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Title: Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries

Abstract

Rational approaches for achieving fine control of the electrodeposition morphology of Li are required to create commercially-relevant rechargeable Li metal batteries.

Authors:
 [1]; ORCiD logo [2];  [3];  [2];  [1]; ORCiD logo [4]
  1. Department of Materials Science and Engineering, Cornell University, Ithaca, USA
  2. Department of Chemical Engineering, Stanford University, Stanford, USA
  3. Global R&D Department, Gotion Inc., Independence, USA
  4. Department of Materials Science and Engineering, Cornell University, Ithaca, USA, Robert Frederick Smith School of Chemical and Biomolecular Engineering
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1607806
Grant/Contract Number:  
SC0012673; SC0016082
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Society Reviews
Additional Journal Information:
Journal Name: Chemical Society Reviews Journal Volume: 49 Journal Issue: 9; Journal ID: ISSN 0306-0012
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zheng, Jingxu, Kim, Mun Sek, Tu, Zhengyuan, Choudhury, Snehashis, Tang, Tian, and Archer, Lynden A. Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CS00883G.
Zheng, Jingxu, Kim, Mun Sek, Tu, Zhengyuan, Choudhury, Snehashis, Tang, Tian, & Archer, Lynden A. Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries. United Kingdom. doi:https://doi.org/10.1039/C9CS00883G
Zheng, Jingxu, Kim, Mun Sek, Tu, Zhengyuan, Choudhury, Snehashis, Tang, Tian, and Archer, Lynden A. Mon . "Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries". United Kingdom. doi:https://doi.org/10.1039/C9CS00883G.
@article{osti_1607806,
title = {Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries},
author = {Zheng, Jingxu and Kim, Mun Sek and Tu, Zhengyuan and Choudhury, Snehashis and Tang, Tian and Archer, Lynden A.},
abstractNote = {Rational approaches for achieving fine control of the electrodeposition morphology of Li are required to create commercially-relevant rechargeable Li metal batteries.},
doi = {10.1039/C9CS00883G},
journal = {Chemical Society Reviews},
number = 9,
volume = 49,
place = {United Kingdom},
year = {2020},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1039/C9CS00883G

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Cited by: 7 works
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Works referenced in this record:

A single ion conducting separator and dual mediator-based electrolyte for high-performance lithium–oxygen batteries with non-carbon cathodes
journal, January 2018

  • Wu, Shichao; Qiao, Yu; Deng, Han
  • Journal of Materials Chemistry A, Vol. 6, Issue 21
  • DOI: 10.1039/C8TA02567C

Origin of lithium whisker formation and growth under stress
journal, October 2019


Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives
journal, January 2018

  • Tikekar, Mukul D.; Li, Gaojin; Archer, Lynden A.
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0271816jes

Lithium Batteries with Nearly Maximum Metal Storage
journal, May 2017

  • Raji, Abdul-Rahman O.; Villegas Salvatierra, Rodrigo; Kim, Nam Dong
  • ACS Nano, Vol. 11, Issue 6
  • DOI: 10.1021/acsnano.7b02731

A soft, multilayered lithium–electrolyte interface
journal, January 2016

  • Bucur, Claudiu B.; Lita, Adrian; Osada, Naoki
  • Energy & Environmental Science, Vol. 9, Issue 1
  • DOI: 10.1039/C5EE03056K

The long life-span of a Li-metal anode enabled by a protective layer based on the pyrolyzed N-doped binder network
journal, January 2017

  • Zhang, Zhenggang; Peng, Zhe; Zheng, Jieyun
  • Journal of Materials Chemistry A, Vol. 5, Issue 19
  • DOI: 10.1039/C7TA02144E

Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries
journal, March 2019


A Semiliquid Lithium Metal Anode
journal, July 2019


Magnetoelectrolysis
journal, September 1983

  • Fahidy, T. Z.
  • Journal of Applied Electrochemistry, Vol. 13, Issue 5
  • DOI: 10.1007/BF00617811

Mechanical behavior of electroplated mossy lithium at room temperature studied by flat punch indentation
journal, July 2019

  • Wang, Yikai; Dang, Dingying; Wang, Ming
  • Applied Physics Letters, Vol. 115, Issue 4
  • DOI: 10.1063/1.5111150

Nanodiamonds suppress the growth of lithium dendrites
journal, August 2017


Formation of a mesh-like electrodeposit induced by electroconvection
journal, February 1994

  • Wang, Mu; van Enckevort, Willem J. P.; Ming, Nai-ben
  • Nature, Vol. 367, Issue 6462
  • DOI: 10.1038/367438a0

Voltage against current curves of cation exchange membranes
journal, January 1979

  • Rubinstein, Isaak; Shtilman, Leonid
  • Journal of the Chemical Society, Faraday Transactions 2, Vol. 75
  • DOI: 10.1039/f29797500231

First principles studies of self-diffusion processes on metallic lithium surfaces
journal, January 2019

  • Gaissmaier, Daniel; Fantauzzi, Donato; Jacob, Timo
  • The Journal of Chemical Physics, Vol. 150, Issue 4
  • DOI: 10.1063/1.5056226

Electrodeposition of metals in microgravity conditions
journal, June 2013


A nanoindentation study of the viscoplastic behavior of pure lithium
journal, March 2017


Fabricating multifunctional nanoparticle membranes by a fast layer-by-layer Langmuir–Blodgett process: application in lithium–sulfur batteries
journal, January 2016

  • Kim, M. S.; Ma, L.; Choudhury, S.
  • Journal of Materials Chemistry A, Vol. 4, Issue 38
  • DOI: 10.1039/C6TA06018H

Langmuir–Blodgett artificial solid-electrolyte interphases for practical lithium metal batteries
journal, September 2018


Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
journal, September 1999


Cryogenic Focused Ion Beam Characterization of Lithium Metal Anodes
journal, January 2019


Pretreatment of Lithium Surface by Using Iodic Acid (HIO 3 ) To Improve Its Anode Performance in Lithium Batteries
journal, February 2017

  • Jia, Weishang; Wang, Qingji; Yang, Jingyi
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 8
  • DOI: 10.1021/acsami.6b14614

In situ atomic force microscopy observation of lithium deposition at an elevated temperature
journal, July 2001


Degradation of precipitation hardening in 7075 alloy subject to thermal exposure: A Cs-corrected STEM study
journal, April 2018


Stabilizing Protic and Aprotic Liquid Electrolytes at High-Bandgap Oxide Interphases
journal, July 2018


The influence of stress field on Li electrodeposition in Li-metal battery
journal, July 2018

  • Yurkiv, Vitaliy; Foroozan, Tara; Ramasubramanian, Ajaykrishna
  • MRS Communications, Vol. 8, Issue 03
  • DOI: 10.1557/mrc.2018.146

Electrodeposition of Copper under Microgravity Conditions
journal, January 1998

  • Fukunaka, Y.
  • Journal of The Electrochemical Society, Vol. 145, Issue 6
  • DOI: 10.1149/1.1838570

The effect of internal resistance on dendritic growth on lithium metal electrodes in the lithium secondary batteries
journal, April 2008


Control of lithium metal anode cycleability by electrolyte temperature
journal, September 1999


When will fossil fuel reserves be diminished?
journal, January 2009


Electrodeposition of zinc films from ionic liquids and ionic liquid/water mixtures
journal, February 2013


Novel Concentrated Li[(FSO 2 )(n-C 4 F 9 SO 2 )N]-Based Ether Electrolyte for Superior Stability of Metallic Lithium Anode
journal, June 2016

  • Fang, Zheng; Ma, Qiang; Liu, Pin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 5
  • DOI: 10.1021/acsami.6b03857

Analysis of Vinylene Carbonate Derived SEI Layers on Graphite Anode
journal, January 2004

  • Ota, Hitoshi; Sakata, Yuuichi; Inoue, Atsuyoshi
  • Journal of The Electrochemical Society, Vol. 151, Issue 10
  • DOI: 10.1149/1.1785795

Highly Efficient Br /NO 3 Dual-Anion Electrolyte for Suppressing Charging Instabilities of Li–O 2 Batteries
journal, July 2017

  • Xin, Xing; Ito, Kimihiko; Kubo, Yoshimi
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 31
  • DOI: 10.1021/acsami.7b05692

Evolution of Dead Lithium Growth in Lithium Metal Batteries: Experimentally Validated Model of the Apparent Capacity Loss
journal, January 2019

  • Xu, Shanshan; Chen, Kuan-Hung; Dasgupta, Neil P.
  • Journal of The Electrochemical Society, Vol. 166, Issue 14
  • DOI: 10.1149/2.0991914jes

A large deformation elastic–viscoplastic model for lithium
journal, October 2018


Operando Observations of SEI Film Evolution by Mass‐Sensitive Scanning Transmission Electron Microscopy
journal, October 2019


Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries
journal, June 2014


Electrodeposition of Epitaxial Cu(111) Thin Films on Au(111) Using Defect-Mediated Growth
journal, July 2001

  • Hwang, Seongpil; Oh, Ilwhan; Kwak, Juhyoun
  • Journal of the American Chemical Society, Vol. 123, Issue 29
  • DOI: 10.1021/ja015666n

The dendrite growth in 3D structured lithium metal anodes: Electron or ion transfer limitation?
journal, December 2019


A stable lithium metal interface
journal, July 2014


The Role of Natural Convection in Electrolytic Processes
journal, January 1949

  • Wagner, Carl
  • Journal of The Electrochemical Society, Vol. 95, Issue 4
  • DOI: 10.1149/1.2776746

Electroconvection in a Viscoelastic Electrolyte
journal, March 2019


Optimization of physicochemical characteristics of a lithium anode interface for high-efficiency cycling: an effect of electrolyte temperature
journal, July 2001


Electric-Field-Directed Parallel Alignment Architecting 3D Lithium-Ion Pathways within Solid Composite Electrolyte
journal, April 2018

  • Liu, Xueqing; Peng, Sha; Gao, Shuyu
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 18
  • DOI: 10.1021/acsami.8b01631

Diffusion Limitation of Lithium Metal and Li–Mg Alloy Anodes on LLZO Type Solid Electrolytes as a Function of Temperature and Pressure
journal, October 2019

  • Krauskopf, Thorben; Mogwitz, Boris; Rosenbach, Carolin
  • Advanced Energy Materials, Vol. 9, Issue 44
  • DOI: 10.1002/aenm.201902568

Effect of Manganese Contamination on the Solid-Electrolyte-Interphase Properties in Li-Ion Batteries
journal, January 2013

  • Delacourt, C.; Kwong, A.; Liu, X.
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.035308jes

Dendrite-free lithium electrode cycling via controlled nucleation in low LiPF6 concentration electrolytes
journal, December 2018


III. On the concentration at the electrodes in a solution, with special reference to the liberation of hydrogen by electrolysis of a mixture of copper sulphate and sulphuric acid
journal, January 1901

  • Sand, Henry J. S.
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 1, Issue 1
  • DOI: 10.1080/14786440109462590

Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials
journal, October 2019

  • Zachman, Michael J.; Hachtel, Jordan A.; Idrobo, Juan Carlos
  • Angewandte Chemie, Vol. 132, Issue 4
  • DOI: 10.1002/ange.201902993

Effect of Sn Addition on Epitaxial GaAs Nanowire Grown at Different Temperatures in Metal–Organic Chemical Vapor Deposition
journal, July 2019


Enabling Stable Lithium Metal Anode through Electrochemical Kinetics Manipulation
journal, September 2019

  • Han, Yehu; Jie, Yulin; Huang, Fanyang
  • Advanced Functional Materials, Vol. 29, Issue 46
  • DOI: 10.1002/adfm.201904629

Lithiophilic Faceted Cu(100) Surfaces: High Utilization of Host Surface and Cavities for Lithium Metal Anodes
journal, March 2019

  • Gu, Yu; Xu, Hong‐Yu; Zhang, Xia‐Guang
  • Angewandte Chemie International Edition, Vol. 58, Issue 10
  • DOI: 10.1002/anie.201812523

Lithium bis(fluorosulfonyl)imide/poly(ethylene oxide) polymer electrolyte
journal, July 2014


Comparison of the growth of lithium filaments and dendrites under different conditions
journal, January 2015


An Electron/Ion Dual‐Conductive Alloy Framework for High‐Rate and High‐Capacity Solid‐State Lithium‐Metal Batteries
journal, September 2018


Mechanically Assisted Self-Healing of Ultrathin Gold Nanowires
journal, April 2018


Designing solid-state interfaces on lithium-metal anodes: a review
journal, September 2019


Electron beam-assisted healing of nanopores in magnesium alloys
journal, May 2013

  • Zheng, He; Liu, Yu; Cao, Fan
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01920

Building Organic/Inorganic Hybrid Interphases for Fast Interfacial Transport in Rechargeable Metal Batteries
journal, December 2017


Effect of plating temperature on Sn surface morphology
journal, July 2010


Mechanical Deformation of a Lithium-Metal Anode Due to a Very Stiff Separator
journal, January 2014

  • Ferrese, Anthony; Newman, John
  • Journal of The Electrochemical Society, Vol. 161, Issue 9
  • DOI: 10.1149/2.0911409jes

A conductive-dielectric gradient framework for stable lithium metal anode
journal, January 2020


Dendrite‐Free Epitaxial Growth of Lithium Metal during Charging in Li–O 2 Batteries
journal, October 2018

  • Xin, Xing; Ito, Kimihiko; Dutta, Arghya
  • Angewandte Chemie International Edition, Vol. 57, Issue 40
  • DOI: 10.1002/anie.201808154

Poor Man’s Atomic Layer Deposition of LiF for Additive-Free Growth of Lithium Columns
journal, October 2018


A buckling-based metrology for measuring the elastic moduli of polymeric thin films
journal, July 2004

  • Stafford, Christopher M.; Harrison, Christopher; Beers, Kathryn L.
  • Nature Materials, Vol. 3, Issue 8, p. 545-550
  • DOI: 10.1038/nmat1175

The filamentary growth of metals
journal, July 2011

  • Schamel, Matthias; Schopf, Carola; Linsler, Dominic
  • International Journal of Materials Research, Vol. 102, Issue 7
  • DOI: 10.3139/146.110541

Effect of vinylene carbonate as additive to electrolyte for lithium metal anode
journal, February 2004


Lithiophilic metallic nitrides modified nickel foam by plasma for stable lithium metal anode
journal, December 2019


Transient natural convection induced by electrodeposition of Li + ions onto a lithium metal vertical cathode in propylene carbonate
journal, February 2004


3D TiC/C Core/Shell Nanowire Skeleton for Dendrite-Free and Long-Life Lithium Metal Anode
journal, December 2017


Coupling of drift, diffusion, and electroconvection, in the vicinity of growing electrodeposits
journal, August 1993


Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions
journal, July 2016

  • Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L.
  • Science Advances, Vol. 2, Issue 7
  • DOI: 10.1126/sciadv.1600320

Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport
journal, September 2017

  • Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna
  • Angewandte Chemie International Edition, Vol. 56, Issue 42
  • DOI: 10.1002/anie.201707754

Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport
journal, September 2017

  • Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna
  • Angewandte Chemie International Edition, Vol. 56, Issue 42
  • DOI: 10.1002/anie.201707754

Surface of lithium electrodes prepared in Ar + CO2 gas
journal, December 1994


Rayleigh-Benard Convection in an Electrochemical Redox Cell
journal, September 1984


General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes
journal, March 2014

  • Yamada, Yuki; Usui, Kenji; Chiang, Ching Hua
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 14, p. 10892-10899
  • DOI: 10.1021/am5001163

Morphological Variation of Electrodeposited Li in Ionic Liquid
conference, January 2012

  • Nishikawa, Kei; Naito, Hitoshi; Kawase, Makoto
  • 220th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.4717956

Influence of grain size and texture on Hall–Petch relationship for a magnesium alloy
journal, December 2011


Reversibility of electrochemical magnesium deposition from tetrahydrofuran solutions containing pyrrolidinyl magnesium halide
journal, July 2011


Mechanism Explaining the Onset Time of Dendritic Lithium Electrodeposition via Considerations of the Li + Transport within the Solid Electrolyte Interphase
journal, January 2018

  • Maraschky, Adam; Akolkar, Rohan
  • Journal of The Electrochemical Society, Vol. 165, Issue 14
  • DOI: 10.1149/2.0601814jes

Electrochemical Characterization and Temperature Dependency of Mass-Transport Properties of LiPF 6 in EC:DEC
journal, December 2014

  • Lundgren, Henrik; Behm, Mårten; Lindbergh, Göran
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.0641503jes

Trapping Lithium into Hollow Silica Microspheres with a Carbon Nanotube Core for Dendrite-Free Lithium Metal Anodes
journal, December 2017


Protected lithium anode with porous Al 2 O 3 layer for lithium–sulfur battery
journal, January 2015

  • Jing, Hang-Kun; Kong, Ling-Long; Liu, Sheng
  • Journal of Materials Chemistry A, Vol. 3, Issue 23
  • DOI: 10.1039/C5TA01490E

S‐Doped Graphene‐Regional Nucleation Mechanism for Dendrite‐Free Lithium Metal Anodes
journal, May 2019

  • Wang, Tianshuai; Zhai, Pengbo; Legut, Dominik
  • Advanced Energy Materials, Vol. 9, Issue 24
  • DOI: 10.1002/aenm.201804000

Role of convection in thin-layer electrodeposition
journal, April 1995

  • Huth, John M.; Swinney, Harry L.; McCormick, William D.
  • Physical Review E, Vol. 51, Issue 4
  • DOI: 10.1103/PhysRevE.51.3444

Double layer structure at the limiting current
journal, January 1967

  • Smyrl, William H.; Newman, John
  • Transactions of the Faraday Society, Vol. 63
  • DOI: 10.1039/tf9676300207

Nuclear magnetic relaxation by self-diffusion in solid lithium:T 1-frequency dependence
journal, February 1975


Thermal relaxation of lithium dendrites
journal, January 2015

  • Aryanfar, Asghar; Brooks, Daniel J.; Colussi, Agustín J.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 12
  • DOI: 10.1039/C4CP05786D

Efficiently photo-charging lithium-ion battery by perovskite solar cell
journal, August 2015

  • Xu, Jiantie; Chen, Yonghua; Dai, Liming
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9103

Nanostructured Electrolytes for Stable Lithium Electrodeposition in Secondary Batteries
journal, October 2015


Decomposition reaction of LiPF6-based electrolytes for lithium ion cells
journal, June 2006


Optical observation of Li dendrite growth in ionic liquid
journal, June 2013


Nafion/Titanium Dioxide-Coated Lithium Anode for Stable Lithium-Sulfur Batteries
journal, May 2018

  • Jiang, Shuang; Lu, Yong; Lu, Yanying
  • Chemistry - An Asian Journal, Vol. 13, Issue 10
  • DOI: 10.1002/asia.201800326

The Study of Reversible Magnesium Deposition by In Situ Scanning Tunneling Microscopy
journal, January 2001

  • Aurbach, D.; Cohen, Y.; Moshkovich, M.
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 8
  • DOI: 10.1149/1.1379828

Epitaxial Growth of Cu on Au(111) and Ag(111) by Surface Limited Redox ReplacementAn Electrochemical and STM Study
journal, March 2007

  • Viyannalage, L. T.; Vasilic, R.; Dimitrov, N.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 10
  • DOI: 10.1021/jp067168c

Review of hybrid polymer electrolytes and rechargeable lithium batteries
journal, August 1994


The gap between long lifespan Li-S coin and pouch cells: The importance of lithium metal anode protection
journal, January 2017


Effect of Initial State of Lithium on the Propensity for Dendrite Formation: A Theoretical Study
journal, December 2016

  • Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 164, Issue 2
  • DOI: 10.1149/2.0661702jes

Effect of prestress on the stability of electrode–electrolyte interfaces during charging in lithium batteries
journal, October 2016

  • Natsiavas, P. P.; Weinberg, K.; Rosato, D.
  • Journal of the Mechanics and Physics of Solids, Vol. 95
  • DOI: 10.1016/j.jmps.2016.05.007

Crystal Growth of Electrodeposited Zinc
journal, January 1959

  • Sato, Ryoitiro
  • Journal of The Electrochemical Society, Vol. 106, Issue 3
  • DOI: 10.1149/1.2427309

Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes
journal, January 2017


Effect of nanopatterning on mechanical properties of Lithium anode
journal, February 2018


Multifunctional Separator Coatings for High-Performance Lithium-Sulfur Batteries
journal, August 2016

  • Kim, Mun Sek; Ma, Lin; Choudhury, Snehashis
  • Advanced Materials Interfaces, Vol. 3, Issue 22
  • DOI: 10.1002/admi.201600450

Perspective on the Mechanical Interaction Between Lithium Dendrites and Polymer Separators at Low Temperature
journal, August 2016

  • Love, Corey T.
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3
  • DOI: 10.1115/1.4034483

Lithium Batteries for Biomedical Applications
journal, August 2002

  • Takeuchi, Esther S.; Leising, Randolph A.
  • MRS Bulletin, Vol. 27, Issue 8
  • DOI: 10.1557/mrs2002.199

Highly Conductive, Sulfonated, UV-Cross-Linked Separators for Li–S Batteries
journal, July 2016


A Diffusion−Reaction Competition Mechanism to Tailor Lithium Deposition
journal, March 2020


In Situ Atomic Force Microscopy Study on Lithium Deposition on Nickel Substrates at Elevated Temperatures
journal, January 2002

  • Mogi, Ryo; Inaba, Minoru; Iriyama, Yasutoshi
  • Journal of The Electrochemical Society, Vol. 149, Issue 4
  • DOI: 10.1149/1.1454138

Precipitation in an Al-Zn-Mg-Cu alloy during isothermal aging: Atomic-scale HAADF-STEM investigation
journal, April 2017


Interfacial Study on Solid Electrolyte Interphase at Li Metal Anode: Implication for Li Dendrite Growth
journal, January 2016

  • Liu, Z.; Qi, Y.; Lin, Y. X.
  • Journal of The Electrochemical Society, Vol. 163, Issue 3
  • DOI: 10.1149/2.0151605jes

Investigation of the temperature-dependent behaviours of Li metal anode
journal, January 2019

  • Guo, Yanpeng; Li, Dian; Xiong, Rundi
  • Chemical Communications, Vol. 55, Issue 66
  • DOI: 10.1039/C9CC04897A

A Superionic Conductive, Electrochemically Stable Dual-Salt Polymer Electrolyte
journal, September 2018


Overcharge Effect on Morphology and Structure of Carbon Electrodes for Lithium-Ion Batteries
journal, January 2012

  • Lu, Wenquan; López, Carmen M.; Liu, Nathan
  • Journal of The Electrochemical Society, Vol. 159, Issue 5
  • DOI: 10.1149/2.jes035205

Studies on the effects of coated Li2CO3 on lithium electrode
journal, September 2003


Morphological stability during electrodeposition
journal, June 2017

  • Enrique, Raúl A.; DeWitt, Stephen; Thornton, Katsuyo
  • MRS Communications, Vol. 7, Issue 3
  • DOI: 10.1557/mrc.2017.38

Direct Observation of Inhomogeneous Solid Electrolyte Interphase on MnO Anode with Atomic Force Microscopy and Spectroscopy
journal, January 2012

  • Zhang, Jie; Wang, Rui; Yang, Xiaocheng
  • Nano Letters, Vol. 12, Issue 4
  • DOI: 10.1021/nl300570d

Engineered Interfaces in Hybrid Ceramic–Polymer Electrolytes for Use in All-Solid-State Li Batteries
journal, December 2016


Tough Gel Electrolyte Using Double Polymer Network Design for the Safe, Stable Cycling of Lithium Metal Anode
journal, January 2018

  • Wu, Haiping; Cao, Yue; Su, Haiping
  • Angewandte Chemie International Edition, Vol. 57, Issue 5
  • DOI: 10.1002/anie.201709774

On morphological instability during electrodeposition with a stagnant binary electrolyte
journal, April 1995


In Situ Observation of Dendrite Behavior of Electrode in Half and Full Cells
journal, January 2019

  • Zhu, Ruidie; Feng, Jiemin; Guo, Zhansheng
  • Journal of The Electrochemical Society, Vol. 166, Issue 6
  • DOI: 10.1149/2.0921906jes

Lithium‐Salt Mediated Synthesis of a Covalent Triazine Framework for Highly Stable Lithium Metal Batteries
journal, November 2019

  • Zhou, Tianhong; Zhao, Yan; Choi, Jang Wook
  • Angewandte Chemie International Edition, Vol. 58, Issue 47
  • DOI: 10.1002/anie.201908513

Magnetic electrodeposition
journal, August 2001


Enhanced strength and temperature dependence of mechanical properties of Li at small scales and its implications for Li metal anodes
journal, December 2016

  • Xu, Chen; Ahmad, Zeeshan; Aryanfar, Asghar
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 1
  • DOI: 10.1073/pnas.1615733114

Uniform Nucleation of Lithium in 3D Current Collectors via Bromide Intermediates for Stable Cycling Lithium Metal Batteries
journal, November 2018

  • Duan, Hui; Zhang, Jing; Chen, Xiang
  • Journal of the American Chemical Society, Vol. 140, Issue 51
  • DOI: 10.1021/jacs.8b10488

Elastic Modulus of Isotopically-Concentrated Lithium
journal, January 1960


Nucleation of Electrodeposited Lithium Metal: Dendritic Growth and the Effect of Co-Deposited Sodium
journal, January 2013

  • Stark, Johanna K.; Ding, Yi; Kohl, Paul A.
  • Journal of The Electrochemical Society, Vol. 160, Issue 9
  • DOI: 10.1149/2.028309jes

�ber die Faserstruktur elektrolytischer Metallniederschl�ge
journal, December 1924

  • Glocker, R.; Kaupp, E.
  • Zeitschrift f�r Physik, Vol. 24, Issue 1
  • DOI: 10.1007/BF01327239

Nanoindentation of high-purity vapor deposited lithium films: A mechanistic rationalization of diffusion-mediated flow
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Thole, Violet
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.84

Nanoindentation of high-purity vapor deposited lithium films: The elastic modulus
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Dudney, Nancy J.
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.83

Li7P3S11/poly(ethylene oxide) hybrid solid electrolytes with excellent interfacial compatibility for all-solid-state batteries
journal, October 2018


Eliminating Tip Dendrite Growth by Lorentz Force for Stable Lithium Metal Anodes
journal, April 2019

  • Wang, Aoxuan; Deng, Qibo; Deng, Lijun
  • Advanced Functional Materials, Vol. 29, Issue 25
  • DOI: 10.1002/adfm.201902630

In Situ Observation of Dendrite Growth of Electrodeposited Li Metal
journal, January 2010

  • Nishikawa, Kei; Mori, Takeshi; Nishida, Tetsuo
  • Journal of The Electrochemical Society, Vol. 157, Issue 11
  • DOI: 10.1149/1.3486468

Three-dimensional pie-like current collectors for dendrite-free lithium metal anodes
journal, March 2018


Three-dimensional pie-like current collectors for dendrite-free lithium metal anodes
journal, March 2018


Operational strategy to stabilize lithium metal anodes by applied thermal gradient
journal, November 2019


Lithium Self-Discharge and Its Prevention: Direct Visualization through In Situ Electrochemical Scanning Transmission Electron Microscopy
journal, September 2017

  • Harrison, Katharine L.; Zavadil, Kevin R.; Hahn, Nathan T.
  • ACS Nano, Vol. 11, Issue 11
  • DOI: 10.1021/acsnano.7b05513

Copper electrodeposition in a magnetic field
journal, November 2007


The interplay between solid electrolyte interface (SEI) and dendritic lithium growth
journal, October 2017


Unique 3D nanoporous/macroporous structure Cu current collector for dendrite-free lithium deposition
journal, February 2019


Nanoscale Organic Hybrid Electrolytes
journal, August 2010

  • Nugent, Jennifer L.; Moganty, Surya S.; Archer, Lynden A.
  • Advanced Materials, Vol. 22, Issue 33
  • DOI: 10.1002/adma.201000898

Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries
journal, March 2020


Synergistic Effect of 3D Current Collectors and ALD Surface Modification for High Coulombic Efficiency Lithium Metal Anodes
journal, December 2018

  • Chen, Kuan-Hung; Sanchez, Adrian J.; Kazyak, Eric
  • Advanced Energy Materials, Vol. 9, Issue 4
  • DOI: 10.1002/aenm.201802534

Mixed Ion and Electron‐Conducting Scaffolds for High‐Rate Lithium Metal Anodes
journal, April 2019


Nano-Sized Cuboid-Shaped Phase in Mg–Nd–Y Alloy and its Behavior During Isothermal Aging
journal, November 2016


The Effect of Mass Transport on Li Deposition and Dissolution
journal, January 1998

  • Langenhuizen, N. P. W.
  • Journal of The Electrochemical Society, Vol. 145, Issue 9
  • DOI: 10.1149/1.1838770

Understanding the role of mechanics in energy materials: A perspective
journal, December 2016


Electrokinetics in Viscoelastic Liquid Electrolytes above the Diffusion Limit
journal, June 2019


Electrochemical Epitaxial Growth of a Pt(111) Phase on an Au(111) Electrode
journal, September 1997

  • Uosaki, Kohei; Ye, Shen; Naohara, Hideo
  • The Journal of Physical Chemistry B, Vol. 101, Issue 38
  • DOI: 10.1021/jp9717406

Improvement of Charge-Discharge Cycling Efficiency of Li by Low-Temperature Precycling of Li
journal, January 1997

  • Ishikawa, Masashi
  • Journal of The Electrochemical Society, Vol. 144, Issue 4
  • DOI: 10.1149/1.1837563

Electrolytic vascular systems for energy-dense robots
journal, June 2019


Striking effects of magnetic field on the growth morphology of electrochemical deposits
journal, September 1996


Nanoindentation of high-purity vapor deposited lithium films: A mechanistic rationalization of the transition from diffusion to dislocation-mediated flow
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Thole, Violet
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.85

In Situ Observation of Lithium Dendrite of Different Graphite Electrodes
journal, June 2018


Physical Orphaning versus Chemical Instability: Is Dendritic Electrodeposition of Li Fatal?
journal, May 2019


Projecting the Future Levelized Cost of Electricity Storage Technologies
journal, January 2019


Towards high performance Li metal batteries: Nanoscale surface modification of 3D metal hosts for pre-stored Li metal anodes
journal, December 2018


Stable Artificial Solid Electrolyte Interphases for Lithium Batteries
journal, May 2017


Columnar Lithium Metal Anodes
journal, September 2017

  • Zhang, Xue-Qiang; Chen, Xiang; Xu, Rui
  • Angewandte Chemie International Edition, Vol. 56, Issue 45
  • DOI: 10.1002/anie.201707093

Building on bubbles in metal electrodeposition
journal, May 2002

  • Tsai, W. L.; Hsu, P. C.; Hwu, Y.
  • Nature, Vol. 417, Issue 6885
  • DOI: 10.1038/417139a

Deciphering the Ethylene Carbonate–Propylene Carbonate Mystery in Li-Ion Batteries
journal, January 2018


Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode
journal, August 2017

  • Yang, Chunpeng; Yao, Yonggang; He, Shuaiming
  • Advanced Materials, Vol. 29, Issue 38
  • DOI: 10.1002/adma.201702714

Epitaxial Growth of β-Bi 2 O 3 Thin Films and Particles with Mist Chemical Vapor Deposition
journal, October 2019

  • Sun, Zaichun; Oka, Daichi; Fukumura, Tomoteru
  • Crystal Growth & Design, Vol. 19, Issue 12
  • DOI: 10.1021/acs.cgd.9b01033

Realizing stable lithium deposition by in situ grown Cu 2 S nanowires inside commercial Cu foam for lithium metal anodes
journal, January 2019

  • Huang, Zhijia; Zhang, Chen; Lv, Wei
  • Journal of Materials Chemistry A, Vol. 7, Issue 2
  • DOI: 10.1039/C8TA10341K

On the Reliability of Sodium Metal Anodes: The Influence of Neglected Parameters
journal, January 2019

  • Rupp, Rico; Vlad, Alexandru
  • Journal of The Electrochemical Society, Vol. 166, Issue 14
  • DOI: 10.1149/2.0161914jes

Quantitative phase-field modeling of dendritic electrodeposition
journal, July 2015


Measurement of Concentration Profiles during Electrodeposition of Li Metal from LiPF[sub 6]-PC Electrolyte Solution
journal, January 2007

  • Nishikawa, K.; Fukunaka, Y.; Sakka, T.
  • Journal of The Electrochemical Society, Vol. 154, Issue 10
  • DOI: 10.1149/1.2767404

Annealing kinetics of electrodeposited lithium dendrites
journal, October 2015

  • Aryanfar, Asghar; Cheng, Tao; Colussi, Agustin J.
  • The Journal of Chemical Physics, Vol. 143, Issue 13
  • DOI: 10.1063/1.4930014

How Electrolytes Influence Battery Safety
journal, January 2012

  • Roth, E. P.; Orendorff, C. J.
  • Interface magazine, Vol. 21, Issue 2
  • DOI: 10.1149/2.F04122if

Effect of electrodeposition parameters on growth habit and morphology
journal, January 1968


Stable lithium electrodeposition in salt-reinforced electrolytes
journal, April 2015


Hybrid Hairy Nanoparticle Electrolytes Stabilizing Lithium Metal Batteries
journal, March 2016


Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits
journal, April 2019


Revealing Nanoscale Passivation and Corrosion Mechanisms of Reactive Battery Materials in Gas Environments
journal, July 2017


Magnetic fields in electrochemistry: The Lorentz force. A mini-review
journal, May 2014


Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes
journal, June 2018

  • Brown, Zachary L.; Jurng, Sunhyung; Nguyen, Cao Cuong
  • ACS Applied Energy Materials, Vol. 1, Issue 7
  • DOI: 10.1021/acsaem.8b00705

Alessandro Volta
journal, January 1965