Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Kissinger, Ryan M.; Chong, Saehwa; Riley, Brian J.; Crum, Jarrod V.

doi:10.1107/S2056989019017092

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄

Abstract

A mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄ (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I4₁/a space group as with a typical CaMoO₄ powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.

Authors:

Kissinger, Ryan M. ^[1]; Chong, Saehwa ^[1];

^[1]; Crum, Jarrod V. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Publication Date:: 2020-01-03

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE)

OSTI Identifier:: 1603651

Report Number(s):: PNNL-SA-150035
Journal ID: ISSN 2056-9890; ACSECI

Grant/Contract Number:: AC05-76RL01830

Resource Type:: Accepted Manuscript

Journal Name:: Acta Crystallographica. Section E, Crystallographic Communications

Additional Journal Information:: Journal Volume: 76; Journal Issue: 2; Journal ID: ISSN 2056-9890

Publisher:: International Union of Crystallography

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; powellite; mixed alkaline-earth powellite; single-crystal XRD

Citation Formats


                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4.  United States: N. p., 2020. 
        Web.  doi:10.1107/S2056989019017092.

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                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., & Crum, Jarrod V. Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4.  United States.  doi:https://doi.org/10.1107/S2056989019017092

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                    Kissinger, Ryan M., Chong, Saehwa, Riley, Brian J., and Crum, Jarrod V. Fri .  
        "Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4".  United States.  doi:https://doi.org/10.1107/S2056989019017092.  https://www.osti.gov/servlets/purl/1603651.

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@article{osti_1603651,

  title        = {Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4},

  author       = {Kissinger, Ryan M. and Chong, Saehwa and Riley, Brian J. and Crum, Jarrod V.},

  abstractNote = {A mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4 (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I41/a space group as with a typical CaMoO4 powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.},

  doi          = {10.1107/S2056989019017092},

  journal      = {Acta Crystallographica. Section E, Crystallographic Communications},

  number       = 2,

  volume       = 76,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

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Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Abstract

Citation Formats

Crystal Structure Refinement of SrMoO 4 , SrWO 4 , CaMoO 4 , and BaWO 4 by Neutron Diffraction journal, August 1971

Low-Temperature Synthesis of AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals journal, October 2013

Structural Disorder in AMoO 4 (A = Ca, Sr, Ba) Scheelite Nanocrystals journal, November 2013

Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data. journal, January 1987

Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis journal, August 2007

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries journal, March 2013

Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite journal, August 1999

Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method journal, March 2008

Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method journal, February 2003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation journal, July 2006

Raman and x-ray diffraction investigations on BaMoO 4 under high pressures journal, April 2006

Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca 2 RE 8 (SiO 4 ) 6 O 2 ( RE = La, Nd, Sm, Eu, or Yb) and NaLa 9 (SiO 4 ) 6 O 2 journal, June 2019

SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions journal, July 2007

Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form journal, November 2018

Rietveld refinement, morphology and optical properties of (Ba 1− x Sr x )MoO 4 crystals journal, September 2013

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Sonochemical Preparation of Luminescent PbWO 4 Nanocrystals with Morphology Evolution journal, January 2006

Potential red phosphor for UV-white LED device journal, January 2007

Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition journal, February 2010

Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials journal, November 2005

Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy journal, January 2013

Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors journal, April 2008

Synthesis of CaWO4 nanoparticles by a molten salt method journal, January 2006

publCIF : software for editing, validating and formatting crystallographic information files journal, June 2010

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature journal, November 2008

Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals journal, May 1983

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄

Crystal Structure Refinement of SrMoO ₄ , SrWO ₄ , CaMoO ₄ , and BaWO ₄ by Neutron Diffraction
journal, August 1971

Low-Temperature Synthesis of AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, October 2013

Structural Disorder in AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, November 2013

Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data.
journal, January 1987

Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis
journal, August 2007

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013

Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite
journal, August 1999

Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method
journal, March 2008

Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method
journal, February 2003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation
journal, July 2006

Raman and x-ray diffraction investigations on BaMoO ₄ under high pressures
journal, April 2006

Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca ₂ RE ₈ (SiO ₄ ) ₆ O ₂ ( RE = La, Nd, Sm, Eu, or Yb) and NaLa ₉ (SiO ₄ ) ₆ O ₂
journal, June 2019

SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions
journal, July 2007

Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form
journal, November 2018

Rietveld refinement, morphology and optical properties of (Ba _{1− x} Sr _x )MoO ₄ crystals
journal, September 2013

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Sonochemical Preparation of Luminescent PbWO ₄ Nanocrystals with Morphology Evolution
journal, January 2006

Potential red phosphor for UV-white LED device
journal, January 2007

Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition
journal, February 2010

Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials
journal, November 2005

Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy
journal, January 2013

Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors
journal, April 2008

Synthesis of CaWO4 nanoparticles by a molten salt method
journal, January 2006

publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature
journal, November 2008

Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals
journal, May 1983