Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Gao, Wen‐Yang; Sur, Aishanee; Wang, Chen‐Hao; Lorzing, Gregory R.; Antonio, Alexandra M.; Taggart, Garrett A.; Ezazi, Andrew A.; Bhuvanesh, Nattamai; Bloch, Eric D.; Powers, David C.

doi:10.1002/ange.202002638

Title: Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Journal Article · 20 April 2020 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202002638 · OSTI ID:1615440

^[1];

^[1]; Lorzing, Gregory R. ^[2]; Antonio, Alexandra M. ^[2]; Taggart, Garrett A. ^[2];

^[1]; Bhuvanesh, Nattamai ^[1];

^[2];

^[1]

Department of Chemistry Texas A&,M University 3255 TAMU College Station TX 77843 USA
Department of Chemistry and Biochemistry University of Delaware Newark DE 19716 USA

Abstract Atomistic control of the coordination environment of lattice ions and the distribution of metal sites within crystalline mixed‐metal coordination polymers remain significant synthetic challenges. Herein is reported the mechanochemical synthesis of a reticular family of crystalline heterobimetallic metal–organic frameworks (MOFs) is now achieved by polymerization of molecular Ru ₂ [II,III] complexes, featuring unprotected carboxylic acid substituents, with Cu(OAc) ₂ . The resulting crystalline heterobimetallic MOFs are solid solutions of Ru ₂ and Cu ₂ sites housed within [M ₃ L ₂ ] phases. The developed mechanochemical strategy is modular and allows for systematic control of the primary coordination sphere of the Ru ₂ sites within an isoreticular family of materials. This strategy is anticipated to provide a rational approach to atomically precise mixed‐metal materials.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0018977

OSTI ID:: 1615440

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 27 Vol. 132; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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