skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on February 25, 2021

Title: Growth and auto-oxidation of Pd on single-layer AgO x /Ag(111)

Abstract

Pd is auto-oxidized during deposition onto AgO x and undergoes a transition from single to bi-layer growth at low Pd coverage.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemical Engineering, University of Florida, Gainesville, USA
  2. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA
  3. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA, School of Engineering and Applied Sciences
  4. School of Engineering and Applied Sciences, Harvard University, Cambridge, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1602887
Grant/Contract Number:  
SC0012573
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 22 Journal Issue: 11; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Mehar, Vikram, O’Connor, Christopher R., Egle, Tobias, Karatok, Mustafa, Madix, Robert J., Friend, Cynthia M., and Weaver, Jason F. Growth and auto-oxidation of Pd on single-layer AgO x /Ag(111). United Kingdom: N. p., 2020. Web. doi:10.1039/C9CP06973A.
Mehar, Vikram, O’Connor, Christopher R., Egle, Tobias, Karatok, Mustafa, Madix, Robert J., Friend, Cynthia M., & Weaver, Jason F. Growth and auto-oxidation of Pd on single-layer AgO x /Ag(111). United Kingdom. doi:10.1039/C9CP06973A.
Mehar, Vikram, O’Connor, Christopher R., Egle, Tobias, Karatok, Mustafa, Madix, Robert J., Friend, Cynthia M., and Weaver, Jason F. Wed . "Growth and auto-oxidation of Pd on single-layer AgO x /Ag(111)". United Kingdom. doi:10.1039/C9CP06973A.
@article{osti_1602887,
title = {Growth and auto-oxidation of Pd on single-layer AgO x /Ag(111)},
author = {Mehar, Vikram and O’Connor, Christopher R. and Egle, Tobias and Karatok, Mustafa and Madix, Robert J. and Friend, Cynthia M. and Weaver, Jason F.},
abstractNote = {Pd is auto-oxidized during deposition onto AgO x and undergoes a transition from single to bi-layer growth at low Pd coverage.},
doi = {10.1039/C9CP06973A},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 11,
volume = 22,
place = {United Kingdom},
year = {2020},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on February 25, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

High-Coverage Oxygen-Induced Surface Structures on Ag(111)
journal, July 2014

  • Martin, N. M.; Klacar, S.; Grönbeck, H.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 28
  • DOI: 10.1021/jp504387p

In Situ Spectroscopic Study of the Oxidation and Reduction of Pd(111)
journal, December 2005

  • Ketteler, Guido; Ogletree, D. Frank; Bluhm, Hendrik
  • Journal of the American Chemical Society, Vol. 127, Issue 51
  • DOI: 10.1021/ja055754y

Mechanism of PdO thin film formation during the oxidation of Pd(111)
journal, September 2009


The oxidation of methanol on a silver (110) catalyst
journal, September 1978


Dynamics of Surface Alloys: Rearrangement of Pd/Ag(111) Induced by CO and O 2
journal, October 2018

  • van Spronsen, Matthijs A.; Daunmu, Kaining; O’Connor, Christopher R.
  • The Journal of Physical Chemistry C, Vol. 123, Issue 13
  • DOI: 10.1021/acs.jpcc.8b08849

Partial oxidation of higher olefins on Ag(111): Conversion of styrene to styrene oxide, benzene, and benzoic acid
journal, December 2006


STM study of high-coverage structures of atomic oxygen on Pt(111): p(2×1) and Pt oxide chain structures
journal, October 2008


Mechanism of Diethyl Ether Formation on Ag(110) and Its Dependence on Coadsorbed Oxygen Species
journal, February 1999

  • Jones, G. Scott; Barteau, Mark A.; Vohs, John M.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 7
  • DOI: 10.1021/jp983997p

Formation, stability and CO adsorption properties of PdAg/Pd(111) surface alloys
journal, April 2009


Thermally Selective Formation of Subsurface Oxygen in Ag(111) and Consequent Surface Structure
journal, June 2016


Structure and local reactivity of PdAg/Pd(111) surface alloys
journal, January 2013

  • Mancera, Luis A.; Behm, R. Jürgen; Groß, Axel
  • Phys. Chem. Chem. Phys., Vol. 15, Issue 5
  • DOI: 10.1039/C2CP42914D

Superior catalytic behaviour of Pt-doped Pd catalysts in the complete oxidation of methane at low temperature
journal, October 2006


Pt–Pd bimetallic catalysts for methane emissions abatement
journal, May 2007


Formation, atomic distribution and mixing energy in two-dimensional PdxAg1−x surface alloys on Pd(111)
journal, January 2012

  • Engstfeld, A. K.; Hoster, H. E.; Behm, R. J.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 30
  • DOI: 10.1039/c2cp41104k

Atomic and molecular oxygen adsorption on Ag(111)
journal, July 1985


Many-electron singularity in X-ray photoemission and X-ray line spectra from metals
journal, February 1970


Surface Chemistry of Late Transition Metal Oxides
journal, December 2012


Surface composition of clean and oxidized Pd75Ag25(100) from photoelectron spectroscopy and density functional theory calculations
journal, December 2012


CO Oxidation on PdO(101) during Temperature-Programmed Reaction Spectroscopy: Role of Oxygen Vacancies
journal, November 2014

  • Zhang, Feng; Pan, Li; Li, Tao
  • The Journal of Physical Chemistry C, Vol. 118, Issue 49
  • DOI: 10.1021/jp509383v

Adsorption and abstraction of oxygen atoms on Pd(111): Characterization of the precursor to PdO formation
journal, April 2008


High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold
journal, June 1972


Formation of surface oxides and Ag2O thin films with atomic oxygen on Ag(111)
journal, November 2015


Surface Characterization Study of the Thermal Decomposition of AgO
journal, August 1994

  • Weaver, Jason F.; Hoflund, Gar B.
  • The Journal of Physical Chemistry, Vol. 98, Issue 34
  • DOI: 10.1021/j100085a035

Photoelectron spectroscopy of the Ag/Pd(110) system
journal, March 1992


Surface Characterization Study of the Thermal Decomposition of Ag2O
journal, October 1994

  • Weaver, Jason F.; Hoflund, Gar B.
  • Chemistry of Materials, Vol. 6, Issue 10
  • DOI: 10.1021/cm00046a022

The formation of diethyl ether via the reaction of iodoethane with atomic oxygen on the Ag(110) surface
journal, January 1999


Selectivity Limitations in the Heterogeneous Epoxidation of Olefins:  Branching Reactions of the Oxametallacycle Intermediate in the Partial Oxidation of Styrene
journal, February 2006

  • Klust, Andreas; Madix, Robert J.
  • Journal of the American Chemical Society, Vol. 128, Issue 4
  • DOI: 10.1021/ja054845s

The interaction of CO with PdAg/Pd(111) surface alloys—A case study of ensemble effects on a bimetallic surface
journal, January 2011

  • Ma, Yunsheng; Diemant, T.; Bansmann, J.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 22
  • DOI: 10.1039/c1cp00009h