skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids

Abstract

Actinide salts were dehydrated with an ionic liquid containing the same anion and subsequently coordinated by N-heterocyclic ligands challenging the concept of O- over N-donor preference.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [2]; ORCiD logo [4]
  1. Department of Chemistry, University of Missouri, Columbia, USA
  2. Department of Materials and Environmental Chemistry, Stockholm University, 106 91 Stockholm, Sweden
  3. College of Arts & Sciences, The University of Alabama, Tuscaloosa, USA
  4. Department of Materials and Environmental Chemistry, Stockholm University, 106 91 Stockholm, Sweden, College of Arts & Sciences
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1605046
Grant/Contract Number:  
[SC0019220]
Resource Type:
Published Article
Journal Name:
ChemComm
Additional Journal Information:
[Journal Name: ChemComm]; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Kelley, Steven P., Smetana, Volodymyr, Emerson, Stephen D., Mudring, Anja-Verena, and Rogers, Robin D. Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CC09852F.
Kelley, Steven P., Smetana, Volodymyr, Emerson, Stephen D., Mudring, Anja-Verena, & Rogers, Robin D. Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids. United Kingdom. doi:10.1039/C9CC09852F.
Kelley, Steven P., Smetana, Volodymyr, Emerson, Stephen D., Mudring, Anja-Verena, and Rogers, Robin D. Wed . "Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids". United Kingdom. doi:10.1039/C9CC09852F.
@article{osti_1605046,
title = {Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids},
author = {Kelley, Steven P. and Smetana, Volodymyr and Emerson, Stephen D. and Mudring, Anja-Verena and Rogers, Robin D.},
abstractNote = {Actinide salts were dehydrated with an ionic liquid containing the same anion and subsequently coordinated by N-heterocyclic ligands challenging the concept of O- over N-donor preference.},
doi = {10.1039/C9CC09852F},
journal = {ChemComm},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9CC09852F

Save / Share:

Works referenced in this record:

Solidification of Ionic Liquids: Theory and Techniques
journal, January 2010

  • Mudring, Anja-Verena
  • Australian Journal of Chemistry, Vol. 63, Issue 4
  • DOI: 10.1071/CH10017

Synthesis and characterization of NpCl 4 (DME) 2 and PuCl 4 (DME) 2 neutral transuranic An( iv ) starting materials
journal, January 2014

  • Reilly, Sean D.; Brown, Jessie L.; Scott, Brian L.
  • Dalton Trans., Vol. 43, Issue 4
  • DOI: 10.1039/C3DT53058B

Highly Efficient Separation of Actinides from Lanthanides by a Phenanthroline-Derived Bis-triazine Ligand
journal, August 2011

  • Lewis, Frank W.; Harwood, Laurence M.; Hudson, Michael J.
  • Journal of the American Chemical Society, Vol. 133, Issue 33
  • DOI: 10.1021/ja203378m

An entry route into non-aqueous plutonyl coordination chemistry
journal, January 2007

  • Gaunt, Andrew J.; Reilly, Sean D.; Hayton, Trevor W.
  • Chemical Communications, Issue 16
  • DOI: 10.1039/b618577k

Interactions of 1-Methylimidazole with UO 2 (CH 3 CO 2 ) 2 and UO 2 (NO 3 ) 2 :  Structural, Spectroscopic, and Theoretical Evidence for Imidazole Binding to the Uranyl Ion
journal, January 2007

  • Gutowski, Keith E.; Cocalia, Violina A.; Griffin, Scott T.
  • Journal of the American Chemical Society, Vol. 129, Issue 3
  • DOI: 10.1021/ja064592i

Structure of di-.mu.-aquo-bis(dioxobis(nitrato)uranium(VI)) diimidazole, [UO2 (NO3)2(H2O)].2C3H4N2, a water bridged dimer of uranyl nitrate
journal, April 1980

  • Perry, Dale L.; Ruben, Helena; Templeton, David H.
  • Inorganic Chemistry, Vol. 19, Issue 4
  • DOI: 10.1021/ic50206a058

A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic molecules
journal, January 2019

  • Zhang, Congcong; Hou, Guohua; Zi, Guofu
  • Dalton Transactions, Vol. 48, Issue 7
  • DOI: 10.1039/C9DT00012G

Uranyl(VI)–Acetylacetonate Coordination Compounds with Various N-Heterocyclic Ligands
journal, December 2010

  • Kawasaki, Takeshi; Nishimura, Tatsuru; Kitazawa, Takafumi
  • Bulletin of the Chemical Society of Japan, Vol. 83, Issue 12
  • DOI: 10.1246/bcsj.20100159

The binding and transport of alternative metals by transferrin
journal, March 2012

  • Vincent, John B.; Love, Sharifa
  • Biochimica et Biophysica Acta (BBA) - General Subjects, Vol. 1820, Issue 3
  • DOI: 10.1016/j.bbagen.2011.07.003

NMR studies on uranyl(VI) complexes with L-histidine, imidazole and derivatives
journal, January 1982


Ionic Liquids as Crystallization Media: Weakly-Coordinating Anions Do Coordinate in 1 [Eu(OTf) 3 (CH 3 CN) 3 ]
journal, May 2011

  • Tang, Sifu; Mudring, Anja-Verena
  • Crystal Growth & Design, Vol. 11, Issue 5
  • DOI: 10.1021/cg200064n

Homoleptic Alkaline Earth Metal Bis(trifluoromethanesulfonyl)imide Complex Compounds Obtained from an Ionic Liquid
journal, April 2006

  • Babai, Arash; Mudring, Anja-Verena
  • Inorganic Chemistry, Vol. 45, Issue 8
  • DOI: 10.1021/ic051820l

Speciation of Uranyl Nitrato Complexes in Acetonitrile and in the Ionic Liquid 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide
journal, November 2007

  • Servaes, Kelly; Hennig, Christoph; Billard, Isabelle
  • European Journal of Inorganic Chemistry, Vol. 2007, Issue 32
  • DOI: 10.1002/ejic.200700475

The crystal structure of bisnitratodiaquodioxo-uranium(VI) tetrahydrate (uranyl nitrate hexahydrate)
journal, September 1965


An Alkali-Metal Halide-Bridged Actinide Phosphinidiide Complex
journal, January 2019


Interactions with Aromatic Rings in Chemical and Biological Recognition
journal, March 2003

  • Meyer, Emmanuel A.; Castellano, Ronald K.; Diederich, François
  • Angewandte Chemie International Edition, Vol. 42, Issue 11
  • DOI: 10.1002/anie.200390319

Formation of ionic co-crystals of amphoteric azoles directed by the ionic liquid co-former 1-ethyl-3-methylimidazolium acetate
journal, January 2017

  • Titi, Hatem M.; Kelley, Steven P.; Easton, Max E.
  • Chemical Communications, Vol. 53, Issue 61
  • DOI: 10.1039/C7CC04429A

Sterically Congested Uranyl Complexes with Seven-Coordination of the UO 2 Unit: the Peculiar Ligation Mode of Nitrate in [UO 2 (NO 3 ) 2 (Rbtp)] Complexes
journal, August 2008

  • Berthet, Jean-Claude; Thuéry, Pierre; Dognon, Jean-Pierre
  • Inorganic Chemistry, Vol. 47, Issue 15
  • DOI: 10.1021/ic8004486

Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides
journal, June 2012

  • Hudson, Michael J.; Harwood, Laurence M.; Laventine, Dominic M.
  • Inorganic Chemistry, Vol. 52, Issue 7
  • DOI: 10.1021/ic3008848

Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions
journal, October 2008


Supramolecular Interactions in PuO 2 Cl 4 2– and PuCl 6 2– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy
journal, December 2013

  • Wilson, Richard E.; Schnaars, David D.; Andrews, Michael B.
  • Inorganic Chemistry, Vol. 53, Issue 1
  • DOI: 10.1021/ic4023294

A seven-co-ordinate actinoid complex: crystal and molecular structure of tetrachlorotris(trimethylamine)thorium(IV)
journal, January 1984

  • Drew, Michael G. B.; Willey, Gerald R.
  • Journal of the Chemical Society, Dalton Transactions, Issue 4
  • DOI: 10.1039/dt9840000727

Reinvestigation of Np 2 Se 5 : A Clear Divergence from Th 2 S 5 and Th 2 Se 5 in Chalcogen–Chalcogen and Metal–Chalcogen Interactions
journal, July 2013

  • Jin, Geng Bang; Hu, Yung-Jin; Bellott, Brian
  • Inorganic Chemistry, Vol. 52, Issue 15
  • DOI: 10.1021/ic401384t

Thermophysical Properties of Imidazolium-Based Ionic Liquids
journal, July 2004

  • Fredlake, Christopher P.; Crosthwaite, Jacob M.; Hert, Daniel G.
  • Journal of Chemical & Engineering Data, Vol. 49, Issue 4
  • DOI: 10.1021/je034261a

Actinide structural studies. 12. 4,4'-Bipyridinium di-μ-hydroxo-bis[dinitratodioxouranate(VI)] monohydrate
journal, July 1987

  • Alcock, N. W.; Flanders, D. J.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 7
  • DOI: 10.1107/S0108270187092205

Structural Characterization of Pu[N(SiMe 3 ) 2 ] 3 , a Synthetically Useful Nonaqueous Plutonium(III) Precursor
journal, January 2008

  • Gaunt, Andrew J.; Enriquez, Alejandro E.; Reilly, Sean D.
  • Inorganic Chemistry, Vol. 47, Issue 1
  • DOI: 10.1021/ic701673e

Synthesis and Crystal Structure of UO 2 Cl 2 (THF) 3 :  A Simple Preparation of an Anhydrous Uranyl Reagent
journal, September 1999

  • Wilkerson, Marianne P.; Burns, Carol J.; Paine, Robert T.
  • Inorganic Chemistry, Vol. 38, Issue 18
  • DOI: 10.1021/ic990159g

Synthesis, Characterization, and Density Functional Theory Analysis of Uranium and Thorium Complexes Containing Nitrogen-Rich 5-Methyltetrazolate Ligands
journal, April 2016


Actinide speciation in aquatic systems
journal, March 2006


Crystallization in Ionic Liquids: Synthesis, Properties, and Polymorphs of Uranyl Salts
journal, October 2014

  • Qu, Feng; Zhu, Qian-Qian; Liu, Chun-Li
  • Crystal Growth & Design, Vol. 14, Issue 12
  • DOI: 10.1021/cg501277d

Crystal chemistry of thorium nitrates and chromates
journal, July 2010


Actinide speciation in the environment
journal, January 2003


Review Article: A Review of the Development and Operational Characteristics of the TALSPEAK Process
journal, October 2007


The first homoleptic bis(trifluoromethanesulfonyl)amide complex compounds of trivalent f-elements
journal, January 2006

  • Babai, Arash; Mudring, Anja-Verena
  • Dalton Transactions, Issue 15
  • DOI: 10.1039/b517694h