skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on March 4, 2021

Title: Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces

Authors:
 [1];  [1];  [2];  [3]; ORCiD logo [4]
  1. Department of ChemistryUniversity of New Hampshire 23 Academic Way Durham NH 03824 USA
  2. Materials Science ProgramUniversity of New Hampshire 23 Academic Way Durham NH 03824 USA
  3. Department of Chemical EngineeringWorcester Polytechnic Institute100 Institute Road Worcester MA 01609 USA
  4. Department of ChemistryUniversity of New Hampshire 23 Academic Way Durham NH 03824 USA, Materials Science ProgramUniversity of New Hampshire 23 Academic Way Durham NH 03824 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1603184
Grant/Contract Number:  
[SC0016417]
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemPhotoChem
Additional Journal Information:
[Journal Name: ChemPhotoChem]; Journal ID: ISSN 2367-0932
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Country unknown/Code not available
Language:
English

Citation Formats

Huang, Peipei, Pantovich, Sebastian A., Okolie, Norbert O., Deskins, N. Aaron, and Li, Gonghu. Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces. Country unknown/Code not available: N. p., 2020. Web. doi:10.1002/cptc.201900282.
Huang, Peipei, Pantovich, Sebastian A., Okolie, Norbert O., Deskins, N. Aaron, & Li, Gonghu. Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces. Country unknown/Code not available. doi:10.1002/cptc.201900282.
Huang, Peipei, Pantovich, Sebastian A., Okolie, Norbert O., Deskins, N. Aaron, and Li, Gonghu. Wed . "Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces". Country unknown/Code not available. doi:10.1002/cptc.201900282.
@article{osti_1603184,
title = {Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces},
author = {Huang, Peipei and Pantovich, Sebastian A. and Okolie, Norbert O. and Deskins, N. Aaron and Li, Gonghu},
abstractNote = {},
doi = {10.1002/cptc.201900282},
journal = {ChemPhotoChem},
number = ,
volume = ,
place = {Country unknown/Code not available},
year = {2020},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 4, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Photocatalytic CO 2 reduction using a molecular cobalt complex deposited on TiO 2 nanoparticles
journal, January 2014

  • Jin, Tong; Liu, Chao; Li, Gonghu
  • Chem. Commun., Vol. 50, Issue 47
  • DOI: 10.1039/C4CC00503A

Effect of the damping function in dispersion corrected density functional theory
journal, March 2011

  • Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars
  • Journal of Computational Chemistry, Vol. 32, Issue 7
  • DOI: 10.1002/jcc.21759

Visible-Light-Driven CO 2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts
journal, January 2015

  • Kuriki, Ryo; Sekizawa, Keita; Ishitani, Osamu
  • Angewandte Chemie, Vol. 127, Issue 8
  • DOI: 10.1002/ange.201411170

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Excited-State Dynamics of Graphitic Carbon Nitride Photocatalyst and Ultrafast Electron Injection to a Ru(II) Mononuclear Complex for Carbon Dioxide Reduction
journal, June 2018

  • Kuriki, Ryo; Ranasinghe, Chandana Sampath Kumara; Yamazaki, Yasuomi
  • The Journal of Physical Chemistry C, Vol. 122, Issue 29
  • DOI: 10.1021/acs.jpcc.8b03996

Gaussian basis sets for accurate calculations on molecular systems in gas and condensed phases
journal, September 2007

  • VandeVondele, Joost; Hutter, Jürg
  • The Journal of Chemical Physics, Vol. 127, Issue 11
  • DOI: 10.1063/1.2770708

Photoinduced Electron Transfer from Nitrogen-Doped Tantalum Oxide to Adsorbed Ruthenium Complex
journal, August 2011

  • Yamanaka, Ken-ichi; Sato, Shunsuke; Iwaki, Masayo
  • The Journal of Physical Chemistry C, Vol. 115, Issue 37
  • DOI: 10.1021/jp205223k

A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO 2 -to-CO Conversion with Visible Light
journal, May 2018

  • Cometto, Claudio; Kuriki, Ryo; Chen, Lingjing
  • Journal of the American Chemical Society, Vol. 140, Issue 24
  • DOI: 10.1021/jacs.8b04007

The Important Role of Tetrahedral Ti 4+ Sites in the Phase Transformation and Photocatalytic Activity of TiO 2 Nanocomposites
journal, April 2008

  • Li, Gonghu; Dimitrijevic, Nada M.; Chen, Le
  • Journal of the American Chemical Society, Vol. 130, Issue 16
  • DOI: 10.1021/ja711118u

Toward Solar-Driven Photocatalytic CO 2 Reduction Using Water as an Electron Donor
journal, February 2015

  • Sato, Shunsuke; Arai, Takeo; Morikawa, Takeshi
  • Inorganic Chemistry, Vol. 54, Issue 11
  • DOI: 10.1021/ic502766g

Nature-Inspired, Highly Durable CO 2 Reduction System Consisting of a Binuclear Ruthenium(II) Complex and an Organic Semiconductor Using Visible Light
journal, April 2016

  • Kuriki, Ryo; Matsunaga, Hironori; Nakashima, Takuya
  • Journal of the American Chemical Society, Vol. 138, Issue 15
  • DOI: 10.1021/jacs.6b01997

Solar CO 2 Reduction Using Surface-Immobilized Molecular Catalysts
journal, September 2015


Enhanced Charge Separation in Nanostructured TiO 2 Materials for Photocatalytic and Photovoltaic Applications
journal, May 2012

  • He, He; Liu, Chao; Dubois, Kevin D.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 37
  • DOI: 10.1021/ie300510n

Heterogenised Molecular Catalysts for the Reduction of CO 2 to Fuels
journal, August 2015

  • Windle, Christopher D.; Reisner, Erwin
  • CHIMIA International Journal for Chemistry, Vol. 69, Issue 7
  • DOI: 10.2533/chimia.2015.435

Visible-Light-Induced Selective CO 2 Reduction Utilizing a Ruthenium Complex Electrocatalyst Linked to a p-Type Nitrogen-Doped Ta 2 O 5 Semiconductor
journal, June 2010

  • Sato, Shunsuke; Morikawa, Takeshi; Saeki, Shu
  • Angewandte Chemie International Edition, Vol. 49, Issue 30
  • DOI: 10.1002/anie.201000613

Photochemical Reduction of CO 2 by Graphitic Carbon Nitride Polymers
journal, November 2013

  • Lin, Jinliang; Pan, Zhiming; Wang, Xinchen
  • ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 3
  • DOI: 10.1021/sc4004295

Synthesizing mixed-phase TiO2 nanocomposites using a hydrothermal method for photo-oxidation and photoreduction applications
journal, January 2008


Pseudopotentials for H to Kr optimized for gradient-corrected exchange-correlation functionals
journal, May 2005


Photochemical carbon dioxide reduction with metal complexes
journal, May 1999


A simple demonstration of reversible oxygenation
journal, October 1983

  • Kildahl, Nicholas K.
  • Journal of Chemical Education, Vol. 60, Issue 10
  • DOI: 10.1021/ed060p898

Photochemical CO 2 reduction using structurally controlled g-C 3 N 4
journal, January 2016

  • Walsh, James J.; Jiang, Chaoran; Tang, Junwang
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 36
  • DOI: 10.1039/C6CP04525A

Direct XANES Evidence for Charge Transfer in Co−CO 2 Complexes
journal, May 1997

  • Fujita, Etsuko; Furenlid, Lars R.; Renner, Mark W.
  • Journal of the American Chemical Society, Vol. 119, Issue 19
  • DOI: 10.1021/ja970151a

What Makes the Photocatalytic CO 2 Reduction on N-Doped Ta 2 O 5 Efficient: Insights from Nonadiabatic Molecular Dynamics
journal, August 2015

  • Akimov, Alexey V.; Asahi, Ryoji; Jinnouchi, Ryosuke
  • Journal of the American Chemical Society, Vol. 137, Issue 35
  • DOI: 10.1021/jacs.5b07454

Photochemical and Photoelectrochemical Reduction of CO 2
journal, May 2012


Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical CO2 Reduction System: Evidence of Co-CO2 Adducts as Intermediates
journal, June 1995

  • Ogata, Tomoyuki; Yanagida, Shozo; Brunschwig, Bruce S.
  • Journal of the American Chemical Society, Vol. 117, Issue 25
  • DOI: 10.1021/ja00130a009

Quickstep: Fast and accurate density functional calculations using a mixed Gaussian and plane waves approach
journal, April 2005

  • VandeVondele, Joost; Krack, Matthias; Mohamed, Fawzi
  • Computer Physics Communications, Vol. 167, Issue 2
  • DOI: 10.1016/j.cpc.2004.12.014

Visible-light CO 2 reduction over a ruthenium( ii )-complex/C 3 N 4 hybrid photocatalyst: the promotional effect of silver species
journal, January 2018

  • Maeda, Kazuhiko; An, Daehyeon; Kumara Ranasinghe, Chandana Sampath
  • Journal of Materials Chemistry A, Vol. 6, Issue 20
  • DOI: 10.1039/C8TA03245A

Visible-Light-Driven CO 2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts
journal, January 2015

  • Kuriki, Ryo; Sekizawa, Keita; Ishitani, Osamu
  • Angewandte Chemie International Edition, Vol. 54, Issue 8
  • DOI: 10.1002/anie.201411170

Efficient and selective electron mediation of cobalt complexes with cyclam and related macrocycles in the p-terphenyl-catalyzed photoreduction of carbon dioxide
journal, January 1993

  • Matsuoka, Shinjiro; Yamamoto, Kiichi; Ogata, Tomoyuki
  • Journal of the American Chemical Society, Vol. 115, Issue 2
  • DOI: 10.1021/ja00055a032

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
journal, October 2018


Upward Shift in Conduction Band of Ta 2 O 5 Due to Surface Dipoles Induced by N-Doping
journal, November 2015

  • Jinnouchi, Ryosuke; Akimov, Alexey V.; Shirai, Soichi
  • The Journal of Physical Chemistry C, Vol. 119, Issue 48
  • DOI: 10.1021/acs.jpcc.5b06932

Visible-Light-Driven CO 2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine
journal, July 2019

  • Roy, Souvik; Reisner, Erwin
  • Angewandte Chemie International Edition, Vol. 58, Issue 35
  • DOI: 10.1002/anie.201907082

Direct assembly synthesis of metal complex–semiconductor hybrid photocatalysts anchored by phosphonate for highly efficient CO2 reduction
journal, January 2011

  • Suzuki, Tomiko M.; Tanaka, Hiromitsu; Morikawa, Takeshi
  • Chemical Communications, Vol. 47, Issue 30
  • DOI: 10.1039/c1cc12491a

A hybrid Gaussian and plane wave density functional scheme
journal, October 1997

  • Lippert, By GERALD; Parrinello, JURG HUTTER and MICHELE
  • Molecular Physics, Vol. 92, Issue 3
  • DOI: 10.1080/002689797170220

Unique Solvent Effects on Visible-Light CO 2 Reduction over Ruthenium(II)-Complex/Carbon Nitride Hybrid Photocatalysts
journal, February 2016

  • Kuriki, Ryo; Ishitani, Osamu; Maeda, Kazuhiko
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 9
  • DOI: 10.1021/acsami.5b11836

Co-porphyrin/carbon nitride hybrids for improved photocatalytic CO2 reduction under visible light
journal, January 2017


Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

  • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001679

Selective CO 2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation
journal, October 2018

  • Huang, Peipei; Huang, Jiahao; Pantovich, Sebastian A.
  • Journal of the American Chemical Society, Vol. 140, Issue 47
  • DOI: 10.1021/jacs.8b10380

Molecular deposition of a macrocyclic cobalt catalyst on TiO2 nanoparticles
journal, November 2016


Visible light-sensitive mesoporous N-doped Ta2O5 spheres: synthesis and photocatalytic activity for hydrogen evolution and CO2 reduction
journal, January 2012

  • Suzuki, Tomiko M.; Nakamura, Tadashi; Saeki, Shu
  • Journal of Materials Chemistry, Vol. 22, Issue 47
  • DOI: 10.1039/c2jm33980c

Metal-Containing Carbon Nitride Compounds: A New Functional Organic-Metal Hybrid Material
journal, April 2009

  • Wang, Xinchen; Chen, Xiufang; Thomas, Arne
  • Advanced Materials, Vol. 21, Issue 16
  • DOI: 10.1002/adma.200802627