skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on March 16, 2021

Title: Aqueous electrocatalytic CO 2 reduction using metal complexes dispersed in polymer ion gels

Abstract

The polymer ion gel support can improve electrocatalytic CO 2 reduction using metal complex catalysts in water.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. The Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1605612
Grant/Contract Number:  
[SC0004993]
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
[Journal Name: ChemComm]; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Sato, Shunsuke, McNicholas, Brendon J., and Grubbs, Robert H. Aqueous electrocatalytic CO 2 reduction using metal complexes dispersed in polymer ion gels. United Kingdom: N. p., 2020. Web. doi:10.1039/D0CC00791A.
Sato, Shunsuke, McNicholas, Brendon J., & Grubbs, Robert H. Aqueous electrocatalytic CO 2 reduction using metal complexes dispersed in polymer ion gels. United Kingdom. doi:10.1039/D0CC00791A.
Sato, Shunsuke, McNicholas, Brendon J., and Grubbs, Robert H. Wed . "Aqueous electrocatalytic CO 2 reduction using metal complexes dispersed in polymer ion gels". United Kingdom. doi:10.1039/D0CC00791A.
@article{osti_1605612,
title = {Aqueous electrocatalytic CO 2 reduction using metal complexes dispersed in polymer ion gels},
author = {Sato, Shunsuke and McNicholas, Brendon J. and Grubbs, Robert H.},
abstractNote = {The polymer ion gel support can improve electrocatalytic CO 2 reduction using metal complex catalysts in water.},
doi = {10.1039/D0CC00791A},
journal = {ChemComm},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 16, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Superior Inorganic Ion Cofactors of Tetraborate Species Attaining Highly Efficient Heterogeneous Electrocatalysis for Water Oxidation on Cobalt Oxyhydroxide Nanoparticles
journal, October 2017

  • Takeuchi, Ryouchi; Sato, Tetsuya; Tanaka, Kou
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 42
  • DOI: 10.1021/acsami.7b13817

Ligand Variations in [ReX(diimine)(CO)3] Complexes: Effects on Photocatalytic CO2 Reduction
journal, August 2006

  • Kurz, Philipp; Probst, Benjamin; Spingler, Bernhard
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 15
  • DOI: 10.1002/ejic.200600166

Thermodynamic Aspects of Electrocatalytic CO 2 Reduction in Acetonitrile and with an Ionic Liquid as Solvent or Electrolyte
journal, October 2015


A monolithic device for CO 2 photoreduction to generate liquid organic substances in a single-compartment reactor
journal, January 2015

  • Arai, Takeo; Sato, Shunsuke; Morikawa, Takeshi
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01314C

Low-Energy Electrocatalytic CO 2 Reduction in Water over Mn-Complex Catalyst Electrode Aided by a Nanocarbon Support and K + Cations
journal, April 2018


Transition Metal Oxides as Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Solutions: An Application-Inspired Renaissance
journal, May 2018

  • Song, Fang; Bai, Lichen; Moysiadou, Aliki
  • Journal of the American Chemical Society, Vol. 140, Issue 25
  • DOI: 10.1021/jacs.8b04546

Kinetics of Electrochemical Reduction of Carbon Dioxide on a Gold Electrode in Phosphate Buffer Solutions
journal, July 1995

  • Noda, Hidetomo; Ikeda, Shoichiro; Yamamoto, Akio
  • Bulletin of the Chemical Society of Japan, Vol. 68, Issue 7
  • DOI: 10.1246/bcsj.68.1889

Surface-Immobilized Conjugated Polymers Incorporating Rhenium Bipyridine Motifs for Electrocatalytic and Photocatalytic CO 2 Reduction
journal, December 2018

  • Orchanian, Nicholas M.; Hong, Lorena E.; Skrainka, John A.
  • ACS Applied Energy Materials, Vol. 2, Issue 1
  • DOI: 10.1021/acsaem.8b01745

Selective Electrocatalysis of a Water-Soluble Rhenium(I) Complex for CO 2 Reduction Using Water As an Electron Donor
journal, December 2017


Reduction of CO 2 on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle
journal, April 2011

  • Agarwal, Jay; Johnson, Richard P.; Li, Gonghu
  • The Journal of Physical Chemistry A, Vol. 115, Issue 13
  • DOI: 10.1021/jp111342r

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
journal, May 2012

  • Smieja, J. M.; Benson, E. E.; Kumar, B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1119863109

Combination of ionic liquids with membrane technology: A new approach for CO2 separation
journal, January 2016


Ionic liquids and derived materials for lithium and sodium batteries
journal, January 2018

  • Yang, Qiwei; Zhang, Zhaoqiang; Sun, Xiao-Guang
  • Chemical Society Reviews, Vol. 47, Issue 6
  • DOI: 10.1039/C7CS00464H

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011

  • Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
  • Science, Vol. 334, Issue 6056, p. 643-644
  • DOI: 10.1126/science.1209786

Mechanisms for CO Production from CO 2 Using Reduced Rhenium Tricarbonyl Catalysts
journal, March 2012

  • Agarwal, Jay; Fujita, Etsuko; Schaefer, Henry F.
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja2105834

Ionic-Liquid-Based CO 2 Capture Systems: Structure, Interaction and Process
journal, May 2017


Electrocatalytic CO 2 reduction near the theoretical potential in water using Ru complex supported on carbon nanotubes
journal, December 2017


Efficient and selective molecular catalyst for the CO 2 -to-CO electrochemical conversion in water
journal, May 2015

  • Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 22
  • DOI: 10.1073/pnas.1507063112

A local proton source in a [Mn(bpy-R)(CO) 3 Br]-type redox catalyst enables CO 2 reduction even in the absence of Brønsted acids
journal, January 2014

  • Franco, Federico; Cometto, Claudio; Ferrero Vallana, Federico
  • Chem. Commun., Vol. 50, Issue 93
  • DOI: 10.1039/C4CC05563B

Graphite-Conjugated Rhenium Catalysts for Carbon Dioxide Reduction
journal, February 2016

  • Oh, Seokjoon; Gallagher, James R.; Miller, Jeffrey T.
  • Journal of the American Chemical Society, Vol. 138, Issue 6
  • DOI: 10.1021/jacs.5b13080

Photophysical properties of polypyridyl carbonyl complexes of rhenium(I)
journal, January 1991

  • Worl, Laura A.; Duesing, Rich; Chen, Pingyun
  • Journal of the Chemical Society, Dalton Transactions, Issue S
  • DOI: 10.1039/dt9910000849

Electrocatalytic CO 2 Reduction with a Homogeneous Catalyst in Ionic Liquid: High Catalytic Activity at Low Overpotential
journal, May 2014

  • Grills, David C.; Matsubara, Yasuo; Kuwahara, Yutaka
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 11
  • DOI: 10.1021/jz500759x

Inorganic/Organic Double‐Network Gels Containing Ionic Liquids
journal, November 2017


Photoreduction of CO 2 to CO by a mononuclear Re( i ) complex and DFT evaluation of the photocatalytic mechanism
journal, January 2015

  • Shakeri, Jamaladin; Farrokhpour, Hossein; Hadadzadeh, Hassan
  • RSC Advances, Vol. 5, Issue 51
  • DOI: 10.1039/C5RA02002F

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation
journal, April 2014

  • Trotochaud, Lena; Young, Samantha L.; Ranney, James K.
  • Journal of the American Chemical Society, Vol. 136, Issue 18
  • DOI: 10.1021/ja502379c

A High Yield Synthesis of Ligand-Free Iridium Oxide Nanoparticles with High Electrocatalytic Activity
journal, February 2011

  • Zhao, Yixin; Hernandez-Pagan, Emil A.; Vargas-Barbosa, Nella M.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 5
  • DOI: 10.1021/jz200051c

Selective Reduction of CO 2 to CO by a Molecular Re(ethynyl-bpy)(CO) 3 Cl Catalyst and Attachment to Carbon Electrode Surfaces
journal, October 2018


Development of an Efficient Photocatalytic System for CO 2 Reduction Using Rhenium(I) Complexes Based on Mechanistic Studies
journal, February 2008

  • Takeda, Hiroyuki; Koike, Kazuhide; Inoue, Haruo
  • Journal of the American Chemical Society, Vol. 130, Issue 6
  • DOI: 10.1021/ja077752e

Unexpected wavelength dependency of the photocatalytic CO 2 reduction performance of the well-known (bpy)Re(CO) 3 Cl complex
journal, January 2019

  • Lang, Philipp; Giereth, Robin; Tschierlei, Stefanie
  • Chemical Communications, Vol. 55, Issue 5
  • DOI: 10.1039/C8CC08742C

A mechanistic investigation of the photoinduced reduction of carbon dioxide mediated by tricarbonylbromo(2,2'-bipyridine)rhenium(I)
journal, December 1985

  • Kutal, Charles.; Weber, Michael A.; Ferraudi, Guillermo.
  • Organometallics, Vol. 4, Issue 12
  • DOI: 10.1021/om00131a016

A Thiourea Tether in the Second Coordination Sphere as a Binding Site for CO 2 and a Proton Donor Promotes the Electrochemical Reduction of CO 2 to CO Catalyzed by a Rhenium Bipyridine-Type Complex
journal, September 2018

  • Haviv, Eynat; Azaiza-Dabbah, Dima; Carmieli, Raanan
  • Journal of the American Chemical Society, Vol. 140, Issue 39
  • DOI: 10.1021/jacs.8b05658

Electrocatalysis of CO 2 Reduction in Brush Polymer Ion Gels
journal, August 2016

  • McNicholas, Brendon J.; Blakemore, James D.; Chang, Alice B.
  • Journal of the American Chemical Society, Vol. 138, Issue 35
  • DOI: 10.1021/jacs.6b08795

A self-generated and degradation-resistive cratered stainless steel electrocatalyst for efficient water oxidation in a neutral electrolyte
journal, January 2017

  • Lee, Minoh; Jeon, Hyo Sang; Lee, Si Young
  • Journal of Materials Chemistry A, Vol. 5, Issue 36
  • DOI: 10.1039/C7TA05932A

Efficient photocatalytic CO2 reduction using [Re(bpy) (CO)3{P(OEt)3}]+
journal, May 1996

  • Hori, Hisao; Johnson, Frank P. A.; Koike, Kazuhide
  • Journal of Photochemistry and Photobiology A: Chemistry, Vol. 96, Issue 1-3
  • DOI: 10.1016/1010-6030(95)04298-9

Polymer electrolytes integrated with ionic liquids for future electrochemical devices
journal, February 2013

  • Park, Moon Jeong; Choi, Ilyoung; Hong, Jaewan
  • Journal of Applied Polymer Science, Vol. 129, Issue 5
  • DOI: 10.1002/app.39064

Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
journal, January 2018

  • Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah
  • Advanced Energy Materials, Vol. 8, Issue 11
  • DOI: 10.1002/aenm.201702774

A Highly Efficient Mononuclear Iridium Complex Photocatalyst for CO 2 Reduction under Visible Light
journal, November 2012

  • Sato, Shunsuke; Morikawa, Takeshi; Kajino, Tsutomu
  • Angewandte Chemie International Edition, Vol. 52, Issue 3
  • DOI: 10.1002/anie.201206137

Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

  • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001679