Impedance Spectroscopy Characterization of PEM Fuel Cells with Fe-N-C-Based Cathodes

Reshetenko, Tatyana; Serov, Alexey; Kulikovsky, Andrei; Atanassov, Plamen

doi:10.1149/2.1431910jes

Title: Impedance Spectroscopy Characterization of PEM Fuel Cells with Fe-N-C-Based Cathodes

Journal Article · 26 June 2019 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/2.1431910jes · OSTI ID:1613520

^[1]; Serov, Alexey ^[2];

^[3]; Atanassov, Plamen ^[4]

Univ. of Hawaii, Honolulu, HI (United States)
Pajarito Powder, LLC, Albuquerque, NM (United States)
Inst. of Energy and Climate Research, Jülich (Germany)
Univ. of California, Irvine, CA (United States)

We report impedance spectroscopy analysis of PEM fuel cells built with platinum group metal-free (PGM-free) Fe-N-C cathodes with the catalyst loading and ionomer to catalyst ratio being variable parameters. The dependence of key cathode transport and kinetic parameters on the cell current density J are obtained in the range from 0.025 to 0.4 A cm^-2. The electrode performance is evaluated using the characteristic current densities for proton and oxygen transport in the cathode catalyst layer. Overall, certain electrode configurations demonstrate proton and oxygen transport properties comparable to those of Pt/C systems, making them promising substitutes for platinum at cathodic side of PEM fuel cells.

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Research Organization:: Pajarito Powder, LLC, Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008419

OSTI ID:: 1613520

Journal Information:: Journal of the Electrochemical Society, Vol. 166, Issue 10; ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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