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Title: Space-Confined Polymerization: Controlled Fabrication of Nitrogen-Doped Polymer and Carbon Microspheres with Refined Hierarchical Architectures

Abstract

The construction of refined architectures plays a crucial role in performance improvement and application expansion of advanced materials. The synthesis of carbon microspheres with a refined hierarchical structure is still a problem in synthetic methodology, because it is difficult to achieve the necessary delicate control of the interior structure and outer shell across the microscale to nanoscale. Nitrogen-doped multichamber carbon (MCC) microspheres with a refined hierarchical structure are realized here via a surfactant-directed space-confined polymerization strategy. The MCC precursor is not the traditional phenolic resol but a new kind of 2,6-diaminopyridine-based multichamber polymer (MCP) with a high nitrogen content up to 20 wt%. The morphology and sizes of MCP microspheres can be easily controlled by a dual-surfactant system. The as-synthesized MCC with a highly microporous shell, a multichamber inner core, and beneficial N-doping can serve as a promising supercapacitor material.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [2];  [3];  [2]; ORCiD logo [1]; ORCiD logo [4]
  1. Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
  2. Xi'an Jiaotong Univ., Xi'an (China). School of Chemical Engineering and Technology
  3. State Key Laboratory of Rare Earth Resource UtilizationChangchun Institute of Applied Chemistry Changchun Jilin 130022 China
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1606772
Alternate Identifier(s):
OSTI ID: 1498568
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 31; Journal Issue: 16; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon spheres; hierarchical structures; polymer microspheres; porous materials; supercapacitors

Citation Formats

Wang, Tao, Sun, Yan, Zhang, Liangliang, Li, Kaiqian, Yi, Yikun, Song, Shuyan, Li, Mingtao, Qiao, Zhen‐An, and Dai, Sheng. Space-Confined Polymerization: Controlled Fabrication of Nitrogen-Doped Polymer and Carbon Microspheres with Refined Hierarchical Architectures. United States: N. p., 2019. Web. doi:10.1002/adma.201807876.
Wang, Tao, Sun, Yan, Zhang, Liangliang, Li, Kaiqian, Yi, Yikun, Song, Shuyan, Li, Mingtao, Qiao, Zhen‐An, & Dai, Sheng. Space-Confined Polymerization: Controlled Fabrication of Nitrogen-Doped Polymer and Carbon Microspheres with Refined Hierarchical Architectures. United States. doi:10.1002/adma.201807876.
Wang, Tao, Sun, Yan, Zhang, Liangliang, Li, Kaiqian, Yi, Yikun, Song, Shuyan, Li, Mingtao, Qiao, Zhen‐An, and Dai, Sheng. Wed . "Space-Confined Polymerization: Controlled Fabrication of Nitrogen-Doped Polymer and Carbon Microspheres with Refined Hierarchical Architectures". United States. doi:10.1002/adma.201807876. https://www.osti.gov/servlets/purl/1606772.
@article{osti_1606772,
title = {Space-Confined Polymerization: Controlled Fabrication of Nitrogen-Doped Polymer and Carbon Microspheres with Refined Hierarchical Architectures},
author = {Wang, Tao and Sun, Yan and Zhang, Liangliang and Li, Kaiqian and Yi, Yikun and Song, Shuyan and Li, Mingtao and Qiao, Zhen‐An and Dai, Sheng},
abstractNote = {The construction of refined architectures plays a crucial role in performance improvement and application expansion of advanced materials. The synthesis of carbon microspheres with a refined hierarchical structure is still a problem in synthetic methodology, because it is difficult to achieve the necessary delicate control of the interior structure and outer shell across the microscale to nanoscale. Nitrogen-doped multichamber carbon (MCC) microspheres with a refined hierarchical structure are realized here via a surfactant-directed space-confined polymerization strategy. The MCC precursor is not the traditional phenolic resol but a new kind of 2,6-diaminopyridine-based multichamber polymer (MCP) with a high nitrogen content up to 20 wt%. The morphology and sizes of MCP microspheres can be easily controlled by a dual-surfactant system. The as-synthesized MCC with a highly microporous shell, a multichamber inner core, and beneficial N-doping can serve as a promising supercapacitor material.},
doi = {10.1002/adma.201807876},
journal = {Advanced Materials},
number = 16,
volume = 31,
place = {United States},
year = {2019},
month = {2}
}

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Cited by: 18 works
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