DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Self‐Assembled NiO Nanocrystal Arrays as Memristive Elements

Journal Article · · Advanced Electronic Materials
ORCiD logo [1];  [2];  [2];  [2]; ORCiD logo [3];  [4]
  1. School of Materials Science and Engineering University of New South Wales Sydney New South Wales 2052 Australia, Centre for Nanostructured Media School of Mathematics and Physics Queens University Belfast University Road Belfast BT7 1NN UK
  2. Department of Physics and Oxide Research Center Hankuk University of Foreign Studies Yongin 17035 Korea
  3. Center for Nanophase and Materials Sciences Oak Ridge National Laboratory Oak Ridge TN 37831 USA
  4. School of Materials Science and Engineering University of New South Wales Sydney New South Wales 2052 Australia

Abstract Memristive switching, a nonlinear current–voltage ( I – V ) characteristic, has seen a tremendous surge in interest as an approach to achieve implementation of synaptic functions. The memristive switching behavior of self‐assembled NiO nanocrystals is investigated via scanning probe microscopy, based on first‐order reversal curve current–voltage spectroscopy. Synaptic switching is clearly observed as a direct consequence of filament growth (i.e., gradually increased conductance) in the nanocrystals. A spatial dependency of the conduction in the nanocrystals suggests that there is a localization of the switching filament. The current understanding of this localization ignores features related to local lateral variation current, which can generate an excessive local heat and temperature such as electrical dissipation. The observation of low electrical dissipation at the edge of the nanocrystals shows that less energy is wasted as heat such that the bias applied can be utilized more efficiently to assist the nucleation of the filament and thus reduces the power consumption. Electrical power dissipation is also found to scale with nanocrystal height and has spatial dependence within the nanocrystals. The combination of synaptic switching and high density of the nanocrystals demonstrate that it is feasible to exploit them to create a basic architecture for neuromorphic memory devices.

Sponsoring Organization:
USDOE
OSTI ID:
1604517
Journal Information:
Advanced Electronic Materials, Journal Name: Advanced Electronic Materials Vol. 6 Journal Issue: 5; ISSN 2199-160X
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

References (47)

Nano/CMOS architectures using a field-programmable nanowire interconnect journal January 2007
Recent progress in resistive random access memories: Materials, switching mechanisms, and performance journal September 2014
Nucleation and growth phenomena in nanosized electrochemical systems for resistive switching memories journal October 2012
An approximate backpropagation learning rule for memristor based neural networks using synaptic plasticity journal May 2017
Switching Power Universality in Unipolar Resistive Switching Memories journal April 2016
The band excitation method in scanning probe microscopy for rapid mapping of energy dissipation on the nanoscale journal September 2007
Filament Shape Dependent Reset Behavior Governed by the Interplay between the Electric Field and Thermal Effects in the Pt/TiO 2 /Cu Electrochemical Metallization Device journal January 2017
Nanofilamentary resistive switching in binary oxide system; a review on the present status and outlook journal May 2011
Synthesis of Epitaxial Metal Oxide Nanocrystals via a Phase Separation Approach journal August 2010
Interface mediated resistive switching in epitaxial NiO nanostructures journal May 2012
Low-power resistive switching in Au/NiO/Au nanowire arrays journal November 2012
Role of structural defects in the unipolar resistive switching characteristics of Pt∕NiO∕Pt structures journal July 2008
A Review of Three-Dimensional Resistive Switching Cross-Bar Array Memories from the Integration and Materials Property Points of View journal July 2014
Nonvolatile Memory Materials for Neuromorphic Intelligent Machines journal April 2018
Effects of electrode materials on bipolar and unipolar switching in NiO resistive switching device journal November 2014
Deterministic Role of Concentration Surplus of Cation Vacancy over Anion Vacancy in Bipolar Memristive NiO journal April 2016
Nanoscale Probing of Elastic–Electronic Response to Vacancy Motion in NiO Nanocrystals journal August 2017
CMOL FPGA: a reconfigurable architecture for hybrid digital circuits with two-terminal nanodevices journal April 2005
Effects of metal electrodes on the resistive memory switching property of NiO thin films journal July 2008
Electrical Modulation of the Local Conduction at Oxide Tubular Interfaces journal September 2013
High-Density Crossbar Arrays Based on a Si Memristive System journal February 2009
Emerging memories: resistive switching mechanisms and current status journal June 2012
Nanoscale resistive switching and filamentary conduction in NiO thin films journal September 2010
Resistive switching and synaptic properties of fully atomic layer deposition grown TiN/HfO 2 /TiN devices journal January 2015
Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges journal July 2009
Correlative Multimodal Probing of Ionically-Mediated Electromechanical Phenomena in Simple Oxides journal October 2013
Write Current Reduction in Transition Metal Oxide Based Resistance Change Memory journal March 2008
Memristor-The missing circuit element journal January 1971
Resistive Switching in Polymer Nanocomposites by Matrix-Controlled in Situ Nanoparticles Generation journal June 2017
Effect of interfaces on the nearby Brownian motion journal October 2015
Identification of a determining parameter for resistive switching of TiO2 thin films journal June 2005
Nanoscale Memristor Device as Synapse in Neuromorphic Systems journal April 2010
Robust Pattern Transfer of Nanoimprinted Features for Sub-5-nm Fabrication journal October 2009
One bipolar transistor selector - One resistive random access memory device for cross bar memory array journal September 2017
Probing Local Ionic Dynamics in Functional Oxides at the Nanoscale journal July 2013
Microscopic mechanism for unipolar resistive switching behaviour of nickel oxides journal January 2012
Thermodynamics of Phase Transitions and Bipolar Filamentary Switching in Resistive Random-Access Memory journal August 2017
How Ligands Affect Resistive Switching in Solution-Processed HfO 2 Nanoparticle Assemblies journal January 2018
Collective Motion of Conducting Filaments in Pt/n-Type TiO2/p-Type NiO/Pt Stacked Resistance Switching Memory journal March 2011
Resistive Switching Mechanisms on TaO x and SrRuO 3 Thin-Film Surfaces Probed by Scanning Tunneling Microscopy journal December 2015
Reduction in the reset current in a resistive random access memory consisting of NiOx brought about by reducing a parasitic capacitance journal July 2008
Self-assembled nanostructured resistive switching memory devices fabricated by templated bottom-up growth journal January 2016
NiO Resistive Random Access Memory Nanocapacitor Array on Graphene journal March 2010
Atomic structure of conducting nanofilaments in TiO2 resistive switching memory journal January 2010
Memristive devices for computing journal January 2013
Resistive switching and its suppression in Pt/Nb:SrTiO3 junctions journal June 2014
Nanoparticle Shape Evolution and Proximity Effects During Tip-Induced Electrochemical Processes journal December 2015

Related Subjects