Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries
Abstract
Recently, considerable attention has been paid to the stabilization of atomic platinum (Pt) catalysts on desirable supports in order to reduce Pt consumption, improve the catalyst stability, and thereafter enhance the catalyst performance in renewable energy devices such as fuel cells and zinc-air batteries (ZABs). Herein, we rationally designed a novel strategy to stabilize atomic Pt catalysts in alloyed platinum cobalt (PtCo) nanosheets with trapped interstitial fluorine (SA-PtCoF) for ZABs. The trapped interstitial F atoms in the PtCoF matrix induce lattice distortion resulting in weakening of the Pt–Co bond, which is the driving force to form atomic Pt. As a result, the onset potentials of SA-PtCoF are 0.95 V and 1.50 V for the oxygen reduction and evolution reactions (ORR and OER), respectively, superior to commercial Pt/C@RuO2. When used in ZABs, the designed SA-PtCoF can afford a peak power density of 125 mW cm-2 with a specific capacity of 808 mA h gZn-1 and excellent cyclability over 240 h, surpassing the state-of-the-art catalysts.
- Authors:
-
[1];
[2];
[3];
[4];
[3];
[1]
- Univ. of Central Florida, Orlando, FL (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Oregon State Univ., Corvallis, OR (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1607991
- Alternate Identifier(s):
- OSTI ID: 1577910
- Grant/Contract Number:
- AC02-06CH11357; CMMI-1851674; 68278
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 3; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; trapped interstitial F; PtCo alloy; atomic catalyst; low Pt loading; zinc-air battery
Citation Formats
Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, and Yang, Yang. Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries. United States: N. p., 2019.
Web. doi:10.1039/c9ee02657f.
Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, & Yang, Yang. Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries. United States. https://doi.org/10.1039/c9ee02657f
Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, and Yang, Yang. Fri .
"Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries". United States. https://doi.org/10.1039/c9ee02657f. https://www.osti.gov/servlets/purl/1607991.
@article{osti_1607991,
title = {Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries},
author = {Li, Zhao and Niu, Wenhan and Yang, Zhenzhong and Zaman, Nusaiba and Samarakoon, Widitha and Wang, Maoyu and Kara, Abdelkader and Lucero, Marcos and Vyas, Manasi V. and Cao, Hui and Zhou, Hua and Sterbinsky, George E. and Feng, Zhenxing and Du, Yingge and Yang, Yang},
abstractNote = {Recently, considerable attention has been paid to the stabilization of atomic platinum (Pt) catalysts on desirable supports in order to reduce Pt consumption, improve the catalyst stability, and thereafter enhance the catalyst performance in renewable energy devices such as fuel cells and zinc-air batteries (ZABs). Herein, we rationally designed a novel strategy to stabilize atomic Pt catalysts in alloyed platinum cobalt (PtCo) nanosheets with trapped interstitial fluorine (SA-PtCoF) for ZABs. The trapped interstitial F atoms in the PtCoF matrix induce lattice distortion resulting in weakening of the Pt–Co bond, which is the driving force to form atomic Pt. As a result, the onset potentials of SA-PtCoF are 0.95 V and 1.50 V for the oxygen reduction and evolution reactions (ORR and OER), respectively, superior to commercial Pt/C@RuO2. When used in ZABs, the designed SA-PtCoF can afford a peak power density of 125 mW cm-2 with a specific capacity of 808 mA h gZn-1 and excellent cyclability over 240 h, surpassing the state-of-the-art catalysts.},
doi = {10.1039/c9ee02657f},
journal = {Energy & Environmental Science},
number = 3,
volume = 13,
place = {United States},
year = {Fri Nov 22 00:00:00 EST 2019},
month = {Fri Nov 22 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 85 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012
- Wang, Deli; Xin, Huolin L.; Hovden, Robert
- Nature Materials, Vol. 12, Issue 1, p. 81-87
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Electrodeposition of cobalt platinum alloys micromagnets
journal, May 2004
- Franz, S.; Cavallotti, P. L.; Bestetti, M.
- Journal of Magnetism and Magnetic Materials, Vol. 272-276
N, P-doped CoS 2 Embedded in TiO 2 Nanoporous Films for Zn-Air Batteries
journal, August 2018
- Guo, Limin; Deng, Jinan; Wang, Guanzhi
- Advanced Functional Materials, Vol. 28, Issue 42
Engineering Sulfur Defects, Atomic Thickness, and Porous Structures into Cobalt Sulfide Nanosheets for Efficient Electrocatalytic Alkaline Hydrogen Evolution
journal, July 2018
- Zhang, Chao; Shi, Yanmei; Yu, Yifu
- ACS Catalysis, Vol. 8, Issue 9
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
journal, January 2015
- Nie, Yao; Li, Li; Wei, Zidong
- Chemical Society Reviews, Vol. 44, Issue 8
Cobalt Catalysts Decorated with Platinum Atoms Supported on Barium Zirconate Provide Enhanced Activity and Selectivity for CO 2 Methanation
journal, March 2016
- Shin, Hyun Ho; Lu, Li; Yang, Zhou
- ACS Catalysis, Vol. 6, Issue 5
Non defect-stabilized thermally stable single-atom catalyst
journal, January 2019
- Lang, Rui; Xi, Wei; Liu, Jin-Cheng
- Nature Communications, Vol. 10, Issue 1
The Power of Single-Atom Catalysis
journal, August 2015
- Liang, Suxia; Hao, Ce; Shi, Yantao
- ChemCatChem, Vol. 7, Issue 17
Boosting oxygen evolution of single-atomic ruthenium through electronic coupling with cobalt-iron layered double hydroxides
journal, April 2019
- Li, Pengsong; Wang, Maoyu; Duan, Xinxuan
- Nature Communications, Vol. 10, Issue 1
Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries
journal, January 2018
- Pan, Jing; Xu, Yang Yang; Yang, Huan
- Advanced Science, Vol. 5, Issue 4
An Investigation of Structure−Catalytic Activity Relationship for Pt−Co/C Bimetallic Nanoparticles toward the Oxygen Reduction Reaction
journal, October 2007
- Hwang, Bing Joe; Kumar, Sakkarapalayam Murugesan Senthil; Chen, Ching-Hsiang
- The Journal of Physical Chemistry C, Vol. 111, Issue 42
Volatilizable template-assisted scalable preparation of honeycomb-like porous carbons for efficient oxygen electroreduction
journal, January 2016
- Niu, Wenhan; Li, Ligui; Wang, Nan
- Journal of Materials Chemistry A, Vol. 4, Issue 28
Scalable 3-D Carbon Nitride Sponge as an Efficient Metal-Free Bifunctional Oxygen Electrocatalyst for Rechargeable Zn–Air Batteries
journal, December 2016
- Shinde, Sambhaji S.; Lee, Chi-Ho; Sami, Abdul
- ACS Nano, Vol. 11, Issue 1
Pt Skin on AuCu Intermetallic Substrate: A Strategy to Maximize Pt Utilization for Fuel Cells
journal, June 2014
- Wang, Gongwei; Huang, Bing; Xiao, Li
- Journal of the American Chemical Society, Vol. 136, Issue 27
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
journal, May 2013
- Li, Yanguang; Gong, Ming; Liang, Yongye
- Nature Communications, Vol. 4, Issue 1
Controllable Hortensia-like MnO 2 Synergized with Carbon Nanotubes as an Efficient Electrocatalyst for Long-Term Metal–Air Batteries
journal, December 2018
- Xu, Nengneng; Nie, Qi; Luo, Lingyiqian
- ACS Applied Materials & Interfaces, Vol. 11, Issue 1
Understanding Synergism of Cobalt Metal and Copper Oxide toward Highly Efficient Electrocatalytic Oxygen Evolution
journal, October 2018
- Niu, Wenhan; Shi, Jianjian; Ju, Licheng
- ACS Catalysis, Vol. 8, Issue 12
Single-Atom to Single-Atom Grafting of Pt 1 onto FeN 4 Center: Pt 1 @FeNC Multifunctional Electrocatalyst with Significantly Enhanced Properties
journal, September 2017
- Zeng, Xiaojun; Shui, Jianglan; Liu, Xiaofang
- Advanced Energy Materials, Vol. 8, Issue 1
Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction
journal, January 2018
- Zhang, Huabin; An, Pengfei; Zhou, Wei
- Science Advances, Vol. 4, Issue 1
Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis
journal, September 2017
- Zhang, Huabin; Liu, Guigao; Shi, Li
- Advanced Energy Materials, Vol. 8, Issue 1
The role of F-doping and oxygen vacancies on the superconductivity in SmFeAsO compounds
journal, December 2008
- Yang, Jie; Ren, Zhi-An; Che, Guang-Can
- Superconductor Science and Technology, Vol. 22, Issue 2
Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting
journal, May 2018
- Fan, Xiujun; Liu, Yuanyue; Chen, Shuai
- Nature Communications, Vol. 9, Issue 1
Single-Site Active Iron-Based Bifunctional Oxygen Catalyst for a Compressible and Rechargeable Zinc–Air Battery
journal, January 2018
- Ma, Longtao; Chen, Shengmei; Pei, Zengxia
- ACS Nano, Vol. 12, Issue 2
Morphology and Magnetic Properties of Co-rich Co-Pt Thin Films Electrodeposited on Cr Seed Layers
journal, January 2006
- Pattanaik, Gyana; Zangari, Giovanni
- Journal of The Electrochemical Society, Vol. 153, Issue 1
Electrochemical Reaction of Lithium with Cobalt Fluoride Thin Film Electrode
journal, January 2005
- Fu, Zheng-Wen; Li, Chi-Lin; Liu, Wen-Yuan
- Journal of The Electrochemical Society, Vol. 152, Issue 2
S-Doped MoP Nanoporous Layer Toward High-Efficiency Hydrogen Evolution in pH-Universal Electrolyte
journal, November 2018
- Liang, Kun; Pakhira, Srimanta; Yang, Zhenzhong
- ACS Catalysis, Vol. 9, Issue 1
A Study of Void Formation in Fluorine Containing Plasma Activated Wafer Bonding
journal, August 2016
- Wang, C.; Liu, Y.; Suga, T.
- ECS Transactions, Vol. 75, Issue 9
Multicomponent electrocatalyst with ultralow Pt loading and high hydrogen evolution activity
journal, July 2018
- Tiwari, Jitendra N.; Sultan, Siraj; Myung, Chang Woo
- Nature Energy, Vol. 3, Issue 9
Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition
journal, December 2007
- Kosova, N. V.; Devyatkina, E. T.; Kaichev, V. V.
- Journal of Power Sources, Vol. 174, Issue 2
Atomically Dispersed Copper-Platinum Dual Sites Alloyed with Palladium Nanorings Catalyze the Hydrogen Evolution Reaction
journal, November 2017
- Chao, Tingting; Luo, Xuan; Chen, Wenxing
- Angewandte Chemie International Edition, Vol. 56, Issue 50
Influence of Fe Substitution into LaCoO 3 Electrocatalysts on Oxygen-Reduction Activity
journal, January 2019
- Wang, Maoyu; Han, Binghong; Deng, Junjing
- ACS Applied Materials & Interfaces, Vol. 11, Issue 6
Metallic cobalt modified MnO–C nanocrystalline composites as an efficient bifunctional oxygen electrocatalyst
journal, January 2018
- Wang, Wei; Wang, Haitao; Yu, Yang
- Catalysis Science & Technology, Vol. 8, Issue 2
Electron Microprobe and Raman Spectroscopy Investigation of an Oxygen-Bearing Pt–Fe–Pd–Ni–Cu Compound from Nurali Chromitite (Southern Urals, Russia)
journal, April 2015
- Zaccarini, Federica; Garuti, Giorgio; Bakker, Ronald J.
- Microscopy and Microanalysis, Vol. 21, Issue 5
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012
- Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
- ACS Catalysis, Vol. 2, Issue 8
Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries
journal, September 2015
- Zhao, Zhenghang; Li, Mingtao; Zhang, Lipeng
- Advanced Materials, Vol. 27, Issue 43
Advanced hybrid Li–air batteries with high-performance mesoporous nanocatalysts
journal, January 2014
- Li, Longjun; Chai, Song-Hai; Dai, Sheng
- Energy & Environmental Science, Vol. 7, Issue 8
Atomic-scale cation dynamics in a monolayer VO X /α-Fe 2 O 3 catalyst
journal, January 2015
- Feng, Z.; Ma, Q.; Lu, J.
- RSC Advances, Vol. 5, Issue 126
Metallic Co 4 N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2015
- Chen, Pengzuo; Xu, Kun; Fang, Zhiwei
- Angewandte Chemie International Edition, Vol. 54, Issue 49
Retaining the 3D Framework of Zinc Sponge Anodes upon Deep Discharge in Zn–Air Cells
journal, October 2014
- Parker, Joseph F.; Nelson, Eric S.; Wattendorf, Matthew D.
- ACS Applied Materials & Interfaces, Vol. 6, Issue 22
Nanostructured Ti 0.7 Mo 0.3 O 2 Support Enhances Electron Transfer to Pt: High-Performance Catalyst for Oxygen Reduction Reaction
journal, August 2011
- Ho, Van Thi Thanh; Pan, Chun-Jern; Rick, John
- Journal of the American Chemical Society, Vol. 133, Issue 30
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Direct Low-Temperature Deposition of Crystallized CoOOH Films by Potentiostatic Electrolysis
journal, January 2005
- Pauporté, T.; Mendoza, L.; Cassir, M.
- Journal of The Electrochemical Society, Vol. 152, Issue 2
Parameter-free calculations of total energies, interatomic forces and vibrational entropies of defects in semiconductors
journal, July 1988
- Scheffler, Matthias; Dabrowski, Jaroslaw
- Philosophical Magazine A, Vol. 58, Issue 1
Influence of silver doping on the photocatalytic activity of titania films
journal, November 2002
- He, Chao; Yu, Yun; Hu, Xingfang
- Applied Surface Science, Vol. 200, Issue 1-4
Atomic Iridium Incorporated in Cobalt Hydroxide for Efficient Oxygen Evolution Catalysis in Neutral Electrolyte
journal, March 2018
- Zhang, Youkui; Wu, Chuanqiang; Jiang, Hongliang
- Advanced Materials, Vol. 30, Issue 18
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
journal, June 2019
- Wang, Maoyu; Árnadóttir, Líney; Xu, Zhichuan J.
- Nano-Micro Letters, Vol. 11, Issue 1
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie International Edition, Vol. 56, Issue 2
Pt Single Atoms Embedded in the Surface of Ni Nanocrystals as Highly Active Catalysts for Selective Hydrogenation of Nitro Compounds
journal, May 2018
- Peng, Yuhan; Geng, Zhigang; Zhao, Songtao
- Nano Letters, Vol. 18, Issue 6
Strain-Induced Modulations in the Surface Morphology of Heteroepitaxial Layers
journal, April 1996
- Cullis, A. G.
- MRS Bulletin, Vol. 21, Issue 4
3D Aluminum Hybrid Plasmonic Nanostructures with Large Areas of Dense Hot Spots and Long-Term Stability
journal, January 2017
- Li, Xi-Mei; Bi, Ming-Hai; Cui, Lan
- Advanced Functional Materials, Vol. 27, Issue 10
Apically Dominant Mechanism for Improving Catalytic Activities of N-Doped Carbon Nanotube Arrays in Rechargeable Zinc-Air Battery
journal, April 2018
- Niu, Wenhan; Pakhira, Srimanta; Marcus, Kyle
- Advanced Energy Materials, Vol. 8, Issue 20
Water splitting by electrolysis at high current densities under 1.6 volts
journal, January 2018
- Zhou, Haiqing; Yu, Fang; Zhu, Qing
- Energy & Environmental Science, Vol. 11, Issue 10
Multifunctional electrocatalyst PtM with low Pt loading and high activity towards hydrogen and oxygen electrode reactions: A computational study
journal, October 2019
- Lv, Xingshuai; Wei, Wei; Wang, Hao
- Applied Catalysis B: Environmental, Vol. 255
A Review of Carbon-Composited Materials as Air-Electrode Bifunctional Electrocatalysts for Metal–Air Batteries
journal, February 2018
- Wang, Yan-Jie; Fang, Baizeng; Zhang, Dan
- Electrochemical Energy Reviews, Vol. 1, Issue 1
Carbon-Supported Pt-Based Alloy Electrocatalysts for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells: Particle Size, Shape, and Composition Manipulation and Their Impact to Activity
journal, April 2015
- Wang, Yan-Jie; Zhao, Nana; Fang, Baizeng
- Chemical Reviews, Vol. 115, Issue 9
Surface Fluorination of ALD TiO 2 Electron Transport Layer for Efficient Planar Perovskite Solar Cells
journal, March 2018
- Zardetto, Valerio; di Giacomo, Francesco; Lifka, Herbert
- Advanced Materials Interfaces, Vol. 5, Issue 9
Competing orders and spin-density-wave instability in La(O 1−x F x )FeAs
journal, June 2008
- Dong, J.; Zhang, H. J.; Xu, G.
- EPL (Europhysics Letters), Vol. 83, Issue 2
Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
journal, May 2017
- Zhang, Jian; Wang, Tao; Liu, Pan
- Nature Communications, Vol. 8, Issue 1
A first principles study of oxygen reduction reaction on a Pt(111) surface modified by a subsurface transition metal M (M = Ni, Co, or Fe)
journal, January 2011
- Duan, Zhiyao; Wang, Guofeng
- Physical Chemistry Chemical Physics, Vol. 13, Issue 45
Enhanced electrochemical activity of Pt nanowire network electrocatalysts for methanol oxidation reaction of fuel cells
journal, January 2011
- Wang, Shuangyin; Jiang, San Ping; Wang, Xin
- Electrochimica Acta, Vol. 56, Issue 3
Single Co Atoms Anchored in Porous N-Doped Carbon for Efficient Zinc−Air Battery Cathodes
journal, August 2018
- Zang, Wenjie; Sumboja, Afriyanti; Ma, Yuanyuan
- ACS Catalysis, Vol. 8, Issue 10
Atomically Dispersed Copper-Platinum Dual Sites Alloyed with Palladium Nanorings Catalyze the Hydrogen Evolution Reaction
journal, November 2017
- Chao, Tingting; Luo, Xuan; Chen, Wenxing
- Angewandte Chemie, Vol. 129, Issue 50
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Ultrafast X-ray Absorption Studies of the Structural Dynamics of Molecular and Biological Systems in Solution
journal, May 2011
- Milne, Christopher J.; Van der Veen, Renske M.; Pham, Van-Thai
- CHIMIA International Journal for Chemistry, Vol. 65, Issue 5
Metallic Co 4 N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2015
- Chen, Pengzuo; Xu, Kun; Fang, Zhiwei
- Angewandte Chemie, Vol. 127, Issue 49
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie, Vol. 129, Issue 2
Apically Dominant Mechanism for Improving Catalytic Activities of N-Doped Carbon Nanotube Arrays in Rechargeable Zinc-Air Battery
preprint, January 2018
- Niu, Wenhan; Pakhira, Srimanta; Marcus, Kyle
- arXiv