One-Pot Pyrolysis Method to Fabricate Carbon Nanotube Supported Ni Single-Atom Catalysts with Ultrahigh Loading

Zhao, Shiyong; Cheng, Yi; Veder, Jean-Pierre; Johannessen, Bernt; Saunders, Martin; Zhang, Lianji; Liu, Chang; Chisholm, Matthew F.; De Marco, Roland; Liu, Jian; Yang, Shi-Ze; Jiang, San Ping

doi:10.1021/acsaem.8b00903

Title: One-Pot Pyrolysis Method to Fabricate Carbon Nanotube Supported Ni Single-Atom Catalysts with Ultrahigh Loading

Journal Article · 10 September 2018 · ACS Applied Energy Materials

DOI: https://doi.org/10.1021/acsaem.8b00903 · OSTI ID:1607268

Zhao, Shiyong ^[1]; Cheng, Yi ^[1]; Veder, Jean-Pierre ^[1]; Johannessen, Bernt ^[2]; Saunders, Martin ^[3]; Zhang, Lianji ^[4]; Liu, Chang ^[4]; Chisholm, Matthew F. ^[5];

^[6];

^[7];

^[5];

^[1]

Curtin Univ., Perth, WA (Australia)
Australian Synchrotron, Clayton, ViIC (Australia)
Univ. of Western Australia, Perth, WA (Australia)
Chinese Academy of Sciences, Shenyang, LN (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Sunshine Coast, Maroochydore DC, QLD (Australia); The Univ. of Queensland, Brisbane (Australia)
Univ. of Surrey, Guildford (United Kingdom)

The practical application of single atom catalysts (SACs) is constrained by the low achievable loading of single metal atoms. In this work, nickel SACs stabilized on a nitrogen-doped carbon nanotube structure (NiSA-N-CNT) with ultrahigh Ni atomic loading up to 20.3 wt % have been successfully synthesized using a new one-pot pyrolysis method employing Ni acetylacetonate (Ni(acac)₂) and dicyandiamide (DCD) as precursors. The yield and formation of NiSA-N-CNT depends strongly on the Ni(acac)₂/DCD ratio and annealing temperature. Pyrolysis at 350 and 650 °C led to the formation of Ni single atom dispersed melem and graphitic carbon nitride (Ni-melem and Ni-g-C₃N₄). Transition from a stacked and layered Ni-g-C₃N₄ structure to a bamboo-shaped tubular NiSA-N-CNT structure most likely occurs via a solid-to-solid curling or rolling-up mechanism, thermally activated at temperatures of 700–900 °C. Extended X-ray absorption fine structure (EXAFS) experiments and simulations show that Ni single atoms are stabilized in the N-CNT structure through nitrogen coordination, forming a structure with four nearest N coordination shell surrounded by two carbon shells, Ni–N₄. The NiSA-N-CNT catalysts show an excellent activity and selectivity for the electrochemical reduction of CO₂, achieving a turnover frequency (TOF) of 11.7 s–1 at -0.55 V (vs RHE), but a low activity for the O₂ reduction and O₂ evolution reactions, as compared to Ni nanoparticles supported on N-CNTs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: Australian Research Council (ARC); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC05-00OR22725; LE120100026; AC02-05CH11231; ACI-1053575

OSTI ID:: 1607268

Journal Information:: ACS Applied Energy Materials, Vol. 1, Issue 10; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 102 works

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References (65)

Single-Atom Electrocatalysts Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong Angewandte Chemie International Edition, Vol. 56, Issue 45 https://doi.org/10.1002/anie.201703864	journal	October 2017
Catalysis by Supported Single Metal Atoms Liu, Jingyue ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b01534	journal	November 2016
Heterogeneous single-atom catalysis Wang, Aiqin; Li, Jun; Zhang, Tao Nature Reviews Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/s41570-018-0010-1	journal	May 2018
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Remarkable Performance of Ir ₁ /FeO _x Single-Atom Catalyst in Water Gas Shift Reaction Lin, Jian; Wang, Aiqin; Qiao, Botao Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja408574m	journal	October 2013
A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions Liu, Wengang; Chen, Yinjuan; Qi, Haifeng Angewandte Chemie International Edition, Vol. 57, Issue 24 https://doi.org/10.1002/anie.201802231	journal	May 2018
Single Atom Hot-Spots at Au–Pd Nanoalloys for Electrocatalytic H ₂ O ₂ Production Jirkovský, Jakub S.; Panas, Itai; Ahlberg, Elisabet Journal of the American Chemical Society, Vol. 133, Issue 48 https://doi.org/10.1021/ja206477z	journal	December 2011
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1215864	journal	March 2012
Single-atom Catalysis Using Pt/Graphene Achieved through Atomic Layer Deposition Sun, Shuhui; Zhang, Gaixia; Gauquelin, Nicolas Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01775	journal	May 2013
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300361m	journal	April 2013
Bottom-up precise synthesis of stable platinum dimers on graphene Yan, Huan; Lin, Yue; Wu, Hong Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01259-z	journal	October 2017
Stabilizing a Platinum ₁ Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity Zhang, Bin; Asakura, Hiroyuki; Zhang, Jia Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201602801	journal	May 2016
Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO ₂ Zhao, Changming; Dai, Xinyao; Yao, Tao Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02736	journal	June 2017
High-Activity, Single-Site Mesoporous Pd/Al ₂ O ₃ Catalysts for Selective Aerobic Oxidation of Allylic Alcohols Hackett, Simon F. J.; Brydson, Rik M.; Gass, Mhairi H. Angewandte Chemie International Edition, Vol. 46, Issue 45 https://doi.org/10.1002/anie.200702534	journal	October 2007
Supported Single Pt ₁ /Au ₁ Atoms for Methanol Steam Reforming Gu, Xiang-Kui; Qiao, Botao; Huang, Chuan-Qi ACS Catalysis, Vol. 4, Issue 11 https://doi.org/10.1021/cs500740u	journal	October 2014
Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation Zhou, Xiong; Yang, Wenshao; Chen, Qiwei The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b11362	journal	January 2016
Photochemical route for synthesizing atomically dispersed palladium catalysts Liu, P.; Zhao, Y.; Qin, R. Science, Vol. 352, Issue 6287 https://doi.org/10.1126/science.aaf5251	journal	May 2016
Single-Atom Catalyst of Platinum Supported on Titanium Nitride for Selective Electrochemical Reactions Yang, Sungeun; Kim, Jiwhan; Tak, Young Joo Angewandte Chemie International Edition, Vol. 55, Issue 6 https://doi.org/10.1002/anie.201509241	journal	December 2015
Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions Zheng, Yao; Jiao, Yan; Zhu, Yihan Journal of the American Chemical Society, Vol. 139, Issue 9 https://doi.org/10.1021/jacs.6b13100	journal	February 2017
Conductive Carbon Nitride for Excellent Energy Storage Xu, Jijian; Xu, Feng; Qian, Meng Advanced Materials, Vol. 29, Issue 31 https://doi.org/10.1002/adma.201701674	journal	June 2017
Nanoporous Graphene with Single-Atom Nickel Dopants: An Efficient and Stable Catalyst for Electrochemical Hydrogen Production Qiu, H. -J.; Ito, Yoshikazu; Cong, Weitao Angewandte Chemie International Edition, Vol. 54, Issue 47 https://doi.org/10.1002/anie.201507381	journal	October 2015
Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis Jiang, Kun; Siahrostami, Samira; Akey, Austin J. Chem, Vol. 3, Issue 6 https://doi.org/10.1016/j.chempr.2017.09.014	journal	December 2017
Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene Yan, Huan; Cheng, Hao; Yi, Hong Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b06485	journal	August 2015
Atomic cobalt on nitrogen-doped graphene for hydrogen generation Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9668	journal	October 2015
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride Chen, Zupeng; Mitchell, Sharon; Vorobyeva, Evgeniya Advanced Functional Materials, Vol. 27, Issue 8 https://doi.org/10.1002/adfm.201605785	journal	January 2017
A Stable Single-Site Palladium Catalyst for Hydrogenations Vilé, Gianvito; Albani, Davide; Nachtegaal, Maarten Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505073	journal	July 2015
Single-Atom Pt as Co-Catalyst for Enhanced Photocatalytic H ₂ Evolution Li, Xiaogang; Bi, Wentuan; Zhang, Lei Advanced Materials, Vol. 28, Issue 12 https://doi.org/10.1002/adma.201505281	journal	January 2016
Single Atoms of Pt-Group Metals Stabilized by N-Doped Carbon Nanofibers for Efficient Hydrogen Production from Formic Acid Bulushev, Dmitri A.; Zacharska, Monika; Lisitsyn, Alexander S. ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00476	journal	April 2016
Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction Cheng, Yi; Zhao, Shiyong; Johannessen, Bernt Advanced Materials, Vol. 30, Issue 13 https://doi.org/10.1002/adma.201706287	journal	February 2018
Oxygen Reduction Electrocatalyst Based on Strongly Coupled Cobalt Oxide Nanocrystals and Carbon Nanotubes Liang, Yongye; Wang, Hailiang; Diao, Peng Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja305623m	journal	September 2012
Elemental superdoping of graphene and carbon nanotubes Liu, Yuan; Shen, Yuting; Sun, Litao Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10921	journal	March 2016
EXAFS, SEXAFS, XANES: X-Ray Absorption - Principles, Applications, Techniques of EXAFS, SEXAFS and XANES. Von D. Koningsberger und R. Prins. John Wiley & Sons Ltd., Chichester 1988. 673 S., Abb., Tab., Formeln. ISBN 0-471-87547-3 Baumgartel, H. Nachrichten aus Chemie, Technik und Laboratorium, Vol. 36, Issue 6 https://doi.org/10.1002/nadc.19880360617	journal	June 1988
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
Theoretical approaches to x-ray absorption fine structure Rehr, J. J.; Albers, R. C. Reviews of Modern Physics, Vol. 72, Issue 3 https://doi.org/10.1103/RevModPhys.72.621	journal	July 2000
The Current Performance of the Wide Range (90–2500 eV) Soft X-ray Beamline at the Australian Synchrotron Cowie, B. C. C.; Tadich, A.; Thomsen, L. SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463197	conference	January 2010
Quick AS NEXAFS Tool ( QANT ): a program for NEXAFS loading and analysis developed at the Australian Synchrotron Gann, Eliot; McNeill, Christopher R.; Tadich, Anton Journal of Synchrotron Radiation, Vol. 23, Issue 1 https://doi.org/10.1107/S1600577515018688	journal	January 2016
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals Chen, Chung Shou; Handoko, Albertus D.; Wan, Jane Hui Catalysis Science & Technology, Vol. 5, Issue 1 https://doi.org/10.1039/C4CY00906A	journal	January 2015
Nickel-Nitrogen-Modified Graphene: An Efficient Electrocatalyst for the Reduction of Carbon Dioxide to Carbon Monoxide Su, Panpan; Iwase, Kazuyuki; Nakanishi, Shuji Small, Vol. 12, Issue 44 https://doi.org/10.1002/smll.201602158	journal	September 2016
3D Interconnected Electrode Materials with Ultrahigh Areal Sulfur Loading for Li-S Batteries Fang, Ruopian; Zhao, Shiyong; Hou, Pengxiang Advanced Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adma.201506014	journal	March 2016
The preparation of chromium, nickel and chromium–nickel alloy nanoparticles on supports Tilley, Richard D.; Jefferson, David A. J. Mater. Chem., Vol. 12, Issue 12 https://doi.org/10.1039/B204774H	journal	January 2002
Electronic structure of Ni(II) porphyrins and phthalocyanine studied by soft X-ray absorption spectroscopy Krasnikov, S. A.; Preobrajenski, A. B.; Sergeeva, N. N. Chemical Physics, Vol. 332, Issue 2-3 https://doi.org/10.1016/j.chemphys.2006.12.015	journal	February 2007
Melem (2,5,8-Triamino-tri- s -triazine), an Important Intermediate during Condensation of Melamine Rings to Graphitic Carbon Nitride: Synthesis, Structure Determination by X-ray Powder Diffractometry, Solid-State NMR, and Theoretical Studies Jürgens, Barbara; Irran, Elisabeth; Senker, Jürgen Journal of the American Chemical Society, Vol. 125, Issue 34 https://doi.org/10.1021/ja0357689	journal	August 2003
A metal-free polymeric photocatalyst for hydrogen production from water under visible light Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne Nature Materials, Vol. 8, Issue 1 https://doi.org/10.1038/nmat2317	journal	November 2008
Melem: an efficient metal-free luminescent material Zheng, H. B.; Chen, W.; Gao, H. J. Mater. Chem. C, Vol. 5, Issue 41 https://doi.org/10.1039/C7TC02966G	journal	January 2017
Photodegradation Performance of g-C ₃ N ₄ Fabricated by Directly Heating Melamine Yan, S. C.; Li, Z. S.; Zou, Z. G. Langmuir, Vol. 25, Issue 17 https://doi.org/10.1021/la900923z	journal	September 2009
Synthesis of bulk and nanoporous carbon nitride polymers from ammonium thiocyanate for photocatalytic hydrogen evolution Cui, Yanjuan; Zhang, Jinshui; Zhang, Guigang Journal of Materials Chemistry, Vol. 21, Issue 34 https://doi.org/10.1039/c1jm11961c	journal	January 2011
Correlation between metal catalyst particle size and carbon nanotube growth Kukovitsky, E. F.; L'vov, S. G.; Sainov, N. A. Chemical Physics Letters, Vol. 355, Issue 5-6 https://doi.org/10.1016/S0009-2614(02)00283-X	journal	April 2002
Chemical Vapor Deposition of Carbon Nanotubes: A Review on Growth Mechanism and Mass Production Kumar, Mukul; Ando, Yoshinori Journal of Nanoscience and Nanotechnology, Vol. 10, Issue 6 https://doi.org/10.1166/jnn.2010.2939	journal	June 2010
Solid state growth mechanisms for carbon nanotubes Harris, Peter J. F. Carbon, Vol. 45, Issue 2 https://doi.org/10.1016/j.carbon.2006.09.023	journal	February 2007
Arc discharge synthesis of carbon nanotubes: Comprehensive review Arora, Neha; Sharma, N. N. Diamond and Related Materials, Vol. 50 https://doi.org/10.1016/j.diamond.2014.10.001	journal	November 2014
High-yield synthesis of millimetre-long, semiconducting carbon nitride nanotubes with intense photoluminescence emission and reproducible photoconductivity Gao, Jun; Zhou, Yong; Li, Zhaosheng Nanoscale, Vol. 4, Issue 12 https://doi.org/10.1039/c2nr30777d	journal	January 2012
Egg albumin as a nanoreactor for growing single-crystalline Fe3O4 nanotubes with high yields Geng, Baoyou; Zhan, Fangming; Jiang, Han Chemical Communications, Issue 44 https://doi.org/10.1039/b813071j	journal	January 2008
Bamboo-like Carbon Nanotube/Fe ₃ C Nanoparticle Hybrids and Their Highly Efficient Catalysis for Oxygen Reduction Yang, Wenxiu; Liu, Xiangjian; Yue, Xiaoyu Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja5129132	journal	January 2015
Synthesis and Characterizations of Amorphous Carbon Nanotubes by Pyrolysis of Ferrocene Confined within AAM Templates Hu, Z. D.; Hu, Y. F.; Chen, Q. The Journal of Physical Chemistry B, Vol. 110, Issue 16 https://doi.org/10.1021/jp0568475	journal	April 2006
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO ₂ Reduction Rosen, Jonathan; Hutchings, Gregory S.; Lu, Qi ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00922	journal	July 2015
Selective Conversion of CO ₂ to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4033549	journal	June 2013
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO Zhu, Wenlei; Michalsky, Ronald; Metin, Önder Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409445p	journal	October 2013
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts Ma, Ming; Trześniewski, Bartek J.; Xie, Jie Angewandte Chemie International Edition, Vol. 55, Issue 33 https://doi.org/10.1002/anie.201604654	journal	July 2016
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction Yang, Hong Bin; Hung, Sung-Fu; Liu, Song Nature Energy, Vol. 3, Issue 2 https://doi.org/10.1038/s41560-017-0078-8	journal	February 2018

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Title: One-Pot Pyrolysis Method to Fabricate Carbon Nanotube Supported Ni Single-Atom Catalysts with Ultrahigh Loading

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