Effect of surface-bound sulfide on oxygen reduction reaction on Pt: Breaking the scaling relationship and mechanistic insights

Wang, Yan-Yan; Chen, De-Jun; Allison, Thomas C.; Tong, YuYe J.

doi:10.1063/1.5053815

Title: Effect of surface-bound sulfide on oxygen reduction reaction on Pt: Breaking the scaling relationship and mechanistic insights

Journal Article · 27 January 2019 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5053815 · OSTI ID:1609802

Wang, Yan-Yan ^[1];

^[2];

^[3];

^[2]

Georgetown Univ., Washington, DC (United States); DOE/OSTI
Georgetown Univ., Washington, DC (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)

A combined in situ electrochemical attenuated total reflection-surface enhanced IR absorption spectroscopy, microkinetic simulation, and density functional theory calculation study shows that not only can the adsorbed sulfide disproportionally affect the surface binding of OOH* (E_OOH*) vs OH* (E_OH*), i.e., breaking the original scaling relationship of pure metals (Ir, Pd, Pt, Au), to enhance oxygen reduction reaction (ORR) activity but can also be used as a reaction pathway alternating species to help deepen our mechanistic understanding of ORR.

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Research Organization:: Georgetown Univ., Washington, DC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-07ER15895

OSTI ID:: 1609802

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 4 Vol. 150; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Effect of surface-bound sulfide on oxygen reduction reaction on Pt: Breaking the scaling relationship and mechanistic insights

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