Cross-Linked Nanocellulosic Materials and Their Applications
Abstract
Nanocelluloses (NCs) have remarkable mechanical properties and contain abundant surface functional groups that can be modified or cross-linked with other materials. They have been widely used as an environment-friendly reinforcing agent in polymer composites. However, for applications that are carried out in humid environments or aqueous suspensions, hydrophilicity of NCs lower their mechanical integrity. Hence, cross-linking techniques have been investigated in recent years for preparing NC-based materials that are dimensionally stable under humid or aqueous environments and have better physicochemical properties. This Minireview examines the quickly growing field of cross-linked NC-based materials, which have many benefits including improved aqueous, structural, mechanical, and thermal stability. In addition, the potential application of cross-linked NC-based materials in adsorption of heavy metal is discussed.
- Authors:
-
[4]
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States); Chinese Academy of Forestry, Nanjing (China)
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1606680
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 1; Journal ID: ISSN 1864-5631
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; adsorption; biomass; heavy metal ions; nanocellulose; nanomaterials
Citation Formats
Liang, Luna, Bhagia, Samarthya, Li, Mi, Huang, Chen, and Ragauskas, Arthur J. Cross-Linked Nanocellulosic Materials and Their Applications. United States: N. p., 2019.
Web. doi:10.1002/cssc.201901676.
Liang, Luna, Bhagia, Samarthya, Li, Mi, Huang, Chen, & Ragauskas, Arthur J. Cross-Linked Nanocellulosic Materials and Their Applications. United States. https://doi.org/10.1002/cssc.201901676
Liang, Luna, Bhagia, Samarthya, Li, Mi, Huang, Chen, and Ragauskas, Arthur J. Thu .
"Cross-Linked Nanocellulosic Materials and Their Applications". United States. https://doi.org/10.1002/cssc.201901676. https://www.osti.gov/servlets/purl/1606680.
@article{osti_1606680,
title = {Cross-Linked Nanocellulosic Materials and Their Applications},
author = {Liang, Luna and Bhagia, Samarthya and Li, Mi and Huang, Chen and Ragauskas, Arthur J.},
abstractNote = {Nanocelluloses (NCs) have remarkable mechanical properties and contain abundant surface functional groups that can be modified or cross-linked with other materials. They have been widely used as an environment-friendly reinforcing agent in polymer composites. However, for applications that are carried out in humid environments or aqueous suspensions, hydrophilicity of NCs lower their mechanical integrity. Hence, cross-linking techniques have been investigated in recent years for preparing NC-based materials that are dimensionally stable under humid or aqueous environments and have better physicochemical properties. This Minireview examines the quickly growing field of cross-linked NC-based materials, which have many benefits including improved aqueous, structural, mechanical, and thermal stability. In addition, the potential application of cross-linked NC-based materials in adsorption of heavy metal is discussed.},
doi = {10.1002/cssc.201901676},
journal = {ChemSusChem},
number = 1,
volume = 13,
place = {United States},
year = {2019},
month = {8}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 8 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ion-crosslinked wood-derived nanocellulose hydrogels with tunable antibacterial properties: Candidate materials for advanced wound care applications
journal, February 2018
- Basu, Alex; Heitz, Karen; Strømme, Maria
- Carbohydrate Polymers, Vol. 181
Tailoring the yield and characteristics of wood cellulose nanocrystals (CNC) using concentrated acid hydrolysis
journal, April 2015
- Chen, Liheng; Wang, Qianqian; Hirth, Kolby
- Cellulose, Vol. 22, Issue 3
Wood nanocelluloses: fundamentals and applications as new bio-based nanomaterials
journal, September 2013
- Isogai, Akira
- Journal of Wood Science, Vol. 59, Issue 6
Cellulose nanocrystal-based materials: from liquid crystal self-assembly and glass formation to multifunctional thin films
journal, January 2014
- Lagerwall, Jan P. F.; Schütz, Christina; Salajkova, Michaela
- NPG Asia Materials, Vol. 6, Issue 1
Nanocellulose from Spinifex as an Effective Adsorbent to Remove Cadmium(II) from Water
journal, January 2018
- Sharma, Priyanka R.; Chattopadhyay, Aurnov; Sharma, Sunil K.
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 3
In situ TEMPO surface functionalization of nanocellulose membranes for enhanced adsorption of metal ions from aqueous medium
journal, January 2017
- Karim, Zoheb; Hakalahti, Minna; Tammelin, Tekla
- RSC Advances, Vol. 7, Issue 9
Chemically Cross-Linked Cellulose Nanocrystal Aerogels with Shape Recovery and Superabsorbent Properties
journal, October 2014
- Yang, Xuan; Cranston, Emily D.
- Chemistry of Materials, Vol. 26, Issue 20
Chitin derivatives. I. Kinetics of the heat-induced conversion of chitosan to chitin
journal, April 1996
- Toffey, Ackah; Samaranayake, Gamini; Frazier, Charles E.
- Journal of Applied Polymer Science, Vol. 60, Issue 1
Chitosan-based biomaterials for tissue engineering
journal, April 2013
- Croisier, Florence; Jérôme, Christine
- European Polymer Journal, Vol. 49, Issue 4
New spherical nanocellulose and thiol-based adsorbent for rapid and selective removal of mercuric ions
journal, January 2018
- Ram, Bhagat; Chauhan, Ghanshyam S.
- Chemical Engineering Journal, Vol. 331
Preparation By Grafting Onto, Characterization, and Properties of Thermally Responsive Polymer-Decorated Cellulose Nanocrystals
journal, December 2010
- Azzam, Firas; Heux, Laurent; Putaux, Jean-Luc
- Biomacromolecules, Vol. 11, Issue 12
Hydrodynamic alignment and assembly of nanofibrils resulting in strong cellulose filaments
journal, June 2014
- Håkansson, Karl M. O.; Fall, Andreas B.; Lundell, Fredrik
- Nature Communications, Vol. 5, Issue 1
Nanocellulose reinforced P(AAm-co-AAc) hydrogels with improved mechanical properties and biocompatibility
journal, September 2018
- Huang, Shu; Zhao, Zhan; Feng, Chuang
- Composites Part A: Applied Science and Manufacturing, Vol. 112
Crosslinked nanofibrillated cellulose: poly(acrylic acid) nanocomposite films; enhanced mechanical performance in aqueous environments
journal, September 2013
- Spoljaric, Steven; Salminen, Arto; Luong, Nguyen Dang
- Cellulose, Vol. 20, Issue 6
Shapeable Fibrous Aerogels of Metal–Organic-Frameworks Templated with Nanocellulose for Rapid and Large-Capacity Adsorption
journal, April 2018
- Zhu, Luting; Zong, Lu; Wu, Xiaochen
- ACS Nano, Vol. 12, Issue 5
Preparation and characterization of chitosan based hydrogels chemical cross‐linked by oxidized cellulose nanowhiskers
journal, October 2018
- Sheng, Chao; Zhou, Yiming; Lu, Jiannan
- Polymer Composites, Vol. 40, Issue 6
Adsorption of Cu (II), Pb (II) and Cr (VI) from aqueous solutions using black wattle tannin-immobilized nanocellulose
journal, October 2017
- Xu, Qinghua; Wang, Yulu; Jin, Liqiang
- Journal of Hazardous Materials, Vol. 339
Adsorption isotherms and mechanisms of Cu( ii ) sorption onto TEMPO-mediated oxidized cellulose nanofibers
journal, January 2016
- Liu, Peng; Garrido, Beatriz; Oksman, Kristiina
- RSC Advances, Vol. 6, Issue 109
Cellulose Nanocrystals vs. Cellulose Nanofibrils: A Comparative Study on Their Microstructures and Effects as Polymer Reinforcing Agents
journal, January 2013
- Xu, Xuezhu; Liu, Fei; Jiang, Long
- ACS Applied Materials & Interfaces, Vol. 5, Issue 8
Mechanically strong hybrid double network hydrogels with antifouling properties
journal, January 2015
- Chen, Hong; Chen, Qiang; Hu, Rundong
- Journal of Materials Chemistry B, Vol. 3, Issue 27
Collagen fibres with improved strength for the repair of soft tissue injuries
journal, June 1994
- Mingche, W.; Pins, G.; Silver, F.
- Biomaterials, Vol. 15, Issue 7
Interface tailoring through covalent hydroxyl-epoxy bonds improves hygromechanical stability in nanocellulose materials
journal, October 2016
- Ansari, Farhan; Lindh, Erik L.; Furo, Istvan
- Composites Science and Technology, Vol. 134
Post-sulfonation of cellulose nanofibrils with a one-step reaction to improve dispersibility
journal, February 2018
- Luo, Jeffrey; Semenikhin, Nikolay; Chang, Huibin
- Carbohydrate Polymers, Vol. 181
Towards Tunable Protein-Carrier Wound Dressings Based on Nanocellulose Hydrogels Crosslinked with Calcium Ions
journal, July 2018
- Basu, Alex; Strømme, Maria; Ferraz, Natalia
- Nanomaterials, Vol. 8, Issue 7
Cellulose Nanofibril Aerogels: Synergistic Improvement of Hydrophobicity, Strength, and Thermal Stability via Cross-Linking with Diisocyanate
journal, January 2017
- Jiang, Feng; Hsieh, You-Lo
- ACS Applied Materials & Interfaces, Vol. 9, Issue 3
Chitin derivatives. II. Time-temperature-transformation cure diagrams of the chitosan amidization process
journal, September 1999
- Toffey, Ackah; Glasser, Wolfgang G.
- Journal of Applied Polymer Science, Vol. 73, Issue 10
Cellulose nanocrystal interactions probed by thin film swelling to predict dispersibility
journal, January 2016
- Reid, Michael S.; Villalobos, Marco; Cranston, Emily D.
- Nanoscale, Vol. 8, Issue 24
Adsorption of heavy metal ions from aqueous solution by carboxylated cellulose nanocrystals
journal, May 2013
- Yu, Xiaolin; Tong, Shengrui; Ge, Maofa
- Journal of Environmental Sciences, Vol. 25, Issue 5
3D-Printable Bioactivated Nanocellulose–Alginate Hydrogels
journal, June 2017
- Leppiniemi, Jenni; Lahtinen, Panu; Paajanen, Antti
- ACS Applied Materials & Interfaces, Vol. 9, Issue 26
Preparation and characterization of hydrophobic derivatives of TEMPO-oxidized nanocelluloses
journal, August 2011
- Johnson, Richard K.; Zink-Sharp, Audrey; Glasser, Wolfgang G.
- Cellulose, Vol. 18, Issue 6
A light-weight and high-efficacy antibacterial nanocellulose-based sponge via covalent immobilization of gentamicin
journal, November 2018
- Xiao, Yongmei; Rong, Liduo; Wang, Bijia
- Carbohydrate Polymers, Vol. 200
Key advances in the chemical modification of nanocelluloses
journal, January 2014
- Habibi, Youssef
- Chem. Soc. Rev., Vol. 43, Issue 5
Sustainable Barrier System via Self-Assembly of Colloidal Montmorillonite and Cross-linking Resins on Nanocellulose Interfaces
journal, December 2018
- H. Tayeb, Ali; Tajvidi, Mehdi
- ACS Applied Materials & Interfaces, Vol. 11, Issue 1
Composite Films of Poly(vinyl alcohol) and Bifunctional Cross-linking Cellulose Nanocrystals
journal, August 2015
- Sirviö, Juho Antti; Honkaniemi, Samuli; Visanko, Miikka
- ACS Applied Materials & Interfaces, Vol. 7, Issue 35
Effect of crosslinking on the mechanical properties of mineralized and non-mineralized collagen fibers: Crosslinking of Mineralized and Non-Mineralized Collagen Fibers
journal, July 2013
- Bou-Akl, Therese; Banglmaier, Richard; Miller, Rebecca
- Journal of Biomedical Materials Research Part A, Vol. 101A, Issue 9
Shape memory aerogels from nanocellulose and polyethyleneimine as a novel adsorbent for removal of Cu(II) and Pb(II)
journal, September 2018
- Li, Jian; Zuo, Keman; Wu, Weibing
- Carbohydrate Polymers, Vol. 196
Barrier and mechanical properties of plasticized and cross-linked nanocellulose coatings for paper packaging applications
journal, July 2017
- Herrera, Martha A.; Mathew, Aji P.; Oksman, Kristiina
- Cellulose, Vol. 24, Issue 9
Effects of nanocellulose on the structure and properties of poly(vinyl alcohol)-borax hybrid foams
journal, July 2017
- Han, Jingquan; Yue, Yiying; Wu, Qinglin
- Cellulose, Vol. 24, Issue 10
Magnetic nanocellulose alginate hydrogel beads as potential drug delivery system
journal, October 2018
- Supramaniam, Jagadeesen; Adnan, Rohana; Mohd Kaus, Noor Haida
- International Journal of Biological Macromolecules, Vol. 118
Superhydrophobic and Superoleophobic Nanocellulose Aerogel Membranes as Bioinspired Cargo Carriers on Water and Oil
journal, March 2011
- Jin, Hua; Kettunen, Marjo; Laiho, Ari
- Langmuir, Vol. 27, Issue 5
On the use of ion-crosslinked nanocellulose hydrogels for wound healing solutions: Physicochemical properties and application-oriented biocompatibility studies
journal, October 2017
- Basu, Alex; Lindh, Jonas; Ålander, Eva
- Carbohydrate Polymers, Vol. 174
Designing pH-responsive and dielectric hydrogels from cellulose nanocrystals
journal, June 2015
- Gao, Xiaoyuan; Sadasivuni, Kishor Kumar; Kim, Hyun-Chan
- Journal of Chemical Sciences, Vol. 127, Issue 6
Preparation of cellulose nanofibers with hydrophobic surface characteristics
journal, December 2009
- Jonoobi, Mehdi; Harun, Jalaluddin; Mathew, Aji P.
- Cellulose, Vol. 17, Issue 2
Helicoidal self-ordering of cellulose microfibrils in aqueous suspension
journal, June 1992
- Revol, J. -F.; Bradford, H.; Giasson, J.
- International Journal of Biological Macromolecules, Vol. 14, Issue 3
Nanocelluloses: A New Family of Nature-Based Materials
journal, May 2011
- Klemm, Dieter; Kramer, Friederike; Moritz, Sebastian
- Angewandte Chemie International Edition, Vol. 50, Issue 24
Chemistry and applications of nanocrystalline cellulose and its derivatives: A nanotechnology perspective
journal, February 2011
- Peng, B. L.; Dhar, N.; Liu, H. L.
- The Canadian Journal of Chemical Engineering, Vol. 89, Issue 5
Fabrication of complex-shaped hydrogels by diffusion controlled gelation of nanocellulose crystallites
journal, January 2017
- Maestri, C. A.; Bettotti, P.; Scarpa, M.
- J. Mater. Chem. B, Vol. 5, Issue 40
High-Strength Nanocomposite Aerogels of Ternary Composition: Poly(vinyl alcohol), Clay, and Cellulose Nanofibrils
journal, February 2017
- Liu, Andong; Medina, Lilian; Berglund, Lars A.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 7
Cellulose: from biocompatible to bioactive material
journal, January 2014
- Credou, Julie; Berthelot, Thomas
- J. Mater. Chem. B, Vol. 2, Issue 30
Humidity and Multiscale Structure Govern Mechanical Properties and Deformation Modes in Films of Native Cellulose Nanofibrils
journal, November 2013
- Benítez, Alejandro J.; Torres-Rendon, Jose; Poutanen, Mikko
- Biomacromolecules, Vol. 14, Issue 12
TEMPO-oxidized cellulose nanofibers
journal, January 2011
- Isogai, Akira; Saito, Tsuguyuki; Fukuzumi, Hayaka
- Nanoscale, Vol. 3, Issue 1
A review on processing techniques of bast fibers nanocellulose and its polylactic acid (PLA) nanocomposites
journal, January 2019
- Kian, L. K.; Saba, N.; Jawaid, M.
- International Journal of Biological Macromolecules, Vol. 121
Behavior of nanocelluloses at interfaces
journal, May 2017
- Capron, Isabelle; Rojas, Orlando J.; Bordes, Romain
- Current Opinion in Colloid & Interface Science, Vol. 29
Water Vapor Uptake of Ultrathin Films of Biologically Derived Nanocrystals: Quantitative Assessment with Quartz Crystal Microbalance and Spectroscopic Ellipsometry
journal, October 2015
- Niinivaara, Elina; Faustini, Marco; Tammelin, Tekla
- Langmuir, Vol. 31, Issue 44
Metal–carboxylate interactions in metal–alginate complexes studied with FTIR spectroscopy
journal, February 2010
- Papageorgiou, Sergios K.; Kouvelos, Evangelos P.; Favvas, Evangelos P.
- Carbohydrate Research, Vol. 345, Issue 4
Coupling chitosan and TEMPO-oxidized nanofibrilliated cellulose by electrostatic attraction and chemical reaction
journal, December 2018
- Tang, Ruilin; Yu, Zhiming; Renneckar, Scott
- Carbohydrate Polymers, Vol. 202
Improvement of the Thermal Stability of TEMPO-Oxidized Cellulose Nanofibrils by Heat-Induced Conversion of Ionic Bonds to Amide Bonds
journal, May 2016
- Lavoine, Nathalie; Bras, Julien; Saito, Tsuguyuki
- Macromolecular Rapid Communications, Vol. 37, Issue 13
Polycaprolactone Nanocomposites Reinforced with Cellulose Nanocrystals Surface-Modified via Covalent Grafting or Physisorption: A Comparative Study
journal, September 2017
- Boujemaoui, Assya; Cobo Sanchez, Carmen; Engström, Joakim
- ACS Applied Materials & Interfaces, Vol. 9, Issue 40
A physically crosslinked polydopamine/nanocellulose hydrogel as potential versatile vehicles for drug delivery and wound healing
journal, May 2018
- Liu, Yingying; Sui, Yulong; Liu, Chao
- Carbohydrate Polymers, Vol. 188
Activable carboxylic acid functionalized crystalline nanocellulose/PVA- co -PE composite nanofibrous membrane with enhanced adsorption for heavy metal ions
journal, October 2017
- Zhu, Qing; Wang, Yao; Li, Mufang
- Separation and Purification Technology, Vol. 186
Mechanism of hexavalent chromium adsorption by persimmon tannin gel
journal, July 2004
- Nakajima, Akira; Baba, Yoshinari
- Water Research, Vol. 38, Issue 12
Dual Physically Cross-Linked Hydrogels with High Stretchability, Toughness, and Good Self-Recoverability
journal, July 2016
- Hu, Yang; Du, Zhengshan; Deng, Xiaolan
- Macromolecules, Vol. 49, Issue 15
Strength and modulus improvement of wet-spun cellulose I filaments by sequential physical and chemical cross-linking
journal, December 2017
- Geng, Lihong; Chen, Binyi; Peng, Xiangfang
- Materials & Design, Vol. 136
Water-Resistant, Transparent Hybrid Nanopaper by Physical Cross-Linking with Chitosan
journal, February 2015
- Toivonen, Matti S.; Kurki-Suonio, Sauli; Schacher, Felix H.
- Biomacromolecules, Vol. 16, Issue 3
Nanocellulosen: eine neue Familie naturbasierter Materialien
journal, May 2011
- Klemm, Dieter; Kramer, Friederike; Moritz, Sebastian
- Angewandte Chemie, Vol. 123, Issue 24
Chemical cross-linked polyvinyl alcohol/cellulose nanocrystal composite films with high structural stability by spraying Fenton reagent as initiator
journal, July 2018
- Song, Meili; Yu, Houyong; Gu, Jiping
- International Journal of Biological Macromolecules, Vol. 113
Biofibres and biocomposites
journal, February 2008
- John, M.; Thomas, S.
- Carbohydrate Polymers, Vol. 71, Issue 3
Nanocellulose/Poly(2-(dimethylamino)ethyl methacrylate)Interpenetrating polymer network hydrogels for removal of Pb(II) and Cu(II) ions
journal, February 2018
- Li, Jian; Xu, Zhaoyang; Wu, Weibing
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 538
Physically and chemically cross-linked cellulose cryogels: Structure, properties and application for controlled release
journal, October 2016
- Ciolacu, Diana; Rudaz, Cyrielle; Vasilescu, Mihai
- Carbohydrate Polymers, Vol. 151
Highly flexible cross-linked cellulose nanofibril sponge-like aerogels with improved mechanical property and enhanced flame retardancy
journal, January 2018
- Guo, Limin; Chen, Zhilin; Lyu, Shaoyi
- Carbohydrate Polymers, Vol. 179
Ion-Mediated Gelation of Aqueous Suspensions of Cellulose Nanocrystals
journal, July 2015
- Chau, Mokit; Sriskandha, Shivanthi E.; Pichugin, Dmitry
- Biomacromolecules, Vol. 16, Issue 8
Hemocompatibility of Ca 2+ -Crosslinked Nanocellulose Hydrogels: Toward Efficient Management of Hemostasis
journal, September 2017
- Basu, Alex; Hong, Jaan; Ferraz, Natalia
- Macromolecular Bioscience, Vol. 17, Issue 11
Cellulose nanocrystals as reinforcements for collagen-based casings with low gas transmission
journal, November 2017
- Long, Keying; Cha, Ruitao; Zhang, Yapei
- Cellulose, Vol. 25, Issue 1
Dual physically crosslinked healable polyacrylamide/cellulose nanofibers nanocomposite hydrogels with excellent mechanical properties
journal, August 2018
- Niu, Jiabao; Wang, Jianquan; Dai, Xiaofu
- Carbohydrate Polymers, Vol. 193
Highly thermal-stable and functional cellulose nanocrystals and nanofibrils produced using fully recyclable organic acids
journal, January 2016
- Chen, Liheng; Zhu, J. Y.; Baez, Carlos
- Green Chemistry, Vol. 18, Issue 13
Fundamentals of double network hydrogels
journal, January 2015
- Chen, Qiang; Chen, Hong; Zhu, Lin
- Journal of Materials Chemistry B, Vol. 3, Issue 18
Cross-linked poly(methyl vinyl ether-co-maleic acid)/poly(ethylene glycol)/nanocellulosics foams via directional freezing
journal, June 2019
- Liang, Luna; Huang, Chen; Hao, Naijia
- Carbohydrate Polymers, Vol. 213
High wet-strength, thermally stable and transparent TEMPO-oxidized cellulose nanofibril film via cross-linking with poly-amide epichlorohydrin resin
journal, January 2017
- Yang, Weisheng; Bian, Huiyang; Jiao, Liang
- RSC Advances, Vol. 7, Issue 50
Crosslinked poly(vinyl alcohol) composite films with cellulose nanocrystals: Mechanical and thermal properties: ARTICLE
journal, September 2017
- Tanpichai, Supachok; Oksman, Kristiina
- Journal of Applied Polymer Science, Vol. 135, Issue 3
Nanocellulose fibers for biosorption of cadmium, nickel, and lead ions from aqueous solution
journal, May 2013
- Kardam, Abhishek; Raj, Kumar Rohit; Srivastava, Shalini
- Clean Technologies and Environmental Policy, Vol. 16, Issue 2