Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Magnetoelectric Radical Hydrocarbons

Abstract

The molecular radicals, systems with unpaired electrons of open-shell electronic structures, set the stage for a multidisciplinary science frontier relevant to the cooperative magnetic exchange interaction and magnetoelectric effect. Here ferroelectricity together with magnetic spin exchange coupling in molecular radical hydrocarbon solids is reported, representing a new class of magnetoelectrics. Electronic correlation through radical–radical interactions plays a decisive role in the coupling between magnetic and charge orders. A substantial photoconductance and visible-light photovoltaic effect are found in radical hydrocarbons. Finally, the ability to simultaneously control and retrieve the changes in magnetic and electrical responses opens up a new breadth of applications, such as radical magnetoelectrics, magnets, and optoelectronics.

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. State Univ. of New York at Buffalo, NY (United States)
  2. Chinese Academy of Sciences (CAS), Shenzhen (China)
Publication Date:
Research Org.:
State Univ. of New York (SUNY), Albany, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; US Army Research Office (ARO); National Science Foundation (NSF)
OSTI Identifier:
1613003
Grant/Contract Number:  
SC0018631; W911NF-18-2-0202; CHE-0959565
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 31; Journal Issue: 3; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; chemistry; science & technology; materials science; physics; molecular radicals; hydrocarbon; magnetoelectrics; ferroelectricity

Citation Formats

Guan, Ying‐Shi, Zhong, Guohua, Hu, Yong, Cannella, Anthony F., Li, Changning, Lee, Namhoon, Jia, Quanxi, Lacy, David C., and Ren, Shenqiang. Magnetoelectric Radical Hydrocarbons. United States: N. p., 2018. Web. doi:10.1002/adma.201806263.
Copy to clipboard
Guan, Ying‐Shi, Zhong, Guohua, Hu, Yong, Cannella, Anthony F., Li, Changning, Lee, Namhoon, Jia, Quanxi, Lacy, David C., & Ren, Shenqiang. Magnetoelectric Radical Hydrocarbons. United States. https://doi.org/10.1002/adma.201806263
Copy to clipboard
Guan, Ying‐Shi, Zhong, Guohua, Hu, Yong, Cannella, Anthony F., Li, Changning, Lee, Namhoon, Jia, Quanxi, Lacy, David C., and Ren, Shenqiang. Tue . "Magnetoelectric Radical Hydrocarbons". United States. https://doi.org/10.1002/adma.201806263. https://www.osti.gov/servlets/purl/1613003.
Copy to clipboard
@article{osti_1613003,
title = {Magnetoelectric Radical Hydrocarbons},
author = {Guan, Ying‐Shi and Zhong, Guohua and Hu, Yong and Cannella, Anthony F. and Li, Changning and Lee, Namhoon and Jia, Quanxi and Lacy, David C. and Ren, Shenqiang},
abstractNote = {The molecular radicals, systems with unpaired electrons of open-shell electronic structures, set the stage for a multidisciplinary science frontier relevant to the cooperative magnetic exchange interaction and magnetoelectric effect. Here ferroelectricity together with magnetic spin exchange coupling in molecular radical hydrocarbon solids is reported, representing a new class of magnetoelectrics. Electronic correlation through radical–radical interactions plays a decisive role in the coupling between magnetic and charge orders. A substantial photoconductance and visible-light photovoltaic effect are found in radical hydrocarbons. Finally, the ability to simultaneously control and retrieve the changes in magnetic and electrical responses opens up a new breadth of applications, such as radical magnetoelectrics, magnets, and optoelectronics.},
doi = {10.1002/adma.201806263},
journal = {Advanced Materials},
number = 3,
volume = 31,
place = {United States},
year = {Tue Nov 20 00:00:00 EST 2018},
month = {Tue Nov 20 00:00:00 EST 2018}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.201806263
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Structural and Bonding Characteristics of Potassium-Doped p -Terphenyl Superconductors
journal, February 2018

  • Zhong, Guo-Hua; Wang, Xiao-Hui; Wang, Ren-Shu
  • The Journal of Physical Chemistry C, Vol. 122, Issue 7
  • DOI: 10.1021/acs.jpcc.7b12616

Experimental determination of the magnetoelectric coupling coefficient via piezoelectric measurements
journal, February 2008

A Multiferroic Perdeutero Metal-Organic Framework
journal, October 2011

  • Fu, Da-Wei; Zhang, Wen; Cai, Hong-Ling
  • Angewandte Chemie International Edition, Vol. 50, Issue 50
  • DOI: 10.1002/anie.201103265

A Molecular Ferroelectric Thin Film of Imidazolium Perchlorate That Shows Superior Electromechanical Coupling
journal, April 2014

Singlet Diradical Character from Experiment
journal, February 2010

  • Kamada, Kenji; Ohta, Koji; Shimizu, Akihiro
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 6
  • DOI: 10.1021/jz100155s

Multiferroic BaTiO3-CoFe2O4 Nanostructures
journal, January 2004

Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)
journal, November 2012

  • Cai, Hong-Ling; Zhang, Yi; Fu, Da-Wei
  • Journal of the American Chemical Society, Vol. 134, Issue 45
  • DOI: 10.1021/ja3073319

The evolution of multiferroics
journal, July 2016

A nonconjugated radical polymer glass with high electrical conductivity
journal, March 2018

π-Conjugated dithieno[3,2-b:2′,3′-d]pyrrole (DTP) oligomers for organic thin-film transistors
journal, January 2016

  • Lin, Gaobo; Qin, Yunke; Guan, Ying-Shi
  • RSC Advances, Vol. 6, Issue 6
  • DOI: 10.1039/C5RA24845K

Structural and electronic properties of potassium-doped 1,2;8,9-dibenzopentacene superconductor: comparing with doped [7]phenacenes
journal, December 2016

Single-bundle nanofiber based OFETs fabricated from a cyclic conjugated organogelator with high field-effect mobility and high photoresponsivity
journal, January 2015

  • Guan, Ying-Shi; Qin, Yunke; Sun, Yuanhui
  • Chemical Communications, Vol. 51, Issue 61
  • DOI: 10.1039/C5CC04711K

Two-Dimensional Metal-Free Organic Multiferroic Material for Design of Multifunctional Integrated Circuits
journal, April 2017

  • Tu, Zhengyuan; Wu, Menghao; Zeng, Xiao Cheng
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 9
  • DOI: 10.1021/acs.jpclett.7b00636

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Multiferroicity in an organic charge-transfer salt that is suggestive of electric-dipole-driven magnetism
journal, August 2012

  • Lunkenheimer, Peter; Müller, Jens; Krohns, Stephan
  • Nature Materials, Vol. 11, Issue 9
  • DOI: 10.1038/nmat3400

Donor–acceptor co-assembled supramolecular nanofibers with high and well-balanced ambipolar charge transport properties under ambient conditions
journal, January 2016

  • Guan, Ying-Shi; Qin, Yunke; Sun, Yuanhui
  • Chemical Communications, Vol. 52, Issue 25
  • DOI: 10.1039/C6CC01300G

Photo-spin-voltaic effect
journal, April 2016

  • Ellsworth, David; Lu, Lei; Lan, Jin
  • Nature Physics, Vol. 12, Issue 9
  • DOI: 10.1038/nphys3738

Radical and Diradical Formation in Naphthalene Diimides through Simple Chemical Oxidation
journal, February 2017

Coexistence of Magnetic and Electric Orderings in the Metal–Formate Frameworks of [NH 4 ][M(HCOO) 3 ]
journal, September 2011

  • Xu, Guan-Cheng; Zhang, Wen; Ma, Xiao-Ming
  • Journal of the American Chemical Society, Vol. 133, Issue 38
  • DOI: 10.1021/ja206891q

Magnetic Ordering in an Organic Polymer
journal, November 2001

Ferroelectricity in a one-dimensional organic quantum magnet
journal, January 2010

  • Kagawa, Fumitaka; Horiuchi, Sachio; Tokunaga, Masashi
  • Nature Physics, Vol. 6, Issue 3
  • DOI: 10.1038/nphys1503

The First Organic-Inorganic Hybrid Luminescent Multiferroic: (Pyrrolidinium)MnBr 3
journal, May 2015

Neutral Radical and Singlet Biradical Forms of Meso-Free, -Keto, and -Diketo Hexaphyrins(1.1.1.1.1.1): Effects on Aromaticity and Photophysical Properties
journal, October 2011

  • Ishida, Masatoshi; Shin, Jae-Yoon; Lim, Jong Min
  • Journal of the American Chemical Society, Vol. 133, Issue 39
  • DOI: 10.1021/ja204626t

Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals
journal, May 2016

  • Rudebusch, Gabriel E.; Zafra, José L.; Jorner, Kjell
  • Nature Chemistry, Vol. 8, Issue 8
  • DOI: 10.1038/nchem.2518

Control of magnetism by electric fields
journal, March 2015

  • Matsukura, Fumihiro; Tokura, Yoshinori; Ohno, Hideo
  • Nature Nanotechnology, Vol. 10, Issue 3
  • DOI: 10.1038/nnano.2015.22

Multiferroic and magnetoelectric materials
journal, August 2006

  • Eerenstein, W.; Mathur, N. D.; Scott, J. F.
  • Nature, Vol. 442, Issue 7104
  • DOI: 10.1038/nature05023

Raman studies of polarons and bipolarons in sodium-doped poly-p-phenylene
journal, March 1993

A Multiferroic Perdeutero Metal-Organic Framework
journal, October 2011

Multiferroic and Magnetoelectric Materials
journal, October 2006

Structural and bonding character of potassium-doped p-terphenyl superconductors
text, January 2017

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Room‐Temperature Magnetoelectric Response in Molecular–Ionic Ferroelectric‐Based Magnetoelectric Composites
    journal, January 2020

    • Li, Dong; Zhao, Xue-Mei; Zhao, Hai-Xia
    • physica status solidi (RRL) – Rapid Research Letters, Vol. 14, Issue 3
    • DOI: 10.1002/pssr.202070018
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: