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Title: Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates

Abstract

We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium( iii ) hydride and rhenium( i ) protio-BDI species readily interconvert between the solid and solution states.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1602593
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 56 Journal Issue: 26; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., and Arnold, John. Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CC09475J.
Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., & Arnold, John. Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates. United Kingdom. doi:10.1039/C9CC09475J.
Lohrey, Trevor D., Fostvedt, Jade I., Bergman, Robert G., and Arnold, John. Tue . "Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates". United Kingdom. doi:10.1039/C9CC09475J.
@article{osti_1602593,
title = {Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates},
author = {Lohrey, Trevor D. and Fostvedt, Jade I. and Bergman, Robert G. and Arnold, John},
abstractNote = {We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium( iii ) hydride and rhenium( i ) protio-BDI species readily interconvert between the solid and solution states.},
doi = {10.1039/C9CC09475J},
journal = {ChemComm},
number = 26,
volume = 56,
place = {United Kingdom},
year = {2020},
month = {3}
}

Journal Article:
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