Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Kissinger, Ryan M.; Chong, Saehwa; Riley, Brian J.; Crum, Jarrod V.

doi:10.1107/S2056989019017092

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄

Abstract

A mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄ (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I4₁/a space group as with a typical CaMoO₄ powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.

Authors:

Kissinger, Ryan M. ^[1]; Chong, Saehwa ^[1];

^[1]; Crum, Jarrod V. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Publication Date:: 2020-01-03

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE)

OSTI Identifier:: 1603651

Report Number(s):: PNNL-SA-150035
Journal ID: ISSN 2056-9890; ACSECI

Grant/Contract Number:: AC05-76RL01830

Resource Type:: Accepted Manuscript

Journal Name:: Acta Crystallographica. Section E, Crystallographic Communications

Additional Journal Information:: Journal Volume: 76; Journal Issue: 2; Journal ID: ISSN 2056-9890

Publisher:: International Union of Crystallography

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; powellite; mixed alkaline-earth powellite; single-crystal XRD

Citation Formats


                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4.  United States: N. p., 2020. 
Web.  doi:10.1107/S2056989019017092.

Copy to clipboard


                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., & Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4.  United States.  https://doi.org/10.1107/S2056989019017092

Copy to clipboard


                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Fri .  
"Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4".  United States.  https://doi.org/10.1107/S2056989019017092.  https://www.osti.gov/servlets/purl/1603651.

Copy to clipboard


                    
@article{osti_1603651,

  title        = {Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4},

  author       = {Kissinger, Ryan M. and Chong, Saehwa and Riley, Brian J. and Crum, Jarrod V.},

  abstractNote = {A mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4 (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I41/a space group as with a typical CaMoO4 powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.},

  doi          = {10.1107/S2056989019017092},

  journal      = {Acta Crystallographica. Section E, Crystallographic Communications},

  number       = 2,

  volume       = 76,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1107/S2056989019017092

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Crystal Structure Refinement of SrMoO ₄ , SrWO ₄ , CaMoO ₄ , and BaWO ₄ by Neutron Diffraction
journal, August 1971

Gürmen, Erdogan; Daniels, Eugene; King, J. S.
The Journal of Chemical Physics, Vol. 55, Issue 3
DOI: 10.1063/1.1676191

Low-Temperature Synthesis of AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, October 2013

Culver, Sean P.; Rabuffetti, Federico A.; Zhou, Shiliang
Chemistry of Materials, Vol. 25, Issue 20
DOI: 10.1021/cm402867y

Structural Disorder in AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, November 2013

Rabuffetti, Federico A.; Culver, Sean P.; Suescun, Leopoldo
Inorganic Chemistry, Vol. 53, Issue 2
DOI: 10.1021/ic4025348

Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data.
journal, January 1987

Wandahl, G.; Christensen, A. Nørlund; Hietanen, S.
Acta Chemica Scandinavica, Vol. 41a
DOI: 10.3891/acta.chem.scand.41a-0358

Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis
journal, August 2007

Ryu, Jeong Ho; Bang, Sin Young; Yoon, Jong-Won
Applied Surface Science, Vol. 253, Issue 20
DOI: 10.1016/j.apsusc.2007.04.010

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013

Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R.
Chemical Reviews, Vol. 113, Issue 7
DOI: 10.1021/cr3001884

Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite
journal, August 1999

Nassif, Vivian; Carbonio, Raúl E.; Alonso, José A.
Journal of Solid State Chemistry, Vol. 146, Issue 1
DOI: 10.1006/jssc.1999.8352

Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method
journal, March 2008

Bi, Jian; Cui, Chun-Hua; Lai, Xin
Materials Research Bulletin, Vol. 43, Issue 3
DOI: 10.1016/j.materresbull.2007.03.021

Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method
journal, February 2003

Kodaira, Cláudia A.; Brito, Hermi F.; Felinto, Maria Cláudia F. C.
Journal of Solid State Chemistry, Vol. 171, Issue 1-2
DOI: 10.1016/S0022-4596(02)00221-9

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Shannon, R. D.
Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
DOI: 10.1107/S0567739476001551

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation
journal, July 2006

Ahmad, G.; Dickerson, M. B.; Church, B. C.
Advanced Materials, Vol. 18, Issue 13
DOI: 10.1002/adma.200600243

Raman and x-ray diffraction investigations on BaMoO ₄ under high pressures
journal, April 2006

Panchal, Vinod; Garg, Nandini; Sharma, Surinder M.
Journal of Physics: Condensed Matter, Vol. 18, Issue 16
DOI: 10.1088/0953-8984/18/16/002

Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca ₂ RE ₈ (SiO ₄ ) ₆ O ₂ ( RE = La, Nd, Sm, Eu, or Yb) and NaLa ₉ (SiO ₄ ) ₆ O ₂
journal, June 2019

Crum, Jarrod V.; Chong, Saehwa; Peterson, Jacob A.
Acta Crystallographica Section E Crystallographic Communications, Vol. 75, Issue 7
DOI: 10.1107/S2056989019008442

SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions
journal, July 2007

Palatinus, Lukáš; Chapuis, Gervais
Journal of Applied Crystallography, Vol. 40, Issue 4
DOI: 10.1107/S0021889807029238

Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form
journal, November 2018

Peterson, Jacob A.; Crum, Jarrod V.; Riley, Brian J.
Journal of Nuclear Materials, Vol. 510
DOI: 10.1016/j.jnucmat.2018.08.048

Rietveld refinement, morphology and optical properties of (Ba _{1− x} Sr _x )MoO ₄ crystals
journal, September 2013

Nogueira, I. C.; Cavalcante, L. S.; Pereira, P. F. S.
Journal of Applied Crystallography, Vol. 46, Issue 5
DOI: 10.1107/S0021889813020335

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Momma, Koichi; Izumi, Fujio
Journal of Applied Crystallography, Vol. 44, Issue 6
DOI: 10.1107/S0021889811038970

Sonochemical Preparation of Luminescent PbWO ₄ Nanocrystals with Morphology Evolution
journal, January 2006

Geng, Jun; Zhu, Jun-Jie; Chen, Hong-Yuan
Crystal Growth & Design, Vol. 6, Issue 1
DOI: 10.1021/cg050235s

Potential red phosphor for UV-white LED device
journal, January 2007

Kim, Taehyung; Kang, Shinhoo
Journal of Luminescence, Vol. 122-123
DOI: 10.1016/j.jlumin.2006.01.339

Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition
journal, February 2010

Lei, Hechang; Zhang, Shoubao; Zhu, Xuebin
Materials Letters, Vol. 64, Issue 3
DOI: 10.1016/j.matlet.2009.11.010

Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials
journal, November 2005

Kato, A.; Oishi, S.; Shishido, T.
Journal of Physics and Chemistry of Solids, Vol. 66, Issue 11
DOI: 10.1016/j.jpcs.2005.09.058

Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy
journal, January 2013

Schmidt, Moritz; Heck, Stephanie; Bosbach, Dirk
Dalton Transactions, Vol. 42, Issue 23
DOI: 10.1039/c3dt50146a

Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors
journal, April 2008

Lei, Fang; Yan, Bing
Journal of Solid State Chemistry, Vol. 181, Issue 4
DOI: 10.1016/j.jssc.2008.01.033

Synthesis of CaWO4 nanoparticles by a molten salt method
journal, January 2006

Wang, Yonggang; Ma, Junfeng; Tao, Jiantao
Materials Letters, Vol. 60, Issue 2
DOI: 10.1016/j.matlet.2005.08.037

publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010

Westrip, Simon P.
Journal of Applied Crystallography, Vol. 43, Issue 4
DOI: 10.1107/S0021889810022120

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature
journal, November 2008

Cavalcante, L. S.; Sczancoski, J. C.; Tranquilin, R. L.
Journal of Physics and Chemistry of Solids, Vol. 69, Issue 11
DOI: 10.1016/j.jpcs.2008.06.107

Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals
journal, May 1983

Arora, S. K.; Godbole, R. S.; Rao, G. S. Trivikrama
Journal of the American Ceramic Society, Vol. 66, Issue 5
DOI: 10.1111/j.1151-2916.1983.tb10040.x

Similar Records in DOE PAGES and OSTI.GOV collections:

Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

Journal Article Brinkman, Kyle ; Marra, James ; Fox, Kevin ; ... - Journal of Alloys and Compounds

Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Momore »« less
https://doi.org/10.1016/j.jallcom.2012.09.049

Full Text Available
Single phase melt processed powellite (Ba,Ca)MoO₄ for the immobilization of Mo-rich nuclear waste

Journal Article Brinkman, Kyle ; Fox, Kevin M. ; Marra, James C. ; ... - Journal of Alloys and Compounds

Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO₄ crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO₄ and CaMoO₄ were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass,more »« less
https://doi.org/10.1016/j.jallcom.2012.09.049
Synthesis and characterization of oxyapatite [Ca₂Nd₈(SiO₄)₆O₂] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO₄] for a glass-ceramic waste form

Journal Article Peterson, Jacob A. ; Crum, Jarrod V. ; Riley, Brian J. ; ... - Journal of Nuclear Materials

This paper discusses the synthesis, characterization, and chemical durability assessment of oxyapatite [Ca₂Nd₈(SiO₄)₆O₂] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO₄]. These are the major crystalline phases that precipitate from the melt during cooling of a glass ceramic waste form currently being evaluated for immobilizing wastes produced during the aqueous reprocessing of used nuclear fuel. The oxyapatite was made at 99.7% purity using a solution-based process followed by heat treatments. The powellite, made by melting carbonates and slow-cooling the melt, formed two different phases, one rich in Ca (74.7%) and Sr (19.4%) (balance is Ba) and the other rich in Sr (25.6%) and Bamore »« less
https://doi.org/10.1016/j.jnucmat.2018.08.048
Crystal structures and comparisons of potassium rare-earth molybdates KRE(MoO₄)₂ (RE = Tb, Dy, Ho, Er, Yb, and Lu)

Journal Article Chong, Saehwa ; Perry, Samuel ; Riley, Brian J. ; ... - Acta Crystallographica. Section E, Crystallographic Communications

Six potassium rare-earth molybdates KRE(MoO₄)₂ (RE = Tb, Dy, Ho, Er, Yb, and Lu) were synthesized by flux-assisted growth in K₂Mo₃O₁₀. The crystal structures were determined using single-crystal X-ray diffraction data. The synthesized molybdates crystallize with the orthorhombic Pbcn space group (No. 60). Trendlines for unit-cell parameters were calculated using data from the current study. The unit-cell parameters a and c increase linearly whereas b decreases with larger RE cations, based on crystal radii. The unit-cell volumes increase linearly and the densities decrease linearly with larger RE cations. The average distances between the RE cations and the nearest O atomsmore »« less
https://doi.org/10.1107/s205698902001542x

Full Text Available
Synthesis and electrical properties of scheelite Ca{sub 1-x}Sm{sub x}MoO{sub 4+{delta}} solid electrolyte ceramics

Journal Article Cheng, Jihai ; Key Lab of Powder and Energy Sources Materials, Hefei University, Hefei 230022 ; Liu, Chenfei ; ... - Materials Research Bulletin

Graphical abstract: Scheelite-type Ca{sub 1-x}Sm{sub x}MoO{sub 4+{delta}} electrolyte ceramics can be considered as one of the best candidates to replace the YSZ electrolyte materials for SOFCs because of their high oxide ion conduction. Research highlights: {yields} Sm{sub x}Ca{sub 1-x}MoO{sub 4+{delta}} solid electrolyte with a tetragonal scheelite structure. {yields} Sm{sub x}Ca{sub 1-x}MoO{sub 4+{delta}} electrolyte is one of the best candidates to replace the YSZ electrolyte for SOFCs because of their high oxide ion conduction. {yields} The sintering temperature is greatly lower than traditional YSZ electrolyte. -- Abstract: Scheelite-type Ca{sub 1-x}Sm{sub x}MoO{sub 4+{delta}} electrolyte powders were prepared by the sol-gel auto-combustion process.more »« less
https://doi.org/10.1016/J.MATERRESBULL.2010.11.019

Similar Records
Related Works
dataset (1)

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Abstract

Citation Formats

Crystal Structure Refinement of SrMoO 4 , SrWO 4 , CaMoO 4 , and BaWO 4 by Neutron Diffraction journal, August 1971

Low-Temperature Synthesis of AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals journal, October 2013

Structural Disorder in AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals journal, November 2013

Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data. journal, January 1987

Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis journal, August 2007

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries journal, March 2013

Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite journal, August 1999

Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method journal, March 2008

Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method journal, February 2003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation journal, July 2006

Raman and x-ray diffraction investigations on BaMoO 4 under high pressures journal, April 2006

Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca 2 RE 8 (SiO 4 ) 6 O 2 ( RE = La, Nd, Sm, Eu, or Yb) and NaLa 9 (SiO 4 ) 6 O 2 journal, June 2019

SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions journal, July 2007

Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form journal, November 2018

Rietveld refinement, morphology and optical properties of (Ba 1− x Sr x )MoO 4 crystals journal, September 2013

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Sonochemical Preparation of Luminescent PbWO 4 Nanocrystals with Morphology Evolution journal, January 2006

Potential red phosphor for UV-white LED device journal, January 2007

Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition journal, February 2010

Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials journal, November 2005

Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy journal, January 2013

Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors journal, April 2008

Synthesis of CaWO4 nanoparticles by a molten salt method journal, January 2006

publCIF : software for editing, validating and formatting crystallographic information files journal, June 2010

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature journal, November 2008

Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals journal, May 1983

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄

Crystal Structure Refinement of SrMoO ₄ , SrWO ₄ , CaMoO ₄ , and BaWO ₄ by Neutron Diffraction
journal, August 1971

Low-Temperature Synthesis of AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, October 2013

Structural Disorder in AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, November 2013

Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data.
journal, January 1987

Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis
journal, August 2007

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013

Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite
journal, August 1999

Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method
journal, March 2008

Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method
journal, February 2003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation
journal, July 2006

Raman and x-ray diffraction investigations on BaMoO ₄ under high pressures
journal, April 2006

Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca ₂ RE ₈ (SiO ₄ ) ₆ O ₂ ( RE = La, Nd, Sm, Eu, or Yb) and NaLa ₉ (SiO ₄ ) ₆ O ₂
journal, June 2019

SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions
journal, July 2007

Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form
journal, November 2018

Rietveld refinement, morphology and optical properties of (Ba _{1− x} Sr _x )MoO ₄ crystals
journal, September 2013

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Sonochemical Preparation of Luminescent PbWO ₄ Nanocrystals with Morphology Evolution
journal, January 2006

Potential red phosphor for UV-white LED device
journal, January 2007

Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition
journal, February 2010

Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials
journal, November 2005

Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy
journal, January 2013

Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors
journal, April 2008

Synthesis of CaWO4 nanoparticles by a molten salt method
journal, January 2006

publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature
journal, November 2008

Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals
journal, May 1983