Utilizing an In Situ Reduction in the Synthesis of BaMoOF5

Felder, Justin B.; Smith, Mark D.; zur Loye, Hans-Conrad

doi:10.1007/s10870-018-00767-0

Title: Utilizing an In Situ Reduction in the Synthesis of BaMoOF₅

Journal Article · 02 January 2019 · Journal of Chemical Crystallography

DOI: https://doi.org/10.1007/s10870-018-00767-0 · OSTI ID:1605383

Felder, Justin B. ^[1]; Smith, Mark D. ^[2];

^[2]

Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemistry and Biochemistry; University of South Carolina
Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemistry and Biochemistry

A new molybdenum containing oxyfluoride, BaMoOF₅, space group Cmcm with lattice parameters of a = 7.1445(3), b = 6.7894(3), c = 10.1969(4), was synthesized via a mild hydrothermal crystal growth method. The synthesis resulted in high-quality single crystals of the title material, which were characterized by single-crystal X-ray diffraction. Here, the structure is discussed in detail.

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Research Organization:: Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0018739

OSTI ID:: 1605383

Journal Information:: Journal of Chemical Crystallography, Journal Name: Journal of Chemical Crystallography Journal Issue: 1 Vol. 49; ISSN 1074-1542

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Crystal growth
Mild hydrothermal
in situ reduction

Title: Utilizing an In Situ Reduction in the Synthesis of BaMoOF5

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Title: Utilizing an In Situ Reduction in the Synthesis of BaMoOF₅