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Title: Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [4];  [2];  [2];  [2];  [2];  [1]; ORCiD logo [1]
  1. College of Environmental and Energy EngineeringBeijing University of Technology Beijing 100124 P.R. China
  2. X-Ray Science Division, Advanced Photon SourceArgonne National Laboratory Lemont, Illinois 60439 USA
  3. Center of Nanoscale MaterialsArgonne National Laboratory Lemont, Illinois 60439 USA
  4. Jiangsu Key Laboratory of Advanced Catalytic Materials and TechnologyChangzhou University Changzhou 213164 P.R. China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1604104
Grant/Contract Number:  
[AC02-06CH11357]
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemElectroChem
Additional Journal Information:
[Journal Name: ChemElectroChem Journal Volume: 7 Journal Issue: 7]; Journal ID: ISSN 2196-0216
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Wang, Hao, Kou, Rong‐Hui, Jin, Qiu, Liu, Yu‐Zi, Yin, Feng‐Xiang, Sun, Cheng‐Jun, Wang, Liang, Ma, Zhi‐Yuan, Ren, Yang, Liu, Ning, and Chen, Biao‐Hua. Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x. Germany: N. p., 2020. Web. doi:10.1002/celc.202000038.
Wang, Hao, Kou, Rong‐Hui, Jin, Qiu, Liu, Yu‐Zi, Yin, Feng‐Xiang, Sun, Cheng‐Jun, Wang, Liang, Ma, Zhi‐Yuan, Ren, Yang, Liu, Ning, & Chen, Biao‐Hua. Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x. Germany. doi:10.1002/celc.202000038.
Wang, Hao, Kou, Rong‐Hui, Jin, Qiu, Liu, Yu‐Zi, Yin, Feng‐Xiang, Sun, Cheng‐Jun, Wang, Liang, Ma, Zhi‐Yuan, Ren, Yang, Liu, Ning, and Chen, Biao‐Hua. Wed . "Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x". Germany. doi:10.1002/celc.202000038.
@article{osti_1604104,
title = {Boosting the Oxygen Reduction Performance via Tuning the Synergy between Metal Core and Oxide Shell of Metal−Organic Frameworks‐Derived Co@CoO x},
author = {Wang, Hao and Kou, Rong‐Hui and Jin, Qiu and Liu, Yu‐Zi and Yin, Feng‐Xiang and Sun, Cheng‐Jun and Wang, Liang and Ma, Zhi‐Yuan and Ren, Yang and Liu, Ning and Chen, Biao‐Hua},
abstractNote = {},
doi = {10.1002/celc.202000038},
journal = {ChemElectroChem},
number = [7],
volume = [7],
place = {Germany},
year = {2020},
month = {4}
}

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Works referenced in this record:

Electronic structure of CoO, Li-doped CoO, and LiCoO 2
journal, September 1991


Impacts of Imidazolate Ligand on Performance of Zeolitic-Imidazolate Framework-Derived Oxygen Reduction Catalysts
journal, September 2019


Hollow Porous Carbon Fiber from Cotton with Nitrogen Doping
journal, December 2013


Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
journal, January 2012

  • Cheng, Fangyi; Chen, Jun
  • Chemical Society Reviews, Vol. 41, Issue 6, p. 2172-2192
  • DOI: 10.1039/c1cs15228a

Metal and Metal Oxide Interactions and Their Catalytic Consequences for Oxygen Reduction Reaction
journal, June 2017

  • Jia, Qingying; Ghoshal, Shraboni; Li, Jingkun
  • Journal of the American Chemical Society, Vol. 139, Issue 23
  • DOI: 10.1021/jacs.7b02378

ATHENA and ARTEMIS Interactive Graphical Data Analysisusing IFEFFIT
journal, January 2005


Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005

  • Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar
  • Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35
  • DOI: 10.1016/j.apcatb.2004.06.021

Hollow Zn/Co ZIF Particles Derived from Core-Shell ZIF-67@ZIF-8 as Selective Catalyst for the Semi-Hydrogenation of Acetylene
journal, August 2015

  • Yang, Jian; Zhang, Fengjun; Lu, Haiyuan
  • Angewandte Chemie International Edition, Vol. 54, Issue 37
  • DOI: 10.1002/anie.201504242

Fuel Cells and Precious-Metal Catalysts
journal, October 1999


Modification of surface electronic structure on TiO2(110) and TiO2(441) by Na deposition
journal, January 1988


Co/CoO Nanoparticles Assembled on Graphene for Electrochemical Reduction of Oxygen
journal, October 2012


Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Platinum group metal-free catalysts boost cost competitiveness of fuel cell vehicles
journal, July 2019


Co@Co 3 O 4 Encapsulated in Carbon Nanotube-Grafted Nitrogen-Doped Carbon Polyhedra as an Advanced Bifunctional Oxygen Electrode
journal, February 2016

  • Aijaz, Arshad; Masa, Justus; Rösler, Christoph
  • Angewandte Chemie International Edition, Vol. 55, Issue 12
  • DOI: 10.1002/anie.201509382

A photoelectron spectroscopy study of sub-monolayer interfaces annealed from 300 up to 623 K
journal, May 1997


Stability of Hydrocarbon Fuel Cell Membranes: Reaction of Hydroxyl Radicals with Sulfonated Phenylated Polyphenylenes
journal, February 2019


Co/CoO Nanoparticles Assembled on Graphene for Electrochemical Reduction of Oxygen
journal, October 2012

  • Guo, Shaojun; Zhang, Sen; Wu, Liheng
  • Angewandte Chemie International Edition, Vol. 51, Issue 47
  • DOI: 10.1002/anie.201206152

Characterization and properties of Zn/Co zeolitic imidazolate frameworks vs. ZIF-8 and ZIF-67
journal, January 2017

  • Zhou, Kui; Mousavi, Bibimaryam; Luo, Zhixiong
  • Journal of Materials Chemistry A, Vol. 5, Issue 3
  • DOI: 10.1039/C6TA07860E

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
journal, January 2017

  • Barkholtz, Heather M.; Liu, Di-Jia
  • Materials Horizons, Vol. 4, Issue 1
  • DOI: 10.1039/C6MH00344C

In situ encapsulation of core–shell-structured Co@Co 3 O 4 into nitrogen-doped carbon polyhedra as a bifunctional catalyst for rechargeable Zn–air batteries
journal, January 2018

  • Guo, Ziyang; Wang, Fengmei; Xia, Yuan
  • Journal of Materials Chemistry A, Vol. 6, Issue 4
  • DOI: 10.1039/C7TA09958D

Co/Co3O4/C–N, a novel nanostructure and excellent catalytic system for the oxygen reduction reaction
journal, September 2014


Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

  • Zhao, Dan; Shui, Jiang-Lan; Chen, Chen
  • Chemical Science, Vol. 3, Issue 11
  • DOI: 10.1039/c2sc20657a

EXPGUI , a graphical user interface for GSAS
journal, April 2001


Metal-organic frameworks for highly efficient oxygen electrocatalysis
journal, February 2018


Bifunktionale Sauerstoffelektroden durch Einbettung von Co@Co 3 O 4 -Nanopartikeln in CNT-gekoppelte Stickstoff-dotierte Kohlenstoffpolyeder
journal, February 2016

  • Aijaz, Arshad; Masa, Justus; Rösler, Christoph
  • Angewandte Chemie, Vol. 128, Issue 12
  • DOI: 10.1002/ange.201509382

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Supercapacitive cobalt oxide (Co3O4) thin films by spray pyrolysis
journal, August 2006


ZIF-67 incorporated with carbon derived from pomelo peels: A highly efficient bifunctional catalyst for oxygen reduction/evolution reactions
journal, May 2017


Electrochemical Catalyst–Support Effects and Their Stabilizing Role for IrO x Nanoparticle Catalysts during the Oxygen Evolution Reaction
journal, September 2016

  • Oh, Hyung-Suk; Nong, Hong Nhan; Reier, Tobias
  • Journal of the American Chemical Society, Vol. 138, Issue 38
  • DOI: 10.1021/jacs.6b07199

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011

  • Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
  • Chemistry - A European Journal, Vol. 17, Issue 7
  • DOI: 10.1002/chem.201003080

Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces
journal, June 2012

  • Zhang, Zhen; Yates, John T.
  • Chemical Reviews, Vol. 112, Issue 10
  • DOI: 10.1021/cr3000626

Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction
journal, April 2013

  • Wu, Gang; Zelenay, Piotr
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar400011z

An electron injection promoted highly efficient electrocatalyst of FeNi 3 @GR@Fe-NiOOH for oxygen evolution and rechargeable metal–air batteries
journal, January 2016

  • Wang, Xin; Liu, Xiangye; Tong, Chuan-Jia
  • Journal of Materials Chemistry A, Vol. 4, Issue 20
  • DOI: 10.1039/C6TA01541G

An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting
journal, December 2014

  • Hou, Yang; Wen, Zhenhai; Cui, Shumao
  • Advanced Functional Materials, Vol. 25, Issue 6
  • DOI: 10.1002/adfm.201403657

Well-Coupled Graphene and Pd-Based Bimetallic Nanocrystals Nanocomposites for Electrocatalytic Oxygen Reduction Reaction
journal, January 2014

  • Yin, Huanhuan; Liu, Suli; Zhang, Chunli
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 3
  • DOI: 10.1021/am405164f

Highly active NiCo alloy hexagonal nanoplates with crystal plane selective dehydrogenation and visible-light photocatalysis
journal, January 2012

  • Zhou, Shiqing; Wen, Ming; Wang, Na
  • Journal of Materials Chemistry, Vol. 22, Issue 33
  • DOI: 10.1039/c2jm32397d

A combination of CoO and Co nanoparticles supported on electrospun carbon nanofibers as highly stable air electrodes
journal, October 2017


Synthesis of an ε-MnO 2 /metal–organic-framework composite and its electrocatalysis towards oxygen reduction reaction in an alkaline electrolyte
journal, January 2015

  • Wang, Hao; Yin, Fengxiang; Chen, Biaohua
  • Journal of Materials Chemistry A, Vol. 3, Issue 31
  • DOI: 10.1039/C5TA02244D

A comparison of cobalt(II) and iron(II) hydroxyl and superoxide free radical formation
journal, November 1989

  • Kadiiska, Maria B.; Maples, Kirk R.; Mason, Ronald P.
  • Archives of Biochemistry and Biophysics, Vol. 275, Issue 1
  • DOI: 10.1016/0003-9861(89)90354-8

Strong Interactions in Supported-Metal Catalysts
journal, March 1981


3D hierarchical Co 3 O 4 microspheres with enhanced lithium-ion battery performance
journal, January 2015


Hollow Zn/Co ZIF Particles Derived from Core-Shell ZIF-67@ZIF-8 as Selective Catalyst for the Semi-Hydrogenation of Acetylene
journal, August 2015