A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide

Jeong, Sohee; Heo, Tae Wook; Oktawiec, Julia; Shi, Rongpei; Kang, ShinYoung; White, James L.; Schneemann, Andreas; Zaia, Edmond W.; Wan, Liwen F.; Ray, Keith G.; Liu, Yi-Sheng; Stavila, Vitalie; Guo, Jinghua; Long, Jeffrey R.; Wood, Brandon C.; Urban, Jeffrey J.

doi:10.1021/acsnano.9b07454

Title: A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH₄)₂ within Reduced Graphene Oxide

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Abstract

Abstract not provided.

Authors:

Jeong, Sohee ^[1];

^[2]; Oktawiec, Julia ^[3]; Shi, Rongpei ^[2]; Kang, ShinYoung ^[2]; White, James L. ^[4];

^[4]; Zaia, Edmond W. ^[1];

^[2]; Ray, Keith G. ^[2];

^[1];

^[4];

^[5];

^[3];

^[2];

^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)

Publication Date:: Fri Jan 10 00:00:00 EST 2020

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). The Molecular Foundry (TMF) and Advanced Light Source (ALS); Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office

OSTI Identifier:: 1604725

Alternate Identifier(s):: OSTI ID: 1782522; OSTI ID: 1810403

Report Number(s):: LLNL-JRNL-772956; SAND-2020-14102J
Journal ID: ISSN 1936-0851; ark:/13030/qt3gt055vq

Grant/Contract Number:: AC02-05CH11231; AC52-07NA27344; NA-0003525; NA0003525; AC04-94AL85000

Resource Type:: Accepted Manuscript

Journal Name:: ACS Nano

Additional Journal Information:: Journal Volume: 14; Journal Issue: 2; Journal ID: ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; magnesium borohydride; hydrogen storage; phase evolution; thermodynamics; kinetic; reduced graphene oxide; 36 MATERIALS SCIENCE; 08 HYDROGEN; 25 ENERGY STORAGE

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                    Jeong, Sohee, Heo, Tae Wook, Oktawiec, Julia, Shi, Rongpei, Kang, ShinYoung, White, James L., Schneemann, Andreas, Zaia, Edmond W., Wan, Liwen F., Ray, Keith G., Liu, Yi-Sheng, Stavila, Vitalie, Guo, Jinghua, Long, Jeffrey R., Wood, Brandon C., and Urban, Jeffrey J. A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide.  United States: N. p., 2020. 
Web.  doi:10.1021/acsnano.9b07454.

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                    Jeong, Sohee, Heo, Tae Wook, Oktawiec, Julia, Shi, Rongpei, Kang, ShinYoung, White, James L., Schneemann, Andreas, Zaia, Edmond W., Wan, Liwen F., Ray, Keith G., Liu, Yi-Sheng, Stavila, Vitalie, Guo, Jinghua, Long, Jeffrey R., Wood, Brandon C., & Urban, Jeffrey J. A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide.  United States.  https://doi.org/10.1021/acsnano.9b07454

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                    Jeong, Sohee, Heo, Tae Wook, Oktawiec, Julia, Shi, Rongpei, Kang, ShinYoung, White, James L., Schneemann, Andreas, Zaia, Edmond W., Wan, Liwen F., Ray, Keith G., Liu, Yi-Sheng, Stavila, Vitalie, Guo, Jinghua, Long, Jeffrey R., Wood, Brandon C., and Urban, Jeffrey J. Fri .  
"A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide".  United States.  https://doi.org/10.1021/acsnano.9b07454.  https://www.osti.gov/servlets/purl/1604725.

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@article{osti_1604725,

  title        = {A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide},

  author       = {Jeong, Sohee and Heo, Tae Wook and Oktawiec, Julia and Shi, Rongpei and Kang, ShinYoung and White, James L. and Schneemann, Andreas and Zaia, Edmond W. and Wan, Liwen F. and Ray, Keith G. and Liu, Yi-Sheng and Stavila, Vitalie and Guo, Jinghua and Long, Jeffrey R. and Wood, Brandon C. and Urban, Jeffrey J.},

  abstractNote = {Abstract not provided.},

  doi          = {10.1021/acsnano.9b07454},

  journal      = {ACS Nano},

  number       = 2,

  volume       = 14,

  place        = {United States},

  year         = {Fri Jan 10 00:00:00 EST 2020},

  month        = {Fri Jan 10 00:00:00 EST 2020}

}

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Title: A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide

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Title: A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH₄)₂ within Reduced Graphene Oxide