Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy
Abstract
Lithium- and manganese-rich (LMR) materials provide cost and environmental advantages to other competing cathodes based on nickel or cobalt chemistries. Within the LMR family, layered-layered-spinel (LLS) cathodes have unique properties, detailed herein, that address several of the challenges faced in large-scale implementation of LMR cathodes. This paper details how a LLS//graphite system was considerably improved by combining optimization strategies. First, a cathode surface-treatment process was optimized. Interestingly, cathodes surface-treated at a low temperature (~100°C) exhibited the best results. The optimized LLS cathode was tested vs. graphite using small amounts of lithium difluoro(oxalate)borate electrolyte additive. The combined approach improved various aspects of the electrochemical performance (e.g., impedance, cycle life, and coulombic efficiency) more than each strategy used alone by mitigating Mn dissolution from the cathode and the ensuing deposition on the anode. The report describes a unique method to improve the performance of practically relevant LMR//graphite cells.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Microvast Power Solutions, Inc., Orlando, FL (United States)
- Thorlabs Quantum Electronics Inc., Jessup, MD (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1607639
- Alternate Identifier(s):
- OSTI ID: 1657930
- Grant/Contract Number:
- AC02-06CH11357; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 166; Journal Issue: 16; Journal ID: ISSN 0013-4651
- Publisher:
- IOP Publishing - The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Gutierrez, Arturo, He, Meinan, Yonemoto, Bryan T., Yang, Zhenzhen, Wang, Jie, Meyer, III, Harry M., Thackeray, Michael M., and Croy, Jason R. Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy. United States: N. p., 2019.
Web. doi:10.1149/2.1281915jes.
Gutierrez, Arturo, He, Meinan, Yonemoto, Bryan T., Yang, Zhenzhen, Wang, Jie, Meyer, III, Harry M., Thackeray, Michael M., & Croy, Jason R. Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy. United States. https://doi.org/10.1149/2.1281915jes
Gutierrez, Arturo, He, Meinan, Yonemoto, Bryan T., Yang, Zhenzhen, Wang, Jie, Meyer, III, Harry M., Thackeray, Michael M., and Croy, Jason R. Fri .
"Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy". United States. https://doi.org/10.1149/2.1281915jes. https://www.osti.gov/servlets/purl/1607639.
@article{osti_1607639,
title = {Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy},
author = {Gutierrez, Arturo and He, Meinan and Yonemoto, Bryan T. and Yang, Zhenzhen and Wang, Jie and Meyer, III, Harry M. and Thackeray, Michael M. and Croy, Jason R.},
abstractNote = {Lithium- and manganese-rich (LMR) materials provide cost and environmental advantages to other competing cathodes based on nickel or cobalt chemistries. Within the LMR family, layered-layered-spinel (LLS) cathodes have unique properties, detailed herein, that address several of the challenges faced in large-scale implementation of LMR cathodes. This paper details how a LLS//graphite system was considerably improved by combining optimization strategies. First, a cathode surface-treatment process was optimized. Interestingly, cathodes surface-treated at a low temperature (~100°C) exhibited the best results. The optimized LLS cathode was tested vs. graphite using small amounts of lithium difluoro(oxalate)borate electrolyte additive. The combined approach improved various aspects of the electrochemical performance (e.g., impedance, cycle life, and coulombic efficiency) more than each strategy used alone by mitigating Mn dissolution from the cathode and the ensuing deposition on the anode. The report describes a unique method to improve the performance of practically relevant LMR//graphite cells.},
doi = {10.1149/2.1281915jes},
journal = {Journal of the Electrochemical Society},
number = 16,
volume = 166,
place = {United States},
year = {2019},
month = {11}
}
Web of Science
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