Ferroic twin domains in metal halide perovskites

Liu, Yongtao; Belianinov, Alex; Collins, Liam; Proksch, Roger; Ievlev, Anton; Hu, Bin; Kalinin, Sergei V.; Ovchinnikova, Olga S.

doi:10.1557/adv.2019.358

Title: Ferroic twin domains in metal halide perovskites

Journal Article · 23 September 2019 · MRS Advances

DOI: https://doi.org/10.1557/adv.2019.358 · OSTI ID:1606920

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Asylum Research, Santa Barbara, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States)

An emerging family of materials—metal halide perovskites (MHPs)—have made incredible achievements in optoelectronics in the past decade. Owing to its potential role in optoelectronic properties, the ferroic state of MHPs has been investigated by lots of researchers. Here in this paper, we review the literature regarding investigations into possible ferroic behaviors in MHPs. We summarize the recent discoveries of ferroic twin domains in MHPs. We examine the ferroelasticity and the ferroelectricity of these twin domains. Several properties relevant to the twin domains are critically analyzed, including crystallographic structure, mechanical variation, chemical variation, etc. Finally, we discussed the effects of these domains on materials’ optoelectronic properties and their potential roles in photovoltaic action.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1606920

Journal Information:: MRS Advances, Vol. 4, Issue 51-52; ISSN 2059-8521

Publisher:: Materials Research Society (MRS)Copyright Statement

Country of Publication:: United States

Language:: English

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