Proton-conducting oxides for energy conversion and storage

Duan, Chuancheng; Huang, Jake; Sullivan, Neal; O'Hayre, Ryan

doi:10.1063/1.5135319

Title: Proton-conducting oxides for energy conversion and storage

Journal Article · 02 March 2020 · Applied Physics Reviews

DOI: https://doi.org/10.1063/1.5135319 · OSTI ID:1602576

;

; Sullivan, Neal;

Proton-conducting oxides are a class of solid-state ion-conducting ceramic materials that demonstrate significant hydrogen ion (proton) conductivity at intermediate temperatures (e.g., 300–700 °C). They are garnering significant attention due to several unique characteristics that distinguish them from both higher temperature oxygen ion conducting oxides and lower temperature proton-conducting polymers. By enabling proton-mediated electrochemistry under both dry and wet environments at moderate temperatures, protonic ceramics provide unique opportunities to enhance or synergize a diverse range of complementary electrochemical and thermochemical processes. Because of this potential, significant efforts have been devoted to advancing numerous energy-related applications using these materials. This review aims to comprehensively summarize these applications and analyze the most up-to-date and future developments of proton-conducting oxides. We aim to bring together this diverse subject matter by integrating the fundamentals of proton-conducting oxides with application-oriented insights. We begin with a historical roadmap, followed by a basic overview of the materials, theories and fundamentals, and fabrication and processing technologies underlying the field. The central section of our review summarizes major applications and developments of proton-conducting ceramics, ranging from maturing applications approaching commercialization to embryonic technologies just now emerging from the lab. These include protonic ceramic fuel cells, protonic ceramic electrolysis cells, reversible protonic ceramic electrochemical cells, protonic ceramic membrane reactors, and protonic ceramic electrochemical reactors. For each application, we analyze both the prospects and challenges and offer recommendations for future research directions so that tomorrow's researchers can continue to advance the development and commercialization of these fascinating materials.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AR0000493; AR0000808; FE0031716

OSTI ID:: 1602576

Journal Information:: Applied Physics Reviews, Journal Name: Applied Physics Reviews Journal Issue: 1 Vol. 7; ISSN 1931-9401

Publisher:: American Institute of PhysicsCopyright Statement

Country of Publication:: United States

Language:: English

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Electrical Properties of p-Type Electronic Defects in the Protonic Conductor SrCe[sub 0.95]Eu[sub 0.05]O[sub 3−δ] Song, S. -J.; Wachsman, E. D.; Dorris, S. E. Journal of The Electrochemical Society, Vol. 150, Issue 6 https://doi.org/10.1149/1.1574031	journal	January 2003
Proton Conduction in Sintered Oxides Based on BaCeO[sub 3] Iwahara, H. Journal of The Electrochemical Society, Vol. 135, Issue 2 https://doi.org/10.1149/1.2095649	journal	January 1988
Electrochemical Methane Coupling Using Protonic Conductors Hamakawa, S. Journal of The Electrochemical Society, Vol. 140, Issue 2 https://doi.org/10.1149/1.2221068	journal	January 1993
Performance of Solid Oxide Fuel Cell Using Proton and Oxide Ion Mixed Conductors Based on BaCe[sub 1−x]Sm[sub x]O[sub 3−α] Iwahara, Hiroyasu Journal of The Electrochemical Society, Vol. 140, Issue 6 https://doi.org/10.1149/1.2221624	journal	January 1993
Fundamentals of Synthesis, Sintering Issues, and Chemical Stability of BaZr _0.1 Ce _0.7 Y _0.1 Yb _0.1 O _3-δ Proton Conducting Electrolyte for SOFCs VahidMohammadi, Armin; Cheng, Zhe Journal of The Electrochemical Society, Vol. 162, Issue 8 https://doi.org/10.1149/2.0021508jes	journal	January 2015
Defect Incorporation and Transport within Dense BaZr _0.8 Y _0.2 O _{3 − δ} (BZY20) Proton-Conducting Membranes Zhu, Huayang; Ricote, Sandrine; Duan, Chuancheng Journal of The Electrochemical Society, Vol. 165, Issue 9 https://doi.org/10.1149/2.0161809jes	journal	January 2018
Composite Oxygen Electrode Based on LSCM for Steam Electrolysis in a Proton Conducting Solid Oxide Electrolyzer Gan, Yun; Zhang, Jun; Li, Yuanxin Journal of The Electrochemical Society, Vol. 159, Issue 11 https://doi.org/10.1149/2.018212jes	journal	January 2012
Steady-State and Dynamic Modeling of Intermediate-Temperature Protonic Ceramic Fuel Cells Albrecht, K. J.; Dubois, A.; Ferguson, K. Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.0651910jes	journal	January 2019
Chemo-Thermo-Mechanical Coupling in Protonic Ceramic Fuel Cells from Fabrication to Operation Dubois, Alexis; Taghikhani, Kasra; Berger, J. R. Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.1071912jes	journal	January 2019
Defect Chemistry and Transport within Dense BaCe _0.7 Zr _0.1 Y _0.1 Yb _0.1 O _{3 − δ} (BCZYYb) Proton-Conducting Membranes Zhu, Huayang; Ricote, Sandrine; Duan, Chuancheng Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1091810jes	journal	January 2018
Lithium-Ion Batteries--The 25th Anniversary of Commercialization Ogumi, Z.; Kostecki, R.; Guyomard, D. Interface magazine, Vol. 25, Issue 3 https://doi.org/10.1149/2.F04163if	journal	January 2016
Defect chemistry and transport properties of Ba _x Ce _0.85 M _0.15 O _3-δ Wu, J.; Li, L. P.; Espinosa, W. T. P. Journal of Materials Research, Vol. 19, Issue 8 https://doi.org/10.1557/JMR.2004.0302	journal	August 2004
Processing of yttrium-doped barium zirconate for high proton conductivity Babilo, Peter; Uda, Tetsuya; Haile, Sossina M. Journal of Materials Research, Vol. 22, Issue 5 https://doi.org/10.1557/jmr.2007.0163	journal	May 2007
The energy-storage frontier: Lithium-ion batteries and beyond Crabtree, George; Kócs, Elizabeth; Trahey, Lynn MRS Bulletin, Vol. 40, Issue 12 https://doi.org/10.1557/mrs.2015.259	journal	November 2015
A Fifteen Year Record of Global Natural Gas Flaring Derived from Satellite Data Elvidge, Christopher; Ziskin, Daniel; Baugh, Kimberly Energies, Vol. 2, Issue 3 https://doi.org/10.3390/en20300595	journal	August 2009
Methods for Global Survey of Natural Gas Flaring from Visible Infrared Imaging Radiometer Suite Data Elvidge, Christopher; Zhizhin, Mikhail; Baugh, Kimberly Energies, Vol. 9, Issue 1 https://doi.org/10.3390/en9010014	journal	December 2015
High-Performance La0.5Ba0.5Co1/3Mn1/3Fe1/3O3−δ-BaZr1−zYzO3−δ Cathode Composites via an Exsolution Mechanism for Protonic Ceramic Fuel Cells Rioja-Monllor, Laura; Ricote, Sandrine; Bernuy-Lopez, Carlos Inorganics, Vol. 6, Issue 3 https://doi.org/10.3390/inorganics6030083	journal	August 2018
Roles of Bulk and Surface Chemistry in the Oxygen Exchange Kinetics and Related Properties of Mixed Conducting Perovskite Oxide Electrodes Perry, Nicola; Ishihara, Tatsumi Materials, Vol. 9, Issue 10 https://doi.org/10.3390/ma9100858	journal	October 2016
Thermodynamic Insights for Electrochemical Hydrogen Compression with Proton-Conducting Membranes Kee, Benjamin L.; Curran, David; Zhu, Huayang Membranes, Vol. 9, Issue 7 https://doi.org/10.3390/membranes9070077	journal	July 2019

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