4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique

Ziesche, Ralf F.; Arlt, Tobias; Finegan, Donal; Heenan, Thomas M. M.; Tengattini, Alessandro; Baum, Daniel; Kardjilov, Nikolay; Markotter, Henning; Manke, Ingo; Kockelmann, Winfried; Brett, Dan J. L.; Shearing, Paul R.

doi:10.1038/s41467-019-13943-3

Title: 4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique

Abstract

The temporally and spatially resolved tracking of lithium intercalation and electrode degradation processes are crucial for detecting and understanding performance losses during the operation of lithium-batteries. Here, high-throughput X-ray computed tomography has enabled the identification of mechanical degradation processes in a commercial Li/MnO₂ primary battery and the indirect tracking of lithium diffusion; furthermore, complementary neutron computed tomography has identified the direct lithium diffusion process and the electrode wetting by the electrolyte. Virtual electrode unrolling techniques provide a deeper view inside the electrode layers and are used to detect minor fluctuations which are difficult to observe using conventional three dimensional rendering tools. Moreover, the 'unrolling' provides a platform for correlating multi-modal image data which is expected to find wider application in battery science and engineering to study diverse effects e.g. electrode degradation or lithium diffusion blocking during battery cycling.

Authors:

^[1]; Arlt, Tobias ^[2];

^[3];

^[4]; Tengattini, Alessandro ^[5];

^[6];

^[7]; Markotter, Henning ^[2];

^[7]; Kockelmann, Winfried ^[8]; Brett, Dan J. L. ^[4]; Shearing, Paul R. ^[4]

Univ. College London (United Kingdom); Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab. (RAL)
Technische Univ. Berlin (Germany)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Univ. College London (United Kingdom); The Faraday Inst. (United Kingdom)
University Grenoble Aples, Institut Laue-Langevin
Zuse Inst. Berlin (Germany)
Helmholtz-Zentrum Berlin (HZB), (Germany). German Research Centre for Materials and Energy
Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab. (RAL)

Publication Date:: 2020-02-07

Research Org.:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:: 1602175

Report Number(s):: NREL-JA-5400-75811
Journal ID: ISSN 2041-1723

Grant/Contract Number:: AC36-08GO28308

Resource Type:: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 30 DIRECT ENERGY CONVERSION; lithium ion batteries; neuron imaging; x-ray computed tomography; image processing

Citation Formats


                    Ziesche, Ralf F., Arlt, Tobias, Finegan, Donal, Heenan, Thomas M. M., Tengattini, Alessandro, Baum, Daniel, Kardjilov, Nikolay, Markotter, Henning, Manke, Ingo, Kockelmann, Winfried, Brett, Dan J. L., and Shearing, Paul R. 4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique.  United States: N. p., 2020. 
Web.  doi:10.1038/s41467-019-13943-3.

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                    Ziesche, Ralf F., Arlt, Tobias, Finegan, Donal, Heenan, Thomas M. M., Tengattini, Alessandro, Baum, Daniel, Kardjilov, Nikolay, Markotter, Henning, Manke, Ingo, Kockelmann, Winfried, Brett, Dan J. L., & Shearing, Paul R. 4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique.  United States.  https://doi.org/10.1038/s41467-019-13943-3

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                    Ziesche, Ralf F., Arlt, Tobias, Finegan, Donal, Heenan, Thomas M. M., Tengattini, Alessandro, Baum, Daniel, Kardjilov, Nikolay, Markotter, Henning, Manke, Ingo, Kockelmann, Winfried, Brett, Dan J. L., and Shearing, Paul R. Fri .  
"4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique".  United States.  https://doi.org/10.1038/s41467-019-13943-3.  https://www.osti.gov/servlets/purl/1602175.

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@article{osti_1602175,

  title        = {4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique},

  author       = {Ziesche, Ralf F. and Arlt, Tobias and Finegan, Donal and Heenan, Thomas M. M. and Tengattini, Alessandro and Baum, Daniel and Kardjilov, Nikolay and Markotter, Henning and Manke, Ingo and Kockelmann, Winfried and Brett, Dan J. L. and Shearing, Paul R.},

  abstractNote = {The temporally and spatially resolved tracking of lithium intercalation and electrode degradation processes are crucial for detecting and understanding performance losses during the operation of lithium-batteries. Here, high-throughput X-ray computed tomography has enabled the identification of mechanical degradation processes in a commercial Li/MnO2 primary battery and the indirect tracking of lithium diffusion; furthermore, complementary neutron computed tomography has identified the direct lithium diffusion process and the electrode wetting by the electrolyte. Virtual electrode unrolling techniques provide a deeper view inside the electrode layers and are used to detect minor fluctuations which are difficult to observe using conventional three dimensional rendering tools. Moreover, the 'unrolling' provides a platform for correlating multi-modal image data which is expected to find wider application in battery science and engineering to study diverse effects e.g. electrode degradation or lithium diffusion blocking during battery cycling.},

  doi          = {10.1038/s41467-019-13943-3},

  journal      = {Nature Communications},

  number       = 1,

  volume       = 11,

  place        = {United States},

  year         = {2020},

  month        = {2}

}

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Title: 4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique

Abstract

Citation Formats

Four-Dimensional Studies of Morphology Evolution in Lithium–Sulfur Batteries journal, August 2018

Tracking Internal Temperature and Structural Dynamics during Nail Penetration of Lithium-Ion Cells journal, January 2017

4D nano-tomography of electrochemical energy devices using lab-based X-ray imaging journal, May 2018

Advances in neutron imaging journal, July 2018

Gas Evolution in Operating Lithium-Ion Batteries Studied In Situ by Neutron Imaging journal, October 2015

Gas Evolution in LiNi 0.5 Mn 1.5 O 4 /Graphite Cells Studied In Operando by a Combination of Differential Electrochemical Mass Spectrometry, Neutron Imaging, and Pressure Measurements journal, February 2016

Fast microtomography using high energy synchrotron radiation journal, April 2005

Expansion of Lithium Ion Pouch Cell Batteries: Observations from Neutron Imaging journal, January 2013

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal, October 2015

From damage to discovery via virtual unwrapping: Reading the scroll from En-Gedi journal, September 2016

Lithiation-Induced Dilation Mapping in a Lithium-Ion Battery Electrode by 3D X-Ray Microscopy and Digital Volume Correlation journal, November 2013

Fiji: an open-source platform for biological-image analysis journal, June 2012

Identifying the Cause of Rupture of Li-Ion Batteries during Thermal Runaway journal, October 2017

CONRAD-2: the new neutron imaging instrument at the Helmholtz-Zentrum Berlin journal, February 2016

Three-dimensional characterization of electrodeposited lithium microstructures using synchrotron X-ray phase contrast imaging journal, January 2015

Revealing hidden text in rolled and folded papyri journal, February 2017

In Situ Neutron Imaging Of Alkaline and Lithium Batteries conference, January 2010

Multidimensional operando analysis of macroscopic structure evolution in lithium sulfur cells by X-ray radiography journal, January 2016

In situ neutron radiography of lithium-ion batteries: the gas evolution on graphite electrodes during the charging journal, May 2004

Probing Multiscale Transport and Inhomogeneity in a Lithium-Ion Pouch Cell Using In Situ Neutron Methods journal, October 2016

Characterising thermal runaway within lithium-ion cells by inducing and monitoring internal short circuits journal, January 2017

In-operando high-speed tomography of lithium-ion batteries during thermal runaway journal, April 2015

Neutron Imaging of Lithium Concentration in LFP Pouch Cell Battery journal, January 2011

NIH Image to ImageJ: 25 years of image analysis journal, June 2012

In situ neutron radiography of lithium-ion batteries during charge/discharge cycling journal, October 2001

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes journal, September 2016

Revealing letters in rolled Herculaneum papyri by X-ray phase-contrast imaging journal, January 2015

Industrial applications at the new cold neutron radiography and tomography facility of the HMI journal, April 2005

Characterization of the 3-dimensional microstructure of a graphite negative electrode from a Li-ion battery journal, March 2010

Investigating lithium-ion battery materials during overcharge-induced thermal runaway: an operando and multi-scale X-ray CT study journal, January 2016

Microstructural degradation of silicon electrodes during lithiation observed via operando X-ray tomographic imaging journal, February 2017

Gas Evolution in Operating Lithium-Ion Batteries Studied in Situ by Neutron Imaging text, January 2015

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes text, January 2016

Four-Dimensional Studies of Morphology Evolution in Lithium–Sulfur Batteries
journal, August 2018

Tracking Internal Temperature and Structural Dynamics during Nail Penetration of Lithium-Ion Cells
journal, January 2017

4D nano-tomography of electrochemical energy devices using lab-based X-ray imaging
journal, May 2018

Advances in neutron imaging
journal, July 2018

Gas Evolution in Operating Lithium-Ion Batteries Studied In Situ by Neutron Imaging
journal, October 2015

Gas Evolution in LiNi _0.5 Mn _1.5 O ₄ /Graphite Cells Studied In Operando by a Combination of Differential Electrochemical Mass Spectrometry, Neutron Imaging, and Pressure Measurements
journal, February 2016

Fast microtomography using high energy synchrotron radiation
journal, April 2005

Expansion of Lithium Ion Pouch Cell Batteries: Observations from Neutron Imaging
journal, January 2013

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015

From damage to discovery via virtual unwrapping: Reading the scroll from En-Gedi
journal, September 2016

Lithiation-Induced Dilation Mapping in a Lithium-Ion Battery Electrode by 3D X-Ray Microscopy and Digital Volume Correlation
journal, November 2013

Fiji: an open-source platform for biological-image analysis
journal, June 2012

Identifying the Cause of Rupture of Li-Ion Batteries during Thermal Runaway
journal, October 2017

CONRAD-2: the new neutron imaging instrument at the Helmholtz-Zentrum Berlin
journal, February 2016

Three-dimensional characterization of electrodeposited lithium microstructures using synchrotron X-ray phase contrast imaging
journal, January 2015

Revealing hidden text in rolled and folded papyri
journal, February 2017

In Situ Neutron Imaging Of Alkaline and Lithium Batteries
conference, January 2010

Multidimensional operando analysis of macroscopic structure evolution in lithium sulfur cells by X-ray radiography
journal, January 2016

In situ neutron radiography of lithium-ion batteries: the gas evolution on graphite electrodes during the charging
journal, May 2004

Probing Multiscale Transport and Inhomogeneity in a Lithium-Ion Pouch Cell Using In Situ Neutron Methods
journal, October 2016

Characterising thermal runaway within lithium-ion cells by inducing and monitoring internal short circuits
journal, January 2017

In-operando high-speed tomography of lithium-ion batteries during thermal runaway
journal, April 2015

Neutron Imaging of Lithium Concentration in LFP Pouch Cell Battery
journal, January 2011

NIH Image to ImageJ: 25 years of image analysis
journal, June 2012

In situ neutron radiography of lithium-ion batteries during charge/discharge cycling
journal, October 2001

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes
journal, September 2016

Revealing letters in rolled Herculaneum papyri by X-ray phase-contrast imaging
journal, January 2015

Industrial applications at the new cold neutron radiography and tomography facility of the HMI
journal, April 2005

Characterization of the 3-dimensional microstructure of a graphite negative electrode from a Li-ion battery
journal, March 2010

Investigating lithium-ion battery materials during overcharge-induced thermal runaway: an operando and multi-scale X-ray CT study
journal, January 2016

Microstructural degradation of silicon electrodes during lithiation observed via operando X-ray tomographic imaging
journal, February 2017

Gas Evolution in Operating Lithium-Ion Batteries Studied in Situ by Neutron Imaging
text, January 2015

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes
text, January 2016