Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Lohrey, Trevor D.; Fostvedt, Jade I.; Bergman, Robert G.; Arnold, John

doi:10.1039/C9CC09475J

Title: Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Journal Article · 31 March 2020 · ChemComm

DOI: https://doi.org/10.1039/C9CC09475J · OSTI ID:1602593

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Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
Department of Chemistry, University of California, Berkeley, USA

We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium( iii ) hydride and rhenium( i ) protio-BDI species readily interconvert between the solid and solution states.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1602593

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 26 Vol. 56; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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