Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2
Abstract
Catalysts consisting of atomically dispersed Pt (Ptiso) species on CeO2 supports have received recent interest due to their potential for efficient metal utilization in catalytic convertors. However, discrepancies exist between the behavior (reducibility, interaction strength with adsorbates) of high surface area Ptiso/CeO2 systems and of well-defined surface science and computational model systems, suggesting differences in Pt local coordination in the two classes of materials. Here, we reconcile these differences by demonstrating that high surface area Ptiso/CeO2 synthesized at low Pt loadings (<0.1% weight) exhibit resistance to reduction and sintering up to 500 °C in 0.05 bar H2 and minimal interactions with CO—properties previously seen only for model system studies. Alternatively, Pt loadings >0.1 weight % produce a distribution of sub-nanometer Pt structures, which are difficult to distinguish using common characterization techniques, and exhibit strong interactions with CO and weak resistance to sintering, even in 0.05 bar H2 at 50 °C—properties previously seen for high surface area materials. This work demonstrates that low metal loadings can be used to selectively populate the most thermodynamically stable adsorption sites on high surface area supports with atomically dispersed metals. Further, the site uniformity afforded by this synthetic approach is critical for the development ofmore »
- Authors:
-
- Univ. of California, Santa Barbara, CA (United States). Dept. of Chemical Engineering
- Fok Ying Tung Research Institute, Hong Kong University of Science and Technology, Guangzhou 511458, PR China
- Univ. of California, Irvine, CA (United States)
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
- Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1605339
- Grant/Contract Number:
- AC02-76SF00515; CBET-1554112; DMR-1720256
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 142; Journal Issue: 1; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Redox reactions; Platinum; Adsorption; Catalysts; Cluster chemistry
Citation Formats
Resasco, Joaquin, DeRita, Leo, Dai, Sheng, Chada, Joseph P., Xu, Mingjie, Yan, Xingxu, Finzel, Jordan, Hanukovich, Sergei, Hoffman, Adam S., Graham, George W., Bare, Simon R., Pan, Xiaoqing, and Christopher, Phillip. Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2. United States: N. p., 2019.
Web. doi:10.1021/jacs.9b09156.
Resasco, Joaquin, DeRita, Leo, Dai, Sheng, Chada, Joseph P., Xu, Mingjie, Yan, Xingxu, Finzel, Jordan, Hanukovich, Sergei, Hoffman, Adam S., Graham, George W., Bare, Simon R., Pan, Xiaoqing, & Christopher, Phillip. Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2. United States. https://doi.org/10.1021/jacs.9b09156
Resasco, Joaquin, DeRita, Leo, Dai, Sheng, Chada, Joseph P., Xu, Mingjie, Yan, Xingxu, Finzel, Jordan, Hanukovich, Sergei, Hoffman, Adam S., Graham, George W., Bare, Simon R., Pan, Xiaoqing, and Christopher, Phillip. Mon .
"Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2". United States. https://doi.org/10.1021/jacs.9b09156. https://www.osti.gov/servlets/purl/1605339.
@article{osti_1605339,
title = {Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2},
author = {Resasco, Joaquin and DeRita, Leo and Dai, Sheng and Chada, Joseph P. and Xu, Mingjie and Yan, Xingxu and Finzel, Jordan and Hanukovich, Sergei and Hoffman, Adam S. and Graham, George W. and Bare, Simon R. and Pan, Xiaoqing and Christopher, Phillip},
abstractNote = {Catalysts consisting of atomically dispersed Pt (Ptiso) species on CeO2 supports have received recent interest due to their potential for efficient metal utilization in catalytic convertors. However, discrepancies exist between the behavior (reducibility, interaction strength with adsorbates) of high surface area Ptiso/CeO2 systems and of well-defined surface science and computational model systems, suggesting differences in Pt local coordination in the two classes of materials. Here, we reconcile these differences by demonstrating that high surface area Ptiso/CeO2 synthesized at low Pt loadings (<0.1% weight) exhibit resistance to reduction and sintering up to 500 °C in 0.05 bar H2 and minimal interactions with CO—properties previously seen only for model system studies. Alternatively, Pt loadings >0.1 weight % produce a distribution of sub-nanometer Pt structures, which are difficult to distinguish using common characterization techniques, and exhibit strong interactions with CO and weak resistance to sintering, even in 0.05 bar H2 at 50 °C—properties previously seen for high surface area materials. This work demonstrates that low metal loadings can be used to selectively populate the most thermodynamically stable adsorption sites on high surface area supports with atomically dispersed metals. Further, the site uniformity afforded by this synthetic approach is critical for the development of relationships between atomic scale local coordination and functional properties. Comparisons to recent studies of Ptiso/TiO2 suggest a general compromise between the stability of atomically dispersed metal catalysts and their ability to interact with and activate molecular species.},
doi = {10.1021/jacs.9b09156},
journal = {Journal of the American Chemical Society},
number = 1,
volume = 142,
place = {United States},
year = {Mon Dec 09 00:00:00 EST 2019},
month = {Mon Dec 09 00:00:00 EST 2019}
}
Web of Science
Works referenced in this record:
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
journal, April 2018
- Liu, Lichen; Corma, Avelino
- Chemical Reviews, Vol. 118, Issue 10
Atomically Dispersed Supported Metal Catalysts
journal, July 2012
- Flytzani-Stephanopoulos, Maria; Gates, Bruce C.
- Annual Review of Chemical and Biomolecular Engineering, Vol. 3, Issue 1
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016
- Jones, J.; Xiong, H.; DeLaRiva, A. T.
- Science, Vol. 353, Issue 6295
Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support
journal, February 2019
- Kunwar, Deepak; Zhou, Shulan; DeLaRiva, Andrew
- ACS Catalysis, Vol. 9, Issue 5
Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017
- Nie, Lei; Mei, Donghai; Xiong, Haifeng
- Science, Vol. 358, Issue 6369
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017
- Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
- Nature Communications, Vol. 8, Issue 1
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Homogeneity of Surface Sites in Supported Single-Site Metal Catalysts: Assessment with Band Widths of Metal Carbonyl Infrared Spectra
journal, September 2016
- Hoffman, Adam S.; Fang, Chia-Yu; Gates, Bruce C.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 19
Beating Heterogeneity of Single-Site Catalysts: MgO-Supported Iridium Complexes
journal, March 2018
- Hoffman, Adam S.; Debefve, Louise M.; Zhang, Shengjie
- ACS Catalysis, Vol. 8, Issue 4
Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO 2
journal, September 2017
- DeRita, Leo; Dai, Sheng; Lopez-Zepeda, Kimberly
- Journal of the American Chemical Society, Vol. 139, Issue 40
Nature of stable single atom Pt catalysts dispersed on anatase TiO2
journal, November 2018
- Thang, Ho Viet; Pacchioni, Gianfranco; DeRita, Leo
- Journal of Catalysis, Vol. 367
Non defect-stabilized thermally stable single-atom catalyst
journal, January 2019
- Lang, Rui; Xi, Wei; Liu, Jin-Cheng
- Nature Communications, Vol. 10, Issue 1
Atomically Dispersed Reduced Graphene Aerogel-Supported Iridium Catalyst with an Iridium Loading of 14.8 wt %
journal, July 2019
- Babucci, Melike; Sarac Oztuna, F. Eylul; Debefve, Louise M.
- ACS Catalysis, Vol. 9, Issue 11
Molecular models of site-isolated cobalt, rhodium, and iridium catalysts supported on zeolites: Ligand bond dissociation energies
journal, December 2015
- Chen, Mingyang; Serna, Pedro; Lu, Jing
- Computational and Theoretical Chemistry, Vol. 1074
Zeolite-Supported Organorhodium Fragments: Essentially Molecular Surface Chemistry Elucidated with Spectroscopy and Theory
journal, June 2009
- Liang, Ann J.; Craciun, Raluca; Chen, Mingyang
- Journal of the American Chemical Society, Vol. 131, Issue 24
Achieving Atomic Dispersion of Highly Loaded Transition Metals in Small‐Pore Zeolite SSZ‐13: High‐Capacity and High‐Efficiency Low‐Temperature CO and Passive NO x Adsorbers
journal, November 2018
- Khivantsev, Konstantin; Jaegers, Nicholas R.; Kovarik, Libor
- Angewandte Chemie, Vol. 130, Issue 51
Effect of Si/Al Ratio and Rh Precursor Used on the Synthesis of HY Zeolite-Supported Rhodium Carbonyl Hydride Complexes
journal, July 2015
- Khivantsev, Konstantin; Vityuk, Artem; Aleksandrov, Hristiyan A.
- The Journal of Physical Chemistry C, Vol. 119, Issue 30
Synthesis, Modeling, and Catalytic Properties of HY Zeolite-Supported Rhodium Dinitrosyl Complexes
journal, August 2017
- Khivantsev, Konstantin; Vityuk, Artem; Aleksandrov, Hristiyan A.
- ACS Catalysis, Vol. 7, Issue 9
High-Energy-Resolution X-ray Absorption Spectroscopy for Identification of Reactive Surface Species on Supported Single-Site Iridium Catalysts
journal, July 2017
- Hoffman, Adam S.; Sokaras, Dimosthenis; Zhang, Shengjie
- Chemistry - A European Journal, Vol. 23, Issue 59
Structural evolution of atomically dispersed Pt catalysts dictates reactivity
journal, April 2019
- DeRita, Leo; Resasco, Joaquin; Dai, Sheng
- Nature Materials, Vol. 18, Issue 7
Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum
journal, June 2014
- Bruix, Albert; Lykhach, Yaroslava; Matolínová, Iva
- Angewandte Chemie International Edition, Vol. 53, Issue 39
Adsorption, Oxidation State, and Diffusion of Pt Atoms on the CeO 2 (111) Surface
journal, July 2010
- Bruix, Albert; Neyman, Konstantin M.; Illas, Francesc
- The Journal of Physical Chemistry C, Vol. 114, Issue 33
Creating single-atom Pt-ceria catalysts by surface step decoration
journal, February 2016
- Dvořák, Filip; Farnesi Camellone, Matteo; Tovt, Andrii
- Nature Communications, Vol. 7, Issue 1
Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
journal, March 2011
- Vayssilov, Georgi N.; Lykhach, Yaroslava; Migani, Annapaola
- Nature Materials, Vol. 10, Issue 4
The structure and stability of reduced and oxidized mononuclear platinum species on nanostructured ceria from density functional modeling
journal, January 2015
- Aleksandrov, Hristiyan A.; Neyman, Konstantin M.; Vayssilov, Georgi N.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 22
Reactivity of atomically dispersed Pt 2+ species towards H 2 : model Pt–CeO 2 fuel cell catalyst
journal, January 2016
- Lykhach, Yaroslava; Figueroba, Alberto; Camellone, Matteo Farnesi
- Physical Chemistry Chemical Physics, Vol. 18, Issue 11
Atomically Dispersed Pd, Ni, and Pt Species in Ceria-Based Catalysts: Principal Differences in Stability and Reactivity
journal, April 2016
- Neitzel, Armin; Figueroba, Alberto; Lykhach, Yaroslava
- The Journal of Physical Chemistry C, Vol. 120, Issue 18
Surface sites on Pt–CeO 2 mixed oxide catalysts probed by CO adsorption: a synchrotron radiation photoelectron spectroscopy study
journal, January 2014
- Neitzel, Armin; Lykhach, Yaroslava; Skála, Tomáš
- Phys. Chem. Chem. Phys., Vol. 16, Issue 45
Role of Site Stability in Methane Activation on Pd x Ce 1 –x O δ Surfaces
journal, September 2015
- Senftle, Thomas P.; van Duin, Adri C. T.; Janik, Michael J.
- ACS Catalysis, Vol. 5, Issue 10
Theoretical Investigations of Pt 1 @CeO 2 Single-Atom Catalyst for CO Oxidation
journal, May 2017
- Tang, Yan; Wang, Yang-Gang; Li, Jun
- The Journal of Physical Chemistry C, Vol. 121, Issue 21
Can the state of platinum species be unambiguously determined by the stretching frequency of an adsorbed CO probe molecule?
journal, January 2016
- Aleksandrov, Hristiyan A.; Neyman, Konstantin M.; Hadjiivanov, Konstantin I.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 32
The Energetics of Supported Metal Nanoparticles: Relationships to Sintering Rates and Catalytic Activity
journal, April 2013
- Campbell, Charles T.
- Accounts of Chemical Research, Vol. 46, Issue 8
Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt 1 Catalyst
journal, December 2016
- Wang, Chunlei; Gu, Xiang-Kui; Yan, Huan
- ACS Catalysis, Vol. 7, Issue 1
Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen
journal, March 2019
- Pereira-Hernández, Xavier Isidro; DeLaRiva, Andrew; Muravev, Valery
- Nature Communications, Vol. 10, Issue 1
Nanoceria-Supported Single-Atom Platinum Catalysts for Direct Methane Conversion
journal, April 2018
- Xie, Pengfei; Pu, Tiancheng; Nie, Anmin
- ACS Catalysis, Vol. 8, Issue 5
The Effect of Size-Dependent Nanoparticle Energetics on Catalyst Sintering
journal, October 2002
- Campbell, C. T.
- Science, Vol. 298, Issue 5594
Trends in Adhesion Energies of Metal Nanoparticles on Oxide Surfaces: Understanding Support Effects in Catalysis and Nanotechnology
journal, January 2017
- Hemmingson, Stephanie L.; Campbell, Charles T.
- ACS Nano, Vol. 11, Issue 2
Interaction trends between single metal atoms and oxide supports identified with density functional theory and statistical learning
journal, July 2018
- O’Connor, Nolan J.; Jonayat, A. S. M.; Janik, Michael J.
- Nature Catalysis, Vol. 1, Issue 7
In situ observation of phase changes of a silica-supported cobalt catalyst for the Fischer–Tropsch process by the development of a synchrotron-compatible in situ/operando powder X-ray diffraction cell
journal, October 2018
- Hoffman, Adam S.; Singh, Joseph A.; Bent, Stacey F.
- Journal of Synchrotron Radiation, Vol. 25, Issue 6
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Quantitative Analysis of Adsorbate Concentrations by Diffuse Reflectance FT-IR
journal, May 2007
- Sirita, Jinda; Phanichphant, Sukon; Meunier, Frederic C.
- Analytical Chemistry, Vol. 79, Issue 10
Tuning the Structure of Platinum Particles on Ceria In Situ for Enhancing the Catalytic Performance of Exhaust Gas Catalysts
journal, September 2017
- Gänzler, Andreas M.; Casapu, Maria; Vernoux, Philippe
- Angewandte Chemie International Edition, Vol. 56, Issue 42
Room-Temperature CO Oxidation Catalyst: Low-Temperature Metal–Support Interaction between Platinum Nanoparticles and Nanosized Ceria
journal, August 2016
- Gatla, Suresh; Aubert, Daniel; Agostini, Giovanni
- ACS Catalysis, Vol. 6, Issue 9
Understanding the Influence of the Pretreatment Procedure on Platinum Particle Size and Particle-Size Distribution for SiO2 Impregnated with [Pt2+(NH3)4](NO3−)2: A Combination of HRTEM, Mass Spectrometry, and Quick EXAFS
journal, January 2002
- Oudenhuijzen, M. K.; Kooyman, P. J.; Tappel, B.
- Journal of Catalysis, Vol. 205, Issue 1
Atomically Dispersed Supported Metal Catalysts: Seeing Is Believing
journal, April 2019
- Gates, Bruce C.
- Trends in Chemistry, Vol. 1, Issue 1
Visibility of Single Atoms
journal, June 1970
- Crewe, A. V.; Wall, J.; Langmore, J.
- Science, Vol. 168, Issue 3937
On the imaging of Pt atoms in zeolite frameworks
journal, November 1990
- Rice, S. B.; Koo, J. Y.; Disko, M. M.
- Ultramicroscopy, Vol. 34, Issue 1-2
Chemical Potential of Metal Atoms in Supported Nanoparticles: Dependence upon Particle Size and Support
journal, November 2017
- Campbell, Charles T.; Mao, Zhongtian
- ACS Catalysis, Vol. 7, Issue 12
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Combining In-Situ Transmission Electron Microscopy and Infrared Spectroscopy for Understanding Dynamic and Atomic-Scale Features of Supported Metal Catalysts
journal, June 2018
- Resasco, Joaquin; Dai, Sheng; Graham, George
- The Journal of Physical Chemistry C, Vol. 122, Issue 44
Nature of the metal-support interface in supported metal catalysts: Results from X-ray absorption spectroscopy
journal, January 1992
- Koningsberger, D. C.; Gates, B. C.
- Catalysis Letters, Vol. 14, Issue 3-4
Structural Insight into Strong Pt–CeO 2 Interaction: From Single Pt Atoms to PtO x Clusters
journal, December 2018
- Derevyannikova, Elizaveta A.; Kardash, Tatyana Yu; Stadnichenko, Andrey I.
- The Journal of Physical Chemistry C, Vol. 123, Issue 2
Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts
journal, September 2017
- Asokan, Chithra; DeRita, Leo; Christopher, Phillip
- Chinese Journal of Catalysis, Vol. 38, Issue 9
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015
- Ding, K.; Gulec, A.; Johnson, A. M.
- Science, Vol. 350, Issue 6257
FT-IR study of CO adsorption on Pt/CeO2: characterisation and structural rearrangement of small Pt particles
journal, January 2005
- Bazin, P.; Saur, O.; Lavalley, J. C.
- Physical Chemistry Chemical Physics, Vol. 7, Issue 1
Strong Local Coordination Structure Effects on Subnanometer PtO x Clusters over CeO 2 Nanowires Probed by Low-Temperature CO Oxidation
journal, August 2015
- Ke, Jun; Zhu, Wei; Jiang, Yingying
- ACS Catalysis, Vol. 5, Issue 9
binding states of CO and H2 on clean and oxidized (111)Pt
journal, June 1977
- McCabe, R. W.; Schmidt, L. D.
- Surface Science, Vol. 65, Issue 1
Utilizing Quantitative in Situ FTIR Spectroscopy To Identify Well-Coordinated Pt Atoms as the Active Site for CO Oxidation on Al 2 O 3 -Supported Pt Catalysts
journal, July 2016
- Kale, Matthew J.; Christopher, Phillip
- ACS Catalysis, Vol. 6, Issue 8
Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part I: Oxidation state and surface species on Pt/CeO2 under reaction conditions
journal, January 2006
- Pozdnyakova, O.; Teschner, D.; Wootsch, A.
- Journal of Catalysis, Vol. 237, Issue 1
Quantitative and Atomic-Scale View of CO-Induced Pt Nanoparticle Surface Reconstruction at Saturation Coverage via DFT Calculations Coupled with in Situ TEM and IR
journal, March 2017
- Avanesian, Talin; Dai, Sheng; Kale, Matthew J.
- Journal of the American Chemical Society, Vol. 139, Issue 12
Adsorption of carbon monoxide and carbon dioxide on cerium oxide studied by Fourier-transform infrared spectroscopy. Part 2.—Formation of formate species on partially reduced CeO2 at room temperature
journal, January 1989
- Li, Can; Sakata, Yoshihisa; Arai, Toru
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 6
Quantitative analysis of the reactivity of formate species seen by DRIFTS over a Au/Ce(La)O2 water–gas shift catalyst: First unambiguous evidence of the minority role of formates as reaction intermediates
journal, April 2007
- Meunier, F.; Reid, D.; Goguet, A.
- Journal of Catalysis, Vol. 247, Issue 2
On the usefulness of carbon isotopic exchange for the operando analysis of metal–carbonyl bands by IR over ceria-containing catalysts
journal, March 2008
- Daly, H.; Ni, J.; Thompsett, D.
- Journal of Catalysis, Vol. 254, Issue 2
Counting electrons on supported nanoparticles
journal, December 2015
- Lykhach, Yaroslava; Kozlov, Sergey M.; Skála, Tomáš
- Nature Materials, Vol. 15, Issue 3
Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts
journal, August 2019
- Daelman, Nathan; Capdevila-Cortada, Marçal; López, Núria
- Nature Materials, Vol. 18, Issue 11
Local Structure and Electronic State of Atomically Dispersed Pt Supported on Nanosized CeO 2
journal, August 2019
- Kottwitz, Matthew; Li, Yuanyuan; Palomino, Robert M.
- ACS Catalysis, Vol. 9, Issue 9
Study of CO Oxidation Kinetics on Rh/Ceria
journal, November 1995
- Bunluesin, T.; Cordatos, H.; Gorte, R. J.
- Journal of Catalysis, Vol. 157, Issue 1
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013
- Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R.
- Science, Vol. 341, Issue 6147
Evidence for a Second CO Oxidation Mechanism on Rh/Ceria
journal, September 1993
- Zafiris, G. S.; Gorte, R. J.
- Journal of Catalysis, Vol. 143, Issue 1
Enhanced CO Oxidation Rates at the Interface of Mesoporous Oxides and Pt Nanoparticles
journal, October 2013
- An, Kwangjin; Alayoglu, Selim; Musselwhite, Nathan
- Journal of the American Chemical Society, Vol. 135, Issue 44
Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt1 atoms
journal, August 2019
- Wang, Hui; Liu, Jin-Xun; Allard, Lawrence F.
- Nature Communications, Vol. 10, Issue 1
A Model for the Temperature-Programmed Reduction of Low and High Surface Area Ceria
journal, July 2000
- Giordano, Francesca; Trovarelli, Alessandro; de Leitenburg, Carla
- Journal of Catalysis, Vol. 193, Issue 2
Reduction of cerias with different textures by hydrogen and their reoxidation by oxygen
journal, January 1994
- Perrichon, Vincent; Laachir, Ahmidou; Bergeret, Gérard
- J. Chem. Soc., Faraday Trans., Vol. 90, Issue 5
Understanding Heterolytic H 2 Cleavage and Water-Assisted Hydrogen Spillover on Fe 3 O 4 (001)-Supported Single Palladium Atoms
journal, July 2019
- Doudin, Nassar; Yuk, Simuck F.; Marcinkowski, Matthew D.
- ACS Catalysis, Vol. 9, Issue 9
Anchored metal nanoparticles: Effects of support and size on their energy, sintering resistance and reactivity
journal, January 2013
- Campbell, Charles T.; Sellers, Jason R. V.
- Faraday Discussions, Vol. 162
First-Principles Kinetic and Spectroscopic Insights into Single-Atom Catalysis
journal, April 2019
- Alexopoulos, Konstantinos; Wang, Yifan; Vlachos, Dionisios G.
- ACS Catalysis, Vol. 9, Issue 6
Observation of ligand effects during alkene hydrogenation catalysed by supported metal clusters
journal, February 2002
- Argo, A. M.; Odzak, J. F.; Lai, F. S.
- Nature, Vol. 415, Issue 6872
An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation
journal, March 2018
- Therrien, Andrew J.; Hensley, Alyssa J. R.; Marcinkowski, Matthew D.
- Nature Catalysis, Vol. 1, Issue 3
Single-Atom Catalysis: How Structure Influences Catalytic Performance
journal, February 2019
- Parkinson, Gareth S.
- Catalysis Letters, Vol. 149, Issue 5
Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts
journal, July 2018
- Ro, Insoo; Resasco, Joaquin; Christopher, Phillip
- ACS Catalysis, Vol. 8, Issue 8
Local Structure and Coordination Define Adsorption in a Model Ir 1 /Fe 3 O 4 Single‐Atom Catalyst
journal, September 2019
- Jakub, Zdenek; Hulva, Jan; Meier, Matthias
- Angewandte Chemie International Edition, Vol. 58, Issue 39