Membrane-Free Zn/MnO2 Flow Battery for Large-Scale Energy Storage
Abstract
The traditional Zn/MnO2 battery has attracted great interest due to its low cost, high safety, high output voltage, and environmental friendliness. However, it remains a big challenge to achieve long-term stability, mainly owing to the poor reversibility of the cathode reaction. Different from previous studies where the cathode redox reaction of MnO2/MnOOH is in solid state with limited reversibility, in this work a new aqueous rechargeable Zn/MnO2 flow battery is constructed with dissolution–precipitation reactions in both cathodes (Mn2+/MnO2) and anodes (Zn2+/Zn), which allow mixing of anolyte and catholyte into only one electrolyte and remove the requirement for an ion selective membrane for cost reduction. Impressively, this new battery exhibits a high discharge voltage of ≈1.78 V, good rate capability (10C discharge), and excellent cycling stability (1000 cycles without decay) at the areal capacity ranging from 0.5 to 2 mAh cm-2. More importantly, this battery can be readily enlarged to a bench scale flow cell of 1.2 Ah with good capacity retention of 89.7% at the 500th cycle, displaying great potential for large-scale energy storage.
- Authors:
-
- Stanford Univ., CA (United States); National Center for Nanoscience and Technology Beijing (People's Republic of China)
- Stanford Univ., CA (United States)
- Stanford Univ., CA (United States); Beijing Key Lab. of Advanced Chemical Energy Storage Technologies and Materials, Beijing (People's Republic of China)
- National Center for Nanoscience and Technology Beijing (People's Republic of China)
- Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); Beijing Natural Science Foundation; Youth Innovation Promotion Association CAS
- OSTI Identifier:
- 1605183
- Alternate Identifier(s):
- OSTI ID: 1596386
- Grant/Contract Number:
- AC02-76SF00515; 21722102; 51672053; 21303029; 2182087; 2016036
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 9; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; aqueous flow batteries; dissolution–precipitation reactions; large-scale energy storage; Mn2+/MnO2 transformation; rechargeable Zn/MnO2
Citation Formats
Li, Guodong, Chen, Wei, Zhang, Hao, Gong, Yongji, Shi, Feifei, Wang, Jiangyan, Zhang, Rufan, Chen, Guangxu, Jin, Yang, Wu, Tong, Tang, Zhiyong, and Cui, Yi. Membrane-Free Zn/MnO2 Flow Battery for Large-Scale Energy Storage. United States: N. p., 2020.
Web. doi:10.1002/aenm.201902085.
Li, Guodong, Chen, Wei, Zhang, Hao, Gong, Yongji, Shi, Feifei, Wang, Jiangyan, Zhang, Rufan, Chen, Guangxu, Jin, Yang, Wu, Tong, Tang, Zhiyong, & Cui, Yi. Membrane-Free Zn/MnO2 Flow Battery for Large-Scale Energy Storage. United States. https://doi.org/10.1002/aenm.201902085
Li, Guodong, Chen, Wei, Zhang, Hao, Gong, Yongji, Shi, Feifei, Wang, Jiangyan, Zhang, Rufan, Chen, Guangxu, Jin, Yang, Wu, Tong, Tang, Zhiyong, and Cui, Yi. Fri .
"Membrane-Free Zn/MnO2 Flow Battery for Large-Scale Energy Storage". United States. https://doi.org/10.1002/aenm.201902085. https://www.osti.gov/servlets/purl/1605183.
@article{osti_1605183,
title = {Membrane-Free Zn/MnO2 Flow Battery for Large-Scale Energy Storage},
author = {Li, Guodong and Chen, Wei and Zhang, Hao and Gong, Yongji and Shi, Feifei and Wang, Jiangyan and Zhang, Rufan and Chen, Guangxu and Jin, Yang and Wu, Tong and Tang, Zhiyong and Cui, Yi},
abstractNote = {The traditional Zn/MnO2 battery has attracted great interest due to its low cost, high safety, high output voltage, and environmental friendliness. However, it remains a big challenge to achieve long-term stability, mainly owing to the poor reversibility of the cathode reaction. Different from previous studies where the cathode redox reaction of MnO2/MnOOH is in solid state with limited reversibility, in this work a new aqueous rechargeable Zn/MnO2 flow battery is constructed with dissolution–precipitation reactions in both cathodes (Mn2+/MnO2) and anodes (Zn2+/Zn), which allow mixing of anolyte and catholyte into only one electrolyte and remove the requirement for an ion selective membrane for cost reduction. Impressively, this new battery exhibits a high discharge voltage of ≈1.78 V, good rate capability (10C discharge), and excellent cycling stability (1000 cycles without decay) at the areal capacity ranging from 0.5 to 2 mAh cm-2. More importantly, this battery can be readily enlarged to a bench scale flow cell of 1.2 Ah with good capacity retention of 89.7% at the 500th cycle, displaying great potential for large-scale energy storage.},
doi = {10.1002/aenm.201902085},
journal = {Advanced Energy Materials},
number = 9,
volume = 10,
place = {United States},
year = {2020},
month = {1}
}
Web of Science
Works referenced in this record:
Exploring Bio-inspired Quinone-Based Organic Redox Flow Batteries: A Combined Experimental and Computational Study
journal, November 2016
- Ding, Yu; Li, Yafei; Yu, Guihua
- Chem, Vol. 1, Issue 5
Rechargeable hybrid aqueous batteries
journal, October 2012
- Yan, Jing; Wang, Jing; Liu, Hao
- Journal of Power Sources, Vol. 216
High performance nickel-cadmium cells for electric vehicles
journal, August 1994
- Cornu, Jean-Pierre
- Journal of Power Sources, Vol. 51, Issue 1-2
Rechargeable alkaline manganese dioxide/zinc batteries
journal, August 1994
- Kordesh, K.; Weissenbacher, M.
- Journal of Power Sources, Vol. 51, Issue 1-2
A manganese–hydrogen battery with potential for grid-scale energy storage
journal, April 2018
- Chen, Wei; Li, Guodong; Pei, Allen
- Nature Energy, Vol. 3, Issue 5
Enhanced reversible divalent zinc storage in a structurally stable α-MnO 2 nanorod electrode
journal, August 2015
- Alfaruqi, Muhammad Hilmy; Gim, Jihyeon; Kim, Sungjin
- Journal of Power Sources, Vol. 288
An aqueous, polymer-based redox-flow battery using non-corrosive, safe and low-cost materials
journal, October 2015
- Janoschka, Tobias; Martin, Norbert; Martin, Udo
- Nature, Vol. 527, Issue 7576, p. 78-81
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011
- Xu, Chengjun; Li, Baohua; Du, Hongda
- Angewandte Chemie International Edition, Vol. 51, Issue 4
Electrochemically Induced Structural Transformation in a γ-MnO 2 Cathode of a High Capacity Zinc-Ion Battery System
journal, May 2015
- Alfaruqi, Muhammad H.; Mathew, Vinod; Gim, Jihyeon
- Chemistry of Materials, Vol. 27, Issue 10
An ultrafast rechargeable aluminium-ion battery
journal, April 2015
- Lin, Meng-Chang; Gong, Ming; Lu, Bingan
- Nature, Vol. 520, Issue 7547
Resolving the Compositional and Structural Defects of Degraded LiNi x Co y Mn z O 2 Particles to Directly Regenerate High-Performance Lithium-Ion Battery Cathodes
journal, June 2018
- Shi, Yang; Chen, Gen; Liu, Fang
- ACS Energy Letters, Vol. 3, Issue 7
Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion
journal, July 2017
- Sun, Wei; Wang, Fei; Hou, Singyuk
- Journal of the American Chemical Society, Vol. 139, Issue 29
Gaston Planté and his invention of the lead–acid battery—The genesis of the first practical rechargeable battery
journal, July 2010
- Kurzweil, P.
- Journal of Power Sources, Vol. 195, Issue 14
Effect of Multiple Cation Electrolyte Mixtures on Rechargeable Zn–MnO 2 Alkaline Battery
journal, June 2016
- Hertzberg, Benjamin J.; Huang, An; Hsieh, Andrew
- Chemistry of Materials, Vol. 28, Issue 13
Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery
journal, February 2013
- Li, Bin; Gu, Meng; Nie, Zimin
- Nano Letters, Vol. 13, Issue 3
The nickel/iron battery
journal, June 1991
- Chakkaravarthy, C.; Periasamy, P.; Jegannathan, S.
- Journal of Power Sources, Vol. 35, Issue 1
What Are Batteries, Fuel Cells, and Supercapacitors?
journal, October 2004
- Winter, Martin; Brodd, Ralph J.
- Chemical Reviews, Vol. 104, Issue 10, p. 4245-4270
A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II) Part I. Preliminary studies
journal, January 2004
- Hazza, Ahmed; Pletcher, Derek; Wills, Richard
- Physical Chemistry Chemical Physics, Vol. 6, Issue 8, p. 1773-1778
The influence of ionic liquid additives on zinc half-cell electrochemical performance in zinc/bromine flow batteries
journal, January 2016
- Rajarathnam, Gobinath P.; Easton, Max E.; Schneider, Martin
- RSC Advances, Vol. 6, Issue 33
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017
- Zhang, Ning; Cheng, Fangyi; Liu, Junxiang
- Nature Communications, Vol. 8, Issue 1
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015
- Suo, L.; Borodin, O.; Gao, T.
- Science, Vol. 350, Issue 6263
A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction
journal, September 2016
- Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori
- Science, Vol. 353, Issue 6303
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Material design and engineering of next-generation flow-battery technologies
journal, November 2016
- Park, Minjoon; Ryu, Jaechan; Wang, Wei
- Nature Reviews Materials, Vol. 2, Issue 1
Opportunities and challenges for a sustainable energy future
journal, August 2012
- Chu, Steven; Majumdar, Arun
- Nature, Vol. 488, Issue 7411, p. 294-303
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage
journal, January 2012
- Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A.
- Nature Communications, Vol. 3, Issue 1, Article No. 1149
A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage
journal, March 2011
- Li, Liyu; Kim, Soowhan; Wang, Wei
- Advanced Energy Materials, Vol. 1, Issue 3, p. 394-400
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
journal, April 2016
- Pan, Huilin; Shao, Yuyan; Yan, Pengfei
- Nature Energy, Vol. 1, Issue 5
An ultrafast nickel–iron battery from strongly coupled inorganic nanoparticle/nanocarbon hybrid materials
journal, January 2012
- Wang, Hailiang; Liang, Yongye; Gong, Ming
- Nature Communications, Vol. 3, Issue 1
Development and testing of an economic grid-scale flow-assisted zinc/nickel-hydroxide alkaline battery
journal, October 2014
- Turney, Damon E.; Shmukler, Michael; Galloway, Kevin
- Journal of Power Sources, Vol. 264
Rechargeable Lithium Batteries with Aqueous Electrolytes
journal, May 1994
- Li, W.; Dahn, J. R.; Wainwright, D. S.
- Science, Vol. 264, Issue 5162, p. 1115-1118
Oxidation–reduction assisted exfoliation of LiCoO 2 into nanosheets and reassembly into functional Li-ion battery cathodes
journal, January 2016
- Cheng, Qian; Yang, Ting; Li, Ying
- Journal of Materials Chemistry A, Vol. 4, Issue 18
High-Power Alkaline Zn-MnO2 Batteries Using γ-MnO2 Nanowires/Nanotubes and Electrolytic Zinc Powder
journal, November 2005
- Cheng, F. Y.; Chen, J.; Gou, X. L.
- Advanced Materials, Vol. 17, Issue 22
An aqueous, polymer-based redox-flow battery using non-corrosive, safe, and low-cost materials
journal, June 2016
- Janoschka, Tobias; Martin, Norbert; Martin, Udo
- Nature, Vol. 534, Issue 7607
Flexible Solid Flow Electrodes for High-Energy Scalable Energy Storage
journal, July 2019
- Wang, Zengyue; Tam, Long-Yin Simon; Lu, Yi-Chun
- Joule, Vol. 3, Issue 7
Ion-Sieving Carbon Nanoshells for Deeply Rechargeable Zn-Based Aqueous Batteries
journal, October 2018
- Wu, Yutong; Zhang, Yamin; Ma, Yao
- Advanced Energy Materials, Vol. 8, Issue 36
Avoiding short circuits from zinc metal dendrites in anode by backside-plating configuration
journal, June 2016
- Higashi, Shougo; Lee, Seok Woo; Lee, Jang Soo
- Nature Communications, Vol. 7, Issue 1
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011
- Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
- Energy & Environmental Science, Vol. 4, Issue 9
Green synthesis of in situ electrodeposited rGO/MnO2 nanocomposite for high energy density supercapacitors
journal, November 2015
- Rusi, ; Majid, S. R.
- Scientific Reports, Vol. 5, Issue 1
Advanced porous membranes with ultra-high selectivity and stability for vanadium flow batteries
journal, January 2016
- Yuan, Zhizhang; Duan, Yinqi; Zhang, Hongzhang
- Energy & Environmental Science, Vol. 9, Issue 2
Alkaline quinone flow battery
journal, September 2015
- Lin, K.; Chen, Q.; Gerhardt, M. R.
- Science, Vol. 349, Issue 6255, p. 1529-1532
Achieving high efficiency and cyclability in inexpensive soluble lead flow batteries
journal, January 2013
- Verde, Michael G.; Carroll, Kyler J.; Wang, Ziying
- Energy & Environmental Science, Vol. 6, Issue 5, p. 1573-1581
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016
- Kundu, Dipan; Adams, Brian D.; Duffort, Victor
- Nature Energy, Vol. 1, Issue 10
A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage
journal, January 2015
- Zhao, Yu; Ding, Yu; Li, Yutao
- Chemical Society Reviews, Vol. 44, Issue 22
Investigation on Zinc Ion Storage in Alpha Manganese Dioxide for Zinc Ion Battery by Electrochemical Impedance Spectrum
journal, November 2012
- Xu, Chengjun; Chiang, Sum Wai; Ma, Jun
- Journal of The Electrochemical Society, Vol. 160, Issue 1
A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II)
journal, August 2009
- Li, Xiaohong; Pletcher, Derek; Walsh, Frank C.
- Electrochimica Acta, Vol. 54, Issue 20, p. 4688-4695
Highly stable zinc–iodine single flow batteries with super high energy density for stationary energy storage
journal, January 2019
- Xie, Congxin; Liu, Yun; Lu, Wenjing
- Energy & Environmental Science, Vol. 12, Issue 6
Preparation and Characterization of Ni/Al-Layered Double Hydroxide
journal, January 1999
- Sugimoto, Akiko
- Journal of The Electrochemical Society, Vol. 146, Issue 4
Flow Batteries: Current Status and Trends
journal, September 2015
- Soloveichik, Grigorii L.
- Chemical Reviews, Vol. 115, Issue 20
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte
journal, August 2010
- Luo, Jia-Yan; Cui, Wang-Jun; He, Ping
- Nature Chemistry, Vol. 2, Issue 9
What Are Batteries, Fuel Cells, and Supercapacitors?
journal, December 2004
- Winter, Martin; Brodd, Ralph J.
- ChemInform, Vol. 35, Issue 50