Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Fallon, M. Jewels; Martinolich, Andrew J.; Maughan, Annalise E.; Gallington, Leighanne C.; Neilson, James R.

doi:10.1039/c9dt03723c

Title: Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Journal Article · 08 October 2019 · Dalton Transactions

DOI: https://doi.org/10.1039/c9dt03723c · OSTI ID:1607386

^[1];

^[2];

^[1]

Colorado State Univ., Fort Collins, CO (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

A low-temperature synthesis of iron selenide using molten triphenylphosphine demonstrates the use of an organic flux in solid-state synthesis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Alfred P. Sloan Foundation; National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1607386

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 43 Vol. 48; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (18)

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Pöttgen, Rainer; Jeitschko, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200462170	journal	November 2005
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Poettgen, Rainer; Jeitschko, Wolfgang ChemInform, Vol. 37, Issue 1 https://doi.org/10.1002/chin.200601226	journal	January 2006
The fese (ironselenium) system Okamoto, H. Journal of Phase Equilibria, Vol. 12, Issue 3 https://doi.org/10.1007/BF02649932	journal	June 1991
Anisotropy of chemical shift and J coupling for P-31 and Se-77 in trimethyl and triphenyl phosphine selenides Grossmann, Gisbert; Potrzebowski, Marek J.; Fleischer, Ulrich Solid State Nuclear Magnetic Resonance, Vol. 13, Issue 1-2 https://doi.org/10.1016/S0926-2040(98)00077-0	journal	November 1998
Lewis Base Mediated Polymorph Selectivity of Pyrite CuSe ₂ through Atom Transfer in Solid-State Metathesis Martinolich, Andrew J.; Higgins, Robert F.; Shores, Matthew P. Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.6b00027	journal	February 2016
A Solution for Solution-Produced β-FeSe: Elucidating and Overcoming Factors that Prevent Superconductivity Greenfield, Joshua T.; Kamali, Saeed; Lee, Kathleen Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm5041612	journal	January 2015
Room-Temperature Synthesis, Hydrothermal Recrystallization, and Properties of Metastable Stoichiometric FeSe Nitsche, F.; Goltz, T.; Klauss, H. -H. Inorganic Chemistry, Vol. 51, Issue 13 https://doi.org/10.1021/ic300798p	journal	June 2012
Transition metal pyrite dichalcogenides. High-pressure synthesis and correlation of properties Bither, Tom A.; Bouchard, R. J.; Cloud, W. H. Inorganic Chemistry, Vol. 7, Issue 11 https://doi.org/10.1021/ic50069a008	journal	November 1968
Molecular Control of the Nanoscale: Effect of Phosphine–Chalcogenide Reactivity on CdS–CdSe Nanocrystal Composition and Morphology Ruberu, T. Purnima A.; Albright, Haley R.; Callis, Brandon ACS Nano, Vol. 6, Issue 6 https://doi.org/10.1021/nn301182h	journal	April 2012
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles Navrotsky, A. Proceedings of the National Academy of Sciences, Vol. 101, Issue 33 https://doi.org/10.1073/pnas.0404778101	journal	August 2004
Superconductivity in the PbO-type structure -FeSe Hsu, F. -C.; Luo, J. -Y.; Yeh, K. -W. Proceedings of the National Academy of Sciences, Vol. 105, Issue 38 https://doi.org/10.1073/pnas.0807325105	journal	September 2008
Crystal growth and superconductivity of FeSe _x Zhang, S. B.; Sun, Y. P.; Zhu, X. D. Superconductor Science and Technology, Vol. 22, Issue 1 https://doi.org/10.1088/0953-2048/22/1/015020	journal	November 2008
Extreme sensitivity of superconductivity to stoichiometry in Fe 1 + δ Se McQueen, T. M.; Huang, Q.; Ksenofontov, V. Physical Review B, Vol. 79, Issue 1 https://doi.org/10.1103/PhysRevB.79.014522	journal	January 2009
A versatile sample-environment cell for non-ambient X-ray scattering experiments Chupas, Peter J.; Chapman, Karena W.; Kurtz, Charles Journal of Applied Crystallography, Vol. 41, Issue 4 https://doi.org/10.1107/S0021889808020165	journal	July 2008
Quantifying amorphous and crystalline phase content with the atomic pair distribution function Peterson, Joseph; TenCate, James; Proffen, Thomas Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889812050595	journal	February 2013
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Turning Down the Heat: Design and Mechanism in Solid-State Synthesis Stein, A.; Keller, S. W.; Mallouk, T. E. Science, Vol. 259, Issue 5101 https://doi.org/10.1126/science.259.5101.1558	journal	March 1993

Similar Records

Fabrication, characterization and applications of iron selenide

Journal Article · 2016 · Journal of Solid State Chemistry · OSTI ID:22658098

Badshah, Amin; Lal, Bhajan

Synthesis of nanocrystalline yttrium iron garnet by low temperature solid state reaction

Journal Article · 2011 · Materials Characterization · OSTI ID:22066278

Liwen, Zeng; Chao, Lu; Wenbo, Zhang; +1 more

Diffusion of iron in gallium selenide

Journal Article · 1987 · Inorg. Mater. (Engl. Transl.); (United States) · OSTI ID:6805092

Firsova, L P

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Citation Formats

References (18)

Similar Records

Related Subjects