Water adsorption on vanadium oxide thin films in ambient relative humidity

Goodacre, Dana; Blum, Monika; Buechner, Christin; Hoek, Harmen; Gericke, Sabrina M.; Jovic, Vedran; Franklin, Joseph B.; Kittiwatanakul, Salinporn; Söhnel, Tilo; Bluhm, Hendrik; Smith, Kevin E.

doi:10.1063/1.5138959

Title: Water adsorption on vanadium oxide thin films in ambient relative humidity

Journal Article · 31 January 2020 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5138959 · OSTI ID:1605264

^[1]; Blum, Monika ^[2];

^[3]; Hoek, Harmen ^[4];

^[5]; Jovic, Vedran ^[6]; Franklin, Joseph B. ^[7];

^[8];

^[9];

^[10];

^[11]

Univ. of Auckland, Auckland (New Zealand); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); MacDiarmid Inst. for Advanced Materials and Nanotechnology, Wellington (New Zealand)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of Twente, Enschede (The Netherlands)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lund Univ., Lund (Sweden)
MacDiarmid Inst. for Advanced Materials and Nanotechnology, Wellington (New Zealand); National Isotope Center, GNS Science, Lower Hutt (New Zealand)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. College London, London (United Kingdom)
Univ. of Virginia, Charlottesville, VA (United States); Chulalongkorn Univ., Bangkok (Thailand)
Univ. of Auckland, Auckland (New Zealand); MacDiarmid Inst. for Advanced Materials and Nanotechnology, Wellington (New Zealand)
Fritz Haber Inst. of the Max Planck Society, Berlin (Germany)
Boston Univ., MA (United States)

Here in this work, ambient pressure x-ray photoelectron spectroscopy (APXPS) is used to study the initial stages of water adsorption on vanadium oxide surfaces. V 2p, O 1s, C 1s, and valence band XPS spectra were collected as a function of relative humidity in a series of isotherm and isobar experiments. Experiments were carried out on two VO₂ thin films on TiO₂ (100) substrates, prepared with different surface cleaning procedures. Hydroxyl and molecular water surface species were identified, with up to 0.5 ML hydroxide present at the minimum relative humidity, and a consistent molecular water adsorption onset occurring around 0.01% relative humidity. The work function was found to increase with increasing relative humidity, suggesting that surface water and hydroxyl species are oriented with the hydrogen atoms directed away from the surface. Changes in the valence band were also observed as a function of relative humidity. The results were similar to those observed in APXPS experiments on other transition metal oxide surfaces, suggesting that H₂O-OH and H₂O-H₂O surface complex formation plays an important role in the oxide wetting process and water dissociation. Compared to polycrystalline vanadium metal, these vanadium oxide films generate less hydroxide and appear to be more favorable for molecular water adsorption.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: European Union (EU); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231; FG02-98ER45680

OSTI ID:: 1605264

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 4 Vol. 152; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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