Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Kissinger, Ryan M.; Chong, Saehwa; Riley, Brian J.; Crum, Jarrod V.

doi:10.1107/S2056989019017092

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄

Journal Article · 02 January 2020 · Acta Crystallographica. Section E, Crystallographic Communications

DOI: https://doi.org/10.1107/S2056989019017092 · OSTI ID:1603651

Kissinger, Ryan M. ^[1]; Chong, Saehwa ^[1];

^[1]; Crum, Jarrod V. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

A mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄ (calcium strontium molybdate), was synthesized by a flux method and its crystal structure was solved using single-crystal X-ray diffraction (SC-XRD) data. The compound crystallized in the I4₁/a space group as with a typical CaMoO₄ powellite, but with larger unit-cell parameters and unit-cell volume as a result of the partial incorporation of larger Sr cations into the Ca sites within the crystal. The unit cell and volume were well fitted with the trendline calculated from literature values, and the powder X-ray diffraction (P-XRD) pattern of the ground crystal is in good agreement with the calculated pattern from the solved structure.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1603651

Report Number(s):: PNNL-SA--150035

Journal Information:: Acta Crystallographica. Section E, Crystallographic Communications, Journal Name: Acta Crystallographica. Section E, Crystallographic Communications Journal Issue: 2 Vol. 76; ISSN ACSECI; ISSN 2056-9890

Publisher:: International Union of CrystallographyCopyright Statement

Country of Publication:: United States

Language:: English

References (27)

Rapid, Room-Temperature Formation of Crystalline Calcium Molybdate Phosphor Microparticles via Peptide-Induced Precipitation Ahmad, G.; Dickerson, M. B.; Church, B. C. Advanced Materials, Vol. 18, Issue 13 https://doi.org/10.1002/adma.200600243	journal	July 2006
Neutron Diffraction Study of the Crystal Structure of BaMoO4: A Suitable Precursor for Metallic BaMoO3 Perovskite Nassif, Vivian; Carbonio, Raúl E.; Alonso, José A. Journal of Solid State Chemistry, Vol. 146, Issue 1 https://doi.org/10.1006/jssc.1999.8352	journal	August 1999
Luminescence investigation of Eu 3+ ion in the RE 2 (WO 4 ) 3 matrix ( RE =La and Gd) produced using the Pechini method Kodaira, Cláudia A.; Brito, Hermi F.; Felinto, Maria Cláudia F. C. Journal of Solid State Chemistry, Vol. 171, Issue 1-2 https://doi.org/10.1016/S0022-4596(02)00221-9	journal	February 2003
Pulsed laser induced synthesis of scheelite-type colloidal nanoparticles in liquid and the size distribution by nanoparticle tracking analysis Ryu, Jeong Ho; Bang, Sin Young; Yoon, Jong-Won Applied Surface Science, Vol. 253, Issue 20 https://doi.org/10.1016/j.apsusc.2007.04.010	journal	August 2007
Potential red phosphor for UV-white LED device Kim, Taehyung; Kang, Shinhoo Journal of Luminescence, Vol. 122-123 https://doi.org/10.1016/j.jlumin.2006.01.339	journal	January 2007
Synthesis and characterization of oxyapatite [Ca2Nd8(SiO4)6O2] and mixed-alkaline-earth powellite [(Ca,Sr,Ba)MoO4] for a glass-ceramic waste form Peterson, Jacob A.; Crum, Jarrod V.; Riley, Brian J. Journal of Nuclear Materials, Vol. 510 https://doi.org/10.1016/j.jnucmat.2018.08.048	journal	November 2018
Evaluation of stoichiometric rare-earth molybdate and tungstate compounds as laser materials Kato, A.; Oishi, S.; Shishido, T. Journal of Physics and Chemistry of Solids, Vol. 66, Issue 11 https://doi.org/10.1016/j.jpcs.2005.09.058	journal	November 2005
BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature Cavalcante, L. S.; Sczancoski, J. C.; Tranquilin, R. L. Journal of Physics and Chemistry of Solids, Vol. 69, Issue 11 https://doi.org/10.1016/j.jpcs.2008.06.107	journal	November 2008
Hydrothermal synthesis and luminescence of CaMO4:RE3+ (M=W, Mo; RE=Eu, Tb) submicro-phosphors Lei, Fang; Yan, Bing Journal of Solid State Chemistry, Vol. 181, Issue 4 https://doi.org/10.1016/j.jssc.2008.01.033	journal	April 2008
Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method Bi, Jian; Cui, Chun-Hua; Lai, Xin Materials Research Bulletin, Vol. 43, Issue 3 https://doi.org/10.1016/j.materresbull.2007.03.021	journal	March 2008
Synthesis of CaWO4 nanoparticles by a molten salt method Wang, Yonggang; Ma, Junfeng; Tao, Jiantao Materials Letters, Vol. 60, Issue 2 https://doi.org/10.1016/j.matlet.2005.08.037	journal	January 2006
Growth and photoluminescence of (00l)-oriented RMoO4 films by chemical solution deposition Lei, Hechang; Zhang, Shoubao; Zhu, Xuebin Materials Letters, Vol. 64, Issue 3 https://doi.org/10.1016/j.matlet.2009.11.010	journal	February 2010
Sonochemical Preparation of Luminescent PbWO ₄ Nanocrystals with Morphology Evolution Geng, Jun; Zhu, Jun-Jie; Chen, Hong-Yuan Crystal Growth & Design, Vol. 6, Issue 1 https://doi.org/10.1021/cg050235s	journal	January 2006
Low-Temperature Synthesis of AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals Culver, Sean P.; Rabuffetti, Federico A.; Zhou, Shiliang Chemistry of Materials, Vol. 25, Issue 20 https://doi.org/10.1021/cm402867y	journal	October 2013
Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R. Chemical Reviews, Vol. 113, Issue 7 https://doi.org/10.1021/cr3001884	journal	March 2013
Structural Disorder in AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals Rabuffetti, Federico A.; Culver, Sean P.; Suescun, Leopoldo Inorganic Chemistry, Vol. 53, Issue 2 https://doi.org/10.1021/ic4025348	journal	November 2013
Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy Schmidt, Moritz; Heck, Stephanie; Bosbach, Dirk Dalton Transactions, Vol. 42, Issue 23 https://doi.org/10.1039/c3dt50146a	journal	January 2013
Crystal Structure Refinement of SrMoO ₄ , SrWO ₄ , CaMoO ₄ , and BaWO ₄ by Neutron Diffraction Gürmen, Erdogan; Daniels, Eugene; King, J. S. The Journal of Chemical Physics, Vol. 55, Issue 3 https://doi.org/10.1063/1.1676191	journal	August 1971
Raman and x-ray diffraction investigations on BaMoO ₄ under high pressures Panchal, Vinod; Garg, Nandini; Sharma, Surinder M. Journal of Physics: Condensed Matter, Vol. 18, Issue 16 https://doi.org/10.1088/0953-8984/18/16/002	journal	April 2006
SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions Palatinus, Lukáš; Chapuis, Gervais Journal of Applied Crystallography, Vol. 40, Issue 4 https://doi.org/10.1107/S0021889807029238	journal	July 2007
publCIF : software for editing, validating and formatting crystallographic information files Westrip, Simon P. Journal of Applied Crystallography, Vol. 43, Issue 4 https://doi.org/10.1107/S0021889810022120	journal	June 2010
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Rietveld refinement, morphology and optical properties of (Ba _{1− x} Sr _x )MoO ₄ crystals Nogueira, I. C.; Cavalcante, L. S.; Pereira, P. F. S. Journal of Applied Crystallography, Vol. 46, Issue 5 https://doi.org/10.1107/S0021889813020335	journal	September 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca ₂ RE ₈ (SiO ₄ ) ₆ O ₂ ( RE = La, Nd, Sm, Eu, or Yb) and NaLa ₉ (SiO ₄ ) ₆ O ₂ Crum, Jarrod V.; Chong, Saehwa; Peterson, Jacob A. Acta Crystallographica Section E Crystallographic Communications, Vol. 75, Issue 7 https://doi.org/10.1107/S2056989019008442	journal	June 2019
Characterization of Flux-Grown Ca(WO4)x(MoO4)1-x Crystals Arora, S. K.; Godbole, R. S.; Rao, G. S. Trivikrama Journal of the American Ceramic Society, Vol. 66, Issue 5 https://doi.org/10.1111/j.1151-2916.1983.tb10040.x	journal	May 1983
Neutron Powder Diffraction Profile Refinement Studies on CaMoO4. A Comparison with Single-Crystal Data. Wandahl, G.; Christensen, A. Nørlund; Hietanen, S. Acta Chemica Scandinavica, Vol. 41a https://doi.org/10.3891/acta.chem.scand.41a-0358	journal	January 1987

Similar Records

Crystal structures and comparisons of potassium rare-earth molybdates KRE(MoO₄)₂ (RE = Tb, Dy, Ho, Er, Yb, and Lu)

Journal Article · 2020 · Acta Crystallographica. Section E, Crystallographic Communications · OSTI ID:1728579

Chong, Saehwa; Perry, Samuel; Riley, Brian J.; +1 more

Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

Journal Article · 2012 · Journal of Alloys and Compounds · OSTI ID:1053795

Brinkman, Kyle; Marra, James; Fox, Kevin; +3 more

Single phase melt processed powellite (Ba,Ca)MoO₄ for the immobilization of Mo-rich nuclear waste

Journal Article · 2012 · Journal of Alloys and Compounds · OSTI ID:1158504

Brinkman, Kyle; Fox, Kevin M.; Marra, James C.; +3 more

Related Subjects

36 MATERIALS SCIENCE
mixed alkaline-earth powellite
powellite
single-crystal XRD

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca0.84Sr0.16MoO4

Citation Formats

References (27)

Linked Research (1)

Similar Records

Related Subjects

Title: Synthesis and crystal structure of a mixed alkaline-earth powellite, Ca_0.84Sr_0.16MoO₄