DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High Strength and Deformation Mechanisms of Al0.3CoCrFeNi High-Entropy Alloy Thin Films Fabricated by Magnetron Sputtering

Journal Article · · Entropy
DOI: https://doi.org/10.3390/e21020146 · OSTI ID:1614938
 [1];  [2];  [1];  [1];  [1];  [1]; ORCiD logo [3]
  1. Shenzhen Univ. (China)
  2. City Univ. of Hong Kong (China); Shanghai Tech Univ. (China)
  3. City Univ. of Hong Kong (China); City Univ. of Hong Kong Shenzhen Research Inst. (China)

Recently, high-entropy alloy thin films (HEATFs) with nanocrystalline structures and high hardness were developed by magnetron sputtering technique and have exciting potential to make small structure devices and precision instruments with sizes ranging from nanometers to micrometers. However, the strength and deformation mechanisms are still unclear. In this work, nanocrystalline Al0.3CoCrFeNi HEATFs with a thickness of ~4 μm were prepared. The microstructures of the thin films were comprehensively characterized, and the mechanical properties were systematically studied. It was found that the thin film was smooth, with a roughness of less than 5 nm. The chemical composition of the high entropy alloy thin film was homogeneous with a main single face-centered cubic (FCC) structure. Furthermore, it was observed that the hardness and the yield strength of the high-entropy alloy thin film was about three times that of the bulk samples, and the plastic deformation was inhomogeneous. Our results could provide an in-depth understanding of the mechanics and deformation mechanism for future design of nanocrystalline HEATFs with desired properties.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
National Natural Science Foundation of China (NSFC); Youth Innovation Talent Project of Guangdong Province; Shenzhen University; Shenzhen Science and Technology Innovation Committee
OSTI ID:
1614938
Journal Information:
Entropy, Journal Name: Entropy Journal Issue: 2 Vol. 21; ISSN 1099-4300
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
ENGLISH

References (41)

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes journal May 2004
High-Entropy Alloy (HEA)-Coated Nanolattice Structures and Their Mechanical Properties journal September 2017
Fatigue behavior of high-entropy alloys: A review journal November 2017
Plastic Deformation of Al0.3CoCrFeNi and AlCoCrFeNi High-Entropy Alloys Under Nanoindentation journal June 2015
High-Entropy Alloys with a Hexagonal Close-Packed Structure Designed by Equi-Atomic Alloy Strategy and Binary Phase Diagrams journal July 2014
Irradiation Resistance in Al x CoCrFeNi High Entropy Alloys journal August 2015
Excellent ductility and serration feature of metastable CoCrFeNi high-entropy alloy at extremely low temperatures journal December 2018
Size-dependent plasticity in an Nb25Mo25Ta25W25 refractory high-entropy alloy journal February 2014
A precipitation-hardened high-entropy alloy with outstanding tensile properties journal January 2016
High-entropy Al0.3CoCrFeNi alloy fibers with high tensile strength and ductility at ambient and cryogenic temperatures journal January 2017
Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range journal February 2017
Preparation and characterization of TaNbTiW multi-element alloy films journal November 2012
Size effects on the mechanical properties of nanocrystalline NbMoTaW refractory high entropy alloy thin films journal August 2017
Refractory high-entropy alloys journal September 2010
Superior high tensile elongation of a single-crystal CoCrFeNiAl0.3 high-entropy alloy by Bridgman solidification journal November 2014
An assessment on the future development of high-entropy alloys: Summary from a recent workshop journal November 2015
Structure formation and properties of sputter deposited Nbx-CoCrCuFeNi high entropy alloy thin films journal October 2015
Combinatorial synthesis of high entropy alloys: Introduction of a novel, single phase, body-centered-cubic FeMnCoCrAl solid solution journal January 2017
Prediction of high-entropy stabilized solid-solution in multi-component alloys journal February 2012
High-entropy alloy: challenges and prospects journal July 2016
Beating hydrogen with its own weapon: Nano-twin gradients enhance embrittlement resistance of a high-entropy alloy journal December 2018
Microstructural development in equiatomic multicomponent alloys journal July 2004
Microstructures and properties of high-entropy alloys journal April 2014
Serration and noise behaviors in materials journal October 2017
Effects of nanotwins on the mechanical properties of Al x CoCrFeNi high entropy alloy thin films journal October 2017
Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering journal November 2004
Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering journal November 2005
High entropy alloy thin films deposited by magnetron sputtering of powder targets journal April 2015
Nanocrystalline high-entropy alloy (CoCrFeNiAl0.3) thin-film coating by magnetron sputtering journal September 2017
Nanocrystalline High-Entropy Alloys: A New Paradigm in High-Temperature Strength and Stability journal February 2017
Confusion by design journal December 1993
Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off journal May 2016
Enhancing radiation tolerance by controlling defect mobility and migration pathways in multicomponent single-phase alloys journal December 2016
Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes journal November 2018
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys journal May 2011
In situ mechanical characterization of CoCrCuFeNi high-entropy alloy micro/nano-pillars for their size-dependent mechanical behavior journal September 2016
A fracture-resistant high-entropy alloy for cryogenic applications journal September 2014
Microstructure, Mechanical and Corrosion Behaviors of CoCrFeNiAl0.3 High Entropy Alloy (HEA) Films journal September 2017
Nano-Crystallization of High-Entropy Amorphous NbTiAlSiWxNy Films Prepared by Magnetron Sputtering journal June 2016
Effects of Nitrogen Content on the Structure and Mechanical Properties of (Al0.5CrFeNiTi0.25)Nx High-Entropy Films by Reactive Sputtering journal August 2018
A Novel Low-Activation VCrFeTaxWx (x = 0.1, 0.2, 0.3, 0.4, and 1) High-Entropy Alloys with Excellent Heat-Softening Resistance journal December 2018

Cited By (2)

Small-scale mechanical behavior of a eutectic high entropy alloy journal February 2020
Constitutive modeling and strain hardening of CoCrFeNiAl x high-entropy alloys journal September 2019