007/s10967-017-5276-0	journal	May 2017
Functionalized TiO2 nanoparticles labelled with 225Ac for targeted alpha radionuclide therapy Cędrowska, Edyta; Pruszynski, Marek; Majkowska-Pilip, Agnieszka Journal of Nanoparticle Research, Vol. 20, Issue 3 https://doi.org/10.1007/s11051-018-4181-y	journal	March 2018
Thorium/uranium mixed oxide nanocrystals: Synthesis, structural characterization and magnetic properties Hudry, Damien; Griveau, Jean-Christophe; Apostolidis, Christos Nano Research, Vol. 7, Issue 1 https://doi.org/10.1007/s12274-013-0379-6	journal	November 2013
Infrared and Raman spectra of the uranyl ion Bagnall, K. W.; Wakerley, M. W. Journal of Inorganic and Nuclear Chemistry, Vol. 37, Issue 1 https://doi.org/10.1016/0022-1902(75)80194-1	journal	January 1975
The synthesis and characterization of some fluorinated uranium(IV) β-diketonates DeVito, Valentino L.; Wester, Dennis W. Journal of Inorganic and Nuclear Chemistry, Vol. 42, Issue 12 https://doi.org/10.1016/0022-1902(80)80147-3	journal	January 1980
Surface and interfacial properties of non-stoichiometric uranium dioxide Hodkin, E. N.; Nicholas, M. G. Journal of Nuclear Materials, Vol. 67, Issue 1-2 https://doi.org/10.1016/0022-3115(77)90172-6	journal	June 1977
The surface properties of uranium dioxide Tasker, P. W. Surface Science, Vol. 87, Issue 2 https://doi.org/10.1016/0039-6028(79)90531-4	journal	August 1979
Transmission electron microscopy observation on irradiation-induced microstructural evolution in high burn-up UO2 disk fuel Sonoda, T.; Kinoshita, M.; Ray, I. L. F. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 191, Issue 1-4 https://doi.org/10.1016/S0168-583X(02)00622-5	journal	May 2002
The high burn-up structure in nuclear fuel Rondinella, Vincenzo V.; Wiss, Thierry Materials Today, Vol. 13, Issue 12 https://doi.org/10.1016/S1369-7021(10)70221-2	journal	December 2010
Lanthanide “second-generation” precursors for MOCVD applications: Effects of the metal ionic radius and polyether length on coordination spheres and mass-transport properties Malandrino, Graziella; Fragalà, Ignazio L. Coordination Chemistry Reviews, Vol. 250, Issue 11-12 https://doi.org/10.1016/j.ccr.2006.03.017	journal	June 2006
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
Small-angle X-ray scattering to determine solution speciation of metal-oxo clusters Nyman, May Coordination Chemistry Reviews, Vol. 352 https://doi.org/10.1016/j.ccr.2016.11.014	journal	December 2017
Inner-shell excitation of gas phase carbonates and α,γ-dicarbonyl compounds Lessard, Robert; Cuny, Jérôme; Cooper, Glyn Chemical Physics, Vol. 331, Issue 2-3 https://doi.org/10.1016/j.chemphys.2006.10.020	journal	January 2007
Sonolysis of actinide(IV) β-diketonates in alkanes Nikitenko, Sergey I.; Moisy, Philippe; Blanc, Pierre Comptes Rendus Chimie, Vol. 7, Issue 12 https://doi.org/10.1016/j.crci.2004.02.020	journal	December 2004
Soft X-ray microscopy and spectroscopy at the molecular environmental science beamline at the Advanced Light Source Bluhm, H.; Andersson, K.; Araki, T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 150, Issue 2-3 https://doi.org/10.1016/j.elspec.2005.07.005	journal	February 2006
Optimization of analysis of soft X-ray spectromicroscopy at the Ca 2p edge Hanhan, S.; Smith, A. M.; Obst, M. Journal of Electron Spectroscopy and Related Phenomena, Vol. 173, Issue 1 https://doi.org/10.1016/j.elspec.2009.04.010	journal	June 2009
The effects of mesoscale confinement in Pu clusters and isolated particles Ryzhkov, M. V.; Mirmelstein, A.; Delley, B. Journal of Electron Spectroscopy and Related Phenomena, Vol. 194 https://doi.org/10.1016/j.elspec.2013.11.015	journal	June 2014
Formation of crystalline PuO2+x·nH2O nanoparticles upon sorption of Pu(V,VI) onto hematite Romanchuk, Anna Yu.; Kalmykov, Stepan N.; Egorov, Alexander V. Geochimica et Cosmochimica Acta, Vol. 121 https://doi.org/10.1016/j.gca.2013.07.016	journal	November 2013
Formulation design for poorly water-soluble drugs based on biopharmaceutics classification system: Basic approaches and practical applications Kawabata, Yohei; Wada, Koichi; Nakatani, Manabu International Journal of Pharmaceutics, Vol. 420, Issue 1 https://doi.org/10.1016/j.ijpharm.2011.08.032	journal	November 2011
Rocky Flats closure: The role of models in facilitating scientific communication with stakeholder groups Clark, David L.; Choppin, Gregory R.; Dayton, Christine S. Journal of Alloys and Compounds, Vol. 444-445 https://doi.org/10.1016/j.jallcom.2007.02.121	journal	October 2007
Effect of burn-up on the thermal conductivity of uranium dioxide up to 100.000 MWdt−1 Ronchi, C.; Sheindlin, M.; Staicu, D. Journal of Nuclear Materials, Vol. 327, Issue 1 https://doi.org/10.1016/j.jnucmat.2004.01.018	journal	April 2004
Detailed characterisations of high burn-up structures in oxide fuels Noirot, J.; Desgranges, L.; Lamontagne, J. Journal of Nuclear Materials, Vol. 372, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2007.04.037	journal	January 2008
Charge distribution and oxygen diffusion in hyperstoichiometric uranium dioxide UO2+x (x⩽0.25) Skomurski, F. N.; Wang, J. W.; Ewing, R. C. Journal of Nuclear Materials, Vol. 434, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2011.09.003	journal	March 2013
Bulk-nanocrystalline oxide nuclear fuels – An innovative material option for increasing fission gas retention, plasticity and radiation-tolerance Spino, J.; Santa Cruz, H.; Jovani-Abril, R. Journal of Nuclear Materials, Vol. 422, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2011.11.056	journal	March 2012
Charge distribution and local structure and speciation in the UO2+x and PuO2+x binary oxides for x⩽0.25 Conradson, Steven D.; Begg, Bruce D.; Clark, David L. Journal of Solid State Chemistry, Vol. 178, Issue 2 https://doi.org/10.1016/j.jssc.2004.09.029	journal	February 2005
Recent developments in the MOCVD and ALD of rare earth oxides and silicates Jones, Anthony C.; Aspinall, Helen C.; Chalker, Paul R. Materials Science and Engineering: B, Vol. 118, Issue 1-3 https://doi.org/10.1016/j.mseb.2004.12.081	journal	April 2005
Soft X-ray spectromicroscopy beamline at the CLS: Commissioning results Kaznatcheev, K. V.; Karunakaran, Ch.; Lanke, U. D. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 582, Issue 1 https://doi.org/10.1016/j.nima.2007.08.083	journal	November 2007
Clarification of high density electronic excitation effects on the microstructural evolution in UO2 Sonoda, T.; Kinoshita, M.; Ishikawa, N. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 19 https://doi.org/10.1016/j.nimb.2010.06.015	journal	October 2010
Crystal structure of the first octanuclear uranium(IV) complex with compartmental Schiff base ligands Salmon, Lionel; Thuéry, Pierre; Ephritikhine, Michel Polyhedron, Vol. 23, Issue 4 https://doi.org/10.1016/j.poly.2003.10.014	journal	February 2004
Electron beam induced synthesis of uranium dioxide nanoparticles: Effect of solvent composition Rath, M. C.; Keny, S. J.; Naik, D. B. Radiation Physics and Chemistry, Vol. 126 https://doi.org/10.1016/j.radphyschem.2016.05.012	journal	September 2016
Surface reactions of uranium oxide powder, thin films and single crystals Idriss, H. Surface Science Reports, Vol. 65, Issue 3 https://doi.org/10.1016/j.surfrep.2010.01.001	journal	March 2010
Maximizing DNA Loading on a Range of Gold Nanoparticle Sizes Hurst, Sarah J.; Lytton-Jean, Abigail K. R.; Mirkin, Chad A. Analytical Chemistry, Vol. 78, Issue 24 https://doi.org/10.1021/ac0613582	journal	December 2006
Chemistry of Covalent Organic Frameworks Waller, Peter J.; Gándara, Felipe; Yaghi, Omar M. Accounts of Chemical Research, Vol. 48, Issue 12 https://doi.org/10.1021/acs.accounts.5b00369	journal	November 2015
Redox Controls over the Stability of U(IV) in Floodplains of the Upper Colorado River Basin Noël, Vincent; Boye, Kristin; Lezama Pacheco, Juan S. Environmental Science & Technology, Vol. 51, Issue 19 https://doi.org/10.1021/acs.est.7b02203	journal	September 2017
Structure and Reactivity of X-ray Amorphous Uranyl Peroxide, U ₂ O ₇ Odoh, Samuel O.; Shamblin, Jacob; Colla, Christopher A. Inorganic Chemistry, Vol. 55, Issue 7 https://doi.org/10.1021/acs.inorgchem.6b00017	journal	March 2016
Low-Temperature Oxidation of Fine UO ₂ Powders: A Process of Nanosized Domain Development Leinders, Gregory; Pakarinen, Janne; Delville, Rémi Inorganic Chemistry, Vol. 55, Issue 8 https://doi.org/10.1021/acs.inorgchem.6b00127	journal	March 2016
Chemical and Morphological Inhomogeneity of Aluminum Metal and Oxides from Soft X-ray Spectromicroscopy Altman, Alison B.; Pemmaraju, C. Das; Alayoglu, Selim Inorganic Chemistry, Vol. 56, Issue 10 https://doi.org/10.1021/acs.inorgchem.7b00280	journal	April 2017
U(IV) Aqueous Speciation from the Monomer to UO ₂ Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands Falaise, Clément; Neal, Harrison A.; Nyman, May Inorganic Chemistry, Vol. 56, Issue 11 https://doi.org/10.1021/acs.inorgchem.7b00616	journal	May 2017
Heterobimetallic Sodium Rare-Earth Complexes: “Third-Generation” MOCVD Precursors for the Deposition of NaREF ₄ (RE = Y, Gd) Films Battiato, Sergio; Rossi, Patrizia; Paoli, Paola Inorganic Chemistry, Vol. 57, Issue 24 https://doi.org/10.1021/acs.inorgchem.8b02267	journal	December 2018
Effect of Surface Ligands on CoP for the Hydrogen Evolution Reaction Ung, David; Cossairt, Brandi M. ACS Applied Energy Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsaem.9b00240	journal	March 2019
Imparting Catalytic Activity to a Covalent Organic Framework Material by Nanoparticle Encapsulation Shi, Xiaofei; Yao, Youjin; Xu, Yulong ACS Applied Materials & Interfaces, Vol. 9, Issue 8 https://doi.org/10.1021/acsami.6b16267	journal	February 2017
Chemistry of Actinide Centers in Heterogeneous Catalytic Transformations of Small Molecules Leduc, Jennifer; Frank, Michael; Jürgensen, Lasse ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.8b04924	journal	April 2019
Synthesis and Low Temperature In Situ Sintering of Uranium Oxide Nanoparticles Nenoff, Tina M.; Jacobs, Benjamin W.; Robinson, David B. Chemistry of Materials, Vol. 23, Issue 23 https://doi.org/10.1021/cm2020669	journal	December 2011
Synthesis, Characterization, and Application of Ultrasmall Nanoparticles Kim, Byung Hyo; Hackett, Michael J.; Park, Jongnam Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm402225z	journal	September 2013
Direct Imaging of Loaded Metal−Organic Framework Materials (Metal@MOF-5) Turner, Stuart; Lebedev, Oleg I.; Schröder, Felicitas Chemistry of Materials, Vol. 20, Issue 17 https://doi.org/10.1021/cm801165s	journal	September 2008
Chemical Vapor Deposition of Cerium Oxide Using the Precursors [Ce(hfac) ₃ (glyme)] Pollard, Kimberly D.; Jenkins, Hilary A.; Puddephatt, Richard J. Chemistry of Materials, Vol. 12, Issue 3 https://doi.org/10.1021/cm990455r	journal	March 2000
Small-particle research: physicochemical properties of extremely small colloidal metal and semiconductor particles Henglein, Arnim Chemical Reviews, Vol. 89, Issue 8 https://doi.org/10.1021/cr00098a010	journal	December 1989
Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges Qiu, Jie; Burns, Peter C. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300159x	journal	October 2012
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
Surfactant Removal for Colloidal Nanoparticles from Solution Synthesis: The Effect on Catalytic Performance Li, Dongguo; Wang, Chao; Tripkovic, Dusan ACS Catalysis, Vol. 2, Issue 7 https://doi.org/10.1021/cs300219j	journal	June 2012
Stabilization of Plutonium Nano-Colloids by Epitaxial Distortion on Mineral Surfaces Powell, Brian A.; Dai, Zurong; Zavarin, Mavrik Environmental Science & Technology, Vol. 45, Issue 7 https://doi.org/10.1021/es1033487	journal	April 2011
Structure of Biogenic Uraninite Produced by Shewanella oneidensis Strain MR-1 Schofield, Eleanor J.; Veeramani, Harish; Sharp, Jonathan O. Environmental Science & Technology, Vol. 42, Issue 21 https://doi.org/10.1021/es800579g	journal	November 2008
XAFS Investigation of the Structure of Aqueous Thorium(IV) Species, Colloids, and Solid Thorium(IV) Oxide/Hydroxide Rothe, J.; Denecke, M. A.; Neck, V. Inorganic Chemistry, Vol. 41, Issue 2 https://doi.org/10.1021/ic010579h	journal	January 2002
XAFS and LIBD Investigation of the Formation and Structure of Colloidal Pu(IV) Hydrolysis Products Rothe, Jörg; Walther, Clemens; Denecke, Melissa A. Inorganic Chemistry, Vol. 43, Issue 15 https://doi.org/10.1021/ic049861p	journal	July 2004
Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η ⁸ -C ₈ H ₈ ) ₂ ] and Uranyl [UO ₂ X ₂ ] Compounds Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel Inorganic Chemistry, Vol. 49, Issue 17 https://doi.org/10.1021/ic101310z	journal	September 2010
Lanthanide N , N -Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors Daly, Scott R.; Kim, Do Young; Girolami, Gregory S. Inorganic Chemistry, Vol. 51, Issue 13 https://doi.org/10.1021/ic201852j	journal	June 2012
Thorium(IV)–Selenate Clusters Containing an Octanuclear Th(IV) Hydroxide/Oxide Core Knope, Karah E.; Vasiliu, Monica; Dixon, David A. Inorganic Chemistry, Vol. 51, Issue 7 https://doi.org/10.1021/ic202706s	journal	March 2012
Plutonium(IV) Cluster with a Hexanuclear [Pu ₆ (OH) ₄ O ₄ ] ¹²⁺ Core Knope, Karah E.; Soderholm, L. Inorganic Chemistry, Vol. 52, Issue 12 https://doi.org/10.1021/ic4007185	journal	May 2013
Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide and Lanthanoid-Actinide Complexes Possessing Redox-Active Bridging Ligands Schelter, Eric J.; Wu, Ruilian; Veauthier, Jacqueline M. Inorganic Chemistry, Vol. 49, Issue 4 https://doi.org/10.1021/ic9024475	journal	February 2010
Early actinide alkoxide chemistry. Synthesis, characterization, and molecular structures of thorium(IV) and uranium(IV) aryloxide complexes Berg, John M.; Clark, David L.; Huffman, John C. Journal of the American Chemical Society, Vol. 114, Issue 27 https://doi.org/10.1021/ja00053a017	journal	December 1992
The Inconsistency in Adsorption Properties and Powder XRD Data of MOF-5 Is Rationalized by Framework Interpenetration and the Presence of Organic and Inorganic Species in the Nanocavities Hafizovic, Jasmina; Bjørgen, Morten; Olsbye, Unni Journal of the American Chemical Society, Vol. 129, Issue 12 https://doi.org/10.1021/ja0675447	journal	March 2007
Synthesis of Colloidal Uranium−Dioxide Nanocrystals Wu, Huimeng; Yang, Yongan; Cao, Y. Charles Journal of the American Chemical Society, Vol. 128, Issue 51 https://doi.org/10.1021/ja067940p	journal	December 2006
Enhanced Hydrolytic Stability of Self-Assembling Alkylated Two-Dimensional Covalent Organic Frameworks Lanni, Laura M.; Tilford, R. William; Bharathy, Muktha Journal of the American Chemical Society, Vol. 133, Issue 35 https://doi.org/10.1021/ja203807h	journal	September 2011
Isolation of the Large {Actinide} ₃₈ Poly-oxo Cluster with Uranium Falaise, Clément; Volkringer, Christophe; Vigier, Jean-François Journal of the American Chemical Society, Vol. 135, Issue 42 https://doi.org/10.1021/ja4067207	journal	October 2013
Mechanistic Studies of Two-Dimensional Covalent Organic Frameworks Rapidly Polymerized from Initially Homogenous Conditions Smith, Brian J.; Dichtel, William R. Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja5037868	journal	June 2014
Lanthanide N , N -Dimethylaminodiboranates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films Daly, Scott R.; Kim, Do Young; Yang, Yu Journal of the American Chemical Society, Vol. 132, Issue 7 https://doi.org/10.1021/ja9098005	journal	February 2010
Theory and X-ray Absorption Spectroscopy for Aluminum Coordination Complexes – Al K-Edge Studies of Charge and Bonding in (BDI)Al, (BDI)AlR ₂ , and (BDI)AlX ₂ Complexes Altman, Alison B.; Pemmaraju, C. D.; Camp, Clément Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b05854	journal	August 2015
From Highly Crystalline to Outer Surface-Functionalized Covalent Organic Frameworks—A Modulation Approach Calik, Mona; Sick, Torben; Dogru, Mirjam Journal of the American Chemical Society, Vol. 138, Issue 4 https://doi.org/10.1021/jacs.5b10708	journal	January 2016
Volatile Single-Source Precursors for the Low-Temperature Preparation of Sodium–Rare Earth Metal Fluorides Barry, Matthew C.; Wei, Zheng; He, Tianyu Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04194	journal	June 2016
Synthesis of Ultrafine and Highly Dispersed Metal Nanoparticles Confined in a Thioether-Containing Covalent Organic Framework and Their Catalytic Applications Lu, Shuanglong; Hu, Yiming; Wan, Shun Journal of the American Chemical Society, Vol. 139, Issue 47 https://doi.org/10.1021/jacs.7b07918	journal	November 2017
Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory” Ejegbavwo, Otega A.; Martin, Corey R.; Olorunfemi, Oyindamola A. Journal of the American Chemical Society, Vol. 141, Issue 29 https://doi.org/10.1021/jacs.9b04737	journal	June 2019
In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal–Organic Framework Gilson, Sara E.; Li, Peng; Szymanowski, Jennifer E. S. Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b06187	journal	July 2019
Surface Restructuring of Nanoparticles: An Efficient Route for Ligand−Metal Oxide Crosstalk Rajh, T.; Chen, L. X.; Lukas, K. The Journal of Physical Chemistry B, Vol. 106, Issue 41 https://doi.org/10.1021/jp021235v	journal	October 2002
Fe ₂ O ₃ Nanoparticle Structures Investigated by X-ray Absorption Near-Edge Structure, Surface Modifications, and Model Calculations Chen, Lin X.; Liu, Tao; Thurnauer, Marion C. The Journal of Physical Chemistry B, Vol. 106, Issue 34 https://doi.org/10.1021/jp025544x	journal	August 2002
Quantitative Study of the Effects of Surface Ligand Concentration on CdSe Nanocrystal Photoluminescence Munro, Andrea M.; Jen-La Plante, Ilan; Ng, Marsha S. The Journal of Physical Chemistry C, Vol. 111, Issue 17 https://doi.org/10.1021/jp068733e	journal	May 2007
Spectroscopic and Energetic Properties of Thorium(IV) Molecular Clusters with a Hexanuclear Core Vasiliu, Monica; Knope, Karah E.; Soderholm, L. The Journal of Physical Chemistry A, Vol. 116, Issue 25 https://doi.org/10.1021/jp303493t	journal	May 2012
Amorphous Alumina Nanoparticles: Structure, Surface Energy, and Thermodynamic Phase Stability Tavakoli, Amir H.; Maram, Pardha Saradhi; Widgeon, Scarlett J. The Journal of Physical Chemistry C, Vol. 117, Issue 33 https://doi.org/10.1021/jp405820g	journal	August 2013
Uranyl–Peroxide Nanocapsules in Aqueous Solution: Force Field Development and First Applications Miró, Pere; Vlaisavljevich, Bess; Dzubak, Allison L. The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp504147s	journal	October 2014
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals Alivisatos, A. P. The Journal of Physical Chemistry, Vol. 100, Issue 31 https://doi.org/10.1021/jp9535506	journal	January 1996
Numerical Simulation of the Platinum L_III Edge White Line Relative to Nanometer Scale Clusters Bazin, D.; Sayers, D.; Rehr, J. J. The Journal of Physical Chemistry B, Vol. 101, Issue 27 https://doi.org/10.1021/jp963949+	journal	July 1997
The Effects of Chemisorption on the Luminescence of CdSe Quantum Dots Bullen, C.; Mulvaney, P. Langmuir, Vol. 22, Issue 7 https://doi.org/10.1021/la051898e	journal	March 2006
Particle Size Determination Using TEM: A Discussion of Image Acquisition and Analysis for the Novice Microscopist Pyrz, William D.; Buttrey, Douglas J. Langmuir, Vol. 24, Issue 20 https://doi.org/10.1021/la801367j	journal	October 2008
Sonochemical synthesis of amorphous iron Suslick, Kenneth S.; Choe, Seok-Burm; Cichowlas, Andrzej A. Nature, Vol. 353, Issue 6343 https://doi.org/10.1038/353414a0	journal	October 1991
Colloidal nanocrystal synthesis and the organic–inorganic interface Yin, Yadong; Alivisatos, A. Paul Nature, Vol. 437, Issue 7059, p. 664-670 https://doi.org/10.1038/nature04165	journal	September 2005
Nanomoulding with amorphous metals Kumar, Golden; Tang, Hong X.; Schroers, Jan Nature, Vol. 457, Issue 7231 https://doi.org/10.1038/nature07718	journal	February 2009
The surface structure of silver-coated gold nanocrystals and its influence on shape control Padmos, J. Daniel; Personick, Michelle L.; Tang, Qing Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8664	journal	July 2015
The surface science of nanocrystals Boles, Michael A.; Ling, Daishun; Hyeon, Taeghwan Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4526	journal	January 2016
Insights into the sonochemical synthesis and properties of salt-free intrinsic plutonium colloids Dalodière, Elodie; Virot, Matthieu; Morosini, Vincent Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep43514	journal	March 2017
Uniform formation of uranium oxide nanocrystals inside ordered mesoporous hosts and their potential applications as oxidative catalysts Zhang, Z. T.; Konduru, M.; Dai, S. Chem. Commun., Issue 20 https://doi.org/10.1039/B204987B	journal	January 2002
Mesoporous materials in the field of nuclear industry: applications and perspectives Makowski, Philippe; Deschanels, Xavier; Grandjean, Agnès New J. Chem., Vol. 36, Issue 3 https://doi.org/10.1039/C1NJ20703B	journal	January 2012
Fabrication of metal nanoparticles in metal–organic frameworks Moon, Hoi Ri; Lim, Dae-Woon; Suh, Myunghyun Paik Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35320B	journal	January 2013
Highly stable covalent organic framework–Au nanoparticles hybrids for enhanced activity for nitrophenol reduction Pachfule, Pradip; Kandambeth, Sharath; Díaz Díaz, David Chem. Commun., Vol. 50, Issue 24 https://doi.org/10.1039/C3CC49176E	journal	January 2014
Chemical controls on uranyl citrate speciation and the self-assembly of nanoscale macrocycles and sandwich complexes in aqueous solutions Basile, M.; Unruh, D. K.; Gojdas, K. Chemical Communications, Vol. 51, Issue 25 https://doi.org/10.1039/C4CC08657K	journal	January 2015
Multifunctional and robust covalent organic framework–nanoparticle hybrids Pachfule, Pradip; Panda, Manas K.; Kandambeth, Sharath J. Mater. Chem. A, Vol. 2, Issue 21 https://doi.org/10.1039/C4TA00284A	journal	January 2014
New thorium( iv )–arsonates with a [Th ₈ O ₁₃ ] ⁶⁺ octanuclear core Qian, Xiang-Ying; Zhou, Tian-Hua; Mao, Jiang-Gao Dalton Transactions, Vol. 44, Issue 30 https://doi.org/10.1039/C5DT01370D	journal	January 2015
Tailor-made porosities of fluorene-based porous organic frameworks for the pre-designable fabrication of palladium nanoparticles with size, location and distribution control Zhong, Hong; Liu, Caiping; Wang, Yangxin Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04351D	journal	January 2016
Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy Altman, Alison B.; Pacold, Joseph I.; Wang, Jian Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00358C	journal	January 2016
Actinide-based MOFs: a middle ground in solution and solid-state structural motifs Dolgopolova, Ekaterina A.; Rice, Allison M.; Shustova, Natalia B. Chemical Communications, Vol. 54, Issue 50 https://doi.org/10.1039/C7CC09780H	journal	January 2018
Ligand induced shape transformation of thorium dioxide nanocrystals Wang, Gaoxue; Batista, Enrique R.; Yang, Ping Physical Chemistry Chemical Physics, Vol. 20, Issue 26 https://doi.org/10.1039/C8CP00240A	journal	January 2018
The preparation of new covalent organic framework embedded with silver nanoparticles and its applications in degradation of organic pollutants from waste water Wang, Rui-Lei; Li, Dong-Peng; Wang, Lu-Jie Dalton Transactions, Vol. 48, Issue 3 https://doi.org/10.1039/C8DT04458A	journal	January 2019
Understanding the size effects on the electronic structure of ThO ₂ nanoparticles Amidani, Lucia; Plakhova, Tatiana V.; Romanchuk, Anna Yu. Physical Chemistry Chemical Physics, Vol. 21, Issue 20 https://doi.org/10.1039/C9CP01283D	journal	January 2019
Probing the local structure of nanoscale actinide oxides: a comparison between PuO ₂ and ThO ₂ nanoparticles rules out PuO _2+x hypothesis Bonato, Laura; Virot, Matthieu; Dumas, Thomas Nanoscale Advances, Vol. 2, Issue 1 https://doi.org/10.1039/C9NA00662A	journal	January 2020
A systematic examination of surface coatings on the optical and chemical properties of semiconductor quantum dots Smith, Andrew M.; Duan, Hongwei; Rhyner, Matthew N. Physical Chemistry Chemical Physics, Vol. 8, Issue 33 https://doi.org/10.1039/b606572b	journal	January 2006
ZnO@ZIF-8: stabilization of quantum confined ZnO nanoparticles by a zinc methylimidazolate framework and their surface structural characterization probed by CO2 adsorption Esken, Daniel; Noei, Heshmat; Wang, Yuemin Journal of Materials Chemistry, Vol. 21, Issue 16 https://doi.org/10.1039/c1jm10091b	journal	January 2011
Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate Wu, Shijun; Wang, Shuao; Diwu, Juan Chemical Communications, Vol. 48, Issue 29 https://doi.org/10.1039/c2cc17517g	journal	January 2012
A facile additive-free method for tunable fabrication of UO2 and U3O8 nanoparticles in aqueous solution Zhao, Ran; Wang, Lin; Gu, Zhan-Jun CrystEngComm, Vol. 16, Issue 13 https://doi.org/10.1039/c3ce42140f	journal	January 2014
Synthesis of transuranium-based nanocrystals via the thermal decomposition of actinyl nitrates Hudry, Damien; Apostolidis, Christos; Walter, Olaf RSC Advances, Vol. 3, Issue 40 https://doi.org/10.1039/c3ra41577e	journal	January 2013
Tuning the electronic behavior of Au nanoparticles with capping molecules Zhang, P.; Sham, T. K. Applied Physics Letters, Vol. 81, Issue 4 https://doi.org/10.1063/1.1494120	journal	July 2002
Soft X-ray Scanning Transmission Microscope Working in an Extended Energy Range at the Advanced Light Source Tyliszczak, T. SYNCHROTRON RADIATION INSTRUMENTATION: Eighth International Conference on Synchrotron Radiation Instrumentation, AIP Conference Proceedings https://doi.org/10.1063/1.1758053	conference	January 2004
Comparison of extended x-ray absorption fine structure and Scherrer analysis of x-ray diffraction as methods for determining mean sizes of polydisperse nanoparticles Calvin, S.; Luo, S. X.; Caragianis-Broadbridge, C. Applied Physics Letters, Vol. 87, Issue 23 https://doi.org/10.1063/1.2137872	journal	December 2005
Analysis of small angle neutron scattering spectra from polydisperse interacting colloids Kotlarchyk, Michael; Chen, Sow‐Hsin The Journal of Chemical Physics, Vol. 79, Issue 5 https://doi.org/10.1063/1.446055	journal	September 1983
Isochronal annealing effects on local structure, crystalline fraction, and undamaged region size of radiation damage in Ga-stabilized δ -Pu Olive, D. T.; Wang, D. L.; Booth, C. H. Journal of Applied Physics, Vol. 120, Issue 3 https://doi.org/10.1063/1.4958856	journal	July 2016
Gadolinium vanadate nanocrystals as carriers of α-emitters ( ²²⁵ Ac, ²²⁷ Th) and contrast agents Toro-González, Miguel; Dame, Ashley N.; Mirzadeh, Saed Journal of Applied Physics, Vol. 125, Issue 21 https://doi.org/10.1063/1.5096880	journal	June 2019
Uranium(IV) adsorption by natural organic matter in anoxic sediments Bone, Sharon E.; Dynes, James J.; Cliff, John Proceedings of the National Academy of Sciences, Vol. 114, Issue 4 https://doi.org/10.1073/pnas.1611918114	journal	January 2017
Alpha-irradiation damage in CeO ₂ , UO ₂ and PuO ₂ Weber, W. J. Radiation Effects, Vol. 83, Issue 1-2 https://doi.org/10.1080/00337578408215798	journal	January 1984
Measurements of Crystal Lattice Strain and Crystallite Size in Irradiated UO ₂ Pellet by X-ray Diffractometry Amaya, Masaki; Nakamura, Jinichi; Fuketa, Toyoshi Journal of Nuclear Science and Technology, Vol. 45, Issue 3 https://doi.org/10.1080/18811248.2008.9711433	journal	March 2008
Actinium-225 for Targeted α Therapy: Coordination Chemistry and Current Chelation Approaches Thiele, Nikki A.; Wilson, Justin J. Cancer Biotherapy and Radiopharmaceuticals, Vol. 33, Issue 8 https://doi.org/10.1089/cbr.2018.2494	journal	October 2018
Extended x-ray absorption fine structure Debye-Waller factors. I. Monatomic crystals Sevillano, E.; Meuth, H.; Rehr, J. J. Physical Review B, Vol. 20, Issue 12 https://doi.org/10.1103/PhysRevB.20.4908	journal	December 1979
X-ray-absorption fine structure in embedded atoms Rehr, J. J.; Booth, C. H.; Bridges, F. Physical Review B, Vol. 49, Issue 17 https://doi.org/10.1103/PhysRevB.49.12347	journal	May 1994
X-ray-absorption fine-structure standards: A comparison of experiment and theory Li, G. G.; Bridges, F.; Booth, C. H. Physical Review B, Vol. 52, Issue 9 https://doi.org/10.1103/PhysRevB.52.6332	journal	September 1995
Lattice effects in La 1 − x Ca x MnO 3 ( x = 0 → 1 ) : Relationships between distortions, charge distribution, and magnetism Booth, C. H.; Bridges, F.; Kwei, G. H. Physical Review B, Vol. 57, Issue 17 https://doi.org/10.1103/PhysRevB.57.10440	journal	May 1998
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure Ankudinov, A. L.; Ravel, B.; Rehr, J. J. Physical Review B, Vol. 58, Issue 12 https://doi.org/10.1103/PhysRevB.58.7565	journal	September 1998
Electronic correlation and transport properties of nuclear fuel materials Yin, Quan; Kutepov, Andrey; Haule, Kristjan Physical Review B, Vol. 84, Issue 19 https://doi.org/10.1103/PhysRevB.84.195111	journal	November 2011
Possible Bose-condensate behavior in a quantum phase originating in a collective excitation in the chemically and optically doped Mott-Hubbard system UO 2 + x Conradson, Steven D.; Durakiewicz, Tomasz; Espinosa-Faller, Francisco J. Physical Review B, Vol. 88, Issue 11 https://doi.org/10.1103/PhysRevB.88.115135	journal	September 2013
Covalency in oxidized uranium Tobin, J. G.; Yu, S. -W.; Qiao, R. Physical Review B, Vol. 92, Issue 4 https://doi.org/10.1103/PhysRevB.92.045130	journal	July 2015
Orbital Specificity in the Unoccupied States of UO 2 from Resonant Inverse Photoelectron Spectroscopy Tobin, J. G.; Yu, S. -W. Physical Review Letters, Vol. 107, Issue 16 https://doi.org/10.1103/PhysRevLett.107.167406	journal	October 2011
Heavy-fermion systems Stewart, G. R. Reviews of Modern Physics, Vol. 56, Issue 4 https://doi.org/10.1103/RevModPhys.56.755	journal	October 1984
Nature of the 5 f states in actinide metals Moore, Kevin T.; van der Laan, Gerrit Reviews of Modern Physics, Vol. 81, Issue 1 https://doi.org/10.1103/RevModPhys.81.235	journal	February 2009
Nika : software for two-dimensional data reduction Ilavsky, Jan Journal of Applied Crystallography, Vol. 45, Issue 2 https://doi.org/10.1107/S0021889812004037	journal	March 2012
A method for normalization of X-ray absorption spectra Weng, Tsu-Chien; Waldo, Geoffrey S.; Penner-Hahn, James E. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049504034193	journal	June 2005
Grain growth and pore coarsening in dense nano‐crystalline UO _{2+ x} fuel pellets Yao, Tiankai; Mo, Kun; Yun, Di Journal of the American Ceramic Society, Vol. 100, Issue 6 https://doi.org/10.1111/jace.14780	journal	March 2017
Ligand effects in catalysis by atomically precise gold nanoclusters Wan, Xian-Kai; Wang, Jia-Qi; Nan, Zi-Ang Science Advances, Vol. 3, Issue 10 https://doi.org/10.1126/sciadv.1701823	journal	October 2017
Porous, Crystalline, Covalent Organic Frameworks Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W. Science, Vol. 310, Issue 5751, p. 1166-1170 https://doi.org/10.1126/science.1120411	journal	November 2005
Plutonium-Based Heavy-Fermion Systems Bauer, E. D.; Thompson, J. D. Annual Review of Condensed Matter Physics, Vol. 6, Issue 1 https://doi.org/10.1146/annurev-conmatphys-031214-014508	journal	March 2015
Estimating Crystallite Size in Polydispersed Samples using EXAFS Calvin, S.; Riedel, C. J.; Carpenter, E. E. Physica Scripta https://doi.org/10.1238/Physica.Topical.115a00744	journal	January 2005
Some β-Diketone Chelate Complexes with Uranium(IV), Thorium(IV), and Cerium(IV). Preparation and IR Spectra Yoshimura, Tetsuhiko; Miyake, Chie; Imoto, Shosuke Bulletin of the Chemical Society of Japan, Vol. 46, Issue 7 https://doi.org/10.1246/bcsj.46.2096	journal	July 1973
Gold Coated Lanthanide Phosphate Nanoparticles for Targeted Alpha Generator Radiotherapy McLaughlin, Mark F.; Woodward, Jonathan; Boll, Rose A. PLoS ONE, Vol. 8, Issue 1 https://doi.org/10.1371/journal.pone.0054531	journal	January 2013
Plutonium sorption to nanocast mesoporous carbon Parsons-Moss, Tashi; Tüysüz, Harun; Wang, Deborah Radiochimica Acta, Vol. 102, Issue 6 https://doi.org/10.1515/ract-2014-2138	journal	January 2014
Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium Weber, W. J.; Ewing, R. C.; Catlow, C. R. A. Journal of Materials Research, Vol. 13, Issue 6 https://doi.org/10.1557/JMR.1998.0205	journal	June 1998
Actinide Colloids in Natural Aquifer Systems Kim, J. I. MRS Bulletin, Vol. 19, Issue 12 https://doi.org/10.1557/S0883769400048703	journal	December 1994
Review of Therapeutic Applications of Radiolabeled Functional Nanomaterials Jeon, Jongho International Journal of Molecular Sciences, Vol. 20, Issue 9 https://doi.org/10.3390/ijms20092323	journal	May 2019

Similar Records

Design of higher valency in covalent organic frameworks

Journal Article · 2020 · Science · OSTI ID:1682513

Gropp, Cornelius; Ma, Tianqiong; Hanikel, Nikita; +1 more

Entanglement of Square Nets in Covalent Organic Frameworks

Journal Article · 2022 · Journal of the American Chemical Society · OSTI ID:1968253

Jin, Fangying; Nguyen, Ha L.; Zhong, Zhiye; +5 more

Roasting and dissolution studies on nonirradiated thorium dioxide/uranium dioxide pellets

Technical Report · 1981 · OSTI ID:5296379

Pickett, J B; Fowler, J R; Mosley, Jr, W C

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY

Title: Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework

Citation Formats

References (173)

Similar Records

Related Subjects