skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Universal crossed beam imaging studies of polyatomic reaction dynamics

Abstract

Crossed-beam imaging studies of polyatomic reactions show surprising dynamics not anticipated by extrapolation from smaller model systems.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, University of Missouri, Columbia, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1607603
Grant/Contract Number:  
SC0017130
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 22 Journal Issue: 20; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Li, Hongwei, and Suits, Arthur G. Universal crossed beam imaging studies of polyatomic reaction dynamics. United Kingdom: N. p., 2020. Web. doi:10.1039/D0CP00522C.
Li, Hongwei, & Suits, Arthur G. Universal crossed beam imaging studies of polyatomic reaction dynamics. United Kingdom. doi:https://doi.org/10.1039/D0CP00522C
Li, Hongwei, and Suits, Arthur G. Wed . "Universal crossed beam imaging studies of polyatomic reaction dynamics". United Kingdom. doi:https://doi.org/10.1039/D0CP00522C.
@article{osti_1607603,
title = {Universal crossed beam imaging studies of polyatomic reaction dynamics},
author = {Li, Hongwei and Suits, Arthur G.},
abstractNote = {Crossed-beam imaging studies of polyatomic reactions show surprising dynamics not anticipated by extrapolation from smaller model systems.},
doi = {10.1039/D0CP00522C},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 20,
volume = 22,
place = {United Kingdom},
year = {2020},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1039/D0CP00522C

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Crossed molecular beams and quasiclassical trajectory studies of the reaction O(1D)+H2(D2)
journal, April 1998

  • Alagia, M.; Balucani, N.; Cartechini, L.
  • The Journal of Chemical Physics, Vol. 108, Issue 16
  • DOI: 10.1063/1.476085

Dynamical importance of van der Waals saddle and excited potential surface in C(1D)+D2 complex-forming reaction
journal, January 2017

  • Shen, Zhitao; Ma, Haitao; Zhang, Chunfang
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14094

Controlling bimolecular reactions: Mode and bond selected reaction of water with hydrogen atoms
journal, April 1991

  • Sinha, Amitabha; Hsiao, Mark C.; Crim, F. Fleming
  • The Journal of Chemical Physics, Vol. 94, Issue 7
  • DOI: 10.1063/1.460578

Crossed beam polyatomic reaction dynamics: recent advances and new insights
journal, January 2017

  • Pan, Huilin; Liu, Kopin; Caracciolo, Adriana
  • Chemical Society Reviews, Vol. 46, Issue 24
  • DOI: 10.1039/C7CS00601B

The Roaming Atom: Straying from the Reaction Path in Formaldehyde Decomposition
journal, November 2004


Direct current slice imaging
journal, April 2003

  • Townsend, Dave; Minitti, Michael P.; Suits, Arthur G.
  • Review of Scientific Instruments, Vol. 74, Issue 4
  • DOI: 10.1063/1.1544053

Crossed-Molecular-Beam Study on the Formation of Phenylacetylene from Phenyl Radicals and Acetylene
journal, September 2007

  • Gu, Xibin; Zhang, Fangtong; Guo, Ying
  • Angewandte Chemie International Edition, Vol. 46, Issue 36
  • DOI: 10.1002/anie.200701890

Extremely short-lived reaction resonances in Cl + HD ( v = 1) → DCl + H due to chemical bond softening
journal, January 2015


Combined crossed beam and theoretical studies of the C( 1 D) + CH 4 reaction
journal, January 2013

  • Leonori, Francesca; Skouteris, Dimitrios; Petrucci, Raffaele
  • The Journal of Chemical Physics, Vol. 138, Issue 2
  • DOI: 10.1063/1.4773579

Reaction Dynamics of Phenyl Radicals (C 6 H 5 , X 2 A‘) with Methylacetylene (CH 3 CCH(X 1 A 1 )), Allene (H 2 CCCH 2 (X 1 A 1 )), and Their D4-Isotopomers
journal, November 2007

  • Gu, Xibin; Zhang, Fangtong; Guo, Ying
  • The Journal of Physical Chemistry A, Vol. 111, Issue 45
  • DOI: 10.1021/jp0738255

Exploring the Gas Phase Synthesis of the Elusive Class of Boronyls and the Mechanism of Boronyl Radical Reactions under Single Collision Conditions
journal, December 2016

  • Kaiser, Ralf I.; Balucani, Nadia
  • Accounts of Chemical Research, Vol. 50, Issue 5
  • DOI: 10.1021/ar300308u

The dynamics of formation of HCl products from the reaction of Cl atoms with methanol, ethanol, and dimethyl ether
journal, September 2002

  • Rudić, Svemir; Murray, Craig; Ascenzi, Daniela
  • The Journal of Chemical Physics, Vol. 117, Issue 12
  • DOI: 10.1063/1.1502646

The last mile of molecular reaction dynamics virtual experiments: the case of the OH(N = 1–10) + CO(j = 0–3) reaction
journal, January 2012

  • Laganà, Antonio; Garcia, Ernesto; Paladini, Alessandra
  • Faraday Discussions, Vol. 157
  • DOI: 10.1039/c2fd20046e

Imaging the Reaction Dynamics of OH + CD 4 . 2. Translational Energy Dependencies
journal, October 2005

  • Zhang, Bailin; Shiu, Weicheng; Liu, Kopin
  • The Journal of Physical Chemistry A, Vol. 109, Issue 40
  • DOI: 10.1021/jp0536605

Molecular Beam Studies of Elementary Chemical Processes
journal, May 1987


Competition between C−C and C−H Activation in Reactions of Neutral Yttrium Atoms with Cyclopropane and Propene
journal, November 2003

  • Hinrichs, Ryan Z.; Schroden, Jonathan J.; Davis, H. Floyd
  • The Journal of Physical Chemistry A, Vol. 107, Issue 44
  • DOI: 10.1021/jp034455x

Quantum and quasi-classical dynamics of the OH + CO → H + CO 2 reaction on a new permutationally invariant neural network potential energy surface
journal, January 2014

  • Li, Jun; Chen, Jun; Zhang, Dong H.
  • The Journal of Chemical Physics, Vol. 140, Issue 4
  • DOI: 10.1063/1.4863138

Biofuel Combustion Chemistry: From Ethanol to Biodiesel
journal, May 2010

  • Kohse-Höinghaus, Katharina; Oßwald, Patrick; Cool, Terrill A.
  • Angewandte Chemie International Edition, Vol. 49, Issue 21
  • DOI: 10.1002/anie.200905335

A review of dynamical resonances in A  +  BC chemical reactions
journal, December 2016


Imaging O(3P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics
journal, November 2002

  • Liu, Xianghong; Gross, Richard L.; Hall, Gregory E.
  • The Journal of Chemical Physics, Vol. 117, Issue 17
  • DOI: 10.1063/1.1510444

Reactive scattering dynamics in atom+polyatomic systems: F+C2H6→HF(v,J)+C2H5
journal, March 2005

  • Whitney, Erin S.; Zolot, Alexander M.; McCoy, Anne B.
  • The Journal of Chemical Physics, Vol. 122, Issue 12
  • DOI: 10.1063/1.1868553

Direct and Indirect Hydrogen Abstraction in Cl + Alkene Reactions
journal, June 2014

  • Preston, Thomas J.; Dunning, Greg T.; Orr-Ewing, Andrew J.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 30
  • DOI: 10.1021/jp5042734

Depression of reactivity by the collision energy in the single barrier H + CD4 -> HD + CD3 reaction
journal, July 2010

  • Zhang, W.; Zhou, Y.; Wu, G.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 29
  • DOI: 10.1073/pnas.1006910107

Reaction dynamics of oxygen atoms with unsaturated hydrocarbons from crossed molecular beam studies: primary products, branching ratios and role of intersystem crossing
journal, April 2015

  • Casavecchia, Piergiorgio; Leonori, Francesca; Balucani, Nadia
  • International Reviews in Physical Chemistry, Vol. 34, Issue 2
  • DOI: 10.1080/0144235X.2015.1039293

Time‐of‐Flight Mass Spectrometer with Improved Resolution
journal, December 1955

  • Wiley, W. C.; McLaren, I. H.
  • Review of Scientific Instruments, Vol. 26, Issue 12
  • DOI: 10.1063/1.1715212

Dynamics of CN+alkane reactions by crossed-beam dc slice imaging
journal, August 2008

  • Huang, Cunshun; Li, Wen; Estillore, Armando D.
  • The Journal of Chemical Physics, Vol. 129, Issue 7
  • DOI: 10.1063/1.2968547

Imaging resonances in low-energy NO-He inelastic collisions
journal, November 2015


Imaging H abstraction dynamics in crossed molecular beams: O( 3 P) + propanol isomers
journal, January 2019

  • Li, Hongwei; Kamasah, Alexander; Suits, Arthur G.
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 26
  • DOI: 10.1039/C8CP06351F

Observation of Feshbach Resonances in the F + H2 -> HF + H Reaction
journal, March 2006


Multiple dynamical pathways in the O([sup 1]D)+CH[sub 4] reaction: A comprehensive crossed beam study
journal, January 2000

  • Lin, J. J.; Shu, J.; Lee, Y. T.
  • The Journal of Chemical Physics, Vol. 113, Issue 13
  • DOI: 10.1063/1.1289462

Spin—Orbit Coupling and the Radiationless Processes in Nitrogen Heterocyclics
journal, June 1963

  • El‐Sayed, M. A.
  • The Journal of Chemical Physics, Vol. 38, Issue 12
  • DOI: 10.1063/1.1733610

UV photodissociation of oxalyl chloride yields four fragments from one photon absorption
journal, May 1997

  • Ahmed, Musahid; Blunt, David; Chen, Daniel
  • The Journal of Chemical Physics, Vol. 106, Issue 18
  • DOI: 10.1063/1.473764

Roaming Atoms and Radicals: A New Mechanism in Molecular Dissociation
journal, July 2008

  • Suits, Arthur G.
  • Accounts of Chemical Research, Vol. 41, Issue 7
  • DOI: 10.1021/ar8000734

Triplet state. Its radiative and nonradiative properties
journal, January 1968


Cold quantum-controlled rotationally inelastic scattering of HD with H2 and D2 reveals collisional partner reorientation
journal, April 2018

  • Perreault, William E.; Mukherjee, Nandini; Zare, Richard N.
  • Nature Chemistry, Vol. 10, Issue 5
  • DOI: 10.1038/s41557-018-0028-5

The Extent of Non-Born-Oppenheimer Coupling in the Reaction of Cl(2P) with para-H2
journal, October 2008


Reactive Resonance in a Polyatomic Reaction
journal, March 2004


Experimental and Theoretical Differential Cross Sections for a Four-Atom Reaction: HD + OH -> H2O + D
journal, July 2011


Reaction of oxygen atoms with ethylene and vinyl bromide
journal, January 1981


Dynamics of the O(3P) + C2H2 reaction from crossed molecular beam experiments with soft electron ionization detection
journal, January 2014

  • Leonori, Francesca; Balucani, Nadia; Capozza, Giovanni
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 21
  • DOI: 10.1039/c3cp54729a

Chemical reaction dynamics: Combination of two models
journal, October 1990

  • Evans, Glenn T.; van Kleef, Eddy; Stolte, Steven
  • The Journal of Chemical Physics, Vol. 93, Issue 7
  • DOI: 10.1063/1.458677

Combined Crossed Molecular Beam and Theoretical Studies of the N( 2 D) + CH 4 Reaction and Implications for Atmospheric Models of Titan
journal, October 2009

  • Balucani, Nadia; Bergeat, Astrid; Cartechini, Laura
  • The Journal of Physical Chemistry A, Vol. 113, Issue 42
  • DOI: 10.1021/jp904302g

Bond‐selected bimolecular chemistry: H+HOD(4ν OH )→OD+H 2
journal, May 1990

  • Sinha, Amitabha; Hsiao, Mark C.; Crim, F. Fleming
  • The Journal of Chemical Physics, Vol. 92, Issue 10
  • DOI: 10.1063/1.458312

Enlarging the reactive cone of acceptance by exciting the C–H bond in the O(3P) + CHD3 reaction
journal, January 2010


A crossed molecular beams investigation of the reactions O( 3 P )+ C 6 H 6 , C 6 D 6
journal, April 1980

  • Sibener, Steven J.; Buss, Richard J.; Casavecchia, Piergiorgio
  • The Journal of Chemical Physics, Vol. 72, Issue 8
  • DOI: 10.1063/1.439714

Reaction dynamics of O(1D)+HD. I. The insertion pathway
journal, November 1999

  • Hsu, Yen-Tsung; Liu, Kopin; Pederson, Lisa A.
  • The Journal of Chemical Physics, Vol. 111, Issue 17
  • DOI: 10.1063/1.480127

Vibrational State Control of Bimolecular Reactions:  Discovering and Directing the Chemistry
journal, October 1999

  • Crim, F. Fleming
  • Accounts of Chemical Research, Vol. 32, Issue 10
  • DOI: 10.1021/ar950046a

Relevance of the Channel Leading to Formaldehyde + Triplet Ethylidene in the O( 3 P) + Propene Reaction under Combustion Conditions
journal, November 2014

  • Cavallotti, Carlo; Leonori, Francesca; Balucani, Nadia
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
  • DOI: 10.1021/jz502236y

High-intensity coherent vacuum ultraviolet source using unfocussed commercial dye lasers
journal, June 2013

  • Albert, Daniel R.; Proctor, David L.; Floyd Davis, H.
  • Review of Scientific Instruments, Vol. 84, Issue 6
  • DOI: 10.1063/1.4806801

Dynamics of CO elimination from reactions of yttrium atoms with formaldehyde, acetaldehyde, and acetone
journal, November 2002

  • Schroden, Jonathan J.; Teo, Maurice; Davis, H. Floyd
  • The Journal of Chemical Physics, Vol. 117, Issue 20
  • DOI: 10.1063/1.1514584

Quantum-state-controlled channel branching in cold Ne(3P2)+Ar chemi-ionization
journal, October 2018


Quasiclassical Trajectory Calculations of the N( 2 D) + H 2 O Reaction Elucidating the Formation Mechanism of HNO and HON Seen in Molecular Beam Experiments
journal, September 2014

  • Homayoon, Zahra; Bowman, Joel M.; Balucani, Nadia
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 20
  • DOI: 10.1021/jz501757s

Low temperature kinetics, crossed beam dynamics and theoretical studies of the reaction S(1D) + CH4 and low temperature kinetics of S(1D) + C2H2
journal, January 2011

  • Berteloite, Coralie; Le Picard, Sébastien D.; Sims, Ian R.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 18
  • DOI: 10.1039/c0cp02813d

Dynamics of the S ( D 2 1 ) + HD ( j = 0 ) Reaction at Collision Energies Approaching the Cold Regime: A Stringent Test for Theory
journal, September 2012


Crossed Molecular Beam Dynamics Studies of the O( 3 P) + Allene Reaction: Primary Products, Branching Ratios, and Dominant Role of Intersystem Crossing
journal, December 2011

  • Leonori, Francesca; Occhiogrosso, Angela; Balucani, Nadia
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 1
  • DOI: 10.1021/jz201519q

Observation of the isotope effect in sub-kelvin reactions
journal, February 2014

  • Lavert-Ofir, Etay; Shagam, Yuval; Henson, Alon B.
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1857

Mode-Specific Energy Disposal in the Four-Atom Reaction OH + D2 rightarrow HOD + D
journal, November 2000


Two‐dimensional imaging of state‐selected photodissociation products detected by multiphoton ionization
journal, July 1987

  • Chandler, David W.; Houston, Paul L.
  • The Journal of Chemical Physics, Vol. 87, Issue 2
  • DOI: 10.1063/1.453276

Imaging H abstraction dynamics in crossed molecular beams: Cl+ROH reactions
journal, January 2000

  • Ahmed, Musahid; Peterka, Darcy S.; Suits, Arthur G.
  • Physical Chemistry Chemical Physics, Vol. 2, Issue 4
  • DOI: 10.1039/a907877k

Transition-State Spectroscopy of Partial Wave Resonances in the F + HD Reaction
journal, March 2010


Collision Energy Dependence of the Competing Mechanisms of Reaction of Chlorine Atoms with Propene
journal, March 2019

  • Cascarini, Frederick J. J.; Hornung, Balázs; Quinn, Mitchell S.
  • The Journal of Physical Chemistry A, Vol. 123, Issue 13
  • DOI: 10.1021/acs.jpca.9b01370

Study of Chemical Reaction Mechanisms with Molecular Beams. The Reaction of K with HBr
journal, September 1955

  • Taylor, Ellison H.; Datz, Sheldon
  • The Journal of Chemical Physics, Vol. 23, Issue 9
  • DOI: 10.1063/1.1742417

Experimental Studies and Theoretical Predictions for the H + D2 rarr > HD + D Reaction
journal, July 1995


Gas-Phase Synthesis of the Silaisocyanoethylene Molecule (C 2 H 3 NSi)
journal, September 2012

  • Parker, D. S. N.; Wilson, A. V.; Kaiser, R. I.
  • The Journal of Organic Chemistry, Vol. 77, Issue 19
  • DOI: 10.1021/jo3015402

Intrabeam Scattering for Ultracold Collisions
journal, October 2017


A crossed beams and ab initio investigation on the formation of cyanodiacetylene in the reaction of cyano radicals with diacetylene
journal, June 2009

  • Zhang, Fangtong; Kim, Seol; Kaiser, Ralf I.
  • The Journal of Chemical Physics, Vol. 130, Issue 23
  • DOI: 10.1063/1.3152714

H Abstraction Channels in the Crossed-Beam Reaction of F + 1-Propanol, 1-Butene and 1-Hexene by DC Slice Imaging
journal, November 2016

  • Shi, Yuanyuan; Kamasah, Alexander; Suits, Arthur G.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 45
  • DOI: 10.1021/acs.jpca.6b08408

Product-state-resolved dynamics of the elementary reaction of atomic oxygen with molecular hydrogen, O(3P) + D2 → OD(X2Π) + D
journal, March 2013

  • Lahankar, Sridhar A.; Zhang, Jianming; McKendrick, Kenneth G.
  • Nature Chemistry, Vol. 5, Issue 4
  • DOI: 10.1038/nchem.1588

Slice imaging: A new approach to ion imaging and velocity mapping
journal, October 2001

  • Gebhardt, Christoph R.; Rakitzis, T. Peter; Samartzis, Peter C.
  • Review of Scientific Instruments, Vol. 72, Issue 10
  • DOI: 10.1063/1.1403010

Intersystem crossing in the exit channel
journal, December 2018


Fuel-nitrogen conversion in the combustion of small amines using dimethylamine and ethylamine as biomass-related model fuels
journal, July 2012


Exploring Insertion Reaction Dynamics:  A Case Study of S( 1 D) + D 2 → SD + D
journal, November 1998

  • Lee, Shih-Huang; Liu, Kopin
  • The Journal of Physical Chemistry A, Vol. 102, Issue 45
  • DOI: 10.1021/jp983220w

Observation of Resonances in Penning Ionization Reactions at Sub-Kelvin Temperatures in Merged Beams
journal, October 2012


Details of the Potential Energy Surface for the Reaction Y + H 2 CCO:  A Crossed-Beams Study
journal, December 2002

  • Schroden, Jonathan J.; Teo, Maurice; Davis, H. Floyd
  • The Journal of Physical Chemistry A, Vol. 106, Issue 48
  • DOI: 10.1021/jp026335f

Quantum Effects in the Differential Cross Sections for the Insertion Reaction N ( D 2 ) + H 2
journal, June 2002


Dynamics of Cl + propane, butanes revisited: a crossed beam slice imaging study
journal, January 2014

  • Joalland, Baptiste; Shi, Yuanyuan; Patel, Nitin
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 2
  • DOI: 10.1039/C3CP51785C

Crossed-beam dc slice imaging of chlorine atom reactions with pentane isomers
journal, April 2010

  • Estillore, Armando D.; Visger, Laura M.; Suits, Arthur G.
  • The Journal of Chemical Physics, Vol. 132, Issue 16
  • DOI: 10.1063/1.3414353

Ab initio methods for reactive potential surfaces
journal, January 2007

  • Harding, Lawrence B.; Klippenstein, Stephen J.; Jasper, Ahren W.
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 31
  • DOI: 10.1039/b705390h

Forward scattering due to slow-down of the intermediate in the H + HD → D + H2 reaction
journal, September 2002

  • Harich, Steven A.; Dai, Dongxu; Wang, Chia C.
  • Nature, Vol. 419, Issue 6904
  • DOI: 10.1038/nature01068

Dynamics of H 2 and C 2 H 4 Elimination in the Y + C 2 H 6 Reaction
journal, February 2000

  • Stauffer, Hans U.; Hinrichs, Ryan Z.; Schroden, Jonathan J.
  • The Journal of Physical Chemistry A, Vol. 104, Issue 6
  • DOI: 10.1021/jp993525q

Note: A short-pulse high-intensity molecular beam valve based on a piezoelectric stack actuator
journal, November 2014

  • Abeysekera, Chamara; Joalland, Baptiste; Shi, Yuanyuan
  • Review of Scientific Instruments, Vol. 85, Issue 11
  • DOI: 10.1063/1.4902153

Dynamical Resonances Accessible Only by Reagent Vibrational Excitation in the F + HD->HF + D Reaction
journal, December 2013


Complete State-Resolved Non-Adiabatic Dynamics of the O( 3 P) + D 2 → OD(X 2 Π) + D Reaction
journal, August 2014

  • Lahankar, Sridhar A.; Zhang, Jianming; Minton, Timothy K.
  • Journal of the American Chemical Society, Vol. 136, Issue 35
  • DOI: 10.1021/ja505743c

Quantum control of molecular collisions at 1 kelvin
journal, October 2017

  • Perreault, William E.; Mukherjee, Nandini; Zare, Richard N.
  • Science, Vol. 358, Issue 6361
  • DOI: 10.1126/science.aao3116

Crossed-Beam Slice Imaging of Cl Reaction Dynamics with Butene Isomers
journal, June 2013

  • Joalland, Baptiste; Van Camp, Richard; Shi, Yuanyuan
  • The Journal of Physical Chemistry A, Vol. 117, Issue 32
  • DOI: 10.1021/jp403030s

Molecular beam studies of the F+H 2 reaction
journal, April 1985

  • Neumark, D. M.; Wodtke, A. M.; Robinson, G. N.
  • The Journal of Chemical Physics, Vol. 82, Issue 7
  • DOI: 10.1063/1.448254

State-Specific Correlation of Coincident Product Pairs in the F + CD4 Reaction
journal, May 2003


A crossed beam and ab initio investigation of the reaction of boron monoxide (11BO; X2Σ+) with acetylene (C2H2; X1Σ+g)
journal, January 2011

  • Parker, Dorian S. N.; Zhang, Fangtong; Maksyutenko, Pavlo
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 18
  • DOI: 10.1039/c0cp02458a

Reactivity Consequences of Conformational Isomerism in 1-Propanol
journal, January 2019


Dynamics of gas phase Ne * + NH 3 and Ne * + ND 3 Penning ionisation at low temperatures
journal, June 2014

  • Jankunas, Justin; Bertsche, Benjamin; Jachymski, Krzysztof
  • The Journal of Chemical Physics, Vol. 140, Issue 24
  • DOI: 10.1063/1.4883517

Competition between C−C and C−H Activation in Reactions of Neutral Yttrium Atoms with Four Butene Isomers
journal, November 2003

  • Schroden, Jonathan J.; Wang, Chia C.; Davis, H. Floyd
  • The Journal of Physical Chemistry A, Vol. 107, Issue 44
  • DOI: 10.1021/jp034453c

Crossed beam studies of four‐atom reactions: The dynamics of OH+D 2
journal, February 1993

  • Alagia, Michele; Balucani, Nadia; Casavecchia, Piergiorgio
  • The Journal of Chemical Physics, Vol. 98, Issue 3
  • DOI: 10.1063/1.464173

CH Stretching Excitation in the Early Barrier F + CHD3 Reaction Inhibits CH Bond Cleavage
journal, July 2009


Imaging the inelastic scattering of vibrationally excited NO (v = 1) with Ar
journal, January 2018


Computational Study of Competition between Direct Abstraction and Addition–Elimination in the Reaction of Cl Atoms with Propene
journal, August 2015

  • Hornung, Balázs; Preston, Thomas J.; Pandit, Shubhrangshu
  • The Journal of Physical Chemistry A, Vol. 119, Issue 36
  • DOI: 10.1021/acs.jpca.5b07052

Reaction Dynamics of O( 3 P) + Propyne: I. Primary Products, Branching Ratios, and Role of Intersystem Crossing from Crossed Molecular Beam Experiments
journal, February 2016

  • Vanuzzo, Gianmarco; Balucani, Nadia; Leonori, Francesca
  • The Journal of Physical Chemistry A, Vol. 120, Issue 27
  • DOI: 10.1021/acs.jpca.6b01563

C−C versus C−H Bond Activation of Alkynes by Early Second-Row Transition Metal Atoms
journal, April 2008

  • Hinrichs, Ryan Z.; Schroden, Jonathan J.; Davis, H. Floyd
  • The Journal of Physical Chemistry A, Vol. 112, Issue 14
  • DOI: 10.1021/jp800077m

Differential Cross Sections for State-to-State Collisions of NO( v = 10) in Near-Copropagating Beams
journal, April 2019

  • Amarasinghe, Chandika; Li, Hongwei; Perera, Chatura A.
  • The Journal of Physical Chemistry Letters, Vol. 10, Issue 10
  • DOI: 10.1021/acs.jpclett.9b00847

Direct mapping of insertion reaction dynamics: S(1D)+H2→SH+H
journal, November 2000


Molecular Reaction Dynamics
book, January 2005


Reaction Dynamics of Zr and Nb with Ethylene
journal, May 1999

  • Willis, Peter A.; Stauffer, Hans U.; Hinrichs, Ryan Z.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 19
  • DOI: 10.1021/jp9846633

van der Waals Interactions in the Cl + HD Reaction
journal, November 1999


On the formation of polyacetylenes and cyanopolyacetylenes in Titan's atmosphere and their role in astrobiology
journal, January 2012

  • Kaiser, Ralf I.; Mebel, Alexander M.
  • Chemical Society Reviews, Vol. 41, Issue 16
  • DOI: 10.1039/c2cs35068h

Correlated Dynamics of the O( 3 P) + CHD 3 ( v =0) Reaction: A Joint Crossed-Beam and Quasiclassical Trajectory Study
journal, December 2014

  • Zhang, Bailin; Liu, Kopin; Czakó, Gábor
  • The Journal of Physical Chemistry A, Vol. 119, Issue 28
  • DOI: 10.1021/jp510377k

Competing reaction pathways from Y+C2H2 collisions
journal, September 1999

  • Stauffer, Hans U.; Hinrichs, Ryan Z.; Willis, Peter A.
  • The Journal of Chemical Physics, Vol. 111, Issue 9
  • DOI: 10.1063/1.479708

Crossed-Beam Imaging of the H Abstraction Channel in the Reaction of CN with 1-Pentene
journal, July 2010

  • Estillore, Armando D.; Visger, Laura M.; Kaiser, Ralf I.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 15
  • DOI: 10.1021/jz100861t

Observation of orbiting resonances in He( 3 S 1 ) + NH 3 Penning ionization
journal, April 2015

  • Jankunas, Justin; Jachymski, Krzysztof; Hapka, Michał
  • The Journal of Chemical Physics, Vol. 142, Issue 16
  • DOI: 10.1063/1.4919369

Reaction Product Imaging: The H + D2 Reaction
journal, June 1993


Megapixel ion imaging with standard video
journal, June 2005

  • Li, Wen; Chambreau, Steven D.; Lahankar, Sridhar A.
  • Review of Scientific Instruments, Vol. 76, Issue 6
  • DOI: 10.1063/1.1921671

Experimental and Theoretical Studies on the Dynamics of the O( 3 P) + Propene Reaction: Primary Products, Branching Ratios, and Role of Intersystem Crossing
journal, March 2015

  • Leonori, Francesca; Balucani, Nadia; Nevrly, Vaclav
  • The Journal of Physical Chemistry C, Vol. 119, Issue 26
  • DOI: 10.1021/jp512670y

Direct mapping of the angle-dependent barrier to reaction for Cl + CHD3 using polarized scattering data
journal, September 2017

  • Pan, Huilin; Wang, Fengyan; Czakó, Gábor
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2858

Imaging the Reaction Dynamics of OH + CD 4 . 3. Isotope Effects
journal, October 2005

  • Zhang, Bailin; Shiu, Weicheng; Liu, Kopin
  • The Journal of Physical Chemistry A, Vol. 109, Issue 40
  • DOI: 10.1021/jp053661x

Reaction dynamics of Cl + butanol isomers by crossed-beam sliced ion imaging
journal, January 2012

  • Estillore, Armando D.; Visger-Kiefer, Laura M.; Suits, Arthur G.
  • Faraday Discussions, Vol. 157
  • DOI: 10.1039/c2fd20059g

Crossed-beam reaction of O(1D)+D2→OD+D by velocity map imaging
journal, February 1999


Crossed beams studies of Mo(a 7S3) and Mo*(a 5S2) collisions with CH4 and C2H6
journal, March 2000

  • Hinrichs, Ryan Z.; Willis, Peter A.; Stauffer, Hans U.
  • The Journal of Chemical Physics, Vol. 112, Issue 10
  • DOI: 10.1063/1.481018

Photoinduced Mechanism of Formation and Growth of Polycyclic Aromatic Hydrocarbons in Low-Temperature Environments via Successive Ethynyl Radical Additions
journal, October 2008

  • Mebel, Alexander M.; Kislov, Vadim V.; Kaiser, Ralf I.
  • Journal of the American Chemical Society, Vol. 130, Issue 41
  • DOI: 10.1021/ja804198a

Vibrational vs. translational energy in promoting a prototype metal-hydrocarbon insertion reaction
journal, August 2008

  • Proctor, D. L.; Davis, H. F.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 35
  • DOI: 10.1073/pnas.0801170105

Revealing the stereospecific chemistry of the reaction of Cl with aligned CHD3(ν1 = 1)
journal, July 2012

  • Wang, Fengyan; Liu, Kopin; Rakitzis, T. Peter
  • Nature Chemistry, Vol. 4, Issue 8
  • DOI: 10.1038/nchem.1383

Crossed molecular beam study of the reaction O( 3 P )+C 2 H 4
journal, December 1989

  • Schmoltner, A. M.; Chu, P. M.; Brudzynski, R. J.
  • The Journal of Chemical Physics, Vol. 91, Issue 11
  • DOI: 10.1063/1.457309

Steric Control of the Reaction of CH Stretch-Excited CHD3 with Chlorine Atom
journal, February 2011


Competition between C−C and C−H Insertion in Prototype Transition Metal−Hydrocarbon Reactions
journal, January 2003

  • Hinrichs, Ryan Z.; Schroden, Jonathan J.; Davis, H. Floyd
  • Journal of the American Chemical Society, Vol. 125, Issue 4
  • DOI: 10.1021/ja0278842

O(3P) versus O(1D) reaction dynamics with n-pentane: a crossed-beam imaging study
journal, July 2003


Rotatable source crossed molecular beams apparatus with pulsed ultraviolet/vacuum ultraviolet photoionization detection
journal, June 1999

  • Willis, P. A.; Stauffer, H. U.; Hinrichs, R. Z.
  • Review of Scientific Instruments, Vol. 70, Issue 6
  • DOI: 10.1063/1.1149817

Reaction Dynamics of Phenyl Radicals in Extreme Environments: A Crossed Molecular Beam Study
journal, February 2009

  • Gu, Xibin; Kaiser, Ralf I.
  • Accounts of Chemical Research, Vol. 42, Issue 2
  • DOI: 10.1021/ar8001365

A mechanical method for the activation of fast reactions
journal, January 1954


Exploring the reaction dynamics of nitrogen atoms: A combined crossed beam and theoretical study of N(2D)+D2→ND+D
journal, May 1999

  • Alagia, M.; Balucani, N.; Cartechini, L.
  • The Journal of Chemical Physics, Vol. 110, Issue 18
  • DOI: 10.1063/1.478806

Imaging the dynamics of chlorine atom reactions with alkenes
journal, August 2010

  • Estillore, Armando D.; Visger, Laura M.; Suits, Arthur G.
  • The Journal of Chemical Physics, Vol. 133, Issue 7
  • DOI: 10.1063/1.3473049

Crossed molecular beam study of the reaction O( 3 P )+allene
journal, August 1993

  • Schmoltner, A. M.; Huang, S. Y.; Brudzynski, R. J.
  • The Journal of Chemical Physics, Vol. 99, Issue 3
  • DOI: 10.1063/1.465334

Dynamics of Y+H2CO reactions
journal, December 1999

  • Stauffer, Hans U.; Hinrichs, Ryan Z.; Schroden, Jonathan J.
  • The Journal of Chemical Physics, Vol. 111, Issue 24
  • DOI: 10.1063/1.480439

Crossed jet reactive scattering dynamics of F+H2O→HF(v,J)+OH:HF(v,J) product quantum state distributions under single-collision conditions
journal, November 2008

  • Zolot, Alexander M.; Nesbitt, David J.
  • The Journal of Chemical Physics, Vol. 129, Issue 18
  • DOI: 10.1063/1.2998524

Experimental and theoretical angular and translational energy distributions for the reaction CN+D2→DCN+D
journal, November 1997

  • Wang, Jeng‐Han; Liu, Kopin; Schatz, George C.
  • The Journal of Chemical Physics, Vol. 107, Issue 19
  • DOI: 10.1063/1.475099

Imaging Dynamics on the F + H2O -> HF + OH Potential Energy Surfaces from Wells to Barriers
journal, January 2014


Application of time-sliced ion velocity imaging to crossed molecular beam experiments
journal, April 2003

  • Lin, Jim J.; Zhou, Jingang; Shiu, Weicheng
  • Review of Scientific Instruments, Vol. 74, Issue 4
  • DOI: 10.1063/1.1561604

The chemical dynamics of the reactions of O( 3 P ) with saturated hydrocarbons. II. Theoretical model
journal, June 1980

  • Luntz, A. C.; Andresen, P.
  • The Journal of Chemical Physics, Vol. 72, Issue 11
  • DOI: 10.1063/1.439109

The chemical dynamics of the reactions of O( 3 P ) with saturated hydrocarbons. I. Experiment
journal, June 1980

  • Andresen, P.; Luntz, A. C.
  • The Journal of Chemical Physics, Vol. 72, Issue 11
  • DOI: 10.1063/1.439108

Electric dipole moments of OH and OD by molecular beam electric resonance
journal, November 1973


Direct observation of forward-scattering oscillations in the H+HD→H2+D reaction
journal, April 2018


Observation of the geometric phase effect in the H + HD → H 2 + D reaction
journal, December 2018


Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen
journal, September 1997

  • Eppink, André T. J. B.; Parker, David H.
  • Review of Scientific Instruments, Vol. 68, Issue 9
  • DOI: 10.1063/1.1148310

Ab Initio and Quasiclassical Trajectory Study of the O( 3 P) + 2-Propanol Hydrogen Abstraction Reaction
journal, July 2019


The Dynamics of Reactions of O( 3 P) Atoms with Saturated Hydrocarbons and Related Compounds
journal, December 2000

  • Ausfelder, Florian; McKendrick, Kenneth G.
  • Progress in Reaction Kinetics and Mechanism, Vol. 25, Issue 4
  • DOI: 10.3184/007967400103165164

Breakdown of the Born-Oppenheimer Approximation in the F+ o-D2 -> DF + D Reaction
journal, August 2007


Crossed-Beams and Theoretical Studies of the O( 3 P) + H 2 O → HO 2 + H Reaction Excitation Function
journal, November 2007

  • Brunsvold, Amy L.; Zhang, Jianming; Upadhyaya, Hari P.
  • The Journal of Physical Chemistry A, Vol. 111, Issue 43
  • DOI: 10.1021/jp0744228

A crossed molecular beams study of the reaction of the ethynyl radical (C2H(X2Σ+)) with allene (H2CCCH2(X1A1))
journal, January 2009

  • Zhang, Fangtong; Kim, Seol; Kaiser, Ralf I.
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 23
  • DOI: 10.1039/b822366a

Crossed beam studies of radical–radical reactions: O( 3 P) + C 3 H 5 (allyl)
journal, January 2007

  • Leonori, F.; Balucani, N.; Capozza, G.
  • Phys. Chem. Chem. Phys., Vol. 9, Issue 11
  • DOI: 10.1039/B618971G

Rovibrational state specific scattering distributions of the O(1D) + CD4→ OD + CD3 (v1, v2, N) reaction
journal, January 2011

  • Kohguchi, Hiroshi; Ogi, Yoshihiro; Suzuki, Toshinori
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 18
  • DOI: 10.1039/c0cp01760d

State-to-State Rates for the D + H2(v = 1, j = 1) rarr HD(v', j') + H Reaction: Predictions and Measurements
journal, July 1992


Molecular hydrogen interacts more strongly when rotationally excited at low temperatures leading to faster reactions
journal, October 2015

  • Shagam, Yuval; Klein, Ayelet; Skomorowski, Wojciech
  • Nature Chemistry, Vol. 7, Issue 11
  • DOI: 10.1038/nchem.2359

Dynamics of Chlorine Atom Reactions with Hydrocarbons: Insights from Imaging the Radical Product in Crossed Beams
journal, August 2014

  • Joalland, Baptiste; Shi, Yuanyuan; Estillore, Armando D.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 40
  • DOI: 10.1021/jp504804n

Dynamics of the Simplest Chlorine Atom Reaction: An Experimental and Theoretical Study
journal, September 1996


Synthesis of the Silaisocyanoacetylene Molecule
journal, August 2012

  • Parker, Dorian S. N.; Wilson, Antony V.; Kaiser, Ralf I.
  • Journal of the American Chemical Society, Vol. 134, Issue 33
  • DOI: 10.1021/ja305569k

A Combined Experimental and Theoretical Study on the Formation of Interstellar C3H Isomers
journal, November 1996


Dynamics of the C(D1)+D2 reaction: A comparison of crossed molecular-beam experiments with quasiclassical trajectory and accurate statistical calculations
journal, June 2005

  • Balucani, Nadia; Capozza, Giovanni; Segoloni, Enrico
  • The Journal of Chemical Physics, Vol. 122, Issue 23
  • DOI: 10.1063/1.1930831

From ab Initio Potential Energy Surfaces to State-Resolved Reactivities: X + H 2 O ↔ HX + OH [X = F, Cl, and O( 3 P)] Reactions
journal, May 2015

  • Li, Jun; Jiang, Bin; Song, Hongwei
  • The Journal of Physical Chemistry A, Vol. 119, Issue 20
  • DOI: 10.1021/acs.jpca.5b02510

High-resolution emission spectrum of OH in an oxyacetylene flame from 3.7 to 0.9 μm
journal, October 1976


A crossed beam and ab initio investigation on the formation of vinyl boron monoxide (C2H3BO; X1A′) via reaction of boron monoxide (11BO; X2Σ+) with ethylene (C2H4; X1Ag)
journal, January 2012

  • Parker, Dorian S. N.; Zhang, Fangtong; Maksyutenko, Pavlo
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 31
  • DOI: 10.1039/c2cp40781g

Roaming dynamics in radical addition–elimination reactions
journal, June 2014

  • Joalland, Baptiste; Shi, Yuanyuan; Kamasah, Alexander
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5064