Hydrophilic microporous membranes for selective ion separation and flow-battery energy storage

Tan, Rui; Wang, Anqi; Malpass-Evans, Richard; Williams, Rhodri; Zhao, Evan Wenbo; Liu, Tao; Ye, Chunchun; Zhou, Xiaoqun; Darwich, Barbara Primera; Fan, Zhiyu; Turcani, Lukas; Jackson, Edward; Chen, Linjiang; Chong, Samantha Y.; Li, Tao; Jelfs, Kim E.; Cooper, Andrew I.; Brandon, Nigel P.; Grey, Clare P.; McKeown, Neil B.; Song, Qilei

doi:10.1038/s41563-019-0536-8

Title: Hydrophilic microporous membranes for selective ion separation and flow-battery energy storage

Journal Article · 02 December 2019 · Nature Materials

DOI: https://doi.org/10.1038/s41563-019-0536-8 · OSTI ID:1616156

Tan, Rui ^[1];

^[1]; Malpass-Evans, Richard ^[2]; Williams, Rhodri ^[2]; Zhao, Evan Wenbo ^[3]; Liu, Tao ^[4]; Ye, Chunchun ^[2]; Zhou, Xiaoqun ^[1]; Darwich, Barbara Primera ^[1]; Fan, Zhiyu ^[1];

^[5];

^[5]; Chen, Linjiang ^[6];

^[6]; Li, Tao ^[7]; Jelfs, Kim E. ^[5]; Cooper, Andrew I. ^[6]; Brandon, Nigel P. ^[5]; Grey, Clare P. ^[3];

^[2] more »

Imperial College London, London (United Kingdom). Barrer Centre
Univ. of Edinburgh, Scotland (United Kingdom)
Univ. of Cambridge (United Kingdom)
Univ. of Cambridge (United Kingdom); Tongji Univ., Shanghai (China). Shanghai Key Lab. of Chemical Assessment and Sustainability, Dept. of Chemistry
Imperial College London, London (United Kingdom)
Univ. of Liverpool (United Kingdom). Leverhulme Research Centre for Functional Materials Design
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States). X-ray Science Division, Joint Center for Energy Storage Research (JCESR)

Membranes with fast and selective ion transport are widely used for water purification and devices for energy conversion and storage including fuel cells, redox flow batteries and electrochemical reactors. However, it remains challenging to design cost-effective, easily processed ion-conductive membranes with well-defined pore architectures. Here in this paper, we report a new approach to designing membranes with narrow molecular-sized channels and hydrophilic functionality that enable fast transport of salt ions and high size-exclusion selectivity towards small organic molecules. These membranes, based on polymers of intrinsic microporosity containing Tröger’s base or amidoxime groups, demonstrate that exquisite control over subnanometre pore structure, the introduction of hydrophilic functional groups and thickness control all play important roles in achieving fast ion transport combined with high molecular selectivity. These membranes enable aqueous organic flow batteries with high energy efficiency and high capacity retention, suggesting their utility for a variety of energy-related devices and water purification processes.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: China Scholarship Council; Engineering and Physical Sciences Research Council (EPSRC); European Research Council (ERC); European Union (EU) - Horizon 2020 Research and Innovation Programme; Imperial College London; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1616156

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 2 Vol. 19; ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (59)

Highly Selective Ionic Transport through Subnanometer Pores in Polymer Films Wen, Qi; Yan, Dongxiao; Liu, Feng Advanced Functional Materials, Vol. 26, Issue 32 https://doi.org/10.1002/adfm.201601689	journal	July 2016
Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity Budd, P. M.; Elabas, E. S.; Ghanem, B. S. Advanced Materials, Vol. 16, Issue 5, p. 456-459 https://doi.org/10.1002/adma.200306053	journal	March 2004
A Spirobifluorene-Based Polymer of Intrinsic Microporosity with Improved Performance for Gas Separation Bezzu, C. Grazia; Carta, Mariolino; Tonkins, Alexander Advanced Materials, Vol. 24, Issue 44 https://doi.org/10.1002/adma.201202393	journal	September 2012
Porous Organic Cage Thin Films and Molecular-Sieving Membranes Song, Qilei; Jiang, Shan; Hasell, Tom Advanced Materials, Vol. 28, Issue 13 https://doi.org/10.1002/adma.201505688	journal	January 2016
Ultra-High Proton/Vanadium Selectivity for Hydrophobic Polymer Membranes with Intrinsic Nanopores for Redox Flow Battery Chae, Il Seok; Luo, Tao; Moon, Gi Hyeon Advanced Energy Materials, Vol. 6, Issue 16 https://doi.org/10.1002/aenm.201600517	journal	June 2016
Alkaline Benzoquinone Aqueous Flow Battery for Large-Scale Storage of Electrical Energy Yang, Zhengjin; Tong, Liuchuan; Tabor, Daniel P. Advanced Energy Materials, Vol. 8, Issue 8 https://doi.org/10.1002/aenm.201702056	journal	December 2017
Highly Conductive Anion-Exchange Membranes from Microporous Tröger's Base Polymers Yang, Zhengjin; Guo, Rui; Malpass-Evans, Richard Angewandte Chemie, Vol. 128, Issue 38 https://doi.org/10.1002/ange.201605916	journal	August 2016
Highly Conductive Anion-Exchange Membranes from Microporous Tröger's Base Polymers Yang, Zhengjin; Guo, Rui; Malpass-Evans, Richard Angewandte Chemie International Edition, Vol. 55, Issue 38 https://doi.org/10.1002/anie.201605916	journal	August 2016
Polymers of Intrinsic Microporosity (PIMs): Organic Materials for Membrane Separations, Heterogeneous Catalysis and Hydrogen Storage McKeown, Neil B.; Budd, Peter M. ChemInform, Vol. 37, Issue 45 https://doi.org/10.1002/chin.200645246	journal	November 2006
Evaluation of Diels–Alder poly(phenylene) anion exchange membranes in all-vanadium redox flow batteries Sun, Che-Nan; Tang, Zhijiang; Belcher, Cami Electrochemistry Communications, Vol. 43, p. 63-66 https://doi.org/10.1016/j.elecom.2014.03.010	journal	June 2014
Alkaline Quinone Flow Battery with Long Lifetime at pH 12 Kwabi, David G.; Lin, Kaixiang; Ji, Yunlong Joule, Vol. 2, Issue 9 https://doi.org/10.1016/j.joule.2018.07.005	journal	September 2018
Alkaline Quinone Flow Battery with Long Lifetime at pH 12 Kwabi, David G.; Lin, Kaixiang; Ji, Yunlong Joule, Vol. 2, Issue 9 https://doi.org/10.1016/j.joule.2018.08.013	journal	September 2018
Water filtration performance of a lyotropic liquid crystal polymer membrane with uniform, sub-1-nm pores Hatakeyama, Evan S.; Gabriel, Christopher J.; Wiesenauer, Brian R. Journal of Membrane Science, Vol. 366, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.09.028	journal	January 2011
Pure- and mixed-gas CO2/CH4 separation properties of PIM-1 and an amidoxime-functionalized PIM-1 Swaidan, Raja; Ghanem, Bader S.; Litwiller, Eric Journal of Membrane Science, Vol. 457 https://doi.org/10.1016/j.memsci.2014.01.055	journal	May 2014
Roll-to-roll dip coating of three different PIMs for Organic Solvent Nanofiltration Cook, Marcus; Gaffney, Piers R. J.; Peeva, Ludmila G. Journal of Membrane Science, Vol. 558 https://doi.org/10.1016/j.memsci.2018.04.046	journal	July 2018
Sulfonated hydrocarbon membranes for medium-temperature and low-humidity proton exchange membrane fuel cells (PEMFCs) Park, Chi Hoon; Lee, Chang Hyun; Guiver, Michael D. Progress in Polymer Science, Vol. 36, Issue 11 https://doi.org/10.1016/j.progpolymsci.2011.06.001	journal	November 2011
Fundamental water and salt transport properties of polymeric materials Geise, Geoffrey M.; Paul, Donald R.; Freeman, Benny D. Progress in Polymer Science, Vol. 39, Issue 1 https://doi.org/10.1016/j.progpolymsci.2013.07.001	journal	January 2014
Hydrocarbon-Based Polymer Electrolyte Membranes: Importance of Morphology on Ion Transport and Membrane Stability Shin, Dong Won; Guiver, Michael D.; Lee, Young Moo Chemical Reviews, Vol. 117, Issue 6 https://doi.org/10.1021/acs.chemrev.6b00586	journal	March 2017
Charge- and Size-Selective Ion Sieving Through Ti ₃ C ₂ T _x MXene Membranes Ren, Chang E.; Hatzell, Kelsey B.; Alhabeb, Mohamed The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01895	journal	September 2015
Impact of Hydration and Sulfonation on the Morphology and Ionic Conductivity of Sulfonated Poly(phenylene) Proton Exchange Membranes Sorte, Eric G.; Paren, Benjamin A.; Rodriguez, Christina G. Macromolecules, Vol. 52, Issue 3 https://doi.org/10.1021/acs.macromol.8b02013	journal	January 2019
Polysulfide-Blocking Microporous Polymer Membrane Tailored for Hybrid Li-Sulfur Flow Batteries Li, Changyi; Ward, Ashleigh L.; Doris, Sean E. Nano Letters, Vol. 15, Issue 9 https://doi.org/10.1021/acs.nanolett.5b02078	journal	August 2015
Flow Batteries: Current Status and Trends Soloveichik, Grigorii L. Chemical Reviews, Vol. 115, Issue 20 https://doi.org/10.1021/cr500720t	journal	September 2015
Acidity of the Amidoxime Functional Group in Aqueous Solution: A Combined Experimental and Computational Study Mehio, Nada; Lashely, Mark A.; Nugent, Joseph W. The Journal of Physical Chemistry B, Vol. 119, Issue 8 https://doi.org/10.1021/jp512778x	journal	February 2015
Molecular Modeling and Gas Permeation Properties of a Polymer of Intrinsic Microporosity Composed of Ethanoanthracene and Tröger’s Base Units Tocci, Elena; De Lorenzo, Luana; Bernardo, Paola Macromolecules, Vol. 47, Issue 22 https://doi.org/10.1021/ma501469m	journal	November 2014
Linear High Molecular Weight Ladder Polymers by Optimized Polycondensation of Tetrahydroxytetramethylspirobisindane and 1,4-Dicyanotetrafluorobenzene ^† Song, Jingshe; Du, Naiying; Dai, Ying Macromolecules, Vol. 41, Issue 20 https://doi.org/10.1021/ma801000u	journal	October 2008
Materials for next-generation desalination and water purification membranes Werber, Jay R.; Osuji, Chinedum O.; Elimelech, Menachem Nature Reviews Materials, Vol. 1, Issue 5 https://doi.org/10.1038/natrevmats.2016.18	journal	April 2016
Covalent organic frameworks: a materials platform for structural and functional designs Huang, Ning; Wang, Ping; Jiang, Donglin Nature Reviews Materials, Vol. 1, Issue 10 https://doi.org/10.1038/natrevmats.2016.68	journal	September 2016
Material design and engineering of next-generation flow-battery technologies Park, Minjoon; Ryu, Jaechan; Wang, Wei Nature Reviews Materials, Vol. 2, Issue 1 https://doi.org/10.1038/natrevmats.2016.80	journal	November 2016
A metal-free organic–inorganic aqueous flow battery Huskinson, Brian; Marshak, Michael P.; Suh, Changwon Nature, Vol. 505, Issue 7482, p. 195-198 https://doi.org/10.1038/nature12909	journal	January 2014
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper Li, Christina W.; Ciston, Jim; Kanan, Matthew W. Nature, Vol. 508, Issue 7497 https://doi.org/10.1038/nature13249	journal	April 2014
An aqueous, polymer-based redox-flow battery using non-corrosive, safe and low-cost materials Janoschka, Tobias; Martin, Norbert; Martin, Udo Nature, Vol. 527, Issue 7576, p. 78-81 https://doi.org/10.1038/nature15746	journal	October 2015
Nanocrack-regulated self-humidifying membranes Park, Chi Hoon; Lee, So Young; Hwang, Doo Sung Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/nature17634	journal	April 2016
An aqueous, polymer-based redox-flow battery using non-corrosive, safe, and low-cost materials Janoschka, Tobias; Martin, Norbert; Martin, Udo Nature, Vol. 534, Issue 7607 https://doi.org/10.1038/nature18909	journal	June 2016
A biomimetic redox flow battery based on flavin mononucleotide Orita, Akihiro; Verde, Michael G.; Sakai, Masanori Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13230	journal	October 2016
A redox-flow battery with an alloxazine-based organic electrolyte Lin, Kaixiang; Gómez-Bombarelli, Rafael; Beh, Eugene S. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.102	journal	July 2016
An operationally flexible fuel cell based on quaternary ammonium-biphosphate ion pairs Lee, Kwan-Soo; Spendelow, Jacob S.; Choe, Yoong-Kee Nature Energy, Vol. 1, Issue 9, Article No. 16120 https://doi.org/10.1038/nenergy.2016.120	journal	August 2016
Metal–organic framework-based separator for lithium–sulfur batteries Bai, Songyan; Liu, Xizheng; Zhu, Kai Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.94	journal	June 2016
Parallel cylindrical water nanochannels in Nafion fuel-cell membranes Schmidt-Rohr, Klaus; Chen, Qiang Nature Materials, Vol. 7, Issue 1 https://doi.org/10.1038/nmat2074	journal	December 2007
Polymer ultrapermeability from the inefficient packing of 2D chains Rose, Ian; Bezzu, C. Grazia; Carta, Mariolino Nature Materials, Vol. 16, Issue 9 https://doi.org/10.1038/nmat4939	journal	July 2017
Tunable sieving of ions using graphene oxide membranes Abraham, Jijo; Vasu, Kalangi S.; Williams, Christopher D. Nature Nanotechnology, Vol. 12, Issue 6 https://doi.org/10.1038/nnano.2017.21	journal	April 2017
A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries Hollas, Aaron; Wei, Xiaoliang; Murugesan, Vijayakumar Nature Energy, Vol. 3, Issue 6 https://doi.org/10.1038/s41560-018-0167-3	journal	June 2018
Self-assembled highly ordered acid layers in precisely sulfonated polyethylene produce efficient proton transport Trigg, Edward B.; Gaines, Taylor W.; Maréchal, Manuel Nature Materials, Vol. 17, Issue 8 https://doi.org/10.1038/s41563-018-0097-2	journal	May 2018
Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries Darling, Robert M.; Gallagher, Kevin G.; Kowalski, Jeffrey A. Energy & Environmental Science, Vol. 7, Issue 11, p. 3459-3477 https://doi.org/10.1039/C4EE02158D	journal	January 2014
Advanced porous membranes with ultra-high selectivity and stability for vanadium flow batteries Yuan, Zhizhang; Duan, Yinqi; Zhang, Hongzhang Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE02896E	journal	January 2016
Rational design of polyaromatic ionomers for alkaline membrane fuel cells with >1 W cm ⁻² power density Maurya, Sandip; Noh, Sangtaik; Matanovic, Ivana Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/C8EE02192A	journal	January 2018
The synthesis, chain-packing simulation and long-term gas permeability of highly selective spirobifluorene-based polymers of intrinsic microporosity Bezzu, C. Grazia; Carta, Mariolino; Ferrari, Maria-Chiara Journal of Materials Chemistry A, Vol. 6, Issue 22 https://doi.org/10.1039/C8TA02601G	journal	January 2018
Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage McKeown, Neil B.; Budd, Peter M. Chemical Society Reviews, Vol. 35, Issue 8, p. 675-683 https://doi.org/10.1039/b600349d	journal	January 2006
Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2 capture Patel, Hasmukh A.; Yavuz, Cafer T. Chemical Communications, Vol. 48, Issue 80 https://doi.org/10.1039/c2cc35392j	journal	January 2012
Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation Song, Qilei; Nataraj, S. K.; Roussenova, Mina V. Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21996d	journal	January 2012
Progress and directions in low-cost redox-flow batteries for large-scale energy storage Li, Bin; Liu, Jun National Science Review, Vol. 4, Issue 1 https://doi.org/10.1093/nsr/nww098	journal	January 2017
Ultrafast selective transport of alkali metal ions in metal organic frameworks with subnanometer pores Zhang, Huacheng; Hou, Jue; Hu, Yaoxin Science Advances, Vol. 4, Issue 2 https://doi.org/10.1126/sciadv.aaq0066	journal	February 2018
Sustainable Hydrogen Production Turner, J. A. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1103197	journal	August 2004
An Efficient Polymer Molecular Sieve for Membrane Gas Separations Carta, M.; Malpass-Evans, R.; Croad, M. Science, Vol. 339, Issue 6117, p. 303-307 https://doi.org/10.1126/science.1228032	journal	January 2013
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes Joshi, R. K.; Carbone, P.; Wang, F. C. Science, Vol. 343, Issue 6172 https://doi.org/10.1126/science.1245711	journal	February 2014
Alkaline quinone flow battery Lin, K.; Chen, Q.; Gerhardt, M. R. Science, Vol. 349, Issue 6255, p. 1529-1532 https://doi.org/10.1126/science.aab3033	journal	September 2015
Full Cell Study of Diels Alder Poly(phenylene) Anion and Cation Exchange Membranes in Vanadium Redox Flow Batteries Pezeshki, A. M.; Tang, Z. J.; Fujimoto, C. Journal of The Electrochemical Society, Vol. 163, Issue 1 https://doi.org/10.1149/2.0201601jes	journal	November 2015
Precise and ultrafast molecular sieving through graphene oxide membranes Joshi, R. K.; Carbone, P.; Wang, F. C. arXiv https://doi.org/10.48550/arxiv.1401.3134	text	January 2014
Tuneable Sieving of Ions Using Graphene Oxide Membranes Abraham, J.; Vasu, K. S.; Williams, C. D. arXiv https://doi.org/10.48550/arxiv.1701.05519	text	January 2017

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