Structure Sensitivity of Acetylene Semi-Hydrogenation on Pt Single Atoms and Subnanometer Clusters
Abstract
Oxide-supported Pt-group single atoms and clusters in the subnanometer size regime maximize the metal utilization and have shown extraordinary catalytic properties for many reactions including selective hydrogenation. Establishing relations between the metal nuclearity and electronic and catalytic properties is crucial for catalyst design. Here, we varied the nuclearity of Pt supported on TiO2 from single atoms to subnanometer clusters to larger nanoparticles to develop such relations for acetylene hydrogenation. We show that, in contrast to the low selectivity on large Pt nanoparticles, in the subnanometer size regime, Pt exhibits remarkably high selectivity to ethylene. Through a combination of X-ray photoelectron spectroscopy and calorimetry, we demonstrate that the origin of high selectivity is the decreased electron density on Pt and destabilization of C2H4 as the Pt nuclearity decreases. However, as the Pt nuclearity decreased, the activity for H2 activation and acetylene hydrogenation decreased, indicating a trade-off between activity and selectivity. Lastly, the results show that, while different properties emerge in the subnanometer regime, Pt supported on TiO2 appears to be bound by similar scaling and Brønsted–Evans–Polanyi relationships as on metal surfaces.
- Authors:
-
[1];
[2];
[2];
[1]
- Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1615019
- Report Number(s):
- PNNL-SA-144951
Journal ID: ISSN 2155-5435
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; single-atom catalysts; subnanometer clusters; H₂ activation; selective hydrogenation; X-ray photoelectron spectroscopy infrared spectroscopy; calorimetry; scanning transmission electron microscopy
Citation Formats
Kuo, Chun-Te, Lu, Yubing, Kovarik, Libor, Engelhard, Mark H., and Karim, Ayman M. Structure Sensitivity of Acetylene Semi-Hydrogenation on Pt Single Atoms and Subnanometer Clusters. United States: N. p., 2019.
Web. doi:10.1021/acscatal.9b02840.
Kuo, Chun-Te, Lu, Yubing, Kovarik, Libor, Engelhard, Mark H., & Karim, Ayman M. Structure Sensitivity of Acetylene Semi-Hydrogenation on Pt Single Atoms and Subnanometer Clusters. United States. https://doi.org/10.1021/acscatal.9b02840
Kuo, Chun-Te, Lu, Yubing, Kovarik, Libor, Engelhard, Mark H., and Karim, Ayman M. Tue .
"Structure Sensitivity of Acetylene Semi-Hydrogenation on Pt Single Atoms and Subnanometer Clusters". United States. https://doi.org/10.1021/acscatal.9b02840. https://www.osti.gov/servlets/purl/1615019.
@article{osti_1615019,
title = {Structure Sensitivity of Acetylene Semi-Hydrogenation on Pt Single Atoms and Subnanometer Clusters},
author = {Kuo, Chun-Te and Lu, Yubing and Kovarik, Libor and Engelhard, Mark H. and Karim, Ayman M.},
abstractNote = {Oxide-supported Pt-group single atoms and clusters in the subnanometer size regime maximize the metal utilization and have shown extraordinary catalytic properties for many reactions including selective hydrogenation. Establishing relations between the metal nuclearity and electronic and catalytic properties is crucial for catalyst design. Here, we varied the nuclearity of Pt supported on TiO2 from single atoms to subnanometer clusters to larger nanoparticles to develop such relations for acetylene hydrogenation. We show that, in contrast to the low selectivity on large Pt nanoparticles, in the subnanometer size regime, Pt exhibits remarkably high selectivity to ethylene. Through a combination of X-ray photoelectron spectroscopy and calorimetry, we demonstrate that the origin of high selectivity is the decreased electron density on Pt and destabilization of C2H4 as the Pt nuclearity decreases. However, as the Pt nuclearity decreased, the activity for H2 activation and acetylene hydrogenation decreased, indicating a trade-off between activity and selectivity. Lastly, the results show that, while different properties emerge in the subnanometer regime, Pt supported on TiO2 appears to be bound by similar scaling and Brønsted–Evans–Polanyi relationships as on metal surfaces.},
doi = {10.1021/acscatal.9b02840},
journal = {ACS Catalysis},
number = 12,
volume = 9,
place = {United States},
year = {2019},
month = {10}
}
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Figures / Tables:
Figure 1: HAADF-STEM images of Pt/TiO2 catalysts after H2 reduction at 350 °C. (a) 0.1% Pt/TiO2 (PtSA-0.7nm), (b) 1% Pt/TiO2 (Pt0.9nm), (c) 5% Pt/TiO2 (Pt1.5nm), (d) 10% Pt/TiO2 (Pt2.1nm).
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Works referenced in this record:
Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017
- Nie, Lei; Mei, Donghai; Xiong, Haifeng
- Science, Vol. 358, Issue 6369
Catalytically Active Single-Atom Sites Fabricated from Silver Particles
journal, March 2012
- Huang, Zhiwei; Gu, Xiao; Cao, Qingqing
- Angewandte Chemie International Edition, Vol. 51, Issue 17
Highly Dense Isolated Metal Atom Catalytic Sites: Dynamic Formation and In Situ Observations
journal, October 2015
- Chen, Yaxin; Kasama, Takeshi; Huang, Zhiwei
- Chemistry - A European Journal, Vol. 21, Issue 48
Improved Low-Temperature CO Oxidation Performance of Pd Supported on La-Stabilized Alumina
journal, April 2013
- Gaudet, Jason R.; de la Riva, Andrew; Peterson, Eric J.
- ACS Catalysis, Vol. 3, Issue 5
Single atom gold catalysts for low-temperature CO oxidation
journal, October 2016
- Qiao, Botao; Liang, Jin-Xia; Wang, Aiqin
- Chinese Journal of Catalysis, Vol. 37, Issue 10
Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI)
journal, July 2015
- Qiao, Botao; Liang, Jin-Xia; Wang, Aiqin
- Nano Research, Vol. 8, Issue 9
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017
- Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
- Nature Communications, Vol. 8, Issue 1
Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO 2
journal, September 2017
- DeRita, Leo; Dai, Sheng; Lopez-Zepeda, Kimberly
- Journal of the American Chemical Society, Vol. 139, Issue 40
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016
- Jones, J.; Xiong, H.; DeLaRiva, A. T.
- Science, Vol. 353, Issue 6295
Identification of the active complex for CO oxidation over single-atom Ir-on-MgAl2O4 catalysts
journal, December 2018
- Lu, Yubing; Wang, Jiamin; Yu, Liang
- Nature Catalysis, Vol. 2, Issue 2
A versatile approach for quantification of surface site fractions using reaction kinetics: The case of CO oxidation on supported Ir single atoms and nanoparticles
journal, October 2019
- Lu, Yubing; Kuo, Chun-Te; Kovarik, Libor
- Journal of Catalysis, Vol. 378
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions
journal, September 2010
- Zhai, Y.; Pierre, D.; Si, R.
- Science, Vol. 329, Issue 5999
Catalytically active Au-O(OH) x - species stabilized by alkali ions on zeolites and mesoporous oxides
journal, November 2014
- Yang, Ming; Li, Sha; Wang, Yuan
- Science, Vol. 346, Issue 6216
A Common Single-Site Pt(II)–O(OH) x – Species Stabilized by Sodium on “Active” and “Inert” Supports Catalyzes the Water-Gas Shift Reaction
journal, March 2015
- Yang, Ming; Liu, Jilei; Lee, Sungsik
- Journal of the American Chemical Society, Vol. 137, Issue 10
Enhanced performance of Rh 1 /TiO 2 catalyst without methanation in water‐gas shift reaction
journal, November 2016
- Guan, Hongling; Lin, Jian; Qiao, Botao
- AIChE Journal, Vol. 63, Issue 6
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Gold Atoms Stabilized on Various Supports Catalyze the Water–Gas Shift Reaction
journal, November 2013
- Flytzani-Stephanopoulos, Maria
- Accounts of Chemical Research, Vol. 47, Issue 3
Selective Oxidation of Alcohols to Esters Using Heterogeneous Co 3 O 4 –N@C Catalysts under Mild Conditions
journal, July 2013
- Jagadeesh, Rajenahally V.; Junge, Henrik; Pohl, Marga-Martina
- Journal of the American Chemical Society, Vol. 135, Issue 29
Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts
journal, July 2014
- Jagadeesh, Rajenahally V.; Junge, Henrik; Beller, Matthias
- Nature Communications, Vol. 5, Issue 1
Co–N–C Catalyst for C–C Coupling Reactions: On the Catalytic Performance and Active Sites
journal, October 2015
- Zhang, Leilei; Wang, Aiqin; Wang, Wentao
- ACS Catalysis, Vol. 5, Issue 11
Selective Aerobic Oxidation of Alcohols over Atomically-Dispersed Non-Precious Metal Catalysts
journal, December 2016
- Xie, Jiahan; Yin, Kehua; Serov, Alexey
- ChemSusChem, Vol. 10, Issue 2
Unique gold chemoselectivity for the aerobic oxidation of allylic alcohols
journal, January 2006
- Abad, Alberto; Almela, Carles; Corma, Avelino
- Chem. Commun., Issue 30
Low-Temperature Dehydrogenation of Ethanol on Atomically Dispersed Gold Supported on ZnZrO x
journal, December 2015
- Wang, Chongyang; Garbarino, Gabriella; Allard, Lawrence F.
- ACS Catalysis, Vol. 6, Issue 1
Organometallic model complexes elucidate the active gallium species in alkane dehydrogenation catalysts based on ligand effects in Ga K-edge XANES
journal, January 2016
- Getsoian, Andrew “Bean”; Das, Ujjal; Camacho-Bunquin, Jeffrey
- Catalysis Science & Technology, Vol. 6, Issue 16
Isolated Fe II on Silica As a Selective Propane Dehydrogenation Catalyst
journal, May 2015
- Hu, Bo; Schweitzer, Neil M.; Zhang, Guanghui
- ACS Catalysis, Vol. 5, Issue 6
A Stable Single-Site Palladium Catalyst for Hydrogenations
journal, July 2015
- Vilé, Gianvito; Albani, Davide; Nachtegaal, Maarten
- Angewandte Chemie International Edition, Vol. 54, Issue 38
Stabilizing a Platinum 1 Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity
journal, May 2016
- Zhang, Bin; Asakura, Hiroyuki; Zhang, Jia
- Angewandte Chemie International Edition, Vol. 55, Issue 29
Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015
- Yan, Huan; Cheng, Hao; Yi, Hong
- Journal of the American Chemical Society, Vol. 137, Issue 33
FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes
journal, December 2014
- Wei, Haisheng; Liu, Xiaoyan; Wang, Aiqin
- Nature Communications, Vol. 5, Issue 1
Enhancing both selectivity and coking-resistance of a single-atom Pd1/C3N4 catalyst for acetylene hydrogenation
journal, February 2017
- Huang, Xiaohui; Xia, Yujia; Cao, Yuanjie
- Nano Research, Vol. 10, Issue 4
Magnetite-supported palladium single-atoms do not catalyse the hydrogenation of alkenes but small clusters do
journal, January 2016
- Rossell, Marta D.; Caparrós, Francisco J.; Angurell, Inmaculada
- Catalysis Science & Technology, Vol. 6, Issue 12
Structure sensitivity in the nonscalable regime explored via catalysed ethylene hydrogenation on supported platinum nanoclusters
journal, January 2016
- Crampton, Andrew S.; Rötzer, Marian D.; Ridge, Claron J.
- Nature Communications, Vol. 7, Issue 1
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene
journal, June 2008
- Studt, F.; Abild-Pedersen, F.; Bligaard, T.
- Science, Vol. 320, Issue 5881
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
journal, April 2018
- Liu, Lichen; Corma, Avelino
- Chemical Reviews, Vol. 118, Issue 10
Free-atom-like d states in single-atom alloy catalysts
journal, August 2018
- Greiner, M. T.; Jones, T. E.; Beeg, S.
- Nature Chemistry, Vol. 10, Issue 10
Elucidating the Stability and Reactivity of Surface Intermediates on Single-Atom Alloy Catalysts
journal, April 2018
- Darby, Matthew T.; Réocreux, Romain; Sykes, E. Charles. H.
- ACS Catalysis, Vol. 8, Issue 6
Lonely Atoms with Special Gifts: Breaking Linear Scaling Relationships in Heterogeneous Catalysis with Single-Atom Alloys
journal, September 2018
- Darby, Matthew T.; Stamatakis, Michail; Michaelides, Angelos
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 18
Understanding the Influence of the Pretreatment Procedure on Platinum Particle Size and Particle-Size Distribution for SiO2 Impregnated with [Pt2+(NH3)4](NO3−)2: A Combination of HRTEM, Mass Spectrometry, and Quick EXAFS
journal, January 2002
- Oudenhuijzen, M. K.; Kooyman, P. J.; Tappel, B.
- Journal of Catalysis, Vol. 205, Issue 1
Size and Shape Control of Metal Nanoparticles for Reaction Selectivity in Catalysis
journal, August 2012
- An, Kwangjin; Somorjai, Gabor A.
- ChemCatChem, Vol. 4, Issue 10
Nature of stable single atom Pt catalysts dispersed on anatase TiO2
journal, November 2018
- Thang, Ho Viet; Pacchioni, Gianfranco; DeRita, Leo
- Journal of Catalysis, Vol. 367
Identifying Size Effects of Pt as Single Atoms and Nanoparticles Supported on FeO x for the Water-Gas Shift Reaction
journal, January 2018
- Chen, Yang; Lin, Jian; Li, Lin
- ACS Catalysis, Vol. 8, Issue 2
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015
- Ding, K.; Gulec, A.; Johnson, A. M.
- Science, Vol. 350, Issue 6257
Stabilizing Single-Atom and Small-Domain Platinum via Combining Organometallic Chemisorption and Atomic Layer Deposition
journal, February 2017
- Liu, Shengsi; Tan, J. Miles; Gulec, Ahmet
- Organometallics, Vol. 36, Issue 4
An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation
journal, March 2018
- Therrien, Andrew J.; Hensley, Alyssa J. R.; Marcinkowski, Matthew D.
- Nature Catalysis, Vol. 1, Issue 3
Small Au and Pt Clusters at the Anatase TiO 2 (101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies
journal, January 2008
- Gong, Xue-Qing; Selloni, Annabella; Dulub, Olga
- Journal of the American Chemical Society, Vol. 130, Issue 1
Structural evolution of atomically dispersed Pt catalysts dictates reactivity
journal, April 2019
- DeRita, Leo; Resasco, Joaquin; Dai, Sheng
- Nature Materials, Vol. 18, Issue 7
Thermodynamics of the dissolution of amorphous and polymorphic TiO2 modifications in acid and alkaline media
journal, February 2016
- Shkol’nikov, E. V.
- Russian Journal of Physical Chemistry A, Vol. 90, Issue 3
Characterization of mono- and bi-metallic platinum catalysts using CO FTIR spectroscopy Size effects and topological segregation
journal, January 1997
- de Me´norval, Louis-Charles; Chaqroune, Abdellah; Coq, Bernard
- Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 20
Platinum bronzes. IV. Preparation, crystal chemistry, and physical properties
journal, June 1974
- Cahen, David.; Ibers, James A.; Wagner, J. Bruce.
- Inorganic Chemistry, Vol. 13, Issue 6
Third Row Transition Metals by X-ray Photoelectron Spectroscopy
journal, January 2000
- Engelhard, Mark; Baer, Don
- Surface Science Spectra, Vol. 7, Issue 1
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO2 Surfaces
journal, November 2009
- Kaden, W. E.; Wu, T.; Kunkel, W. A.
- Science, Vol. 326, Issue 5954
Electronic structure of anatase TiO 2 oxide
journal, March 1994
- Sanjinés, R.; Tang, H.; Berger, H.
- Journal of Applied Physics, Vol. 75, Issue 6
2s and 2p X-ray photoelectron spectra of Ti4+ ion in TiO2
journal, May 1976
- Sen, S. K.; Riga, J.; Verbist, J.
- Chemical Physics Letters, Vol. 39, Issue 3
The hydrogenation of acetylene I. The reaction of acetylene with hydrogen catalyzed by alumina-supported platinum
journal, April 1965
- Bond, G.
- Journal of Catalysis, Vol. 4, Issue 2
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts
journal, September 2016
- Matsubu, John C.; Zhang, Shuyi; DeRita, Leo
- Nature Chemistry, Vol. 9, Issue 2
Toward Rational Design of Oxide-Supported Single-Atom Catalysts: Atomic Dispersion of Gold on Ceria
journal, April 2017
- Liu, Jin-Cheng; Wang, Yang-Gang; Li, Jun
- Journal of the American Chemical Society, Vol. 139, Issue 17
Classical strong metal–support interactions between gold nanoparticles and titanium dioxide
journal, October 2017
- Tang, Hailian; Su, Yang; Zhang, Bingsen
- Science Advances, Vol. 3, Issue 10
Strong Metal–Support Interactions Achieved by Hydroxide-to-Oxide Support Transformation for Preparation of Sinter-Resistant Gold Nanoparticle Catalysts
journal, October 2017
- Wang, Liang; Zhang, Jian; Zhu, Yihan
- ACS Catalysis, Vol. 7, Issue 11
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction
journal, August 2017
- Li, Siwei; Xu, Yao; Chen, Yifu
- Angewandte Chemie International Edition, Vol. 56, Issue 36
TiO 2– x -Modified Ni Nanocatalyst with Tunable Metal–Support Interaction for Water–Gas Shift Reaction
journal, October 2017
- Xu, Ming; He, Shan; Chen, Hao
- ACS Catalysis, Vol. 7, Issue 11
Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface
journal, July 2017
- Kattel, Shyam; Liu, Ping; Chen, Jingguang G.
- Journal of the American Chemical Society, Vol. 139, Issue 29
Low-Temperature CO 2 Methanation over CeO 2 -Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support Interactions and H-Spillover Effect
journal, May 2018
- Guo, Yu; Mei, Sheng; Yuan, Kun
- ACS Catalysis, Vol. 8, Issue 7
Selective Hydrogenation for Fine Chemicals: Recent Trends and New Developments
journal, January 2003
- Blaser, Hans-Ulrich; Malan, Christophe; Pugin, Benoît
- Advanced Synthesis & Catalysis, Vol. 345, Issue 12
Microcalorimetric, Spectroscopic, and Kinetic Studies of Silica Supported Pt and Pt/Sn Catalysts for Isobutane Dehydrogenation
journal, August 1994
- Cortright, R. D.; Dumesic, J. A.
- Journal of Catalysis, Vol. 148, Issue 2
Microcalorimetric, Infrared Spectroscopic, and DFT Studies of Ethylene Adsorption on Pt/SiO 2 and Pt−Sn/SiO 2 Catalysts
journal, May 1999
- Shen, Jianyi; Hill, Josephine M.; Watwe, Ramchandra M.
- The Journal of Physical Chemistry B, Vol. 103, Issue 19
Microcalorimetric Studies of H2, C2H4, and C2H2Adsorption on Pt Powder
journal, June 1998
- Spiewak, B. E.; Cortright, R. D.; Dumesic, J. A.
- Journal of Catalysis, Vol. 176, Issue 2
Microcalorimetric, Infrared Spectroscopic, and DFT Studies of Ethylene Adsorption on Pd and Pd/Sn Catalysts
journal, March 2000
- Hill, Josephine M.; Shen, Jianyi; Watwe, Ramchandra M.
- Langmuir, Vol. 16, Issue 5
Microcalorimetric and infrared spectroscopic studies of CO and C2H4 adsorption on Pd/SiO2 and Pd–Ag/SiO2 catalysts
journal, February 2001
- Li, Mingshi; Shen, Jianyi
- Materials Chemistry and Physics, Vol. 68, Issue 1-3
Oxide- and Zeolite-Supported Isostructural Ir(C 2 H 4 ) 2 Complexes: Molecular-Level Observations of Electronic Effects of Supports as Ligands
journal, August 2012
- Lu, Jing; Aydin, Ceren; Browning, Nigel D.
- Langmuir, Vol. 28, Issue 35
Oxide- and Zeolite-Supported Molecular Metal Complexes and Clusters: Physical Characterization and Determination of Structure, Bonding, and Metal Oxidation State
journal, July 2006
- Fierro-Gonzalez, Juan C.; Kuba, Stefan; Hao, Yalin
- The Journal of Physical Chemistry B, Vol. 110, Issue 27
Supported Molecular Iridium Catalysts: Resolving Effects of Metal Nuclearity and Supports as Ligands
journal, October 2011
- Lu, Jing; Serna, Pedro; Aydin, Ceren
- Journal of the American Chemical Society, Vol. 133, Issue 40
Zeolite- and MgO-Supported Molecular Iridium Complexes: Support and Ligand Effects in Catalysis of Ethene Hydrogenation and H–D Exchange in the Conversion of H 2 + D 2
journal, October 2011
- Lu, Jing; Serna, Pedro; Gates, Bruce C.
- ACS Catalysis, Vol. 1, Issue 11
Isostructural Zeolite-Supported Rhodium and Iridium Complexes: Tuning Catalytic Activity and Selectivity by Ligand Modification
journal, August 2015
- Martinez-Macias, Claudia; Serna, Pedro; Gates, Bruce C.
- ACS Catalysis, Vol. 5, Issue 10
Syntheses of palladium(0) and platinum(0) olefin complexes; molecular structures of [Pt(C2F4)(C2H4)2] and tris(bicyclo[2.2.1]heptene)platinum
journal, January 1975
- Green, Michael; Howard, Judith A. K.; Spencer, John L.
- Journal of the Chemical Society, Chemical Communications, Issue 11
The Electronic Structure of the Tris(ethylene) Complexes [M(C2H4)3] (M=Ni, Pd, and Pt): A Combined Experimental and Theoretical Study
journal, December 2007
- Hebben, Nicole; Himmel, Hans-Jörg; Eickerling, Georg
- Chemistry - A European Journal, Vol. 13, Issue 36
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene
journal, May 2015
- Pei, Guang Xian; Liu, Xiao Yan; Wang, Aiqin
- ACS Catalysis, Vol. 5, Issue 6
Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon–carbon vs. carbon–hydrogen bond formation reactions of ethene in the presence of H2
journal, December 2013
- Serna, Pedro; Gates, Bruce C.
- Journal of Catalysis, Vol. 308
Hydrogen and Oxygen Adsorption on Rh n ( n = 1−6) Clusters
journal, December 2003
- Mainardi, Daniela S.; Balbuena, Perla B.
- The Journal of Physical Chemistry A, Vol. 107, Issue 48
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journal, February 2020
- Stathi, Panagiota; Solakidou, Maria; Louloudi, Maria
- Energies, Vol. 13, Issue 3
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journal, March 2020
- Lu, Yubing; Thompson, Coogan; Kunwar, Deepak
- ChemCatChem, Vol. 12, Issue 6
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journal, January 2020
- Hamayun, Muhammad Haris; Maafa, Ibrahim M.; Hussain, Murid
- Energies, Vol. 13, Issue 1
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