Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
Abstract
Biological fluoride ion channels are sub-1-nanometer protein pores with ultrahigh F- conductivity and selectivity over other halogen ions. Developing synthetic F- channels with biological-level selectivity is highly desirable for ion separations such as water defluoridation, but it remains a great challenge. Here we report synthetic F- channels fabricated from zirconium-based metal-organic frameworks (MOFs), UiO-66-X ( x = H, NH2, and N+(CH3)3). These MOFs are comprised of nanometer-sized cavities connected by sub-1-nanometer-sized windows and have specific F- binding sites along the channels, sharing some features of biological F- channels. UiO-66-X channels consistently show ultrahigh F- conductivity up to ~10 S m-1, and ultrahigh F-/Cl- selectivity, from ~13 to ~240. Molecular dynamics simulations reveal that the ultrahigh F- conductivity and selectivity can be ascribed mainly to the high F- concentration in the UiO-66 channels, arising from specific interactions between F- ions and F- binding sites in the MOF channels.
- Authors:
-
[1];
[1];
[2];
[5];
[3];
- Monash Univ., Clayton, VIC (Australia)
- Univ. of Melbourne, Parkville, VIC (Australia)
- Commonwealth Scientific and Industrial Research Organisation (CSIRO), Clayton, VIC (Australia)
- Monash Univ., Clayton, VIC (Australia); Commonwealth Scientific and Industrial Research Organisation (CSIRO), Clayton, VIC (Australia)
- Univ. of Texas, Austin, TX (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Materials for Water and Energy Systems (M-WET); Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Australian Research Council; Australia-China Science and Research Fund
- OSTI Identifier:
- 1613158
- Grant/Contract Number:
- SC0019272; DP150100765; DP180100298; DE170100006; ACSRF48154
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 59 BASIC BIOLOGICAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Li, Xingya, Zhang, Huacheng, Wang, Peiyao, Hou, Jue, Lu, Jun, Easton, Christopher D., Zhang, Xiwang, Hill, Matthew R., Thornton, Aaron W., Liu, Jefferson Zhe, Freeman, Benny D., Hill, Anita J., Jiang, Lei, and Wang, Huanting. Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-10420-9.
Li, Xingya, Zhang, Huacheng, Wang, Peiyao, Hou, Jue, Lu, Jun, Easton, Christopher D., Zhang, Xiwang, Hill, Matthew R., Thornton, Aaron W., Liu, Jefferson Zhe, Freeman, Benny D., Hill, Anita J., Jiang, Lei, & Wang, Huanting. Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels. United States. https://doi.org/10.1038/s41467-019-10420-9
Li, Xingya, Zhang, Huacheng, Wang, Peiyao, Hou, Jue, Lu, Jun, Easton, Christopher D., Zhang, Xiwang, Hill, Matthew R., Thornton, Aaron W., Liu, Jefferson Zhe, Freeman, Benny D., Hill, Anita J., Jiang, Lei, and Wang, Huanting. Tue .
"Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels". United States. https://doi.org/10.1038/s41467-019-10420-9. https://www.osti.gov/servlets/purl/1613158.
@article{osti_1613158,
title = {Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels},
author = {Li, Xingya and Zhang, Huacheng and Wang, Peiyao and Hou, Jue and Lu, Jun and Easton, Christopher D. and Zhang, Xiwang and Hill, Matthew R. and Thornton, Aaron W. and Liu, Jefferson Zhe and Freeman, Benny D. and Hill, Anita J. and Jiang, Lei and Wang, Huanting},
abstractNote = {Biological fluoride ion channels are sub-1-nanometer protein pores with ultrahigh F- conductivity and selectivity over other halogen ions. Developing synthetic F- channels with biological-level selectivity is highly desirable for ion separations such as water defluoridation, but it remains a great challenge. Here we report synthetic F- channels fabricated from zirconium-based metal-organic frameworks (MOFs), UiO-66-X ( x = H, NH2, and N+(CH3)3). These MOFs are comprised of nanometer-sized cavities connected by sub-1-nanometer-sized windows and have specific F- binding sites along the channels, sharing some features of biological F- channels. UiO-66-X channels consistently show ultrahigh F- conductivity up to ~10 S m-1, and ultrahigh F-/Cl- selectivity, from ~13 to ~240. Molecular dynamics simulations reveal that the ultrahigh F- conductivity and selectivity can be ascribed mainly to the high F- concentration in the UiO-66 channels, arising from specific interactions between F- ions and F- binding sites in the MOF channels.},
doi = {10.1038/s41467-019-10420-9},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Tue Jun 11 00:00:00 EDT 2019},
month = {Tue Jun 11 00:00:00 EDT 2019}
}
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Widespread Genetic Switches and Toxicity Resistance Proteins for Fluoride
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