Magnetic ground state and magnetic excitations in black dioptase Cu6Si6O18

Podlesnyak, Andrey A.; Prokhnenko, Oleksandr; Nikitin, Stanislav E.; Kolesnikov, Alexander I.; Matsuda, Masaaki; Dissanayake, Sachith E.; Prisk, T. R.; Nojiri, H.; Díaz-Ortega, I. F.; Kidder, Michelle K.; Anovitz, Lawrence M.

doi:10.1103/PhysRevB.100.184401

Title: Magnetic ground state and magnetic excitations in black dioptase ${Cu}_{6} {Si}_{6} O_{18}$

Journal Article · 01 November 2019 · Physical Review B

DOI: https://doi.org/10.1103/PhysRevB.100.184401 · OSTI ID:1607105

^[1]; Prokhnenko, Oleksandr ^[2]; Nikitin, Stanislav E. ^[3];

^[1];

^[1]; Prisk, T. R. ^[4]; Nojiri, H. ^[5]; Díaz-Ortega, I. F. ^[5];

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Helmholtz-Zentrum Berlin für Materialien und Energie, Berlin (Germany)
Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Technische Univ. Dresden (Germany)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Tohoku Univ., Sendai (Japan)

The low-temperature magnetic properties and magnetic structure of fully dehydrated black dioptase ${Cu}_{6} {Si}_{6} O_{18}$ have been studied by single-crystal neutron diffraction and magnetization measurements in magnetic fields up to 30 T. Here, the intrachain $J_{c}$ and interchain $J_{a b}$ interactions as well as the anisotropy of the exchange coupling $J_{c}$ have been determined using inelastic neutron-scattering techniques. Zero-field antiferromagnetic order at $T_{N} = 6.7$ K can be described by a commensurate propagation vector of $k = (0, 0, 3 / 2)$ with respect to the hexagonal $R \bar{3}$ :H unit cell. The Cu magnetic moments are aligned antiferromagnetically along the $c$ axis with about $12^{°}$ tilt and are coupled ferromagnetically between the chains. The high-field magnetization measurements provide strong evidence for the presence of a spin-flop phase above 8 T. We found that $J_{c}$ in black dioptase is significantly increased, while $J_{a b}$ is much weaker compared to its counterpart, green dioptase ${Cu}_{6} [{Si}_{6} O_{18}] 6 H_{2} O$ . We suggest that black dioptase behaves like a nearly ideal $S = 1 / 2$ antiferromagnetic Heisenberg spiral chain with enhanced quantum fluctuations and weak spinon confinement $J_{a b} / J_{c} ~ 0.02$ .

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1607105

Journal Information:: Physical Review B, Vol. 100, Issue 18; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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References (60)

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Title: Magnetic ground state and magnetic excitations in black dioptase Cu 6 Si 6 O 18

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Title: Magnetic ground state and magnetic excitations in black dioptase ${Cu}_{6} {Si}_{6} O_{18}$