An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments

Stone-Weiss, Nicholas; Youngman, Randall E.; Thorpe, Ryan; Smith, Nicholas J.; Pierce, Eric M.; Goel, Ashutosh

doi:10.1039/c9cp06064b

Title: An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments

Abstract

Sodium aluminoborosilicate glasses with wide-ranging compositions and structures corrode according to remarkably similar mechanisms in acidic environments.

Authors:

^[1];

^[2]; Thorpe, Ryan ^[1];

^[2];

^[3];

^[1]

Rutgers Univ., Piscataway, NJ (United States)
Corning Incorporated, Corning, NY (United States). Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2019-12-18

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); USDOE Office of River Protection (ORP), Richland, WA (United States); Rutgers Univ., New Brunswick, NJ (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE); USDOE Office of Environmental Management (EM); National Science Foundation (NSF)

OSTI Identifier:: 1606802

Alternate Identifier(s):: OSTI ID: 1581658; OSTI ID: 1749862

Grant/Contract Number:: AC05-00OR22725; 1507131; NE0008597; EM0003207

Resource Type:: Accepted Manuscript

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Volume: 22; Journal Issue: 4; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; corrosion; structure; composition

Citation Formats


                    Stone-Weiss, Nicholas, Youngman, Randall E., Thorpe, Ryan, Smith, Nicholas J., Pierce, Eric M., and Goel, Ashutosh. An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments.  United States: N. p., 2019. 
Web.  doi:10.1039/c9cp06064b.

Copy to clipboard


                    Stone-Weiss, Nicholas, Youngman, Randall E., Thorpe, Ryan, Smith, Nicholas J., Pierce, Eric M., & Goel, Ashutosh. An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments.  United States.  https://doi.org/10.1039/c9cp06064b

Copy to clipboard


                    Stone-Weiss, Nicholas, Youngman, Randall E., Thorpe, Ryan, Smith, Nicholas J., Pierce, Eric M., and Goel, Ashutosh. Wed .  
"An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments".  United States.  https://doi.org/10.1039/c9cp06064b.  https://www.osti.gov/servlets/purl/1606802.

Copy to clipboard


                    
@article{osti_1606802,

  title        = {An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments},

  author       = {Stone-Weiss, Nicholas and Youngman, Randall E. and Thorpe, Ryan and Smith, Nicholas J. and Pierce, Eric M. and Goel, Ashutosh},

  abstractNote = {Sodium aluminoborosilicate glasses with wide-ranging compositions and structures corrode according to remarkably similar mechanisms in acidic environments.},

  doi          = {10.1039/c9cp06064b},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 4,

  volume       = 22,

  place        = {United States},

  year         = {2019},

  month        = {12}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1039/c9cp06064b

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

The controversial role of inter-diffusion in glass alteration
journal, November 2016

Gin, S.; Neill, L.; Fournier, M.
Chemical Geology, Vol. 440
DOI: 10.1016/j.chemgeo.2016.07.014

Non-stoichiometric non-bridging oxygens and five-coordinated aluminum in alkaline earth aluminosilicate glasses: Effect of modifier cation size
journal, August 2012

Thompson, Linda M.; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 358, Issue 15
DOI: 10.1016/j.jnoncrysol.2012.05.022

Aluminum speciation and equilibria in aqueous solution: V. Gibbsite solubility at 50°C and pH 3–9 in 0.1 molal NaCl solutions (a general model for aluminum speciation; analytical methods)
journal, July 1994

Wesolowski, David J.; Palmer, Donald A.
Geochimica et Cosmochimica Acta, Vol. 58, Issue 14
DOI: 10.1016/0016-7037(94)90171-6

Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses
journal, November 2013

Vienna, John D.; Ryan, Joseph V.; Gin, Stéphane
International Journal of Applied Glass Science, Vol. 4, Issue 4
DOI: 10.1111/ijag.12050

Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra
journal, December 2001

Massiot, Dominique; Fayon, Franck; Capron, Mickael
Magnetic Resonance in Chemistry, Vol. 40, Issue 1
DOI: 10.1002/mrc.984

Experimental determination of rhyolitic glass dissolution rates at 40–200°C and 2
journal, January 2013

Declercq, Julien; Diedrich, Tamara; Perrot, Melissa
Geochimica et Cosmochimica Acta, Vol. 100
DOI: 10.1016/j.gca.2012.10.006

The influence of H2O and SiO2 on the structure of silicoborate glasses
journal, September 2019

Balzer, Robert; Behrens, Harald; Schuth, Stephan
Journal of Non-Crystalline Solids, Vol. 519
DOI: 10.1016/j.jnoncrysol.2019.05.030

Topological Disorder and Reactivity of Borosilicate Glasses: Quantum Chemical Calculations and ¹⁷ O and ¹¹ B NMR Study
journal, December 2001

Lee, Sung Keun; Musgrave, Charles B.; Zhao, Peidong
The Journal of Physical Chemistry B, Vol. 105, Issue 50
DOI: 10.1021/jp012119f

Tutorial review. Calculating standard deviations and confidence intervals with a universally applicable spreadsheet technique
journal, January 1994

Kragten, J.
The Analyst, Vol. 119, Issue 10
DOI: 10.1039/an9941902161

Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy
journal, May 2006

Neuville, Daniel R.; Cormier, Laurent; Massiot, Dominique
Chemical Geology, Vol. 229, Issue 1-3
DOI: 10.1016/j.chemgeo.2006.01.019

XPS analysis of oxides
journal, July 1988

Paparazzo, E.
Surface and Interface Analysis, Vol. 12, Issue 2
DOI: 10.1002/sia.740120210

Concept and development of an autonomous wearable micro-fluidic platform for real time pH sweat analysis
journal, December 2012

Curto, Vincenzo F.; Coyle, S.; Byrne, R.
Sensors and Actuators B: Chemical, Vol. 175
DOI: 10.1016/j.snb.2012.02.010

Interdiffusion of hydrogen and alkali ions in a glass surface
journal, December 1975

Doremus, R. H.
Journal of Non-Crystalline Solids, Vol. 19
DOI: 10.1016/0022-3093(75)90079-4

An international initiative on long-term behavior of high-level nuclear waste glass
journal, June 2013

Gin, S.; Abdelouas, A.; Criscenti, L. J.
Materials Today, Vol. 16, Issue 6
DOI: 10.1016/j.mattod.2013.06.008

Effects of glass structure on the corrosion behavior of sodium-aluminosilicate glasses
journal, December 1997

Hamilton, J.
Journal of Non-Crystalline Solids, Vol. 222, Issue 1-2
DOI: 10.1016/S0022-3093(97)00395-5

Irreversibility of Pressure Induced Boron Speciation Change in Glass
journal, January 2014

Smedskjaer, Morten M.; Youngman, Randall E.; Striepe, Simon
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep03770

The kinetics of corrosion of e-glass fibres in sulphuric acid
journal, October 2010

Jones, R. L.; Stewart, J.
Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49
DOI: 10.1016/j.jnoncrysol.2010.07.062

Dissolution rate of a basalt glass in silica-rich solutions: Implications for long-term alteration
journal, November 1994

Berger, Gilles; Claparols, Catherine; Guy, Christophe
Geochimica et Cosmochimica Acta, Vol. 58, Issue 22
DOI: 10.1016/0016-7037(94)90218-6

Glass dissolution rate measurement and calculation revisited
journal, August 2016

Fournier, Maxime; Ull, Aurélien; Nicoleau, Elodie
Journal of Nuclear Materials, Vol. 476
DOI: 10.1016/j.jnucmat.2016.04.028

Mechanism, rates, and consequences of basaltic glass dissolution: II. An experimental study of the dissolution rates of basaltic glass as a function of pH and temperature
journal, October 2003

Gislason, Sigurdur R.; Oelkers, Eric H.
Geochimica et Cosmochimica Acta, Vol. 67, Issue 20
DOI: 10.1016/S0016-7037(03)00176-5

Structural and Chemical Approach toward Understanding the Aqueous Corrosion of Sodium Aluminoborate Glasses
journal, November 2018

Kapoor, Saurabh; Youngman, Randall E.; Zakharchuk, Kiryl
The Journal of Physical Chemistry B, Vol. 122, Issue 48
DOI: 10.1021/acs.jpcb.8b06155

Elemental areal density calculation and oxygen speciation for flat glass surfaces using x-ray photoelectron spectroscopy
journal, October 2016

Banerjee, Joy; Kim, Seong H.; Pantano, Carlo G.
Journal of Non-Crystalline Solids, Vol. 450
DOI: 10.1016/j.jnoncrysol.2016.07.029

Towards a unifying mechanistic model for silicate glass corrosion
journal, September 2018

Lenting, Christoph; Plümper, Oliver; Kilburn, Matt
npj Materials Degradation, Vol. 2, Issue 1
DOI: 10.1038/s41529-018-0048-z

The pH of beverages in the United States
journal, April 2016

Reddy, Avanija; Norris, Don F.; Momeni, Stephanie S.
The Journal of the American Dental Association, Vol. 147, Issue 4
DOI: 10.1016/j.adaj.2015.10.019

Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis
journal, December 1995

Oelkers, Eric H.; Schott, Jacques
Geochimica et Cosmochimica Acta, Vol. 59, Issue 24
DOI: 10.1016/0016-7037(95)00326-6

Fivefold-coordinated aluminum in tectosilicate glasses observed by triple quantum MAS NMR
journal, October 2000

Toplis, Michael J.; Kohn, Simon C.; Smith, Mark E.
American Mineralogist, Vol. 85, Issue 10
DOI: 10.2138/am-2000-1031

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009

Wu, Jingshi; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 355, Issue 9
DOI: 10.1016/j.jnoncrysol.2009.01.025

Short-Range Order and Site Connectivities in Sodium Aluminoborate Glasses: I. Quantification of Local Environments by High-Resolution 11 B, 23 Na, and 27 Al Solid-State NMR
journal, June 1998

Züchner, Lars; Chan, Jerry C. C.; Müller-Warmuth, Werner
The Journal of Physical Chemistry B, Vol. 102, Issue 23
DOI: 10.1021/jp980587s

Structure of boroaluminosilicate glasses: Impact of [Al $_{2}$ O $_{3}$ ]/[SiO $_{2}$ ] ratio on the structural role of sodium
journal, August 2012

Zheng, Q. J.; Youngman, R. E.; Hogue, C. L.
Physical Review B, Vol. 86, Issue 5
DOI: 10.1103/PhysRevB.86.054203

Irreversibility of pressure induced boron speciation change in glass
other, January 2014

Smedskjaer, Marten M.; Youngman, Randalf E.; Striepe, Simon
London : Nature Publishing Group
DOI: 10.15488/610

Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals
journal, July 2016

Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep30256

Corrosive attack of glass by a pharmaceutical compound
journal, February 2007

Iacocca, Ronald G.; Allgeier, Matthew
Journal of Materials Science, Vol. 42, Issue 3
DOI: 10.1007/s10853-006-0156-y

Characterisation of Al coordination at the outer surface of dealuminated mordenites by X-ray photoelectron spectroscopy
journal, December 1993

Remy, M. J.; Genet, M. J.; Notté, P. P.
Microporous Materials, Vol. 2, Issue 1
DOI: 10.1016/0927-6513(93)80057-2

A review of the biological response to ionic dissolution products from bioactive glasses and glass-ceramics
journal, April 2011

Hoppe, Alexander; Güldal, Nusret S.; Boccaccini, Aldo R.
Biomaterials, Vol. 32, Issue 11
DOI: 10.1016/j.biomaterials.2011.01.004

Structure of Sodium Aluminosilicate Glasses : X-Ray Photoelectron Spectroscopy
journal, December 1985

Tasker, G. W.; Uhlmann, D. R.; Onorato, P. I. K.
Le Journal de Physique Colloques, Vol. 46, Issue C8
DOI: 10.1051/jphyscol:1985840

The mechanism of borosilicate glass corrosion revisited
journal, June 2015

Geisler, Thorsten; Nagel, Thorsten; Kilburn, Matt R.
Geochimica et Cosmochimica Acta, Vol. 158
DOI: 10.1016/j.gca.2015.02.039

Theoretical and 27Al CPMAS NMR investigation of aluminum coordination changes during aluminosilicate dissolution
journal, May 2005

Criscenti, Louise J.; Brantley, Susan L.; Mueller, Karl T.
Geochimica et Cosmochimica Acta, Vol. 69, Issue 9
DOI: 10.1016/j.gca.2004.10.020

The dissolution rates of natural glasses as a function of their composition at pH 4 and 10.6, and temperatures from 25 to 74°C
journal, December 2004

Wolff-Boenisch, Domenik; Gislason, Sigurdur R.; Oelkers, Eric H.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 23
DOI: 10.1016/j.gca.2004.05.027

The effect of fluoride on the dissolution rates of natural glasses at pH 4 and 25°C
journal, November 2004

Wolff-Boenisch, Domenik; Gislason, Sigurdur R.; Oelkers, Eric H.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 22
DOI: 10.1016/j.gca.2004.05.026

Leached Layer Formation on Float Glass Surfaces in the Presence of Acid Interleave Coatings
journal, March 2008

Smith, Nicholas J.; Pantano, Carlo G.
Journal of the American Ceramic Society, Vol. 91, Issue 3
DOI: 10.1111/j.1551-2916.2007.02079.x

High-Resolution Multinuclear NMR Structural Study of Binary Aluminosilicate and Other Related Glasses
journal, June 2004

Sen, S.; Youngman, R. E.
The Journal of Physical Chemistry B, Vol. 108, Issue 23
DOI: 10.1021/jp031348u

Dissolution of nepheline, jadeite and albite glasses: toward better models for aluminosilicate dissolution
journal, November 2001

Hamilton, James P.; Brantley, Susan L.; Pantano, Carlo G.
Geochimica et Cosmochimica Acta, Vol. 65, Issue 21
DOI: 10.1016/S0016-7037(01)00724-4

The mechanism, rates and consequences of basaltic glass dissolution: I. An experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si and oxalic acid concentration at 25°C and pH = 3 and 11
journal, November 2001

Oelkers, Eric H.; Gislason, Sigurdur R.
Geochimica et Cosmochimica Acta, Vol. 65, Issue 21
DOI: 10.1016/S0016-7037(01)00664-0

Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism
journal, June 2010

Geisler, Thorsten; Janssen, Arne; Scheiter, Daniel
Journal of Non-Crystalline Solids, Vol. 356, Issue 28-30
DOI: 10.1016/j.jnoncrysol.2010.04.033

Network connectivity in aluminoborosilicate glasses: A high-resolution 11B, 27Al and 17O NMR study
journal, November 2005

Du, Lin-Shu; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 351, Issue 43-45
DOI: 10.1016/j.jnoncrysol.2005.08.033

Molecular mechanisms for corrosion of silica and silicate glasses
journal, November 1994

Bunker, B. C.
Journal of Non-Crystalline Solids, Vol. 179
DOI: 10.1016/0022-3093(94)90708-0

Separating the effects of composition and fictive temperature on Al and B coordination in Ca, La, Y aluminosilicate, aluminoborosilicate and aluminoborate glasses
journal, January 2016

Morin, Elizabeth I.; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 432
DOI: 10.1016/j.jnoncrysol.2015.10.035

NMR evidence for formation of octahedral and tetrahedral Al and repolymerization of the Si network during dissolution of aluminosilicate glass and crystal
journal, January 2003

Tsomaia, Natia; Brantley, Susan L.; Hamilton, James P.
American Mineralogist, Vol. 88, Issue 1
DOI: 10.2138/am-2003-0107

Evaluation of a simple correction for the hydrocarbon contamination layer in quantitative surface analysis by XPS
journal, July 2005

Smith, Graham C.
Journal of Electron Spectroscopy and Related Phenomena, Vol. 148, Issue 1
DOI: 10.1016/j.elspec.2005.02.004

Sodium diffusion in boroaluminosilicate glasses
journal, November 2011

Smedskjaer, Morten M.; Zheng, Qiuju; Mauro, John C.
Journal of Non-Crystalline Solids, Vol. 357, Issue 22-23
DOI: 10.1016/j.jnoncrysol.2011.07.008

The degree of aluminum avoidance in aluminosilicate glasses
journal, June 1999

Lee, Sung Keun; Stebbins, Jonathan F.
American Mineralogist, Vol. 84, Issue 5-6
DOI: 10.2138/am-1999-5-630

Impact of iron on nuclear glass alteration in geological repository conditions: A multiscale approach
journal, April 2013

Burger, E.; Rebiscoul, D.; Bruguier, F.
Applied Geochemistry, Vol. 31
DOI: 10.1016/j.apgeochem.2012.12.016

Toward an understanding of surface layer formation, growth, and transformation at the glass–fluid interface
journal, May 2018

Hopf, J.; Eskelsen, J. R.; Chiu, M.
Geochimica et Cosmochimica Acta, Vol. 229
DOI: 10.1016/j.gca.2018.01.035

Chemical durability of glasses; a thermodynamic approach
journal, November 1977

Paul, A.
Journal of Materials Science, Vol. 12, Issue 11
DOI: 10.1007/BF00552247

The effect of molecular structure on borosilicate glass leaching
journal, October 1986

Bunker, B. C.; Arnold, G. W.; Day, D. E.
Journal of Non-Crystalline Solids, Vol. 87, Issue 1-2
DOI: 10.1016/S0022-3093(86)80080-1

Topological Principles of Borosilicate Glass Chemistry
journal, November 2011

Smedskjaer, Morten M.; Mauro, John C.; Youngman, Randall E.
The Journal of Physical Chemistry B, Vol. 115, Issue 44
DOI: 10.1021/jp208796b

Short and Medium Range Order in Sodium Aluminoborate Glasses. 2. Site Connectivities and Cation Distributions Studied by Rotational Echo Double Resonance NMR Spectroscopy
journal, July 2000

Bertmer, Marko; Züchner, Lars; Chan, Jerry C. C.
The Journal of Physical Chemistry B, Vol. 104, Issue 28
DOI: 10.1021/jp9941918

Density-driven structural transformations in $B_{2} O_{3}$ glass
journal, July 2014

Zeidler, Anita; Wezka, Kamil; Whittaker, Dean A. J.
Physical Review B, Vol. 90, Issue 2
DOI: 10.1103/PhysRevB.90.024206

Modifier cation (Ba, Ca, La, Y) field strength effects on aluminum and boron coordination in aluminoborosilicate glasses: the roles of fictive temperature and boron content
journal, April 2014

Morin, Elizabeth I.; Wu, Jingshi; Stebbins, Jonathan F.
Applied Physics A, Vol. 116, Issue 2
DOI: 10.1007/s00339-014-8369-4

Corrosion of E-glass fibers in acidic environments
journal, January 1997

Qiu, Q.; Kumosa, M.
Composites Science and Technology, Vol. 57, Issue 5
DOI: 10.1016/S0266-3538(96)00158-3

Understanding the structural drivers governing glass–water interactions in borosilicate based model bioactive glasses
journal, January 2018

Stone-Weiss, Nicholas; Pierce, Eric M.; Youngman, Randall E.
Acta Biomaterialia, Vol. 65
DOI: 10.1016/j.actbio.2017.11.006

Structural origin of high crack resistance in sodium aluminoborate glasses
journal, March 2017

Januchta, Kacper; Youngman, Randall E.; Goel, Ashutosh
Journal of Non-Crystalline Solids, Vol. 460
DOI: 10.1016/j.jnoncrysol.2017.01.019

New Insight into the Residual Rate of Borosilicate Glasses: Effect of S/V and Glass Composition
journal, October 2013

Gin, Stéphane; Frugier, Pierre; Jollivet, Patrick
International Journal of Applied Glass Science, Vol. 4, Issue 4
DOI: 10.1111/ijag.12048

Site connectivities in sodium aluminoborate glasses: multinuclear and multiple quantum NMR results
journal, January 2005

Du, Lin-Shu; Stebbins, Jonathan F.
Solid State Nuclear Magnetic Resonance, Vol. 27, Issue 1-2
DOI: 10.1016/j.ssnmr.2004.08.003

Dissolution of albite glass and crystal
journal, August 2000

Hamilton, James P.; Pantano, Carlo G.; Brantley, Susan L.
Geochimica et Cosmochimica Acta, Vol. 64, Issue 15
DOI: 10.1016/S0016-7037(00)00388-4

A Comparison of Glass Reaction at High and Low Glass Surface/Solution Volume
journal, December 1993

Ebert, William L.; Bates, John K.
Nuclear Technology, Vol. 104, Issue 3
DOI: 10.13182/NT93-A34898

Composition-structure-property relationships in Li2O–Al2O3–B2O3 glasses
journal, December 2018

Fernandes, Hugo R.; Kapoor, Saurabh; Patel, Yoami
Journal of Non-Crystalline Solids, Vol. 502
DOI: 10.1016/j.jnoncrysol.2018.08.005

Comparative Study of XPS and DFT with Reference to the Distributions of Al in Tetrahedral and Octahedral Sheets of Phyllosilicates
journal, February 1997

Ebina, Takeo; Iwasaki, Takashi; Chatterjee, Abhijit
The Journal of Physical Chemistry B, Vol. 101, Issue 7
DOI: 10.1021/jp9622647

XPS study of the major minerals in bauxite: Gibbsite, bayerite and (pseudo-)boehmite
journal, April 2006

Kloprogge, J. Theo; Duong, Loc V.; Wood, Barry J.
Journal of Colloid and Interface Science, Vol. 296, Issue 2
DOI: 10.1016/j.jcis.2005.09.054

Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join
journal, May 2010

Pierce, E. M.; Reed, L. R.; Shaw, W. J.
Geochimica et Cosmochimica Acta, Vol. 74, Issue 9
DOI: 10.1016/j.gca.2009.09.006

The Structure of Aluminosilicate Glasses: High-Resolution ¹⁷ O and ²⁷ Al MAS and 3QMAS NMR Study
journal, May 2000

Lee, Sung Keun; Stebbins, Jonathan F.
The Journal of Physical Chemistry B, Vol. 104, Issue 17
DOI: 10.1021/jp994273w

Similar Records in DOE PAGES and OSTI.GOV collections:

Monte Carlo Simulations of the Corrosion of Aluminoborosilicate Glasses

Journal Article Kerisit, Sebastien ; Ryan, Joseph V ; Pierce, Eric M - Journal of Non-Crystalline Solids

Aluminum is one of the most common components included in nuclear waste glasses. Therefore, Monte Carlo (MC) simulations were carried out to investigate the influence of aluminum on the rate and mechanism of dissolution of sodium borosilicate glasses in static conditions. The glasses studied were in the compositional range (70 2x)% SiO2x% Al2O3 15% B2O3 (15 + x)% Na2O, where 0 x 15%. The simulation results show that increasing amounts of aluminum in the pristine glasses slow down the initial rate of dissolution as determined from the rate of boron release. However, the extent of corrosion as measured by themore »« less
https://doi.org/10.1016/j.jnoncrysol.2013.07.014
Extended electron energy loss fine structure simulation of the local boron environment in sodium aluminoborosilicate glasses containing gadolinium

Journal Article Qian, Morris ; Li, Hong ; Li, Liyu ; ... - Journal of Non-crystalline Solids

Phase separation in sodium-aluminoborosilicate glasses was systematically studied as a function of Gd2O3 concentration with transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDS), and electron energy loss spectroscopy (EELS) methods. Gadolinium-induced phase separation in the three systems can be consistently explained by proposing that Gd cations partition to the borate-rich environments and subsequent agglomeration of the Gd-borate moieties, or short-range ordered structural groups, in the glass. Agglomeration of the Gd-borate rich environments is further discussed within the context of excess metal oxides,[Na2O]ex or[Al2O3]ex=|Na2O - Al2O3|, and excess B2O3,[B2O3]ex, available for incorporating Gd cations. Results showed that agglomeration of themore »« less
https://doi.org/10.1016/S0022-3093(03)00477-0
Monte Carlo Simulations of the Corrosion of Aluminoborosilicate Glasses

Journal Article Kerisit, Sebastien N. ; Ryan, Joseph V. ; Pierce, Eric M. - Journal of Non-crystalline Solids, 378:273-281

Aluminum is one of the most common components included in nuclear waste glasses. Therefore, Monte Carlo (MC) simulations were carried out to investigate the influence of aluminum on the rate and mechanism of dissolution of sodium borosilicate glasses in static conditions. The glasses studied were in the compositional range (70-2x)% SiO2 x% Al2O3 15% B2O3 (15+x)% Na2O, where 0 ≤ x ≤ 15%. The simulation results show that increasing amounts of aluminum in the pristine glasses slow down the initial rate of dissolution as determined from the rate of boron release. However, the extent of corrosion - as measured bymore »« less
https://doi.org/10.1016/j.jnoncrysol.2013.07.014
Compositional Dependence of Solubility/Retention of Molybdenum Oxides in Aluminoborosilicate-Based Model Nuclear Waste Glasses

Journal Article Brehault, Antoine ; Patil, Deepak ; Kamat, Hrishikesh ; ... - Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

We present that molybdenum oxides are an integral component of the high-level waste streams being generated from the nuclear reactors in several countries. Although borosilicate glass has been chosen as the baseline waste form by most of the countries to immobilize these waste streams, molybdate oxyanions (MoO₄^2-) exhibit very low solubility (~1 mol %) in these glass matrices. In the past three to four decades, several studies describing the compositional and structural dependence of molybdate anions in borosilicate and aluminoborosilicate glasses have been reported in the literature, providing a basis for our understanding of fundamental science that governs the solubilitymore »« less
Cited by 5
https://doi.org/10.1021/acs.jpcb.7b09158

Full Text Available
Dissolution kinetics of a sodium borosilicate glass in Tris buffer solutions: impact of Tris concentration and acid (HCl/HNO₃) identity

Journal Article Stone-Weiss, Nicholas ; Smith, Nicholas J. ; Youngman, Randall E. ; ... - Physical Chemistry Chemical Physics. PCCP

Here, understanding the corrosion behavior of glasses in near-neutral environments is crucial for many technologies including glasses for regenerative medicine and nuclear waste immobilization. To maintain consistent pH values throughout experiments in the pH = 7 to 9 regime, buffer solutions containing tris(hydroxymethyl)aminomethane (“Tris”, or sometimes called THAM) are recommended in ISO standards 10993-14 and 23317 for evaluating biomaterial degradation and utilized throughout glass dissolution behavior literature—a key advantage being the absence of dissolved alkali/alkaline earth cations (i.e. Na⁺ or Ca²⁺) that can convolute experimental results due to solution feedback effects. Although Tris is effective at maintaining the solution pH,more »« less
https://doi.org/10.1039/d0cp06425d

Full Text Available

Similar Records

Title: An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments

Abstract

Citation Formats

The controversial role of inter-diffusion in glass alteration journal, November 2016

Non-stoichiometric non-bridging oxygens and five-coordinated aluminum in alkaline earth aluminosilicate glasses: Effect of modifier cation size journal, August 2012

Aluminum speciation and equilibria in aqueous solution: V. Gibbsite solubility at 50°C and pH 3–9 in 0.1 molal NaCl solutions (a general model for aluminum speciation; analytical methods) journal, July 1994

Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses journal, November 2013

Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra journal, December 2001

Experimental determination of rhyolitic glass dissolution rates at 40–200°C and 2 journal, January 2013

The influence of H2O and SiO2 on the structure of silicoborate glasses journal, September 2019

Topological Disorder and Reactivity of Borosilicate Glasses: Quantum Chemical Calculations and 17 O and 11 B NMR Study journal, December 2001

Tutorial review. Calculating standard deviations and confidence intervals with a universally applicable spreadsheet technique journal, January 1994

Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy journal, May 2006

XPS analysis of oxides journal, July 1988

Concept and development of an autonomous wearable micro-fluidic platform for real time pH sweat analysis journal, December 2012

Interdiffusion of hydrogen and alkali ions in a glass surface journal, December 1975

An international initiative on long-term behavior of high-level nuclear waste glass journal, June 2013

Effects of glass structure on the corrosion behavior of sodium-aluminosilicate glasses journal, December 1997

Irreversibility of Pressure Induced Boron Speciation Change in Glass journal, January 2014

The kinetics of corrosion of e-glass fibres in sulphuric acid journal, October 2010

Dissolution rate of a basalt glass in silica-rich solutions: Implications for long-term alteration journal, November 1994

Glass dissolution rate measurement and calculation revisited journal, August 2016

Mechanism, rates, and consequences of basaltic glass dissolution: II. An experimental study of the dissolution rates of basaltic glass as a function of pH and temperature journal, October 2003

Structural and Chemical Approach toward Understanding the Aqueous Corrosion of Sodium Aluminoborate Glasses journal, November 2018

Elemental areal density calculation and oxygen speciation for flat glass surfaces using x-ray photoelectron spectroscopy journal, October 2016

Towards a unifying mechanistic model for silicate glass corrosion journal, September 2018

The pH of beverages in the United States journal, April 2016

Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis journal, December 1995

Fivefold-coordinated aluminum in tectosilicate glasses observed by triple quantum MAS NMR journal, October 2000

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR journal, April 2009

Short-Range Order and Site Connectivities in Sodium Aluminoborate Glasses: I. Quantification of Local Environments by High-Resolution 11 B, 23 Na, and 27 Al Solid-State NMR journal, June 1998

Structure of boroaluminosilicate glasses: Impact of [Al 2 O 3 ]/[SiO 2 ] ratio on the structural role of sodium journal, August 2012

Irreversibility of pressure induced boron speciation change in glass other, January 2014

Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals journal, July 2016

Corrosive attack of glass by a pharmaceutical compound journal, February 2007

Characterisation of Al coordination at the outer surface of dealuminated mordenites by X-ray photoelectron spectroscopy journal, December 1993

A review of the biological response to ionic dissolution products from bioactive glasses and glass-ceramics journal, April 2011

Structure of Sodium Aluminosilicate Glasses : X-Ray Photoelectron Spectroscopy journal, December 1985

The mechanism of borosilicate glass corrosion revisited journal, June 2015

Theoretical and 27Al CPMAS NMR investigation of aluminum coordination changes during aluminosilicate dissolution journal, May 2005

The dissolution rates of natural glasses as a function of their composition at pH 4 and 10.6, and temperatures from 25 to 74°C journal, December 2004

The effect of fluoride on the dissolution rates of natural glasses at pH 4 and 25°C journal, November 2004

Leached Layer Formation on Float Glass Surfaces in the Presence of Acid Interleave Coatings journal, March 2008

High-Resolution Multinuclear NMR Structural Study of Binary Aluminosilicate and Other Related Glasses journal, June 2004

Dissolution of nepheline, jadeite and albite glasses: toward better models for aluminosilicate dissolution journal, November 2001

The mechanism, rates and consequences of basaltic glass dissolution: I. An experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si and oxalic acid concentration at 25°C and pH = 3 and 11 journal, November 2001

Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism journal, June 2010

Network connectivity in aluminoborosilicate glasses: A high-resolution 11B, 27Al and 17O NMR study journal, November 2005

Molecular mechanisms for corrosion of silica and silicate glasses journal, November 1994

Separating the effects of composition and fictive temperature on Al and B coordination in Ca, La, Y aluminosilicate, aluminoborosilicate and aluminoborate glasses journal, January 2016

NMR evidence for formation of octahedral and tetrahedral Al and repolymerization of the Si network during dissolution of aluminosilicate glass and crystal journal, January 2003

Evaluation of a simple correction for the hydrocarbon contamination layer in quantitative surface analysis by XPS journal, July 2005

Sodium diffusion in boroaluminosilicate glasses journal, November 2011

The degree of aluminum avoidance in aluminosilicate glasses journal, June 1999

Impact of iron on nuclear glass alteration in geological repository conditions: A multiscale approach journal, April 2013

Toward an understanding of surface layer formation, growth, and transformation at the glass–fluid interface journal, May 2018

Chemical durability of glasses; a thermodynamic approach journal, November 1977

The effect of molecular structure on borosilicate glass leaching journal, October 1986

Topological Principles of Borosilicate Glass Chemistry journal, November 2011

Short and Medium Range Order in Sodium Aluminoborate Glasses. 2. Site Connectivities and Cation Distributions Studied by Rotational Echo Double Resonance NMR Spectroscopy journal, July 2000

Density-driven structural transformations in B 2 O 3 glass journal, July 2014

Modifier cation (Ba, Ca, La, Y) field strength effects on aluminum and boron coordination in aluminoborosilicate glasses: the roles of fictive temperature and boron content journal, April 2014

Corrosion of E-glass fibers in acidic environments journal, January 1997

Understanding the structural drivers governing glass–water interactions in borosilicate based model bioactive glasses journal, January 2018

Structural origin of high crack resistance in sodium aluminoborate glasses journal, March 2017

New Insight into the Residual Rate of Borosilicate Glasses: Effect of S/V and Glass Composition journal, October 2013

Site connectivities in sodium aluminoborate glasses: multinuclear and multiple quantum NMR results journal, January 2005

Dissolution of albite glass and crystal journal, August 2000

A Comparison of Glass Reaction at High and Low Glass Surface/Solution Volume journal, December 1993

Composition-structure-property relationships in Li2O–Al2O3–B2O3 glasses journal, December 2018

Comparative Study of XPS and DFT with Reference to the Distributions of Al in Tetrahedral and Octahedral Sheets of Phyllosilicates journal, February 1997

XPS study of the major minerals in bauxite: Gibbsite, bayerite and (pseudo-)boehmite journal, April 2006

Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join journal, May 2010

The Structure of Aluminosilicate Glasses: High-Resolution 17 O and 27 Al MAS and 3QMAS NMR Study journal, May 2000

The controversial role of inter-diffusion in glass alteration
journal, November 2016

Non-stoichiometric non-bridging oxygens and five-coordinated aluminum in alkaline earth aluminosilicate glasses: Effect of modifier cation size
journal, August 2012

Aluminum speciation and equilibria in aqueous solution: V. Gibbsite solubility at 50°C and pH 3–9 in 0.1 molal NaCl solutions (a general model for aluminum speciation; analytical methods)
journal, July 1994

Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses
journal, November 2013

Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra
journal, December 2001

Experimental determination of rhyolitic glass dissolution rates at 40–200°C and 2
journal, January 2013

The influence of H2O and SiO2 on the structure of silicoborate glasses
journal, September 2019

Topological Disorder and Reactivity of Borosilicate Glasses: Quantum Chemical Calculations and ¹⁷ O and ¹¹ B NMR Study
journal, December 2001

Tutorial review. Calculating standard deviations and confidence intervals with a universally applicable spreadsheet technique
journal, January 1994

Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy
journal, May 2006

XPS analysis of oxides
journal, July 1988

Concept and development of an autonomous wearable micro-fluidic platform for real time pH sweat analysis
journal, December 2012

Interdiffusion of hydrogen and alkali ions in a glass surface
journal, December 1975

An international initiative on long-term behavior of high-level nuclear waste glass
journal, June 2013

Effects of glass structure on the corrosion behavior of sodium-aluminosilicate glasses
journal, December 1997

Irreversibility of Pressure Induced Boron Speciation Change in Glass
journal, January 2014

The kinetics of corrosion of e-glass fibres in sulphuric acid
journal, October 2010

Dissolution rate of a basalt glass in silica-rich solutions: Implications for long-term alteration
journal, November 1994

Glass dissolution rate measurement and calculation revisited
journal, August 2016

Mechanism, rates, and consequences of basaltic glass dissolution: II. An experimental study of the dissolution rates of basaltic glass as a function of pH and temperature
journal, October 2003

Structural and Chemical Approach toward Understanding the Aqueous Corrosion of Sodium Aluminoborate Glasses
journal, November 2018

Elemental areal density calculation and oxygen speciation for flat glass surfaces using x-ray photoelectron spectroscopy
journal, October 2016

Towards a unifying mechanistic model for silicate glass corrosion
journal, September 2018

The pH of beverages in the United States
journal, April 2016

Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis
journal, December 1995

Fivefold-coordinated aluminum in tectosilicate glasses observed by triple quantum MAS NMR
journal, October 2000

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009

Short-Range Order and Site Connectivities in Sodium Aluminoborate Glasses: I. Quantification of Local Environments by High-Resolution 11 B, 23 Na, and 27 Al Solid-State NMR
journal, June 1998

Structure of boroaluminosilicate glasses: Impact of [Al $_{2}$ O $_{3}$ ]/[SiO $_{2}$ ] ratio on the structural role of sodium
journal, August 2012

Irreversibility of pressure induced boron speciation change in glass
other, January 2014

Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals
journal, July 2016

Corrosive attack of glass by a pharmaceutical compound
journal, February 2007

Characterisation of Al coordination at the outer surface of dealuminated mordenites by X-ray photoelectron spectroscopy
journal, December 1993

A review of the biological response to ionic dissolution products from bioactive glasses and glass-ceramics
journal, April 2011

Structure of Sodium Aluminosilicate Glasses : X-Ray Photoelectron Spectroscopy
journal, December 1985

The mechanism of borosilicate glass corrosion revisited
journal, June 2015

Theoretical and 27Al CPMAS NMR investigation of aluminum coordination changes during aluminosilicate dissolution
journal, May 2005

The dissolution rates of natural glasses as a function of their composition at pH 4 and 10.6, and temperatures from 25 to 74°C
journal, December 2004

The effect of fluoride on the dissolution rates of natural glasses at pH 4 and 25°C
journal, November 2004

Leached Layer Formation on Float Glass Surfaces in the Presence of Acid Interleave Coatings
journal, March 2008

High-Resolution Multinuclear NMR Structural Study of Binary Aluminosilicate and Other Related Glasses
journal, June 2004

Dissolution of nepheline, jadeite and albite glasses: toward better models for aluminosilicate dissolution
journal, November 2001

The mechanism, rates and consequences of basaltic glass dissolution: I. An experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si and oxalic acid concentration at 25°C and pH = 3 and 11
journal, November 2001

Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism
journal, June 2010

Network connectivity in aluminoborosilicate glasses: A high-resolution 11B, 27Al and 17O NMR study
journal, November 2005

Molecular mechanisms for corrosion of silica and silicate glasses
journal, November 1994

Separating the effects of composition and fictive temperature on Al and B coordination in Ca, La, Y aluminosilicate, aluminoborosilicate and aluminoborate glasses
journal, January 2016

NMR evidence for formation of octahedral and tetrahedral Al and repolymerization of the Si network during dissolution of aluminosilicate glass and crystal
journal, January 2003

Evaluation of a simple correction for the hydrocarbon contamination layer in quantitative surface analysis by XPS
journal, July 2005

Sodium diffusion in boroaluminosilicate glasses
journal, November 2011

The degree of aluminum avoidance in aluminosilicate glasses
journal, June 1999

Impact of iron on nuclear glass alteration in geological repository conditions: A multiscale approach
journal, April 2013

Toward an understanding of surface layer formation, growth, and transformation at the glass–fluid interface
journal, May 2018

Chemical durability of glasses; a thermodynamic approach
journal, November 1977

The effect of molecular structure on borosilicate glass leaching
journal, October 1986

Topological Principles of Borosilicate Glass Chemistry
journal, November 2011

Short and Medium Range Order in Sodium Aluminoborate Glasses. 2. Site Connectivities and Cation Distributions Studied by Rotational Echo Double Resonance NMR Spectroscopy
journal, July 2000

Density-driven structural transformations in $B_{2} O_{3}$ glass
journal, July 2014

Modifier cation (Ba, Ca, La, Y) field strength effects on aluminum and boron coordination in aluminoborosilicate glasses: the roles of fictive temperature and boron content
journal, April 2014

Corrosion of E-glass fibers in acidic environments
journal, January 1997

Understanding the structural drivers governing glass–water interactions in borosilicate based model bioactive glasses
journal, January 2018

Structural origin of high crack resistance in sodium aluminoborate glasses
journal, March 2017

New Insight into the Residual Rate of Borosilicate Glasses: Effect of S/V and Glass Composition
journal, October 2013

Site connectivities in sodium aluminoborate glasses: multinuclear and multiple quantum NMR results
journal, January 2005

Dissolution of albite glass and crystal
journal, August 2000

A Comparison of Glass Reaction at High and Low Glass Surface/Solution Volume
journal, December 1993

Composition-structure-property relationships in Li2O–Al2O3–B2O3 glasses
journal, December 2018

Comparative Study of XPS and DFT with Reference to the Distributions of Al in Tetrahedral and Octahedral Sheets of Phyllosilicates
journal, February 1997

XPS study of the major minerals in bauxite: Gibbsite, bayerite and (pseudo-)boehmite
journal, April 2006

Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join
journal, May 2010

The Structure of Aluminosilicate Glasses: High-Resolution ¹⁷ O and ²⁷ Al MAS and 3QMAS NMR Study
journal, May 2000