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Title: Low-spin cobalt( ii ) redox shuttle by isocyanide coordination

Abstract

The electron transfer kinetics in the DSSCs were tuned dramatically by coordination of the strong-field ligand 2,6-dimethyl isocyanide to induce a low-spin Co( ii ) redox shuttle.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, Michigan State University, Michigan 48824, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1606275
Grant/Contract Number:  
SC0017342
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Name: Sustainable Energy & Fuels Journal Volume: 4 Journal Issue: 5; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Raithel, Austin L., Kim, Tea-Yon, Nielsen, Karl C., Staples, Richard J., and Hamann, Thomas W. Low-spin cobalt( ii ) redox shuttle by isocyanide coordination. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0SE00314J.
Raithel, Austin L., Kim, Tea-Yon, Nielsen, Karl C., Staples, Richard J., & Hamann, Thomas W. Low-spin cobalt( ii ) redox shuttle by isocyanide coordination. United Kingdom. https://doi.org/10.1039/D0SE00314J
Raithel, Austin L., Kim, Tea-Yon, Nielsen, Karl C., Staples, Richard J., and Hamann, Thomas W. Wed . "Low-spin cobalt( ii ) redox shuttle by isocyanide coordination". United Kingdom. https://doi.org/10.1039/D0SE00314J.
@article{osti_1606275,
title = {Low-spin cobalt( ii ) redox shuttle by isocyanide coordination},
author = {Raithel, Austin L. and Kim, Tea-Yon and Nielsen, Karl C. and Staples, Richard J. and Hamann, Thomas W.},
abstractNote = {The electron transfer kinetics in the DSSCs were tuned dramatically by coordination of the strong-field ligand 2,6-dimethyl isocyanide to induce a low-spin Co( ii ) redox shuttle.},
doi = {10.1039/D0SE00314J},
journal = {Sustainable Energy & Fuels},
number = 5,
volume = 4,
place = {United Kingdom},
year = {2020},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0SE00314J

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