Rare Earth Element Determination in Uranium Ore Concentrates Using Online and Offline Chromatography Coupled to ICP-MS
Abstract
The determination of trace elements, particularly rare earth elements, in uranium ore concentrates (UOCs) is important as the pattern can be indictive ore characteristics. Presented here is a methodology for accurately quantifying rare earth elements (REE) in UOCs. To improve the measurement uncertainty, isotope dilution mass spectrometry (IDMS) was utilized over other quantification techniques such as external calibration or standard addition. The isotopic determinations were measured by inductively coupled plasma-mass spectrometry (ICP-MS). To obtain high-fidelity isotopic measurements, separation of the REE from the uranium matrix was achieved by high-performance ion chromatography (HPIC), reducing the isobaric interferences. After separation, the target analytes were analyzed in two different modalities. For high precision analysis, the separated analytes were collected and measured by ICP-MS in an “offline” fashion. For a rapid approach, the separated analytes were sent directly into an ICP-MS for “online” analysis. These methods have been demonstrated to accurately quantify the REE content in a well-characterized UOC sample.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Missouri, Columbia, MO (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Missouri, Columbia, MO (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1606756
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Minerals
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2075-163X
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; uranium ore concentrate; ICP-MS; isotope dilution mass spectrometry; ion chromatography
Citation Formats
Bradley, Veronica C., Manard, Benjamin T., Roach, Benjamin D., Metzger, Shalina C., Rogers, Kayron T., Ticknor, Brian W., Wysor, Sarah K., Brockman, John D., and Hexel, Cole R. Rare Earth Element Determination in Uranium Ore Concentrates Using Online and Offline Chromatography Coupled to ICP-MS. United States: N. p., 2020.
Web. doi:10.3390/min10010055.
Bradley, Veronica C., Manard, Benjamin T., Roach, Benjamin D., Metzger, Shalina C., Rogers, Kayron T., Ticknor, Brian W., Wysor, Sarah K., Brockman, John D., & Hexel, Cole R. Rare Earth Element Determination in Uranium Ore Concentrates Using Online and Offline Chromatography Coupled to ICP-MS. United States. https://doi.org/10.3390/min10010055
Bradley, Veronica C., Manard, Benjamin T., Roach, Benjamin D., Metzger, Shalina C., Rogers, Kayron T., Ticknor, Brian W., Wysor, Sarah K., Brockman, John D., and Hexel, Cole R. Wed .
"Rare Earth Element Determination in Uranium Ore Concentrates Using Online and Offline Chromatography Coupled to ICP-MS". United States. https://doi.org/10.3390/min10010055. https://www.osti.gov/servlets/purl/1606756.
@article{osti_1606756,
title = {Rare Earth Element Determination in Uranium Ore Concentrates Using Online and Offline Chromatography Coupled to ICP-MS},
author = {Bradley, Veronica C. and Manard, Benjamin T. and Roach, Benjamin D. and Metzger, Shalina C. and Rogers, Kayron T. and Ticknor, Brian W. and Wysor, Sarah K. and Brockman, John D. and Hexel, Cole R.},
abstractNote = {The determination of trace elements, particularly rare earth elements, in uranium ore concentrates (UOCs) is important as the pattern can be indictive ore characteristics. Presented here is a methodology for accurately quantifying rare earth elements (REE) in UOCs. To improve the measurement uncertainty, isotope dilution mass spectrometry (IDMS) was utilized over other quantification techniques such as external calibration or standard addition. The isotopic determinations were measured by inductively coupled plasma-mass spectrometry (ICP-MS). To obtain high-fidelity isotopic measurements, separation of the REE from the uranium matrix was achieved by high-performance ion chromatography (HPIC), reducing the isobaric interferences. After separation, the target analytes were analyzed in two different modalities. For high precision analysis, the separated analytes were collected and measured by ICP-MS in an “offline” fashion. For a rapid approach, the separated analytes were sent directly into an ICP-MS for “online” analysis. These methods have been demonstrated to accurately quantify the REE content in a well-characterized UOC sample.},
doi = {10.3390/min10010055},
journal = {Minerals},
number = 1,
volume = 10,
place = {United States},
year = {2020},
month = {1}
}
Web of Science
Works referenced in this record:
Attribution of uranium ore concentrates using elemental and anionic data
journal, August 2012
- Keegan, Elizabeth; Wallenius, Maria; Mayer, Klaus
- Applied Geochemistry, Vol. 27, Issue 8
A REVIEW OF THE BASIC CHEMISTRY AND RECENT DEVELOPMENTS IN TRIVALENT f-ELEMENTS SEPARATIONS
journal, May 1993
- Nash, Kenneth L.
- Solvent Extraction and Ion Exchange, Vol. 11, Issue 4
Origin of uranium deposits revealed by their rare earth element signature: Origin of U deposits revealed by the rare earth elements
journal, May 2011
- Mercadier, Julien; Cuney, Michel; Lach, Philippe
- Terra Nova, Vol. 23, Issue 4
An automated micro-separation system for the chromatographic removal of uranium matrix for trace element analysis by ICP-OES
journal, November 2018
- Wylie, E. Miller; Manard, Benjamin T.; Quarles, C. Derrick
- Talanta, Vol. 189
Trace elemental analysis of bulk uranium materials using an inline automated sample preparation technique for ICP-OES
journal, December 2018
- Quarles, C. Derrick; Manard, Benjamin T.; Wylie, E. Miller
- Talanta, Vol. 190
Solid-phase extraction microfluidic devices for matrix removal in trace element assay of actinide materials
journal, May 2017
- Gao, Jun; Manard, Benjamin T.; Castro, Alonso
- Talanta, Vol. 167
Rapid, high-purity, lanthanide separations using HPLC
journal, July 2006
- Schwantes, Jon M.; Rundberg, Robert S.; Taylor, Wayne A.
- Journal of Alloys and Compounds, Vol. 418, Issue 1-2
Ion chromatography with inductively coupled plasma mass spectrometry, a powerful analytical tool for complex matrices
journal, May 2003
- Bruzzoniti, M. C.; Cavalli, S.; Mangia, A.
- Journal of Chromatography A, Vol. 997, Issue 1-2
Determination of lanthanides and actinides in uranium materials by high-performance liquid chromatography with inductively coupled plasma mass spectrometric detection
journal, July 1996
- Röllin, S.; Kopatjtic, Z.; Wernli, B.
- Journal of Chromatography A, Vol. 739, Issue 1-2
Inorganic trace analysis by isotope-dilution mass-spectrometry - New frontiers
journal, May 1988
- Fassett, J. D.
- Journal of Research of the National Bureau of Standards, Vol. 93, Issue 3
Elemental Analysis Using ICP-OES and ICP/MS
journal, January 1991
- Olesik, John W.
- Analytical Chemistry, Vol. 63, Issue 1
Studies on simultaneous separation and determination of lanthanides and actinides by ion chromatography inductively coupled plasma mass spectrometry combined with isotope dilution mass spectrometry
journal, January 2002
- Perna, L.; Bocci, F.; Aldave de las Heras, L.
- J. Anal. At. Spectrom., Vol. 17, Issue 9
Trace impurity analysis in uranium oxide via hybrid quantification techniques—gravimetric standard addition and isotope dilution mass spectrometry
journal, August 2018
- Rogers, Kayron T.; Giaquinto, Joseph; Essex, Richard M.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1
Integration of a hyphenated HPIC-ICPMS protocol for the measurement of transplutonium isotopic mass distributions for 252Cf campaigns at Oak Ridge National Laboratory
journal, August 2018
- Roach, Benjamin D.; Giaquinto, Joseph M.; Keever, Tamara J.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1
Rapid concentration and isotopic measurements of ultra-trace 235U fission products with comparison to an ORIGEN isotope depletion model
journal, December 2019
- Roach, Benjamin D.; Fenske, Emilie K.; Glasgow, David C.
- Talanta, Vol. 205
Determination of rare-earth elements in uranium-bearing materials by inductively coupled plasma mass spectrometry
journal, March 2010
- Varga, Zsolt; Katona, Róbert; Stefánka, Zsolt
- Talanta, Vol. 80, Issue 5
Rapid measurements of 235U fission product isotope ratios using an online, high-pressure ion chromatography inductively coupled plasma mass spectrometry protocol with comparison to isotopic depletion models
journal, February 2019
- Fenske, Emilie K.; Roach, Benjamin D.; Glasgow, David C.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 320, Issue 1
Identification of uranium signatures relevant for nuclear safeguards and forensics
journal, April 2017
- Varga, Zsolt; Krajkó, Judit; Peńkin, Maxim
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 312, Issue 3
A preliminary study for the determination of long-lived radionuclides (second transition group 4-d) in environmental samples by ion chromatography inductively coupled plasma-mass spectrometry (IC-ICP-MS)
journal, December 2000
- Betti, M.; Menichetti, L.; Barrero Moreno, J. M.
- Microchemical Journal, Vol. 67, Issue 1-3
Avoiding polyatomic interferences in measurements of lanthanides in uranium material for nuclear forensic purposes
journal, June 2019
- Vesterlund, Anna; Ramebäck, Henrik
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, Issue 2
Determination of actinides in environmental and biological samples using high-performance chelation ion chromatography coupled to sector-field inductively coupled plasma mass spectrometry
journal, August 2001
- Truscott, Jason B.; Jones, Phil; Fairman, Ben E.
- Journal of Chromatography A, Vol. 928, Issue 1
Evaluation and Specifications for In-Line Uranium Separations Using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) Detection for Trace Elemental Analysis
journal, March 2019
- Manard, Benjamin T.; Metzger, Shalina C.; Quarles, C. Derrick
- Applied Spectroscopy, Vol. 73, Issue 8
Isotope Dilution Mass Spectrometry for Accurate Elemental Analysis
journal, May 1989
- Fassett, Jack D.; Paulsen, Paul J.
- Analytical Chemistry, Vol. 61, Issue 10
Use of ion chromatography for the determination of fission products and actinides in nuclear applications
journal, November 1997
- Betti, Maria
- Journal of Chromatography A, Vol. 789, Issue 1-2
Development of a fast and efficient analytical technique for the isotopic analysis of fission and actinide elements in environmental matrices
journal, February 2019
- Roach, Benjamin D.; Fenske, Emilie K.; Ilgner, Ralph H.
- Journal of Chromatography A, Vol. 1587
Trace element and U isotope analysis of uraninite and ore concentrate: Applications for nuclear forensic investigations
journal, September 2017
- Spano, Tyler L.; Simonetti, Antonio; Balboni, Enrica
- Applied Geochemistry, Vol. 84