skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on March 2, 2021

Title: Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale

ORCiD logo [1]; ORCiD logo [2]
  1. Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, Michigan 48824, USA
  2. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA, Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
[Journal Name: Journal of Chemical Physics Journal Volume: 152 Journal Issue: 9]; Journal ID: ISSN 0021-9606
American Institute of Physics
Country of Publication:
United States

Citation Formats

Cheng, Shiwang, and Sokolov, Alexei P. Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale. United States: N. p., 2020. Web. doi:10.1063/1.5143360.
Cheng, Shiwang, & Sokolov, Alexei P. Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale. United States. doi:10.1063/1.5143360.
Cheng, Shiwang, and Sokolov, Alexei P. Sat . "Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale". United States. doi:10.1063/1.5143360.
title = {Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale},
author = {Cheng, Shiwang and Sokolov, Alexei P.},
abstractNote = {},
doi = {10.1063/1.5143360},
journal = {Journal of Chemical Physics},
number = [9],
volume = [152],
place = {United States},
year = {2020},
month = {3}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 2, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Growing length and time scales in glass-forming liquids
journal, February 2009

  • Karmakar, S.; Dasgupta, C.; Sastry, S.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 10
  • DOI: 10.1073/pnas.0811082106

Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites
journal, March 2007

  • Rittigstein, Perla; Priestley, Rodney D.; Broadbelt, Linda J.
  • Nature Materials, Vol. 6, Issue 4
  • DOI: 10.1038/nmat1870

A Direct Quantitative Measure of Surface Mobility in a Glassy Polymer
journal, February 2014

Enhancing the Mechanical Properties of Glassy Nanocomposites by Tuning Polymer Molecular Weight
journal, September 2018

  • Genix, Anne-Caroline; Bocharova, Vera; Kisliuk, Alexander
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 39
  • DOI: 10.1021/acsami.8b13109

Glass transition and molecular dynamics in poly(dimethylsiloxane)/silica nanocomposites
journal, July 2005

Length Scale of Dynamic Heterogeneities at the Glass Transition Determined by Multidimensional Nuclear Magnetic Resonance
journal, September 1998

Measuring the Surface Dynamics of Glassy Polymers
journal, February 2008

Designed Interfaces in Polymer Nanocomposites: A Fundamental Viewpoint
journal, April 2007

  • Schadler, Linda S.; Kumar, Sanat K.; Benicewicz, Brian C.
  • MRS Bulletin, Vol. 32, Issue 4
  • DOI: 10.1557/mrs2007.232

Segmental Dynamics of Polymer Melts with Spherical Nanoparticles
journal, July 2014

  • Gong, Shushan; Chen, Quan; Moll, Joseph F.
  • ACS Macro Letters, Vol. 3, Issue 8
  • DOI: 10.1021/mz500252f

Interfacial Properties of Polymer Nanocomposites: Role of Chain Rigidity and Dynamic Heterogeneity Length Scale
journal, March 2017

Enhanced Glassy State Mechanical Properties of Polymer Nanocomposites via Supramolecular Interactions
journal, July 2015

Stabilizing Liquid Drops in Nonequilibrium Shapes by the Interfacial Jamming of Nanoparticles
journal, October 2013

Length Scale of Dynamic Heterogeneity in Supercooled d -Sorbitol:  Comparison to Model Predictions
journal, January 2003

  • Ediger, M. D.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 2
  • DOI: 10.1021/jp021888b

Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future
journal, November 2013

  • Ediger, M. D.; Forrest, J. A.
  • Macromolecules, Vol. 47, Issue 2
  • DOI: 10.1021/ma4017696

Quantitative relations between cooperative motion, emergent elasticity, and free volume in model glass-forming polymer materials
journal, February 2015

  • Pazmiño Betancourt, Beatriz A.; Hanakata, Paul Z.; Starr, Francis W.
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 10
  • DOI: 10.1073/pnas.1418654112

Revealing spatially heterogeneous relaxation in a model nanocomposite
journal, November 2015

  • Cheng, Shiwang; Mirigian, Stephen; Carrillo, Jan-Michael Y.
  • The Journal of Chemical Physics, Vol. 143, Issue 19
  • DOI: 10.1063/1.4935595

The shapes of cooperatively rearranging regions in glass-forming liquids
journal, March 2006

  • Stevenson, Jacob D.; Schmalian, Jörg; Wolynes, Peter G.
  • Nature Physics, Vol. 2, Issue 4
  • DOI: 10.1038/nphys261

Densification of Alkoxide-Derived Fine Silica Powder Compact by Ultra-High-Pressure Cold Isostatic Pressing
journal, January 1993

On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965

  • Adam, Gerold; Gibbs, Julian H.
  • The Journal of Chemical Physics, Vol. 43, Issue 1
  • DOI: 10.1063/1.1696442

Nonlinear dielectric susceptibilities: Accurate determination of the growing correlation volume in a supercooled liquid
journal, September 2011

Unraveling the Mechanism of Nanoscale Mechanical Reinforcement in Glassy Polymer Nanocomposites
journal, May 2016

Non-monotonic temperature evolution of dynamic correlations in glass-forming liquids
journal, October 2011

  • Kob, Walter; Roldán-Vargas, Sándalo; Berthier, Ludovic
  • Nature Physics, Vol. 8, Issue 2
  • DOI: 10.1038/nphys2133

Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films
journal, June 2010

The distribution of glass-transition temperatures in nanoscopically confined glass formers
journal, September 2003

  • Ellison, Christopher J.; Torkelson, John M.
  • Nature Materials, Vol. 2, Issue 10
  • DOI: 10.1038/nmat980

Interfacial mobility scale determines the scale of collective motion and relaxation rate in polymer films
journal, June 2014

  • Hanakata, Paul Z.; Douglas, Jack F.; Starr, Francis W.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5163

Current issues in research on structure–property relationships in polymer nanocomposites
journal, July 2010

Glassy dynamics and glass transition in nanometric layers and films: A silver lining on the horizon
journal, January 2015

Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time
journal, October 2013

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
  • DOI: 10.1021/jz4018943

Layer-by-Layer Surface Modification of Functional Nanoparticles for Dispersion in Organic Solvents
journal, December 2010

  • Iijima, Motoyuki; Kamiya, Hidehiro
  • Langmuir, Vol. 26, Issue 23
  • DOI: 10.1021/la1030747

Focus: Structure and dynamics of the interfacial layer in polymer nanocomposites with attractive interactions
journal, May 2017

  • Cheng, Shiwang; Carroll, Bobby; Bocharova, Vera
  • The Journal of Chemical Physics, Vol. 146, Issue 20
  • DOI: 10.1063/1.4978504

The relationship of dynamical heterogeneity to the Adam-Gibbs and random first-order transition theories of glass formation
journal, March 2013

  • Starr, Francis W.; Douglas, Jack F.; Sastry, Srikanth
  • The Journal of Chemical Physics, Vol. 138, Issue 12
  • DOI: 10.1063/1.4790138

Analyzing the Interfacial Layer Properties in Polymer Nanocomposites by Broadband Dielectric Spectroscopy
journal, August 2017

Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between
journal, July 2005

Quantitative equivalence between polymer nanocomposites and thin polymer films
journal, August 2005

  • Bansal, Amitabh; Yang, Hoichang; Li, Chunzhao
  • Nature Materials, Vol. 4, Issue 9
  • DOI: 10.1038/nmat1447

Direct Experimental Evidence of a Growing Length Scale Accompanying the Glass Transition
journal, December 2005

When Does a Glass Transition Temperature Not Signify a Glass Transition?
journal, March 2014

  • Forrest, J. A.; Dalnoki-Veress, K.
  • ACS Macro Letters, Vol. 3, Issue 4
  • DOI: 10.1021/mz4006217

Progress towards a phenomenological picture and theoretical understanding of glassy dynamics and vitrification near interfaces and under nanoconfinement
journal, December 2019

  • Schweizer, Kenneth S.; Simmons, David S.
  • The Journal of Chemical Physics, Vol. 151, Issue 24
  • DOI: 10.1063/1.5129405

Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts
journal, March 2015

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • Macromolecules, Vol. 48, Issue 6
  • DOI: 10.1021/ma5022083

On the surface of glasses
journal, December 2008

  • Stevenson, Jacob D.; Wolynes, Peter G.
  • The Journal of Chemical Physics, Vol. 129, Issue 23
  • DOI: 10.1063/1.3041651

Fifth-order susceptibility unveils growth of thermodynamic amorphous order in glass-formers
journal, June 2016

Filler–elastomer interaction in model filled rubbers, a 1H NMR study
journal, September 2002

Theory of the spatial transfer of interface-nucleated changes of dynamical constraints and its consequences in glass-forming films
journal, January 2019

  • Phan, Anh D.; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 150, Issue 4
  • DOI: 10.1063/1.5079250

An Emerging Unified View of Dynamic Interphases in Polymers
journal, December 2015

Numerical determination of the exponents controlling the relationship between time, length, and temperature in glass-forming liquids
journal, January 2009

  • Cammarota, Chiara; Cavagna, Andrea; Gradenigo, Giacomo
  • The Journal of Chemical Physics, Vol. 131, Issue 19
  • DOI: 10.1063/1.3257739

Dynamically Correlated Regions and Configurational Entropy in Supercooled Liquids
journal, August 2008

  • Capaccioli, Simone; Ruocco, Giancarlo; Zamponi, Francesco
  • The Journal of Physical Chemistry B, Vol. 112, Issue 34
  • DOI: 10.1021/jp802097u

Nanoparticle Polymer Composites: Where Two Small Worlds Meet
journal, November 2006

  • Balazs, A. C.; Emrick, T.; Russell, T. P.
  • Science, Vol. 314, Issue 5802, p. 1107-1110
  • DOI: 10.1126/science.1130557