Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Fallon, M. Jewels; Martinolich, Andrew J.; Maughan, Annalise E.; Gallington, Leighanne C.; Neilson, James R.

doi:10.1039/c9dt03723c

Title: Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Abstract

A low-temperature synthesis of iron selenide using molten triphenylphosphine demonstrates the use of an organic flux in solid-state synthesis.

Authors:

^[1];

^[2];

^[1]

Colorado State Univ., Fort Collins, CO (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: 2019-10-08

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: National Science Foundation (NSF); Alfred P. Sloan Foundation; USDOE Office of Science (SC)

OSTI Identifier:: 1607386

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Dalton Transactions

Additional Journal Information:: Journal Volume: 48; Journal Issue: 43; Journal ID: ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Fallon, M. Jewels, Martinolich, Andrew J., Maughan, Annalise E., Gallington, Leighanne C., and Neilson, James R. Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux.  United States: N. p., 2019. 
Web.  doi:10.1039/c9dt03723c.

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                    Fallon, M. Jewels, Martinolich, Andrew J., Maughan, Annalise E., Gallington, Leighanne C., & Neilson, James R. Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux.  United States.  https://doi.org/10.1039/c9dt03723c

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                    Fallon, M. Jewels, Martinolich, Andrew J., Maughan, Annalise E., Gallington, Leighanne C., and Neilson, James R. Tue .  
"Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux".  United States.  https://doi.org/10.1039/c9dt03723c.  https://www.osti.gov/servlets/purl/1607386.

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@article{osti_1607386,

  title        = {Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux},

  author       = {Fallon, M. Jewels and Martinolich, Andrew J. and Maughan, Annalise E. and Gallington, Leighanne C. and Neilson, James R.},

  abstractNote = {A low-temperature synthesis of iron selenide using molten triphenylphosphine demonstrates the use of an organic flux in solid-state synthesis.},

  doi          = {10.1039/c9dt03723c},

  journal      = {Dalton Transactions},

  number       = 43,

  volume       = 48,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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Title: Low-temperature synthesis of superconducting iron selenide using a triphenylphosphine flux

Abstract

Citation Formats

Quantifying amorphous and crystalline phase content with the atomic pair distribution function journal, February 2013

Transition metal pyrite dichalcogenides. High-pressure synthesis and correlation of properties journal, November 1968

Extreme sensitivity of superconductivity to stoichiometry in Fe 1 + δ Se journal, January 2009

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds journal, November 2005

Crystal growth and superconductivity of FeSe x journal, November 2008

Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles journal, August 2004

Turning Down the Heat: Design and Mechanism in Solid-State Synthesis journal, March 1993

Anisotropy of chemical shift and J coupling for P-31 and Se-77 in trimethyl and triphenyl phosphine selenides journal, November 1998

The fese (ironselenium) system journal, June 1991

Superconductivity in the PbO-type structure -FeSe journal, September 2008

Room-Temperature Synthesis, Hydrothermal Recrystallization, and Properties of Metastable Stoichiometric FeSe journal, June 2012

A Solution for Solution-Produced β-FeSe: Elucidating and Overcoming Factors that Prevent Superconductivity journal, January 2015

A versatile sample-environment cell for non-ambient X-ray scattering experiments journal, July 2008

GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal, March 2013

Molecular Control of the Nanoscale: Effect of Phosphine–Chalcogenide Reactivity on CdS–CdSe Nanocrystal Composition and Morphology journal, April 2012

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Commentary: The Materials Project: A materials genome approach to accelerating materials innovation journal, July 2013

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journal, February 2013

Transition metal pyrite dichalcogenides. High-pressure synthesis and correlation of properties
journal, November 1968

Extreme sensitivity of superconductivity to stoichiometry in ${Fe}_{1 + δ} Se$
journal, January 2009

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, November 2005

Crystal growth and superconductivity of FeSe _x
journal, November 2008

Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles
journal, August 2004

Turning Down the Heat: Design and Mechanism in Solid-State Synthesis
journal, March 1993

Anisotropy of chemical shift and J coupling for P-31 and Se-77 in trimethyl and triphenyl phosphine selenides
journal, November 1998

The fese (ironselenium) system
journal, June 1991

Superconductivity in the PbO-type structure -FeSe
journal, September 2008

Room-Temperature Synthesis, Hydrothermal Recrystallization, and Properties of Metastable Stoichiometric FeSe
journal, June 2012

A Solution for Solution-Produced β-FeSe: Elucidating and Overcoming Factors that Prevent Superconductivity
journal, January 2015

A versatile sample-environment cell for non-ambient X-ray scattering experiments
journal, July 2008

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Molecular Control of the Nanoscale: Effect of Phosphine–Chalcogenide Reactivity on CdS–CdSe Nanocrystal Composition and Morphology
journal, April 2012

Lewis Base Mediated Polymorph Selectivity of Pyrite CuSe ₂ through Atom Transfer in Solid-State Metathesis
journal, February 2016

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, January 2006