Selected Negative Linear Compressibilities in the Metal–Organic Framework of [Cu(4,4'-bpy)2(H2O)2]·SiF6

Chen, Zhongwei; Xu, Bin; Li, Qian; Meng, Yue; Quan, Zewei; Zou, Bo

doi:10.1021/acs.inorgchem.9b02884

Title: Selected Negative Linear Compressibilities in the Metal–Organic Framework of [Cu(4,4'-bpy)₂(H₂O)₂]·SiF₆

Journal Article · 21 January 2020 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.9b02884 · OSTI ID:1606533

^[1]; Xu, Bin ^[1];

^[1]; Meng, Yue ^[2];

^[1];

^[3]

Southern Univ. of Science and Technology (SUSTech), Shenzhen (P.R. China)
Argonne National Lab. (ANL), Argonne, IL (United States). HPCAT
Jilin Univ., Changchun (P.R. China). State Key Lab. of Superhard Materials

Negative linear compressibility (NLC) is a rare high-pressure observation that lattice contraction is accompanied by the structural expansion along a specific direction. Generally, this counterintuitive phenomenon only derives from the intrinsic structural characteristics of materials and cannot be tuned by external perturbations. Searching for an effective method to control NLC effect is still a challenge in both chemical and material science. In this work, we successfully discover and select the NLC behaviors in the metal-organic framework (MOF) of [Cu(4,4'-bpy)₂(H₂O)₂]·SiF₆ (Cu(bpy)·SiF) through controlling the pressure conditions therein. The NLC effect of Cu(bpy)·SiF originates from the wine-rack mechanism that quasi-square grids transfer to rhombic ones with the structural expansion along the diagonal direction at high pressure. Meanwhile, both of the pressure range and magnitude of the NLC responses are enlarged with optimized pressure conditions. This study not only presents the intriguing selected NLC behaviors of a MOF but also proves the effects of pressure conditions on NLC, which offers promising strategies for further design and applications of NLC materials.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Chang Jiang Scholars Program; National Natural Science Foundation of China (NSFC); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1606533

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 3 Vol. 59; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Selected Negative Linear Compressibilities in the Metal–Organic Framework of [Cu(4,4'-bpy)2(H2O)2]·SiF6

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Title: Selected Negative Linear Compressibilities in the Metal–Organic Framework of [Cu(4,4'-bpy)₂(H₂O)₂]·SiF₆