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Title: Pyridine-d 5 as a 2 H NMR probe for investigation of macrostructure and pore shapes in a layered Sn( iv ) phosphonate–phosphate material

Abstract

Isotropic and anisotropic motions and molecular states of pyridine-d 5 , adsorbed on the surface within the pores of a layered Sn( iv ) phosphonate–phosphate material ( 1 ) have been characterized thermodynamically and kinetically by solid-state NMR.

Authors:
ORCiD logo [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [2]
  1. Department of Chemistry, Texas A&M University, College Station, USA
  2. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1602078
Grant/Contract Number:  
[NE0000746; SC0017864]
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
[Journal Name: ChemComm Journal Volume: 56 Journal Issue: 25]; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Bakhmutov, Vladimir I., Elliott, Douglas W., Wylie, Gregory P., Clearfield, Abraham, Contreras-Ramirez, Aida, and Zhou, Hong-Cai. Pyridine-d 5 as a 2 H NMR probe for investigation of macrostructure and pore shapes in a layered Sn( iv ) phosphonate–phosphate material. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CC09254D.
Bakhmutov, Vladimir I., Elliott, Douglas W., Wylie, Gregory P., Clearfield, Abraham, Contreras-Ramirez, Aida, & Zhou, Hong-Cai. Pyridine-d 5 as a 2 H NMR probe for investigation of macrostructure and pore shapes in a layered Sn( iv ) phosphonate–phosphate material. United Kingdom. doi:10.1039/C9CC09254D.
Bakhmutov, Vladimir I., Elliott, Douglas W., Wylie, Gregory P., Clearfield, Abraham, Contreras-Ramirez, Aida, and Zhou, Hong-Cai. Thu . "Pyridine-d 5 as a 2 H NMR probe for investigation of macrostructure and pore shapes in a layered Sn( iv ) phosphonate–phosphate material". United Kingdom. doi:10.1039/C9CC09254D.
@article{osti_1602078,
title = {Pyridine-d 5 as a 2 H NMR probe for investigation of macrostructure and pore shapes in a layered Sn( iv ) phosphonate–phosphate material},
author = {Bakhmutov, Vladimir I. and Elliott, Douglas W. and Wylie, Gregory P. and Clearfield, Abraham and Contreras-Ramirez, Aida and Zhou, Hong-Cai},
abstractNote = {Isotropic and anisotropic motions and molecular states of pyridine-d 5 , adsorbed on the surface within the pores of a layered Sn( iv ) phosphonate–phosphate material ( 1 ) have been characterized thermodynamically and kinetically by solid-state NMR.},
doi = {10.1039/C9CC09254D},
journal = {ChemComm},
number = [25],
volume = [56],
place = {United Kingdom},
year = {2020},
month = {3}
}

Journal Article:
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Works referenced in this record:

Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles
journal, January 2015

  • Costantino, Ferdinando; Vivani, Riccardo; Bastianini, Maria
  • Chemical Communications, Vol. 51, Issue 88
  • DOI: 10.1039/C5CC06292F

31 P, 1 H NMR Relaxation and Molecular Mobility in Layered α-Zirconium Phosphate: Variable-Temperature NMR Experiments
journal, December 2016

  • Bakhmutov, Vladimir I.; Clearfield, Abraham
  • The Journal of Physical Chemistry C, Vol. 121, Issue 1
  • DOI: 10.1021/acs.jpcc.6b11247

Zirconium(IV) Phosphonate–Phosphates as Efficient Ion-Exchange Materials
journal, January 2016


Layered metal(IV) phosphonate materials: Solid-state 1 H, 13 C, 31 P NMR spectra and NMR relaxation
journal, January 2018

  • Sheikh, Javeed Ahmad; Bakhmutov, Vladimir I.; Clearfield, Abraham
  • Magnetic Resonance in Chemistry, Vol. 56, Issue 4
  • DOI: 10.1002/mrc.4698

Organically pillared microporous zirconium phosphonates
journal, July 2002

  • Clearfield, Abraham; Wang, Zhike
  • Journal of the Chemical Society, Dalton Transactions, Issue 15
  • DOI: 10.1039/b202371g

Benzene- d 6 and toluene- d 8 as guest molecules in micropores of a layered zirconium phosphonate: 2 H, 13 C{ 1 H}, and 31 P{ 1 H} solid-state NMR, deuterium NMR relaxation, and molecular motions
journal, July 2018

  • Contreras, Aida R.; Bakhmutov, Vladimir I.; Elliott, Douglas W.
  • Magnetic Resonance in Chemistry, Vol. 56, Issue 12
  • DOI: 10.1002/mrc.4779

Guest Molecules in a Layered Microporous Tin(IV) Phosphonate–Phosphate Material: Solid State NMR Studies
journal, November 2018

  • Bakhmutov, Vladimir I.; Elliott, Douglas W.; Contreras, Aida R.
  • The Journal of Physical Chemistry A, Vol. 122, Issue 51
  • DOI: 10.1021/acs.jpca.8b09144

Structural and dynamical properties of guest molecules confined in mesoporous silica materials revealed by NMR
journal, January 2007

  • Buntkowsky, Gerd; Breitzke, Hergen; Adamczyk, Anna
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 35
  • DOI: 10.1039/b707322d

Diffusion of Benzene in the Breathing Metal–Organic Framework MIL-53(Cr): A Joint Experimental–Computational Investigation
journal, April 2015

  • Kolokolov, D. I.; Jobic, H.; Rives, S.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 15
  • DOI: 10.1021/acs.jpcc.5b01465

Direct intercalation of cisplatin into zirconium phosphate nanoplatelets for potential cancer nanotherapy
journal, January 2013

  • Díaz, Agustín; González, Millie L.; Pérez, Riviam J.
  • Nanoscale, Vol. 5, Issue 23
  • DOI: 10.1039/c3nr02206d

Pillared metal(IV) phosphate-phosphonate extraction of actinides
journal, June 2012

  • Burns, J. D.; Clearfield, A.; Borkowski, Marian
  • Radiochimica Acta, Vol. 100, Issue 6
  • DOI: 10.1524/ract.2012.1929

Layered microporous tin( iv ) bisphosphonates
journal, January 2007

  • Gómez-Alcántara, María del Mar; Cabeza, Aurelio; Olivera-Pastor, Pascual
  • Dalton Trans., Issue 23
  • DOI: 10.1039/B618762E

Zirconium phosphate nano-platelets: a novel platform for drug delivery in cancer therapy
journal, January 2012

  • Díaz, Agustín; Saxena, Vipin; González, Julissa
  • Chemical Communications, Vol. 48, Issue 12
  • DOI: 10.1039/c2cc16218k

Zr/Sn(IV) Phosphonates as Radiolytically Stable Ion-Exchange Materials
journal, March 2016


Measurement of the Quadrupole Coupling Constant and Asymmetry Parameter of the Ring Deuterons in Several Deuterated Benzene Derivatives
journal, October 1972

  • Barnes, R. G.; Bloom, J. W.
  • The Journal of Chemical Physics, Vol. 57, Issue 8
  • DOI: 10.1063/1.1678722

2 H Solid‐State NMR Spectroscopy Reveals the Dynamics of a Pyridine Probe Interacting with Coordinatively Unsaturated Metal Sites of MIL‐100(Al) Metal–Organic Frameworks
journal, July 2019

  • Khudozhitkov, Alexander E.; Toktarev, Alexander V.; Arzumanov, Sergei S.
  • Chemistry – A European Journal, Vol. 25, Issue 46
  • DOI: 10.1002/chem.201901956

Phase separation in confined systems
journal, December 1999


Deuterium NMR studies of framework and guest mobility in the metal–organic framework compound MOF-5, Zn4O(O2CC6H4CO2)3
journal, September 2005