Curie-Weiss behavior of liquid structure and ideal glass state

Ryu, C. W.; Dmowski, W.; Kelton, K. F.; Lee, G. W.; Park, E. S.; Morris, J. R.; Egami, T.

doi:10.1038/s41598-019-54758-y

Title: Curie-Weiss behavior of liquid structure and ideal glass state

Abstract

We present the results of a structural study of metallic alloy liquids from high temperature through the glass transition. We use high energy X-ray scattering and electro-static levitation in combination with molecular dynamics simulation and show that the height of the first peak of the structure function, S(Q) -1, follows the Curie-Weiss law. The structural coherence length is proportional to the height of the first peak, and we suggest that its increase with cooling may be related to the rapid increase in viscosity. The Curie temperature is negative, implying an analogy with spin-glass. The Curie-Weiss behavior provides a pathway to an ideal glass state, a state with long-range correlation without lattice periodicity, which is characterized by highly diverse local structures, reminiscent of spin-glass.

Authors:

Ryu, C. W. ^[1]; Dmowski, W. ^[2]; Kelton, K. F. ^[3]; Lee, G. W. ^[4]; Park, E. S. ^[5];

^[6]; Egami, T. ^[7]

Univ. of Tennessee, Knoxville, TN (United States); Seoul National Univ. (South Korea)
Univ. of Tennessee, Knoxville, TN (United States)
Washington Univ., St. Louis, MO (United States)
Korea Research Inst. of Standards and Science, Daejeon (Korea, Republic of); Univ. of Science and Technology, Daejon (Korea, Republic of)
Seoul National Univ. (South Korea)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ames Lab., Ames, IA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy

Publication Date:: 2019-12-09

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1607208

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Ryu, C. W., Dmowski, W., Kelton, K. F., Lee, G. W., Park, E. S., Morris, J. R., and Egami, T. Curie-Weiss behavior of liquid structure and ideal glass state.  United States: N. p., 2019. 
Web.  doi:10.1038/s41598-019-54758-y.

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                    Ryu, C. W., Dmowski, W., Kelton, K. F., Lee, G. W., Park, E. S., Morris, J. R., & Egami, T. Curie-Weiss behavior of liquid structure and ideal glass state.  United States.  https://doi.org/10.1038/s41598-019-54758-y

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                    Ryu, C. W., Dmowski, W., Kelton, K. F., Lee, G. W., Park, E. S., Morris, J. R., and Egami, T. Mon .  
"Curie-Weiss behavior of liquid structure and ideal glass state".  United States.  https://doi.org/10.1038/s41598-019-54758-y.  https://www.osti.gov/servlets/purl/1607208.

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@article{osti_1607208,

  title        = {Curie-Weiss behavior of liquid structure and ideal glass state},

  author       = {Ryu, C. W. and Dmowski, W. and Kelton, K. F. and Lee, G. W. and Park, E. S. and Morris, J. R. and Egami, T.},

  abstractNote = {We present the results of a structural study of metallic alloy liquids from high temperature through the glass transition. We use high energy X-ray scattering and electro-static levitation in combination with molecular dynamics simulation and show that the height of the first peak of the structure function, S(Q) -1, follows the Curie-Weiss law. The structural coherence length is proportional to the height of the first peak, and we suggest that its increase with cooling may be related to the rapid increase in viscosity. The Curie temperature is negative, implying an analogy with spin-glass. The Curie-Weiss behavior provides a pathway to an ideal glass state, a state with long-range correlation without lattice periodicity, which is characterized by highly diverse local structures, reminiscent of spin-glass.},

  doi          = {10.1038/s41598-019-54758-y},

  journal      = {Scientific Reports},

  number       = 1,

  volume       = 9,

  place        = {United States},

  year         = {2019},

  month        = {12}

}

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Works referencing / citing this record:

Local Density Correlations in Liquids
journal, February 2020

Egami, Takeshi
Frontiers in Physics, Vol. 8
DOI: 10.3389/fphy.2020.00050

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Similar Records

Title: Curie-Weiss behavior of liquid structure and ideal glass state

Abstract

Citation Formats

Metallic Phase with Long-Range Orientational Order and No Translational Symmetry journal, November 1984

A Geometrical Approach to the Structure Of Liquids journal, January 1959

Glass transition in metallic glasses: A microscopic model of topological fluctuations in the bonding network journal, July 2007

Relating Dynamic Properties to Atomic Structure in Metallic Glasses journal, July 2012

Charge-transfer-enhanced prism-type local order in amorphous Mg65Cu25Y10: Short-to-medium-range structural evolution underlying liquid fragility and heat capacity journal, May 2013

Icosahedral Bond Orientational Order in Supercooled Liquids journal, November 1981

A structural signature of liquid fragility journal, August 2014

Elementary Excitations and Crossover Phenomenon in Liquids journal, May 2013

Glass and Jamming Transitions: From Exact Results to Finite-Dimensional Descriptions journal, March 2017

Fragility and thermal stability of Pt- and Pd-based bulk glass forming liquids and their correlation with deformability journal, June 2006

Infinite Number of Order Parameters for Spin-Glasses journal, December 1979

The mysterious glass transition journal, February 2007

Fast Parallel Algorithms for Short-Range Molecular Dynamics journal, March 1995

A highly modular beamline electrostatic levitation facility, optimized for in situ high-energy x-ray scattering studies of equilibrium and supercooled liquids journal, March 2011

Structural defects in amorphous solids Statistical analysis of a computer model journal, October 1981

Atomic level stresses journal, August 2011

Structure identification methods for atomistic simulations of crystalline materials journal, May 2012

Organic Glasses with Exceptional Thermodynamic and Kinetic Stability journal, January 2007

Supercooled liquids and the glass transition journal, March 2001

Should All Crystals Be bcc? Landau Theory of Solidification and Crystal Nucleation journal, September 1978

Critical-like behaviour of glass-forming liquids journal, February 2010

The world's biggest glassy alloy ever made journal, November 2012

Kinetics of Solidification of Supercooled Liquid Mercury Droplets journal, March 1952

Experimental and molecular dynamics simulation study of structure of liquid and amorphous Ni62Nb38 alloy journal, November 2016

The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures. journal, October 1948

Ultrastable glasses from in silico vapour deposition journal, January 2013

Order, frustration, and defects in liquids and glasses journal, November 1983

Anisotropy of the solid–liquid interface properties of the Ni–Zr B33 phase from molecular dynamics simulation journal, December 2014

Atomic Level Structure in Multicomponent Bulk Metallic Glass journal, June 2009

Density fluctuations and the pair distribution function journal, July 2005

Geometric Frustration of Icosahedron in Metallic Glasses journal, July 2013

Through the Glass Lightly journal, March 1995

Probing the structure of a liquid metal during vitrification journal, April 2015

Proposal for universality in the viscosity of metallic liquids journal, September 2015

Nearly-Free-Electron Approach to the Theory of Metallic Glass Alloys journal, August 1975

Molecular-dynamics study of orientational order in liquids and glasses and its relation to the glass transition journal, August 1995

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment journal, December 2005

Atomic-level structure and structure–property relationship in metallic glasses journal, May 2011

Formation of Glasses from Liquids and Biopolymers journal, March 1995

Anisotropy of stress correlation in two-dimensional liquids and a pseudospin model journal, November 2015

Fitting of viscosity: Distinguishing the temperature dependences predicted by various models of supercooled liquids journal, January 1996

Through the Glass Lightly journal, March 1995

Through the Glass Lightly journal, March 1995

Through the Glass Lightly journal, March 1995

Through the Glass Lightly journal, March 1995

Through the Glass Lightly journal, March 1995

Structure identification methods for atomistic simulations of crystalline materials text, January 2012

Glass and Jamming Transitions: From Exact Results to Finite-Dimensional Descriptions text, January 2016

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment text, January 2005

Local Density Correlations in Liquids journal, February 2020

Metallic Phase with Long-Range Orientational Order and No Translational Symmetry
journal, November 1984

A Geometrical Approach to the Structure Of Liquids
journal, January 1959

Glass transition in metallic glasses: A microscopic model of topological fluctuations in the bonding network
journal, July 2007

Relating Dynamic Properties to Atomic Structure in Metallic Glasses
journal, July 2012

Charge-transfer-enhanced prism-type local order in amorphous Mg65Cu25Y10: Short-to-medium-range structural evolution underlying liquid fragility and heat capacity
journal, May 2013

Icosahedral Bond Orientational Order in Supercooled Liquids
journal, November 1981

A structural signature of liquid fragility
journal, August 2014

Elementary Excitations and Crossover Phenomenon in Liquids
journal, May 2013

Glass and Jamming Transitions: From Exact Results to Finite-Dimensional Descriptions
journal, March 2017

Fragility and thermal stability of Pt- and Pd-based bulk glass forming liquids and their correlation with deformability
journal, June 2006

Infinite Number of Order Parameters for Spin-Glasses
journal, December 1979

The mysterious glass transition
journal, February 2007

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995

A highly modular beamline electrostatic levitation facility, optimized for in situ high-energy x-ray scattering studies of equilibrium and supercooled liquids
journal, March 2011

Structural defects in amorphous solids Statistical analysis of a computer model
journal, October 1981

Atomic level stresses
journal, August 2011

Structure identification methods for atomistic simulations of crystalline materials
journal, May 2012

Organic Glasses with Exceptional Thermodynamic and Kinetic Stability
journal, January 2007

Supercooled liquids and the glass transition
journal, March 2001

Should All Crystals Be bcc? Landau Theory of Solidification and Crystal Nucleation
journal, September 1978

Critical-like behaviour of glass-forming liquids
journal, February 2010

The world's biggest glassy alloy ever made
journal, November 2012

Kinetics of Solidification of Supercooled Liquid Mercury Droplets
journal, March 1952

Experimental and molecular dynamics simulation study of structure of liquid and amorphous Ni62Nb38 alloy
journal, November 2016

The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures.
journal, October 1948

Ultrastable glasses from in silico vapour deposition
journal, January 2013

Order, frustration, and defects in liquids and glasses
journal, November 1983

Anisotropy of the solid–liquid interface properties of the Ni–Zr B33 phase from molecular dynamics simulation
journal, December 2014

Atomic Level Structure in Multicomponent Bulk Metallic Glass
journal, June 2009

Density fluctuations and the pair distribution function
journal, July 2005

Geometric Frustration of Icosahedron in Metallic Glasses
journal, July 2013

Through the Glass Lightly
journal, March 1995

Probing the structure of a liquid metal during vitrification
journal, April 2015

Proposal for universality in the viscosity of metallic liquids
journal, September 2015

Nearly-Free-Electron Approach to the Theory of Metallic Glass Alloys
journal, August 1975

Molecular-dynamics study of orientational order in liquids and glasses and its relation to the glass transition
journal, August 1995

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
journal, December 2005

Atomic-level structure and structure–property relationship in metallic glasses
journal, May 2011

Formation of Glasses from Liquids and Biopolymers
journal, March 1995

Anisotropy of stress correlation in two-dimensional liquids and a pseudospin model
journal, November 2015

Fitting of viscosity: Distinguishing the temperature dependences predicted by various models of supercooled liquids
journal, January 1996

Through the Glass Lightly
journal, March 1995

Through the Glass Lightly
journal, March 1995

Through the Glass Lightly
journal, March 1995

Through the Glass Lightly
journal, March 1995

Through the Glass Lightly
journal, March 1995

Structure identification methods for atomistic simulations of crystalline materials
text, January 2012

Glass and Jamming Transitions: From Exact Results to Finite-Dimensional Descriptions
text, January 2016

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
text, January 2005

Local Density Correlations in Liquids
journal, February 2020