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Title: Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles

Abstract

This paper explores the utility and limitations of RDE techniques for mechanistic and kinetic analysis of homogeneous molecular catalysts that mediate multi-electron, multi-substrate redox transformations.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Univ. of North Carolina, Chapel Hill, NC (United States)
Publication Date:
Research Org.:
Univ. of North Carolina, Chapel Hill, NC (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; Alfred P. Sloan Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1604866
Alternate Identifier(s):
OSTI ID: 1595166; OSTI ID: 1693437
Grant/Contract Number:  
SC0015303
Resource Type:
Accepted Manuscript
Journal Name:
Analyst
Additional Journal Information:
Journal Volume: 145; Journal Issue: 4; Journal ID: ISSN 0003-2654
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN

Citation Formats

Lee, Katherine J., Gruninger, Cole T., Lodaya, Kunal M., Qadeer, Saad, Griffith, Boyce E., and Dempsey, Jillian L. Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles. United States: N. p., 2020. Web. doi:10.1039/C9AN02192B.
Lee, Katherine J., Gruninger, Cole T., Lodaya, Kunal M., Qadeer, Saad, Griffith, Boyce E., & Dempsey, Jillian L. Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles. United States. https://doi.org/10.1039/C9AN02192B
Lee, Katherine J., Gruninger, Cole T., Lodaya, Kunal M., Qadeer, Saad, Griffith, Boyce E., and Dempsey, Jillian L. Mon . "Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles". United States. https://doi.org/10.1039/C9AN02192B. https://www.osti.gov/servlets/purl/1604866.
@article{osti_1604866,
title = {Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles},
author = {Lee, Katherine J. and Gruninger, Cole T. and Lodaya, Kunal M. and Qadeer, Saad and Griffith, Boyce E. and Dempsey, Jillian L.},
abstractNote = {This paper explores the utility and limitations of RDE techniques for mechanistic and kinetic analysis of homogeneous molecular catalysts that mediate multi-electron, multi-substrate redox transformations.},
doi = {10.1039/C9AN02192B},
journal = {Analyst},
number = 4,
volume = 145,
place = {United States},
year = {2020},
month = {1}
}

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