Effects of Improved 17O Correction on Interlaboratory Agreement in Clumped Isotope Calibrations, Estimates of Mineral-Specific Offsets, and Temperature Dependence of Acid Digestion Fractionation
Abstract
The clumped isotopic composition of carbonate-CO2 (denoted Δ47) is a function of carbonate formation temperature and in natural samples can act as a recorder of paleoclimate, burial, or diagenetic conditions. The absolute abundance of heavy isotopes in the universal standards VPDB and VSMOW (defined by four parameters: R 13VPDB, R17VSMOW, R 18VSMOW, and λ) impact calculated Δ47 values. In this work, we investigate whether use of updated and more accurate values for these parameters can remove observed interlaboratory differences in the measured T-Δ47 relationship. Using the updated parameters, we reprocess 14 published calibration data sets measured in 11 different laboratories, representing many mineralogies, bulk compositions, sample types, reaction temperatures, and sample preparation and analysis methods. Exploiting this large composite data set (n = 1,253 sample replicates), we investigate the possibility for a “universal” clumped isotope calibration. We find that applying updated parameters improves the T-Δ47 relationship (reduces residuals) within most labs and improves overall agreement but does not eliminate all interlaboratory differences. We reaffirm earlier findings that different mineralogies do not require different calibration equations and that cleaning procedures, method of pressure baseline correction, and mass spectrometer type do not affect interlaboratory agreement. We also present new estimates ofmore »
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[1];
[2];
[3];
[4];
[3];
[5];
[3];
[6];
[7];
[8];
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[3];
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[6];
[13];
[10]
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- Univ. of Michigan, Ann Arbor, MI (United States)
- Texas A & M Univ., College Station, TX (United States); Univ. of California, Los Angeles, CA (United States)
- Univ. of Washington, Seattle, WA (United States)
- Lab. des Sciences du Climat et de l'Environnement, Gif‐sur‐Yvette (France)
- Imperial College, London (United Kingdom)
- ETH‐Zurich (Switzerland)
- Univ. of Chicago, IL (United States)
- Heidelberg Univ. (Germany)
- Goethe‐Univ., Frankfurt am Main (Germany)
- Inst. de Physique du Globe, Paris (France)
- Ruhr‐Univ., Bochum (Germany); Cambridge Univ. (United Kingdom)
- Stony Brook Univ., NY (United States)
- Cambridge Univ. (United Kingdom)
- Hungarian Academy of Sciences, Budapest (Hungary)
- Jet Propulsion Lab., Pasadena, CA (United States)
- Univ. of South Florida, St. Petersburg, FL (United States)
- Univ. of California, Los Angeles, CA (United States)
- Grand Valley State Univ., Allendale, MI (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)
- OSTI Identifier:
- 1611378
- Alternate Identifier(s):
- OSTI ID: 1543367
- Grant/Contract Number:
- SC0010288; EAR-1156134; 1713275; 093831
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 7; Journal ID: ISSN 1525-2027
- Publisher:
- American Geophysical Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; geochemistry & geophysics; clumped isotopes; stable isotopes; calibration; standardization
Citation Formats
Petersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., Olack, G. A., Schauer, A. J., Bajnai, D., Bonifacie, M., Breitenbach, S. F. M., Fiebig, J., Fernandez, A. B., Henkes, G. A., Hodell, D., Katz, A., Kele, S., Lohmann, K. C., Passey, B. H., Peral, M. Y., Petrizzo, D. A., Rosenheim, B. E., Tripati, A., Venturelli, R., Young, E. D., and Winkelstern, I. Z. Effects of Improved 17O Correction on Interlaboratory Agreement in Clumped Isotope Calibrations, Estimates of Mineral-Specific Offsets, and Temperature Dependence of Acid Digestion Fractionation. United States: N. p., 2019.
Web. doi:10.1029/2018gc008127.
Petersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., Olack, G. A., Schauer, A. J., Bajnai, D., Bonifacie, M., Breitenbach, S. F. M., Fiebig, J., Fernandez, A. B., Henkes, G. A., Hodell, D., Katz, A., Kele, S., Lohmann, K. C., Passey, B. H., Peral, M. Y., Petrizzo, D. A., Rosenheim, B. E., Tripati, A., Venturelli, R., Young, E. D., & Winkelstern, I. Z. Effects of Improved 17O Correction on Interlaboratory Agreement in Clumped Isotope Calibrations, Estimates of Mineral-Specific Offsets, and Temperature Dependence of Acid Digestion Fractionation. United States. https://doi.org/10.1029/2018gc008127
Petersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., Olack, G. A., Schauer, A. J., Bajnai, D., Bonifacie, M., Breitenbach, S. F. M., Fiebig, J., Fernandez, A. B., Henkes, G. A., Hodell, D., Katz, A., Kele, S., Lohmann, K. C., Passey, B. H., Peral, M. Y., Petrizzo, D. A., Rosenheim, B. E., Tripati, A., Venturelli, R., Young, E. D., and Winkelstern, I. Z. Fri .
"Effects of Improved 17O Correction on Interlaboratory Agreement in Clumped Isotope Calibrations, Estimates of Mineral-Specific Offsets, and Temperature Dependence of Acid Digestion Fractionation". United States. https://doi.org/10.1029/2018gc008127. https://www.osti.gov/servlets/purl/1611378.
@article{osti_1611378,
title = {Effects of Improved 17O Correction on Interlaboratory Agreement in Clumped Isotope Calibrations, Estimates of Mineral-Specific Offsets, and Temperature Dependence of Acid Digestion Fractionation},
author = {Petersen, S. V. and Defliese, W. F. and Saenger, C. and Daëron, M. and Huntington, K. W. and John, C. M. and Kelson, J. R. and Bernasconi, S. M. and Colman, A. S. and Kluge, T. and Olack, G. A. and Schauer, A. J. and Bajnai, D. and Bonifacie, M. and Breitenbach, S. F. M. and Fiebig, J. and Fernandez, A. B. and Henkes, G. A. and Hodell, D. and Katz, A. and Kele, S. and Lohmann, K. C. and Passey, B. H. and Peral, M. Y. and Petrizzo, D. A. and Rosenheim, B. E. and Tripati, A. and Venturelli, R. and Young, E. D. and Winkelstern, I. Z.},
abstractNote = {The clumped isotopic composition of carbonate-CO2 (denoted Δ47) is a function of carbonate formation temperature and in natural samples can act as a recorder of paleoclimate, burial, or diagenetic conditions. The absolute abundance of heavy isotopes in the universal standards VPDB and VSMOW (defined by four parameters: R 13VPDB, R17VSMOW, R 18VSMOW, and λ) impact calculated Δ47 values. In this work, we investigate whether use of updated and more accurate values for these parameters can remove observed interlaboratory differences in the measured T-Δ47 relationship. Using the updated parameters, we reprocess 14 published calibration data sets measured in 11 different laboratories, representing many mineralogies, bulk compositions, sample types, reaction temperatures, and sample preparation and analysis methods. Exploiting this large composite data set (n = 1,253 sample replicates), we investigate the possibility for a “universal” clumped isotope calibration. We find that applying updated parameters improves the T-Δ47 relationship (reduces residuals) within most labs and improves overall agreement but does not eliminate all interlaboratory differences. We reaffirm earlier findings that different mineralogies do not require different calibration equations and that cleaning procedures, method of pressure baseline correction, and mass spectrometer type do not affect interlaboratory agreement. We also present new estimates of the temperature dependence of the acid digestion fractionation for Δ47 (Δ*25-X), based on combining reprocessed data from four studies, and new theoretical equilibrium values to be used in calculation of the empirical transfer function. Overall, we have ruled out a number of possible causes of interlaboratory disagreement in the T-Δ47 relationship, but many more remain to be investigated.},
doi = {10.1029/2018gc008127},
journal = {Geochemistry, Geophysics, Geosystems},
number = 7,
volume = 20,
place = {United States},
year = {Fri May 31 00:00:00 EDT 2019},
month = {Fri May 31 00:00:00 EDT 2019}
}
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Implications of high-precision measurements of 13 C– 18 O bond ordering in CO 2 for thermometry in modern bivalved mollusc shells
journal, October 2014
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Geochemistry and petrology of listvenite in the Samail ophiolite, Sultanate of Oman: Complete carbonation of peridotite during ophiolite emplacement
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Carbonate clumped isotope thermometry of deep-sea corals and implications for vital effects
journal, August 2011
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- Geochimica et Cosmochimica Acta, Vol. 75, Issue 16
Reducing Uncertainties in Carbonate Clumped Isotope Analysis Through Consistent Carbonate-Based Standardization
journal, September 2018
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Quantifying kinetic fractionation in Bunker Cave speleothems using Δ47
journal, August 2012
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Defining an absolute reference frame for ‘clumped’ isotope studies of CO2
journal, November 2011
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Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates
journal, August 1997
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Clumped Isotope Calibration Data from Winkelstern et al. 2016, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Winkelstern, Ian; Lohmann, Kyger
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Defliese et al. 2015, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Defliese, William; Lohmann, Kyger
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Kluge et al. 2015, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; John, Cedric; Kluge, Tobias
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Garcia de Real et al. 2016, reprocessed as part of a community calibration effort
dataset, January 2019
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- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Kelson et al. 2017, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Kelson, Julia; Huntington, Katharine
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Tang et al. 2014, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Rosenheim, Brad; Venturelli, Ryan
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Fernandez et al. 2014, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Fernandez, Alvaro; Rosenheim, Brad
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Passey and Henkes 2012, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Passey, Benjamin; Henkes, Gregory
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Henkes et al. 2013, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Henkes, Gregory; Passey, Benjamin
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Peral et al. 2018, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Peral, Marion; Daeron, Mathieu
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Wacker et al. 2014, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Fiebig, Jens; Bajnai, David
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Petrizzo et al. 2014, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Petrizzo, Daniel; Young, Edward
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Katz et al. 2017, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Katz, Amandine; Bonifacie, Magalie
- Interdisciplinary Earth Data Alliance (IEDA)
Clumped Isotope Calibration Data from Breitenbach et al. 2018, reprocessed as part of a community calibration effort
dataset, January 2019
- Petersen, Sierra; Breitenbach, Sebastian; Hodell, David
- Interdisciplinary Earth Data Alliance (IEDA)
Works referencing / citing this record:
Exploring the Temperature Dependence of Clumped Isotopes in Modern Porites Corals
journal, January 2020
- Guo, Yangrui; Deng, Wenfeng; Wei, Gangjian
- Journal of Geophysical Research: Biogeosciences, Vol. 125, Issue 1
Southern high-latitude warmth during the Jurassic–Cretaceous: New evidence from clumped isotope thermometry
journal, May 2019
- Vickers, Madeleine L.; Bajnai, David; Price, Gregory D.
- Geology, Vol. 47, Issue 8
The DeepMIP contribution to PMIP4: methodologies for selection, compilation and analysis of latest Paleocene and early Eocene climate proxy data, incorporating version 0.1 of the DeepMIP database
journal, January 2019
- Hollis, Christopher J.; Dunkley Jones, Tom; Anagnostou, Eleni
- Geoscientific Model Development, Vol. 12, Issue 7