skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on March 19, 2021

Title: Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas

Abstract

2D plume and spectral imaging illustrate expansion dynamics and corresponding chemical evolution of atoms and molecules in filament produced plasmas.

Authors:
ORCiD logo [1];  [2];  [1];  [3]; ORCiD logo [1]
  1. Pacific Northwest National Laboratory, Richland, USA
  2. Opticslah, LLC, Albuquerque, USA
  3. Opticslah, LLC, Albuquerque, USA, James C. Wyant College of Optical Sciences
Publication Date:
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation (NA-20)
OSTI Identifier:
1605950
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Kautz, Elizabeth J., Yeak, Jeremy, Bernacki, Bruce E., Phillips, Mark C., and Harilal, Sivanandan S. Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas. United Kingdom: N. p., 2020. Web. doi:10.1039/D0CP00078G.
Kautz, Elizabeth J., Yeak, Jeremy, Bernacki, Bruce E., Phillips, Mark C., & Harilal, Sivanandan S. Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas. United Kingdom. doi:10.1039/D0CP00078G.
Kautz, Elizabeth J., Yeak, Jeremy, Bernacki, Bruce E., Phillips, Mark C., and Harilal, Sivanandan S. Wed . "Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas". United Kingdom. doi:10.1039/D0CP00078G.
@article{osti_1605950,
title = {Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas},
author = {Kautz, Elizabeth J. and Yeak, Jeremy and Bernacki, Bruce E. and Phillips, Mark C. and Harilal, Sivanandan S.},
abstractNote = {2D plume and spectral imaging illustrate expansion dynamics and corresponding chemical evolution of atoms and molecules in filament produced plasmas.},
doi = {10.1039/D0CP00078G},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 19, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Femtosecond laser-induced breakdown spectroscopy
journal, January 2016

  • Labutin, Timur A.; Lednev, Vasily N.; Ilyin, Alexey A.
  • Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 1
  • DOI: 10.1039/C5JA00301F

Dynamics of molecular emission features from nanosecond, femtosecond laser and filament ablation plasmas
journal, January 2016

  • Harilal, S. S.; Yeak, J.; Brumfield, B. E.
  • Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 6
  • DOI: 10.1039/C6JA00036C

Physical conditions for UO formation in laser-produced uranium plumes
journal, January 2019

  • Harilal, S. S.; Kautz, E. J.; Bernacki, B. E.
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 29
  • DOI: 10.1039/C9CP02250C

Influence of spot size on propagation dynamics of laser-produced tin plasma
journal, December 2007

  • Harilal, S. S.
  • Journal of Applied Physics, Vol. 102, Issue 12
  • DOI: 10.1063/1.2822450

Kilometer range filamentation
journal, January 2013

  • Durand, Magali; Houard, Aurélien; Prade, Bernard
  • Optics Express, Vol. 21, Issue 22
  • DOI: 10.1364/OE.21.026836

Influence of exothermic chemical reactions on laser-induced shock waves
journal, January 2014

  • Gottfried, Jennifer L.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 39
  • DOI: 10.1039/C4CP02903H

Investigation of nanoparticle generation during femtosecond laser ablation of metals
journal, May 2007


Time-resolved imaging of atoms and molecules in laser-produced uranium plasmas
journal, January 2019

  • Kautz, E. J.; Skrodzki, P. J.; Burger, M.
  • Journal of Analytical Atomic Spectrometry, Vol. 34, Issue 11
  • DOI: 10.1039/C9JA00228F

Electronic spectroscopy and ionization potential of UO2 in the gas phase
journal, March 2004

  • Han, Jiande; Goncharov, Vasiliy; Kaledin, Leonid A.
  • The Journal of Chemical Physics, Vol. 120, Issue 11
  • DOI: 10.1063/1.1647531

Laser-induced plasma temperature
journal, July 2014

  • Zhang, Shudi; Wang, Xiaohua; He, Miaohong
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 97
  • DOI: 10.1016/j.sab.2014.04.009

Plume splitting and oscillatory behavior in transient plasmas generated by high-fluence laser ablation in vacuum
journal, December 2017


Characterization of laser-induced plasmas as a complement to high-explosive large-scale detonations
journal, September 2017

  • Kimblin, Clare; Trainham, Rusty; Capelle, Gene A.
  • AIP Advances, Vol. 7, Issue 9
  • DOI: 10.1063/1.4999793

Dynamics of femtosecond laser produced tungsten nanoparticle plumes
journal, November 2013

  • Harilal, S. S.; Farid, N.; Hassanein, A.
  • Journal of Applied Physics, Vol. 114, Issue 20
  • DOI: 10.1063/1.4833564

Filament-induced remote surface ablation for long range laser-induced breakdown spectroscopy operation
journal, August 2005

  • Rohwetter, Ph.; Stelmaszczyk, K.; Wöste, L.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 60, Issue 7-8
  • DOI: 10.1016/j.sab.2005.03.017

Femtosecond and nanosecond laser induced breakdown spectroscopic studies of NTO, HMX, and RDX
journal, January 2013

  • Sunku, Sreedhar; Gundawar, Manoj Kumar; Myakalwar, Ashwin Kumar
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 79-80
  • DOI: 10.1016/j.sab.2012.11.002

Femtosecond Laser-Induced Breakdown Spectroscopy: Physics, Applications, and Perspectives
journal, October 2007


Dual-comb spectroscopy of laser-induced plasmas
journal, March 2018


Temporally and spectrally resolved imaging of laser-induced plasmas
journal, January 2004


Dynamics of femto- and nanosecond laser ablation plumes investigated using optical emission spectroscopy
journal, November 2012

  • Verhoff, B.; Harilal, S. S.; Freeman, J. R.
  • Journal of Applied Physics, Vol. 112, Issue 9
  • DOI: 10.1063/1.4764060

Laser fluence dependence on emission dynamics of ultrafast laser induced copper plasma
journal, November 2016

  • Anoop, K. K.; Harilal, S. S.; Philip, Reji
  • Journal of Applied Physics, Vol. 120, Issue 18
  • DOI: 10.1063/1.4967313

The effect of excitation wavelength on dynamics of laser-produced tin plasma
journal, March 2011

  • Harilal, S. S.; Sizyuk, T.; Hassanein, A.
  • Journal of Applied Physics, Vol. 109, Issue 6
  • DOI: 10.1063/1.3562143

Plasma temperature clamping in filamentation laser induced breakdown spectroscopy
journal, January 2015

  • Harilal, S. S.; Yeak, J.; Phillips, M. C.
  • Optics Express, Vol. 23, Issue 21
  • DOI: 10.1364/OE.23.027113

Internal structure and expansion dynamics of laser ablation plumes into ambient gases
journal, March 2003

  • Harilal, S. S.; Bindhu, C. V.; Tillack, M. S.
  • Journal of Applied Physics, Vol. 93, Issue 5
  • DOI: 10.1063/1.1544070

Atomic-scale Studies of Uranium Oxidation and Corrosion by Water Vapour
journal, July 2016

  • Martin, T. L.; Coe, C.; Bagot, P. A. J.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep25618

Characteristics of plasma plume in ultrafast laser ablation with a weakly ionized air channel
journal, January 2018


A model of early formation of uranium molecular oxides in laser-ablated plasmas
journal, November 2017

  • Finko, Mikhail S.; Curreli, Davide; Weisz, David G.
  • Journal of Physics D: Applied Physics, Vol. 50, Issue 48
  • DOI: 10.1088/1361-6463/aa92f5

Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes
journal, June 2017


Elucidating uranium monoxide spectral features from a laser-produced plasma
journal, January 2018

  • Harilal, Sivanandan S.; Brumfield, Brian E.; Glumac, Nick
  • Optics Express, Vol. 26, Issue 16
  • DOI: 10.1364/OE.26.020319

Consequences of femtosecond laser filament generation conditions in standoff laser induced breakdown spectroscopy
journal, January 2016

  • Harilal, S. S.; Yeak, J.; Brumfield, B. E.
  • Optics Express, Vol. 24, Issue 16
  • DOI: 10.1364/OE.24.017941

Target properties – Plasma dynamics relationship in laser ablation of metals: Common trends for fs, ps and ns irradiation regimes
journal, March 2020


Filamentation without intensity clamping
journal, January 2010

  • Kiran, P. Prem; Bagchi, Suman; Arnold, Cord L.
  • Optics Express, Vol. 18, Issue 20
  • DOI: 10.1364/OE.18.021504

Multidiagnostic analysis of ion dynamics in ultrafast laser ablation of metals over a large fluence range
journal, February 2015

  • Anoop, K. K.; Polek, M. P.; Bruzzese, R.
  • Journal of Applied Physics, Vol. 117, Issue 8
  • DOI: 10.1063/1.4913505

Hyperfine structures and isotopic shifts of uranium transitions using tunable laser spectroscopy of laser ablation plumes
journal, March 2020

  • Harilal, S. S.; Murzyn, C. M.; Phillips, M. C.
  • Spectrochimica Acta Part B: Atomic Spectroscopy
  • DOI: 10.1016/j.sab.2020.105828

Simulation of uranium plasma plume dynamics in atmospheric oxygen produced via femtosecond laser ablation
journal, August 2018

  • Finko, Mikhail S.; Curreli, Davide
  • Physics of Plasmas, Vol. 25, Issue 8
  • DOI: 10.1063/1.5034470

Shock Waves in Laser-Induced Plasmas
journal, June 2019

  • Campanella, Beatrice; Legnaioli, Stefano; Pagnotta, Stefano
  • Atoms, Vol. 7, Issue 2
  • DOI: 10.3390/atoms7020057

Emission characteristics and dynamics of C2 from laser produced graphite plasma
journal, April 1997

  • Harilal, S. S.; Issac, Riju C.; Bindhu, C. V.
  • Journal of Applied Physics, Vol. 81, Issue 8
  • DOI: 10.1063/1.365482

The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body Unit and Combined System Tests
journal, June 2012

  • Wiens, Roger C.; Maurice, Sylvestre; Barraclough, Bruce
  • Space Science Reviews, Vol. 170, Issue 1-4
  • DOI: 10.1007/s11214-012-9902-4

Optimization of distances between the target surface and focal point on spatially confined laser-induced breakdown spectroscopy with a cylindrical cavity
journal, January 2017

  • Guo, Jin; Shao, Junfeng; Wang, Tingfeng
  • Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 2
  • DOI: 10.1039/C6JA00396F

Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry
journal, March 2017

  • Hartig, Kyle C.; Ghebregziabher, Isaac; Jovanovic, Igor
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep43852

Plume splitting and sharpening in laser-produced aluminium plasma
journal, November 2002

  • Harilal, S. S.; Bindhu, C. V.; Tillack, M. S.
  • Journal of Physics D: Applied Physics, Vol. 35, Issue 22
  • DOI: 10.1088/0022-3727/35/22/307

Long-distance remote laser-induced breakdown spectroscopy using filamentation in air
journal, November 2004

  • Stelmaszczyk, Kamil; Rohwetter, Philipp; Méjean, Guillaume
  • Applied Physics Letters, Vol. 85, Issue 18
  • DOI: 10.1063/1.1812843

Ab initio study on the reaction of uranium with oxygen
journal, February 2013

  • Zeng, Xiu-Lin; Huang, Shan-Qisong; Ju, Xue-Hai
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 298, Issue 1
  • DOI: 10.1007/s10967-013-2442-x

Femtosecond, picosecond and nanosecond laser ablation of solids
journal, August 1996

  • Chichkov, B. N.; Momma, C.; Nolte, S.
  • Applied Physics A Materials Science & Processing, Vol. 63, Issue 2
  • DOI: 10.1007/BF01567637

Plume dynamics and gas-phase molecular formation in transient laser-produced uranium plasmas
journal, August 2019

  • Skrodzki, P. J.; Burger, M.; Jovanovic, I.
  • Physics of Plasmas, Vol. 26, Issue 8
  • DOI: 10.1063/1.5087704

Molecular signatures in femtosecond laser-induced organic plasmas: comparison with nanosecond laser ablation
journal, January 2016

  • Serrano, Jorge; Moros, Javier; Javier Laserna, J.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 4
  • DOI: 10.1039/C5CP06456B

Tracking of oxide formation in laser-produced uranium plasmas
journal, January 2018

  • Skrodzki, P. J.; Burger, M.; Jovanovic, I.
  • Optics Letters, Vol. 43, Issue 20
  • DOI: 10.1364/OL.43.005118

Single-shot, multi-signature remote detection of uranium by filament-induced breakdown spectroscopy
journal, January 2019

  • Finney, L. A.; Skrodzki, P. J.; Burger, M.
  • Optics Letters, Vol. 44, Issue 11
  • DOI: 10.1364/OL.44.002783

Progress of laser-induced breakdown spectroscopy in nuclear industry applications
journal, October 2019


Correlation of molecular, atomic emissions with detonation parameters in femtosecond and nanosecond LIBS plasma of high energy materials
journal, January 2017

  • Kalam, S. Abdul; Murthy, N. Linga; Mathi, P.
  • Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 8
  • DOI: 10.1039/C7JA00136C

Two-dimensional imaging of atomic and nanoparticle components in copper plasma plume produced by ultrafast laser ablation
journal, January 2014


A comparison of nanosecond and femtosecond laser-induced plasma spectroscopy of brass samples
journal, November 2000


Spectroscopic study of a lead plasma produced by the 1064nm, 532nm and 355nm of a Nd:YAG laser
journal, October 2013

  • Shaikh, Nek. M.; Kalhoro, M. S.; Hussain, Abid
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 88
  • DOI: 10.1016/j.sab.2013.07.007

Significance of ambient conditions in uranium absorption and emission features of laser ablation plasmas
journal, November 2016

  • Skrodzki, P. J.; Shah, N. P.; Taylor, N.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 125
  • DOI: 10.1016/j.sab.2016.09.012

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis
journal, June 2018

  • Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.
  • Applied Physics Reviews, Vol. 5, Issue 2
  • DOI: 10.1063/1.5016053

Tightly focused femtosecond laser pulse in air: from filamentation to breakdown
journal, January 2010


Effects of Plume Hydrodynamics and Oxidation on the Composition of a Condensing Laser-Induced Plasma
journal, February 2018

  • Weisz, David G.; Crowhurst, Jonathan C.; Finko, Mikhail S.
  • The Journal of Physical Chemistry A, Vol. 122, Issue 6
  • DOI: 10.1021/acs.jpca.7b11994

Comparison of optical emission from nanosecond and femtosecond laser produced plasma in atmosphere and vacuum conditions
journal, September 2013

  • Freeman, J. R.; Harilal, S. S.; Diwakar, P. K.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 87
  • DOI: 10.1016/j.sab.2013.05.011