Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

Barrett, Seth M.; Stratakes, Bethany M.; Chambers, Matthew B.; Kurtz, Daniel A.; Pitman, Catherine L.; Dempsey, Jillian L.; Miller, Alexander M.

doi:10.1039/d0sc00422g

Title: Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

Journal Article · 01 January 2020 · Chemical Science

DOI: https://doi.org/10.1039/d0sc00422g · OSTI ID:1605045

^[1]; Stratakes, Bethany M. ^[2];

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Department of Chemistry; University of North Carolina at Chapel Hill; Chapel Hill; USA; Department of Chemistry
Department of Chemistry; University of North Carolina at Chapel Hill; Chapel Hill; USA

The innate H₂ evolution photochemistry of an iridium hydride complex is diverted towards photochemical hydrodechlorination of dichloromethane with high selectivity and quantum yield.

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Research Organization:: Univ. of North Carolina, Chapel Hill, NC (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001011; SC0014255

OSTI ID:: 1605045

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 25 Vol. 11; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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