Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca 0.84Sr 0.16MoO 4
Abstract
A mixed alkaline-earth powellite, Ca 0.84Sr 0.16MoO 4 (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I4 1/a space group as with a typical CaMoO 4 powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1603651
- Report Number(s):
- PNNL-SA-150035
Journal ID: ISSN 2056-9890; ACSECI
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Crystallographica. Section E, Crystallographic Communications
- Additional Journal Information:
- Journal Volume: 76; Journal Issue: 2; Journal ID: ISSN 2056-9890
- Publisher:
- International Union of Crystallography
- Country of Publication:
- United States
- Language:
- English
- Subject:
- powellite; mixed alkaline-earth powellite; single-crystal XRD
Citation Formats
Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4. United States: N. p., 2020.
Web. doi:10.1107/S2056989019017092.
Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., & Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4. United States. doi:10.1107/S2056989019017092.
Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Fri .
"Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4". United States. doi:10.1107/S2056989019017092. https://www.osti.gov/servlets/purl/1603651.
@article{osti_1603651,
title = {Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4},
author = {Kissinger, Ryan M. and Chong, Saehwa and Riley, Brian J. and Crum, Jarrod V.},
abstractNote = {A mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4 (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I41/a space group as with a typical CaMoO4 powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.},
doi = {10.1107/S2056989019017092},
journal = {Acta Crystallographica. Section E, Crystallographic Communications},
number = 2,
volume = 76,
place = {United States},
year = {2020},
month = {1}
}
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Works referenced in this record:
Crystal Structure Refinement of SrMoO 4 , SrWO 4 , CaMoO 4 , and BaWO 4 by Neutron Diffraction
journal, August 1971
- Gürmen, Erdogan; Daniels, Eugene; King, J. S.
- The Journal of Chemical Physics, Vol. 55, Issue 3
Low-Temperature Synthesis of AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, October 2013
- Culver, Sean P.; Rabuffetti, Federico A.; Zhou, Shiliang
- Chemistry of Materials, Vol. 25, Issue 20
Structural Disorder in AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, November 2013
- Rabuffetti, Federico A.; Culver, Sean P.; Suescun, Leopoldo
- Inorganic Chemistry, Vol. 53, Issue 2
Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data.
journal, January 1987
- Wandahl, G.; Christensen, A. Nørlund; Hietanen, S.
- Acta Chemica Scandinavica, Vol. 41a
Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis
journal, August 2007
- Ryu, Jeong Ho; Bang, Sin Young; Yoon, Jong-Won
- Applied Surface Science, Vol. 253, Issue 20
Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013
- Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R.
- Chemical Reviews, Vol. 113, Issue 7
Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite
journal, August 1999
- Nassif, Vivian; Carbonio, Raúl E.; Alonso, José A.
- Journal of Solid State Chemistry, Vol. 146, Issue 1
Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method
journal, March 2008
- Bi, Jian; Cui, Chun-Hua; Lai, Xin
- Materials Research Bulletin, Vol. 43, Issue 3
Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method
journal, February 2003
- Kodaira, Cláudia A.; Brito, Hermi F.; Felinto, Maria Cláudia F. C.
- Journal of Solid State Chemistry, Vol. 171, Issue 1-2
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation
journal, July 2006
- Ahmad, G.; Dickerson, M. B.; Church, B. C.
- Advanced Materials, Vol. 18, Issue 13
Raman and x-ray diffraction investigations on BaMoO 4 under high pressures
journal, April 2006
- Panchal, Vinod; Garg, Nandini; Sharma, Surinder M.
- Journal of Physics: Condensed Matter, Vol. 18, Issue 16
Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca 2 RE 8 (SiO 4 ) 6 O 2 ( RE = La, Nd, Sm, Eu, or Yb) and NaLa 9 (SiO 4 ) 6 O 2
journal, June 2019
- Crum, Jarrod V.; Chong, Saehwa; Peterson, Jacob A.
- Acta Crystallographica Section E Crystallographic Communications, Vol. 75, Issue 7
SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions
journal, July 2007
- Palatinus, Lukáš; Chapuis, Gervais
- Journal of Applied Crystallography, Vol. 40, Issue 4
Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form
journal, November 2018
- Peterson, Jacob A.; Crum, Jarrod V.; Riley, Brian J.
- Journal of Nuclear Materials, Vol. 510
Rietveld refinement, morphology and optical properties of (Ba 1− x Sr x )MoO 4 crystals
journal, September 2013
- Nogueira, I. C.; Cavalcante, L. S.; Pereira, P. F. S.
- Journal of Applied Crystallography, Vol. 46, Issue 5
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011
- Momma, Koichi; Izumi, Fujio
- Journal of Applied Crystallography, Vol. 44, Issue 6
Sonochemical Preparation of Luminescent PbWO 4 Nanocrystals with Morphology Evolution
journal, January 2006
- Geng, Jun; Zhu, Jun-Jie; Chen, Hong-Yuan
- Crystal Growth & Design, Vol. 6, Issue 1
Potential red phosphor for UV-white LED device
journal, January 2007
- Kim, Taehyung; Kang, Shinhoo
- Journal of Luminescence, Vol. 122-123
Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition
journal, February 2010
- Lei, Hechang; Zhang, Shoubao; Zhu, Xuebin
- Materials Letters, Vol. 64, Issue 3
Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials
journal, November 2005
- Kato, A.; Oishi, S.; Shishido, T.
- Journal of Physics and Chemistry of Solids, Vol. 66, Issue 11
Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy
journal, January 2013
- Schmidt, Moritz; Heck, Stephanie; Bosbach, Dirk
- Dalton Transactions, Vol. 42, Issue 23
Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors
journal, April 2008
- Lei, Fang; Yan, Bing
- Journal of Solid State Chemistry, Vol. 181, Issue 4
Synthesis of CaWO4 nanoparticles by a molten salt method
journal, January 2006
- Wang, Yonggang; Ma, Junfeng; Tao, Jiantao
- Materials Letters, Vol. 60, Issue 2
publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010
- Westrip, Simon P.
- Journal of Applied Crystallography, Vol. 43, Issue 4
BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature
journal, November 2008
- Cavalcante, L. S.; Sczancoski, J. C.; Tranquilin, R. L.
- Journal of Physics and Chemistry of Solids, Vol. 69, Issue 11
Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals
journal, May 1983
- Arora, S. K.; Godbole, R. S.; Rao, G. S. Trivikrama
- Journal of the American Ceramic Society, Vol. 66, Issue 5