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Title: 4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries

Authors:
; ; ; ; ; ORCiD logo; ORCiD logo
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1603742
Resource Type:
Published Article
Journal Name:
Journal of the Electrochemical Society (Online)
Additional Journal Information:
[Journal Name: Journal of the Electrochemical Society (Online) Journal Volume: 167 Journal Issue: 7]; Journal ID: ISSN 1945-7111
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Yang, Jianzhong, Shkrob, Ilya, Liu, Kewei, Connell, Justin, Dietz Rago, Nancy L., Zhang, Zhengcheng, and Liao, Chen. 4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries. United States: N. p., 2020. Web. doi:10.1149/1945-7111/ab7a9e.
Yang, Jianzhong, Shkrob, Ilya, Liu, Kewei, Connell, Justin, Dietz Rago, Nancy L., Zhang, Zhengcheng, & Liao, Chen. 4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries. United States. doi:10.1149/1945-7111/ab7a9e.
Yang, Jianzhong, Shkrob, Ilya, Liu, Kewei, Connell, Justin, Dietz Rago, Nancy L., Zhang, Zhengcheng, and Liao, Chen. Wed . "4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries". United States. doi:10.1149/1945-7111/ab7a9e.
@article{osti_1603742,
title = {4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries},
author = {Yang, Jianzhong and Shkrob, Ilya and Liu, Kewei and Connell, Justin and Dietz Rago, Nancy L. and Zhang, Zhengcheng and Liao, Chen},
abstractNote = {},
doi = {10.1149/1945-7111/ab7a9e},
journal = {Journal of the Electrochemical Society (Online)},
number = [7],
volume = [167],
place = {United States},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1149/1945-7111/ab7a9e

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Works referenced in this record:

A review on electrolyte additives for lithium-ion batteries
journal, November 2006


Improved Interfacial Properties of MCMB Electrode by 1-(Trimethylsilyl)imidazole as New Electrolyte Additive To Suppress LiPF 6 Decomposition
journal, January 2017

  • Wotango, Aselefech Sorsa; Su, Wei-Nien; Leggesse, Ermias Girma
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 3
  • DOI: 10.1021/acsami.6b13105

Decomposition reaction of LiPF6-based electrolytes for lithium ion cells
journal, June 2006


An accelerated calendar and cycle life study of Li-ion cells
journal, October 2001


High Voltage LiNi 0.5 Mn 0.3 Co 0.2 O 2 /Graphite Cell Cycled at 4.6 V with a FEC/HFDEC-Based Electrolyte
journal, April 2017

  • He, Meinan; Su, Chi-Cheung; Feng, Zhenxing
  • Advanced Energy Materials, Vol. 7, Issue 15
  • DOI: 10.1002/aenm.201700109

Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes
journal, January 2006

  • Choi, W.; Manthiram, A.
  • Journal of The Electrochemical Society, Vol. 153, Issue 9
  • DOI: 10.1149/1.2219710

Tunable and Robust Phosphite-Derived Surface Film to Protect Lithium-Rich Cathodes in Lithium-Ion Batteries
journal, April 2015

  • Han, Jung-Gu; Lee, Sung Jun; Lee, Jaegi
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 15
  • DOI: 10.1021/acsami.5b01770

Interpreting High Precision Coulometry Results on Li-ion Cells
journal, January 2011

  • Smith, A. J.; Burns, J. C.; Xiong, D.
  • Journal of The Electrochemical Society, Vol. 158, Issue 10
  • DOI: 10.1149/1.3625232

Editors' Choice—Practical Assessment of Anionic Redox in Li-Rich Layered Oxide Cathodes: A Mixed Blessing for High Energy Li-Ion Batteries
journal, January 2016

  • Assat, Gaurav; Delacourt, Charles; Corte, Daniel Alves Dalla
  • Journal of The Electrochemical Society, Vol. 163, Issue 14
  • DOI: 10.1149/2.0531614jes

Dehydration Rather Than HF Capture Explains Performance Improvements of Li-Ion Cells by Ceramic Nanoparticles
journal, July 2019

  • Rodrigues, Marco-Tulio F.; Liao, Chen; Kalaga, Kaushik
  • ACS Applied Energy Materials, Vol. 2, Issue 8
  • DOI: 10.1021/acsaem.9b00976

A causal study of the capacity fading of Li1.01Mn1.99O4 cathode at 80°C, and the suppressing substances of its fading
journal, August 2001


Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013

  • Li, Y.; Bettge, M.; Polzin, B.
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.002305jes

Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries
journal, January 2016

  • Qi, Xin; Tao, Liang; Hahn, Hendrik
  • RSC Advances, Vol. 6, Issue 44
  • DOI: 10.1039/C6RA06555D

Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016

  • Long, Brandon R.; Rinaldo, Steven G.; Gallagher, Kevin G.
  • Journal of The Electrochemical Society, Vol. 163, Issue 14
  • DOI: 10.1149/2.0691614jes

High capacity silicon nitride-based composite anodes for lithium ion batteries
journal, January 2014

  • de Guzman, Rhet C.; Yang, Jinho; Ming-Cheng Cheng, Mark
  • J. Mater. Chem. A, Vol. 2, Issue 35
  • DOI: 10.1039/C4TA02596B

Evaluating electrolyte additives for lithium-ion cells: A new Figure of Merit approach
journal, October 2017


Improving the electrochemical performance of high voltage spinel cathode at elevated temperature by a novel electrolyte additive
journal, January 2016


Effect of heptamethyldisilazane as an additive on the stability performance of LiMn2O4 cathode for lithium-ion battery
journal, April 2009


The mechanism of HF formation in LiPF6 based organic carbonate electrolytes
journal, January 2012


A Bifunctional Electrolyte Additive for High-Voltage LiNi 0.5 Mn 1.5 O 4 Positive Electrodes
journal, March 2019

  • Lee, Tae Jin; Soon, Jiyong; Chae, Seulki
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 12
  • DOI: 10.1021/acsami.8b19009

A bifunctional electrolyte additive for H 2 O/HF scavenging and enhanced graphite/LiNi 0.5 Co 0.2 Mn 0.3 O 2 cell performance at a high voltage
journal, January 2018

  • Zhou, Rong; Huang, Jianxing; Lai, Shaobo
  • Sustainable Energy & Fuels, Vol. 2, Issue 7
  • DOI: 10.1039/C8SE00064F

Photo electron transfer induced desilylation of N , N -bis(trimethylsilyl)aminodibenzoborole to aminodibenzoborole
journal, January 2019

  • Keck, Constanze; Maichle-Mössmer, Cäcilia; Bettinger, Holger F.
  • Chemical Communications, Vol. 55, Issue 52
  • DOI: 10.1039/C9CC03415C

Development of novel lithium borate additives for designed surface modification of high voltage LiNi 0.5 Mn 1.5 O 4 cathodes
journal, January 2016

  • Xu, Mengqing; Zhou, Liu; Dong, Yingnan
  • Energy & Environmental Science, Vol. 9, Issue 4
  • DOI: 10.1039/C5EE03360H

Thermal Decomposition of LiPF[sub 6]-Based Electrolytes for Lithium-Ion Batteries
journal, January 2005

  • Campion, Christopher L.; Li, Wentao; Lucht, Brett L.
  • Journal of The Electrochemical Society, Vol. 152, Issue 12
  • DOI: 10.1149/1.2083267