Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Lohrey, Trevor D.; Fostvedt, Jade I.; Bergman, Robert G.; Arnold, John

doi:10.1039/C9CC09475J

Title: Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Abstract

We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium( iii ) hydride and rhenium( i ) protio-BDI species readily interconvert between the solid and solution states.

Authors:

^[1];

^[2];

^[1]

Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
Department of Chemistry, University of California, Berkeley, USA

Publication Date:: Tue Mar 31 00:00:00 EDT 2020

Sponsoring Org.:: USDOE

OSTI Identifier:: 1602593

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 56 Journal Issue: 26; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., and Arnold, John. Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/C9CC09475J.

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                    Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., & Arnold, John. Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates.  United Kingdom.  https://doi.org/10.1039/C9CC09475J

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                    Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., and Arnold, John. Tue .  
"Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates".  United Kingdom.  https://doi.org/10.1039/C9CC09475J.

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@article{osti_1602593,

  title        = {Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates},

  author       = {Lohrey, Trevor D. and Fostvedt, Jade I. and Bergman, Robert G. and Arnold, John},

  abstractNote = {We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium( iii ) hydride and rhenium( i ) protio-BDI species readily interconvert between the solid and solution states.},

  doi          = {10.1039/C9CC09475J},

  journal      = {ChemComm},

  number       = 26,

  volume       = 56,

  place        = {United Kingdom},

  year         = {Tue Mar 31 00:00:00 EDT 2020},

  month        = {Tue Mar 31 00:00:00 EDT 2020}

}

Copy to clipboard

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Works referenced in this record:

Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand
journal, January 1984

Kubas, G. J.; Ryan, R. R.; Swanson, B. I.
Journal of the American Chemical Society, Vol. 106, Issue 2
DOI: 10.1021/ja00314a049

Dinitrogen complexes of rhenium(I) and rhenium(II)
journal, January 1973

Chatt, J.; Dilworth, J. R.; Leigh, G. J.
Journal of the Chemical Society, Dalton Transactions, Issue 6
DOI: 10.1039/dt9730000612

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis
journal, August 2011

Gunanathan, Chidambaram; Milstein, David
Accounts of Chemical Research, Vol. 44, Issue 8
DOI: 10.1021/ar2000265

Dehydrogenation of Dimethylamine–Borane Catalyzed by Half-Sandwich Ir and Rh Complexes: Mechanism and the Role of Cp* Noninnocence
journal, February 2018

Pal, Shrinwantu; Kusumoto, Shuhei; Nozaki, Kyoko
Organometallics, Vol. 37, Issue 6
DOI: 10.1021/acs.organomet.7b00889

The First Decaisopropylmetallocene: One-Pot Synthesis of[Rh(C5iPr5)2]PF6 from[Rh(C5Me5)2]PF6 by Formation of 20 Carbon–Carbon Bonds
journal, September 1994

Buchholz, Dirk; Astruc, Didier
Angewandte Chemie International Edition in English, Vol. 33, Issue 1516
DOI: 10.1002/anie.199416371

Cyclopentadiene-mediated hydride transfer from rhodium complexes
journal, January 2016

Pitman, C. L.; Finster, O. N. L.; Miller, A. J. M.
Chemical Communications, Vol. 52, Issue 58
DOI: 10.1039/C6CC00575F

H ₂ Activation and Direct Access to Terminal Nitride and cyclo -P ₃ Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate
journal, September 2019

Lohrey, Trevor D.; Rao, Guodong; Britt, R. David
Inorganic Chemistry, Vol. 58, Issue 19
DOI: 10.1021/acs.inorgchem.9b02556

Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding
journal, January 2019

Chambers, Geoffrey M.; Johnson, Samantha I.; Raugei, Simone
Chemical Science, Vol. 10, Issue 5
DOI: 10.1039/C8SC04239J

Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer
journal, September 2019

Drover, Marcus W.; Schild, Dirk J.; Oyala, Paul H.
Angewandte Chemie International Edition, Vol. 58, Issue 43
DOI: 10.1002/anie.201909050

Proton–hydride tautomerism in hydrogen evolution catalysis
journal, May 2016

Quintana, Luis M. Aguirre; Johnson, Samantha I.; Corona, Sydney L.
Proceedings of the National Academy of Sciences, Vol. 113, Issue 23
DOI: 10.1073/pnas.1606018113

Synthesis of a Tungsten–Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex
journal, March 2016

Fukuda, Tetsuya; Yoshimoto, Takashi; Hashimoto, Hisako
Organometallics, Vol. 35, Issue 7
DOI: 10.1021/acs.organomet.6b00095

Homogeneous Catalytic Reduction of Dioxygen Using Transfer Hydrogenation Catalysts
journal, November 2007

Heiden, Zachariah M.; Rauchfuss, Thomas B.
Journal of the American Chemical Society, Vol. 129, Issue 46
DOI: 10.1021/ja073774p

Backbone Reactivity of Lithium β‐Diketiminate (NacNac) Complexes with CO ₂ , t BuNCO and i PrNCO
journal, October 2019

Gauld, Richard M.; McLellan, Ross; Kennedy, Alan R.
Chemistry – A European Journal, Vol. 25, Issue 64
DOI: 10.1002/chem.201904013

Heterotetrametallic Re–Zn–Zn–Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate
journal, December 2018

Lohrey, Trevor D.; Maron, Laurent; Bergman, Robert G.
Journal of the American Chemical Society, Vol. 141, Issue 2
DOI: 10.1021/jacs.8b12494

Über aromatenkomplexe von metallen
journal, June 1966

Fischer, Ernst Otto; Wawersik, Henning
Journal of Organometallic Chemistry, Vol. 5, Issue 6
DOI: 10.1016/S0022-328X(00)85160-8

Thermodynamic Hydricity of Transition Metal Hydrides
journal, June 2016

Wiedner, Eric S.; Chambers, Matthew B.; Pitman, Catherine L.
Chemical Reviews, Vol. 116, Issue 15
DOI: 10.1021/acs.chemrev.6b00168

Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing
journal, January 2019

Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John
Dalton Transactions, Vol. 48, Issue 48
DOI: 10.1039/C9DT04489B

Synthesis, structure and possible formation pathway of a novel cobalt carbonyl compound with new type BO bond, Co(CO)3(PPh3)2BEt3, and mixed metal CoFeS cluster with possible nonlinear optical property, [Et4N][CoFe2(CO)8S(PPh3)]
journal, August 2002

Zhuang, Botao; Sun, Haofen; He, Lingjie
Journal of Organometallic Chemistry, Vol. 655, Issue 1-2
DOI: 10.1016/S0022-328X(02)01568-1

Fe-Mediated HER vs N ₂ RR: Exploring Factors That Contribute to Selectivity in P ₃ ^E Fe(N ₂ ) (E = B, Si, C) Catalyst Model Systems
journal, January 2018

Matson, Benjamin D.; Peters, Jonas C.
ACS Catalysis, Vol. 8, Issue 2
DOI: 10.1021/acscatal.7b03068

On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds
journal, January 2016

Camp, Clément; Arnold, John
Dalton Transactions, Vol. 45, Issue 37
DOI: 10.1039/C6DT02013E

Role of Ligand Protonation in Dihydrogen Evolution from a Pentamethylcyclopentadienyl Rhodium Catalyst
journal, September 2017

Johnson, Samantha I.; Gray, Harry B.; Blakemore, James D.
Inorganic Chemistry, Vol. 56, Issue 18
DOI: 10.1021/acs.inorgchem.7b01698

Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand
journal, October 2017

Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John
Angewandte Chemie International Edition, Vol. 56, Issue 45
DOI: 10.1002/anie.201707957

Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation
journal, February 2019

Chalkley, Matthew J.; Oyala, Paul H.; Peters, Jonas C.
Journal of the American Chemical Society, Vol. 141, Issue 11
DOI: 10.1021/jacs.9b00193

Base-Promoted, Remote C–H Activation at a Cationic (η ⁵ -C ₅ Me ₅ )Ir(III) Center Involving Reversible C–C Bond Formation of Bound C ₅ Me ₅
journal, January 2019

Moreno, Juan J.; Espada, María F.; Campos, Jesús
Journal of the American Chemical Society, Vol. 141, Issue 6
DOI: 10.1021/jacs.8b11752

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure
journal, November 2014

Crabtree, Robert H.
Chemical Reviews, Vol. 115, Issue 1
DOI: 10.1021/cr5004375

Nucleophilic and electrophilic reactions of C5 cyclo-polyenes coordinated to the [CpMoL2]n+ fragment (n = 1,2; L = 1/2dppe, PMe3, P(OMe)3, CO)
journal, October 1997

de Azevedo, Cristina G.; Calhorda, Maria J.; de C. T. Carrondo, M. A. A. F.
Journal of Organometallic Chemistry, Vol. 544, Issue 2
DOI: 10.1016/S0022-328X(97)00331-8

Synthesis and Reactivity toward H ₂ of (η ⁵ -C ₅ Me ₅ )Rh(III) Complexes with Bulky Aminopyridinate Ligands
journal, June 2015

Zamorano, Ana; Rendón, Nuria; Valpuesta, José E. V.
Inorganic Chemistry, Vol. 54, Issue 13
DOI: 10.1021/acs.inorgchem.5b00905

A New Intermolecular Interaction: UnconventionalHydrogen Bonds with Element−Hydride Bonds as ProtonAcceptor
journal, January 1996

Crabtree, Robert H.; Siegbahn, Per E. M.; Eisenstein, Odile
Accounts of Chemical Research, Vol. 29, Issue 7
DOI: 10.1021/ar950150s

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Title: Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Abstract

Citation Formats

Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand journal, January 1984

Dinitrogen complexes of rhenium(I) and rhenium(II) journal, January 1973

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis journal, August 2011

Dehydrogenation of Dimethylamine–Borane Catalyzed by Half-Sandwich Ir and Rh Complexes: Mechanism and the Role of Cp* Noninnocence journal, February 2018

The First Decaisopropylmetallocene: One-Pot Synthesis of[Rh(C5iPr5)2]PF6 from[Rh(C5Me5)2]PF6 by Formation of 20 Carbon–Carbon Bonds journal, September 1994

Cyclopentadiene-mediated hydride transfer from rhodium complexes journal, January 2016

H 2 Activation and Direct Access to Terminal Nitride and cyclo -P 3 Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate journal, September 2019

Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding journal, January 2019

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Über aromatenkomplexe von metallen journal, June 1966

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Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing journal, January 2019

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Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand journal, October 2017

Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation journal, February 2019

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Cyclopentadiene-mediated hydride transfer from rhodium complexes
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Synthesis, structure and possible formation pathway of a novel cobalt carbonyl compound with new type BO bond, Co(CO)3(PPh3)2BEt3, and mixed metal CoFeS cluster with possible nonlinear optical property, [Et4N][CoFe2(CO)8S(PPh3)]
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Nucleophilic and electrophilic reactions of C5 cyclo-polyenes coordinated to the [CpMoL2]n+ fragment (n = 1,2; L = 1/2dppe, PMe3, P(OMe)3, CO)
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