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Title: Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters

Abstract

Temperature-dependent metalation of a new hexadentate enables the selective synthesis of both mononuclear ( i.e. kinetic product) and trinuclear ( i.e. thermodynamic product) complexes.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, Texas A&M University, College Station, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1616332
Grant/Contract Number:  
SC0018977
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 56 Journal Issue: 44; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Hyun, Sung-Min, Upadhyay, Apoorva, Das, Anuvab, Burns, Corey P., Sung, Siyoung, Beaty, Jeremy D., Bhuvanesh, Nattamai, Nippe, Michael, and Powers, David C. Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters. United Kingdom: N. p., 2020. Web. doi:10.1039/D0CC02346A.
Hyun, Sung-Min, Upadhyay, Apoorva, Das, Anuvab, Burns, Corey P., Sung, Siyoung, Beaty, Jeremy D., Bhuvanesh, Nattamai, Nippe, Michael, & Powers, David C. Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters. United Kingdom. doi:https://doi.org/10.1039/D0CC02346A
Hyun, Sung-Min, Upadhyay, Apoorva, Das, Anuvab, Burns, Corey P., Sung, Siyoung, Beaty, Jeremy D., Bhuvanesh, Nattamai, Nippe, Michael, and Powers, David C. Tue . "Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters". United Kingdom. doi:https://doi.org/10.1039/D0CC02346A.
@article{osti_1616332,
title = {Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters},
author = {Hyun, Sung-Min and Upadhyay, Apoorva and Das, Anuvab and Burns, Corey P. and Sung, Siyoung and Beaty, Jeremy D. and Bhuvanesh, Nattamai and Nippe, Michael and Powers, David C.},
abstractNote = {Temperature-dependent metalation of a new hexadentate enables the selective synthesis of both mononuclear ( i.e. kinetic product) and trinuclear ( i.e. thermodynamic product) complexes.},
doi = {10.1039/D0CC02346A},
journal = {ChemComm},
number = 44,
volume = 56,
place = {United Kingdom},
year = {2020},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1039/D0CC02346A

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